Material Safety Data Sheet

Transcription

1 Page: 1 of 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER SEPTONE ACETONE Product Name Product Code Company Name Address Emergency Tel. Telephone/Fax Number Recommended Use Other Information ASA500, ASA1, ASA4, ASA20 ITW AAMTech (ABN ) 1-9 NINA LINK DANDENONG SOUTH VIC 3175 AUSTRALIA Tel: Fax: info@aamtech.com.au Cleaning Solvent 2. HAZARDS IDENTIFICATION Hazard Classification Risk Phrase(s) Safety Phrase(s) Website: * info@aamtech.com.au * New Zealand 2/38 Trugood Drive, East Tamaki, Auckland Tel: Flammable Liquids: Category 2 Eye Damage/Irritation: Category 2A STOT Single Exposure Category 3 R11 Highly flammable. R3 Irritating to eyes. R Repeated exposure may cause skin dryness and cracking. R7 Vapours may cause drowsiness and dizziness S1/2 Keep locked up and out of reach of children. S1 Keep away from sources of ignition - No smoking. S2 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S4 If swallowed, seek medical advice immediately and show this container or label. S9 Keep container in a well ventilated place. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Characterization Ingredients Liquid 4. FIRST AID MEASURES Inhalation Ingestion Skin Name CAS Proportion Acetone % Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. If patient finds breathing difficult and develops a bluish discolouration of the skin (which suggests a lack of oxygen in the blood - cyanosis), ensure airways are clear of any obstruction and have a qualified person give oxygen through a face mask. Apply artificial respiration if patient is not breathing. Seek immediate medical advice. Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water. Seek immediate medical assistance. If skin contact occurs, remove contaminated clothing and wash skin with running water. If irritation occurs seek Print Date: 30/0/2015

2 Page: 2 of Eye Advice to Doctor 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media Specific Methods Specific Hazards Hazchem Code medical advice. If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre or a doctor, or for at least 15 minutes. Treat symptomatically. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, fine water spray or water fog can be used. On burning will emit toxic fumes. Keep containers cool with water spray. If safe to do so, remove containers from path of fire. Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion. Highly flammable liquid. May form flammable vapour mixtures with air. Avoid all ignition sources. All potential sources of ignition (open flames, pilot lights, furnaces, spark producing switches and electrical equipment etc) must be eliminated both in and near the work area. Do NOT smoke. Flameproof equipment is necessary in all areas where this chemical is being used. Nearby equipment must be earthed. Vapour may travel a considerable distance to source of ignition and flash back. 2[Y]E. ACCIDENTAL RELEASE MEASURES Emergency Procedures Methods and Materials for Containment and Clean Up Procedures 7. HANDLING AND STORAGE Precautions for Safe Handling Conditions for Safe Storage Storage Regulations Shut off all possible sources of ignition. Clear area of all unprotected personnel. If contamination of sewers or waterways has occurred advise local emergency services. Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contact and breathing in vapours. Work up wind or increase ventilation. Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material). Avoid skin and eye contact and breathing in vapour. Store in a cool, dry, well ventilated place and out of direct sunlight. Store away from sources of heat or ignition. Store away from foodstuffs. Store away from incompatible materials described in Section 10. Keep containers closed when not in use - check regularly for leaks. This product is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards Biological Limit Values Engineering Controls Respiratory Protection Name STEL TWA mg/m3 ppm mg/m3 ppm Footnote Acetone Biological Exposure Index (Acetone): Acetone in urine = 50 mg/l (end of shift) Ensure ventilation is adequate to maintain air concentrations below Workplace Exposure Standards. Vapour heavier than air - prevent concentration in hollows or sumps. DO NOT enter confined spaces where vapour may have collected. Keep containers closed when not in use. Organic vapour/particulate respirator. Print Date: 30/0/2015

3 Page: 3 of Eye Protection Hand Protection Body Protection Other Information Chemical goggles. Impervious gloves. Overalls. The selection of PPE is dependent on a detailed risk assessment arising from the work situation, the physical form of the chemical, the handling methods, and environmental factors. 9. PHYSICAL AND CHEMICAL PROPERTIES Liquid Form Appearance Odour Boiling Point Solubility in Water Specific Gravity Vapour Pressure Vapour Density (Air=1) Evaporation Rate Viscosity Volatile Component Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - Upper Clear Colourless Liquid Sweet 57 C Soluble C 180 mm Hg 2.0 (n-butyl acetate = 1) C 100% v/v -17C(TAG Closed Cup) Highly flammable. Isolate from all sources of heat or ignition, including sparks and naked flames. Do not smoke whilst using this product. Take precautions against static electricity discharges. Earth and bond all equipment. An explosive air-vapour mix may form - ensure adequate ventilation. Vapours are heavier than air. Keep away from strongly oxidising materials. Store containers in a cool, well ventilated place away from sources of heat and ignition. 45 C 2.% v/v in air 12.8% v/v in air 10. STABILITY AND REACTIVITY Stable under normal conditions of use. Considered stable to heat and light. Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization Sources of heat or ignition, including sparks and naked flames. Static electricity discharges. An explosive air-vapour mix may form - ensure adequate ventilation. Vapours are heavier than air. Strong oxidising agents, strong alkalis, bromine, and mineral acids. During combustion, this product may produce carbon monoxide and other unidentifiable organic compounds. Will not occur. 11. TOXICOLOGICAL INFORMATION Inhalation Vapour concentrations above 500 ppm are irritating to the nose and throat. Breathing in vapour can result in headaches, dizziness, drowsiness, and possible nausea. Breathing in high concentrations can produce central nervous system depression, which can lead to loss of co-ordination, impaired judgement and if exposure is prolonged, unconsciousness. Odour threshold Print Date: 30/0/2015

4 Page: 4 of Ingestion Skin Eye Chronic Effects Reproductive Toxicity Mutagenicity Carcinogenicity p.p.m. Swallowing can result in nausea, vomiting and central nervous system depression. If the victim is showing signs of central system depression (like those of drunkeness) there is greater likelihood of the patient breathing in vomit and causing damage to the lungs. Breathing in vomit may lead to aspiration pneumonia (inflammation of the lung). Mildly irritating to the skin. Signs of irritation include redness, itchiness and eventually cracking of the skin. Irritation usually only occurs after prolonged, repeated skin contact and is due to the de-fatting effect on the skin of the product. May lead to the onset of dermatitis. An eye irritant. Signs of irritation include redness, soreness and tear production. Skin irritation may occur after prolonged, repeated skin contact and is due to the de-fatting effect on the skin of the product. May lead to the onset of dermatitis. This product is not regarded as being toxic to the unborn foetus. 12. ECOLOGICAL INFORMATION Short Summary of Assessment of Environmental Impact 13. DISPOSAL CONSIDERATIONS Disposal Considerations 14. TRANSPORT INFORMATION 1090 U.N. Number Proper Shipping Name DG Class Hazchem Code Packaging Method Packing Group EPG Number IERG Number IMDG UN No IMDG Description IMDG Hazard Class IMDG Pack. Group This product is not regarded as a mutagen This product is not regarded as a carcinogen. Acetone released to the atmosphere is degraded by a combination of photolysis and reaction with hydroxyl radicals. The average half-life for acetone degradation in the atmosphere is approximately 30 days. Acetone can be physically removed from air by wet deposition. The dominant degradation process for acetone in soil and water is biodegradation, and acetone is readily biodegradable. Volatilization of acetone from the aquatic environment can be a significant transport process. Acetone is a volatile compound that will evaporate from dry surfaces. Since acetone is miscible in water, it can leach readily in most types of soil. Concurrent biodegradation may diminish the general significance of leaching if biodegradation occurs fast enough. Fish toxicity (rainbow trout, goldfish, bluegill): LC50 (9 hr): mg/l. Refer to Waste Management Authority. Dispose of material through a licensed waste contractor. Advise flammable nature. Normally suitable for incineration by an approved agent. Empty containers remain classified as Dangerous Goods until all traces of product have been removed. ACETONE 3 2[Y]E 3.8.3RT1 II 3A Acetone 3 II Print Date: 30/0/2015

5 Page: 5 of IMDG EMS IMDG Marine Pollutant (MP) F-E, S-D No 15. REGULATORY INFORMATION Regulatory Information HAZARDOUS SUBSTANCE. SCHEDULED POISON. Poisons Schedule National and or International Regulatory Information Hazard Category AICS (Australia) Classified as Hazardous according to criteria of National Occupational Health & Safety Commission, Australia (NOHSC). Classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). S5 NZ HSNO Hazard Classification 3.1B;.1E;.3B;.4A Approval Code: HSR Irritant,Highly Flammable Listed 1. OTHER INFORMATION Contact Person/Point Literature References Australia: 24 HOUR EMERGENCY CONTACT (ACOHS Pty Ltd): Poisons Information Centre (Australia): New Zealand: 24 HOUR EMERGENCY CONTACT (ACOHS Pty Ltd): NZ National Poisons Centre (24 Hour): DISCLAIMER: This Material Safety Data Sheet summarises at the date of issue to the best of our knowledge, the health and safety hazards of the product and how to safely handle and use the product. As ITW AAMTech cannot anticipate or control the conditions under which the product is used, customers are encouraged, prior to usage, to assess and control the risks associated with their use of the product. Data sheets from unauthorised sources may contain information that is no longer current or accurate. This MSDS is valid for 5 years from date of issue. However, this version may be revoked and revised at any time, and users should contact ITW AAMTech to ensure they are in possession of the latest version. Safe Work Australia: Hazardous Substances Information System. Hazard Classification, Risk and Safety Phrases and Exposure Standards information. National Code of Practice for the Preparation of Material Safety Data Sheets, 2nd Edition [NOHSC:2011(2003)] Approved Criteria for Classifying Hazardous Substances, 3rd Edition [NOHSC:1008(2004)] Australian Code for the Transport of Dangerous Goods by Road and Rail. International Maritime Dangerous Goods Code. International Air Transport Association Dangerous Goods Regulations. New Zealand Toxic Substances Regulations International Maritime Dangerous Goods Code. International Air Transport Association Dangerous Goods Regulations. Standard for the Uniform Scheduling of Drugs and Poisons - National Drugs & Poison Schedule Committee. National Code of Practice for the Preparation of Material Safety Data Sheets, 2nd Edition [NOHSC: 2011 (2003)] Approved Criteria for Classifying Hazardous Substances, 3rd Edition {NOHSC: 1008 (2004)] Australian Code for the Transport of Dangerous Goods by Road and Rail. International Maritime Dangerous Goods Code. User Guide to the HSNO Control Regulations ERMA New Zealand User Guide to the HSNO Thresholds and Classifications ERMA New Zealand Globally Harmonised System of Classification and Labelling of Chemicals,ST/SG/AC.10/30, United Nations 2003 Print Date: 30/0/2015

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