TÜRKAK TÜRK AKREDITASYON KURUMU TURKISH ACCREDITATION AGENCY. TÜV Rheinland. Tel: Fax: Deney Raporu Test report
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1 TÜRKAK TÜRK AKREDITASYON KURUMU TURKISH ACCREDITATION AGENCY tarafından akredıte edilmiştır. TÜV Rheinland Uluslararası Standartlar Sertıfıkasyon ve Denetım A.Ş. Saniye Ermutlu Sokak Çolakoğlu Plaza B Blok No: 12 Kozyatağı-ISTANBUL Tel: Fax: emaıl : info@tr.tuv.com web: Deney Raporu report Müşterinin adı/adresi Costumer name/address YAKUT AYAKKABICILIK SARR.DERİC.LTD.ŞTİ / SARIYAKUP MAH SOK. NO: 37/A ADANA Alıcı Adı Buyer name Sipariş/Artikel Numarası Order/Article Ziylan Mağazacılık ve Pazarlama A.Ş / Siyah - Kahve - Açık Kahve - Lacivert - Bordo Numunenin adı ve tarifi Name and identity of test item Numunenin kabul tarihi Date of receipt of test item Açıklamalar Remarks Proje tarihi Project date Raporun Sayfa Sayısı Number of pages of the Report Kapsamı Scope 2016 IY / Garamond / Oxide /Yerli / The results given in this test report belong to the received sample by vendor SOP for Determination of Phthalates & Azo Dyes & O-tin compounds Regulation dated 14/01/2015 duplicate issue Official journal Sonucu Result PASS Türk Akreditasyon kurumu (TÜRKAK) deney raporlarının tanınması konusunda Avrupa Akreditasyon Birliği (EA) ve Uluslar arası Laboratuar Akreditasyon Birliği (ILAC) ile karşılıklı tanınma anlaşmasını imzalamıştır. The Turkish Accreditation Acency (TÜRKAK) is signatory to the multilateral agreements of the European co-operation for the Accreditation (EA) and of the International Laboratory Accreditation (ILAC) for the Mutual recognation of the test reports. Deney ve /veya ölçüm sonuçları, genişletilmiş ölçüm belirsizlikleri (olması halinde) ve deney metodları bu sertifikanın tamamlayıcı kısmı olan takip eden sayfalarda verilmiştir. The test and/or measurement results, the uncertainties (if applicable) with confidence probability and test methods are given on the following, pages which are part of this report. Tarih Date Customer Relations Manager Organic ing Team Leader Tomris Hasançebi Kıvanç Karataş Bu rapor, laboratuvarın yazılı izni olmadan kısmen kopyalanıp çoğaltılamaz. Bu rapor e-imza ile onaylanmıştır. This test report shall not be reproduced other than in full except with the permission of the laboratory. This test report is signed by e- signature. Doc No: MS _en / Page 1 of 10
2 1. Photo 2. List of Materials Material List: Material Material Color Location M001 Plastic Black Shoe A-Outsole;Shoe B-Outsole;Shoe E-Outsole;Shoe F-Outsole;Shoe R- Outsole;Shoe S-Outsole / Page 2 of 10
3 M002 Plastic Dk.Brown Shoe A-Welt;Shoe B-Welt M003 Plastic Milky brown Shoe E-Welt;Shoe F-Welt;Shoe R- Welt;Shoe S-Welt M004 Plastic Black Shoe C-Outsole;Shoe D-Outsole M005 Plastic Black Shoe G-Outsole;Shoe H-Outsole;Shoe I-Outsole;Shoe J-Outsole;Shoe K- Outsole;Shoe L-Outsole M006 Plastic + printing Dk.Brown/Lt.Brown Shoe M-Outsole;Shoe N-Outsole M007 Plastic + printing Brown/Lt.Brown Shoe M-Top piece;shoe N-Top piece;shoe O-Top piece;shoe P-Top piece M008 Plastic Black Shoe M-Welt;Shoe N-Welt;Shoe O- Welt;Shoe P-Welt M009 Plastic + printing Lt.Brown/Brown/Dk.Brown Shoe O-Outsole w/print;shoe P- Outsole w/print M010 Leather Dk.Brown Shoe A-Upper M011 Leather Black Shoe B-Upper M012 Leather Black Shoe A-Tongue applique;shoe B- Quarter applique M013 Leather Dk.Brown Shoe A-Quarter applique;shoe B- Tongue applique M014 Leather Navy Shoe C-Upper M015 Leather Black Shoe D-Upper M016 Leather Bordeaux Shoe C-Counter cap & tongue applique;shoe D-Counter cap & tongue applique;shoe I-Vamp applique & top line;shoe R-Tongue applique& shoe lace M017 Leather Brown Shoe C-Shoe lace;shoe D-Shoe lace;shoe F-Shoe lace & tongue applique;shoe J-Vamp applique & top line M018 Leather Dk.Beige Shoe E-Upper M019 Leather Navy Shoe F-Upper M020 Leather Black Shoe E-Tongue applique & shoe lace M021 Leather Brown Shoe G-Upper;Shoe K-Upper M022 Leather Black Shoe H-Upper;Shoe J-Upper M023 Leather Black Shoe G-Vamp;Shoe K-Quarter M024 Leather Navy Shoe H-Vamp;Shoe L-Quarter M025 Leather Navy Shoe I-Upper;Shoe L-Upper M026 Leather Black Shoe M-Upper suede M027 Leather Navy Shoe N-Upper suede;shoe O-Upper suede / Page 3 of 10
4 M028 Leather Mink Shoe P-Upper suede M029 Leather Black Shoe M-Quarter M030 Leather Navy Shoe N-Quarter M031 Leather Navy Shoe R-Upper suede M032 Leather Bordeaux Shoe S-Upper suede M033 Leather Brown Shoe A-Lining;Shoe G-Lining;Shoe K- Lining M034 Leather Brown Shoe A-Insock;Shoe G-Insock;Shoe K- Insock M035 Leather Black Shoe B-Lining;Shoe H-Lining;Shoe J- Lining M036 Leather Black Shoe B-Insock;Shoe H-Insock;Shoe J- Insock M037 Leather Bordeaux Shoe C-Lining;Shoe D-Lining;Shoe I- Tongue lining;shoe O-Lining;Shoe P- Lining;Shoe R-Lining M038 Leather Bordeaux Shoe C-Insock;Shoe D-Insock;Shoe O- Insock;Shoe P-Insock;Shoe R-Insock M039 Leather Plum Shoe I-Lining M040 Leather Plum Shoe I-Insock M041 Leather Lt.Brown Shoe E-Lining;Shoe M-Quarter lining & insock;shoe N-Quarter lining & insock M042 Leather Lt.Brown Shoe E-Insock;Shoe M-Seat sock;shoe N-Seat sock M043 Leather Navy Shoe F-Lining M044 Leather Navy Shoe L-Lining;Shoe S-Lining M045 Leather Navy Shoe F-Insock;Shoe L-Insock;Shoe S- Insock M046 Leather Brown Shoe K-Lining M047 Leather Brown Shoe K-Insock M048 Leather Brown Shoe A-Counter lining;shoe C-Counter lining;shoe D-Counter lining M049 Leather Lt.Brown Shoe G-Counter lining;shoe K-Counter lining M050 Leather Mink Shoe I-Counter lining;shoe M-Counter lining;shoe N-Counter lining;shoe O- Counter lining;shoe P-Counter lining M051 Leather Black Shoe B-Counter lining;shoe H-Counter lining;shoe J-Counter lining M052 Leather Indigo blue Shoe L-Counter lining / Page 4 of 10
5 M053 Textile Black Shoe A-Elastic band- textile section;shoe B-Elastic band- textile section;shoe C-Elastic band- textile section;shoe D-Elastic band- textile section;shoe E-Elastic band- textile section;shoe F-Elastic band- textile section;shoe I-Elastic band- textile section;shoe J-Elastic band- textile section;shoe R-Elastic band- textile section;shoe S-Elastic band- textile section M054 Textile Brown Shoe K-Shoe lace M055 Textile Navy Shoe L-Shoe lace M056 Textile Bordeaux Shoe O-Shoe lace;shoe P-Shoe lace M057 Textile Navy Shoe O-Top line;shoe P-Top line M058 Plastic Transparent Shoe K-Aglet;Shoe L-Aglet;Shoe O- Aglet;Shoe P-Aglet M059 Textile Brown Shoe A-Front lining;shoe B-Front lining M060 Textile Navy Shoe C-Front lining;shoe D-Front lining M061 Textile Red Shoe I-Seam thread on outsole;shoe J-Seam thread on outsole;shoe K- Seam thread on outsole;shoe L-Seam thread on outsole *Above articles have been described in accordance with the standard DIN EN 19952: Banned azo dyes Method: EN :2012 (Textiles) ISO :2010 (Leather) EN :2012 (Textile, 4-aminoazobenzene confirmation) ISO :2011 (Leather, 4-aminoazobenzene confirmation) result: T001 T002 T003 Material M010 + M011 + M012 M013 + M014 + M015 M016 + M017 + M018 Parameter Method Unit RL Regulatory ISO mg/kg ISO mg/kg ISO mg/kg Result / Page 5 of 10
6 T004 T005 T006 T007 T008 T009 T010 T011 T012 T013 Material M019 + M020 + M021 M022 + M023 + M024 M025 + M026 + M027 M028 + M029 + M030 M031 + M032 + M033 M034 + M035 + M036 M037 + M038 + M039 M040 + M041 + M042 M043 + M044 + M045 M046 + M047 + M048 T014 M049 + M050 T015 M051 + M052 Parameter Method Unit RL Regulatory ISO mg/kg ISO mg/kg ISO mg/kg ISO mg/kg ISO mg/kg ISO mg/kg ISO mg/kg ISO mg/kg ISO mg/kg ISO mg/kg Result ISO ISO mg/kg / Page 6 of 10
7 T016 Material M053 + M054 + M055 T017 M056 + M057 T018 M059 + M060 Parameter Method Unit RL Regulatory Result EN EN EN mg/kg T019 M061 EN M010 + T020 M011 + M012 T021 T022 T023 T024 T025 T026 T027 T028 T029 T030 T031 T032 M013 + M014 + M015 M016 + M017 + M018 M019 + M020 + M021 M022 + M023 + M024 M025 + M026 + M027 M028 + M029 + M030 M031 + M032 + M033 M034 + M035 + M036 M037 + M038 + M039 M040 + M041 + M042 M043 + M044 + M045 M046 + M047 + M048 T033 M051 + M052 T034 M059 + M060 EN :2012 to detect 4- aminoazobenzene / Page 7 of 10
8 Abbreviation: n.d. = not detected (< Reporting Limit) RL = Reporting Limit mg/kg = milligram per kilogram Remark: * The CAS-number (A5) and (A6) are further reduced to CAS-number (A18) and (A19). ** Azo colorants that are able to form 4-aminoazobenzene (A22) CAS-number , generate under the condition of this method (A25) CAS-number and 4-aminoaniline (A26) CASnumber *** Azo colorants that are able to form 4-aminoazobenzene (A22), is confirmed by EN :2012 / ISO :2011. **** Azo colorants are detected & quantified by GC/MS and confirmed by LC/MS. ^ Additional azo colorants were tested according to customer's requirement. ID Azo colorant CAS ID Azo colorant CAS A1 biphenyl-4-ylamine / 4- aminobiphenyl / xenylamine A14 p-cresidine A2 benzidine A15 4,4'-methylene-bis-(2-chloroaniline) / 2,2'-dichloro-4,4'- methylene-dianiline A3 4-chloro-o-toluidine A16 4,4`-oxydianiline A4 2-naphthylamine A17 4,4`-thiodianiline A5* o-aminoazotoluene / 4-amino-2',3- dimethylazobenzene / 4-o-tolylazoo-toluidine A18 o-toluidine / 2-aminotoluene A6* 5-nitro-o-toluidine A19 4-methyl-m- amine A7 4-chloroaniline A20 2,4,5-trimethylaniline A8 4-methoxy-m- amine A21 o-anisidine / 2-methoxyaniline A9 A10 4,4'-methylenedianiline / 4,4'- diaminodiphenylmethane 3,3'-dichlorobenzidine / 3,3'- dichlorobiphenyl-4,4'-ylenediamine A22** 4-aminoazobenzene A23^ 2,4-xylidine A11 3,3`-dimethoxybenzidine A24^ 2,6-xylidine A12 3,3'-dimethylbenzidine / 4,4'-bi-otoluidine A25^ A13 4,4`-methylenedi-o-toluidine A26^ 4-aminoaniline CPSIA Sect 108: Phthalates CPSIA Sect. 108 Phthalates PASS Method: CPSC-CH-C Result: / Page 8 of 10
9 T001 T002 T003 Material M001 + M002 + M004 + M006 M005 + M007 M003 Parameter CAS NO Unit RL Regulatory Result Result Result Dibutyl phthalate % n.d. n.d. n.d. (DBP) Benzylbutyl phthalate % n.d. n.d. n.d. (BBP) Diethylhexyl % n.d. n.d. n.d. phthalate (DEHP) Di-n-octyl phthalate % n.d. n.d. n.d. (DNOP) Diisodecyl phthalate , % n.d. n.d. n.d. (DIDP) Diisononyl phthalate (DINP) Sum of above 6 phthalates , Abbreviation: Abbreviation n.d. = Not Detected (< RL) RL = Reporting Limit % denotes percentage % n.d. n.d. n.d. % n.d. n.d. n.d. T004 T005 Material M008 + M009 M058 Parameter CAS NO Unit RL Regulatory Result Result Dibutyl phthalate % n.d. n.d. (DBP) Benzylbutyl phthalate % n.d. n.d. (BBP) Diethylhexyl % n.d. n.d. phthalate (DEHP) Di-n-octyl phthalate % n.d. n.d. (DNOP) Diisodecyl phthalate , % n.d. n.d. (DIDP) Diisononyl phthalate , % n.d. n.d. (DINP) Sum of above 6 phthalates % n.d. n.d. 3.Organotin Compounds (DOT) Method: Organic solvent extraction, GCMS MS_ tr / Page 9 of 10
10 T001 Material M053 + M059 + M060 Parameter Unit RL Regulatory Result DOT(Dioctyltin) % n.d. Abbreviation: n.d. = not detected (< Reporting Limit) RL = Reporting Limit % = percentage NA = Not Applicable *1 Single components with an amount of <0.01% were not considered in the calculation of the sum. In the case of all five tri-substituted organotins were not detected, the result is stated n.d. *2 The assessment for tri-substituted organotins is based on the sum of TBT, TPT, TOT, TCyT and TPrT only. *3 According to REACH Regulation (EC) 1907/2006 Annex XVII Item 20 and amendment Commission Regulation (EU) 276/2010 (formerly known as 2009/425/EC), organostannic compounds shall not be used or be placed on the market- - END - / Page 10 of 10
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