SAFETY DATA SHEET. MSc Wash

Transcription

1 MSc Wash Page 1 of 8 SAFETY DATA SHEET MSc Wash The safety data sheet is in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) SECTION 1: Identification of the substance / mixture and of the company / undertaking Date issued Revision date Product identifier Product name MSc Wash Article no Relevant identified uses of the substance or mixture and uses advised against Use of the substance / preparation For laboratory use Details of the supplier of the safety data sheet Company name FOSS A/S Postal address Foss Allé 1 Postcode 3400 City Hillerød Country Danmark Telephone number RegulatorySupport@Foss.dk 1.4. Emergency telephone number Emergency telephone Telephone number: NHS:111 Description: Poison Control Centers may be available in specific States SECTION 2: Hazards identification 2.1. Classification of substance or mixture Classification according to Regulation (EC) No 1272/2008 [CLP / GHS] Skin Corr 1A; H Label elements

2 MSc Wash Page 2 of 8 Hazard pictograms (CLP) Composition on the label Sodium hydroxide 10 < 30 % Signal word Hazard statements Precautionary statements Danger H314 Causes severe skin burns and eye damage. P280 Wear protective gloves / protective clothing / eye protection / face protection. P303+P361+P353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water / shower. P310 Immediately call a POISON CENTER or doctor / physician. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards Other hazards - SECTION 3: Composition / information on ingredients 3.2. Mixtures Substance Identification Classification Contents Sodium hydroxide CAS No.: EC No.: Index No.: Sodium carbonate CAS No.: EC No.: Index No.: Sodium dodecyl sulphate (SDS) CAS No.: EC No.: Skin Corr. 1A;H < 30 % Eye Irrit. 2;H < 30 % Acute tox. 4; H302; Skin Irrit. 2; H315; Eye Dam. 1; H318; Aquatic Chronic 3; H412; Substance comments The full text for all hazard statements is displayed in section % SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion Move injured person into fresh air and keep person calm under observation. If uncomfortable: Seek hospital and bring these instructions. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Drink plenty of water. Do NOT induce vomiting Most important symptoms and effects, both acute and delayed

3 MSc Wash Page 3 of 8 General symptoms and effects See section 11 for more detailed information on health effects and symptoms Indication of any immediate medical attention and special treatment needed Other information SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Improper extinguishing media Water spray, foam, dry powder or carbon dioxide. Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Fire and explosion hazards The product is non-combustible. When heated and in case of fire, corrosive vapours/gases may be formed. Water used for fire extinguishing, which has been in contact with the product, may be corrosive Advice for firefighters Fire fighting procedures Containers close to fire should be removed or cooled with water. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Personal protection measures Evacuate area. Use personal protective equipment as required. Look out! The product is corrosive. Avoid inhalation of aerosols and contact with skin and eyes Environmental precautions Environmental precautionary measures Avoid discharge into water courses or onto the ground. Contact local authorities in case of spillage to drain/aquatic environment Methods and material for containment and cleaning up Containment Sweep up and place into an appropriate container Reference to other sections Other instructions For personal protection, see section 8. For waste disposal, see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Handling Observe good chemical hygiene practices. Do not handle broken packages without protective equipment. Provide easy access to water supply or an emergency shower. Provide good ventilation. Immediately change drenched clothing. Wash hands before breaks and before smoking, eating or drinking Conditions for safe storage, including any incompatibilities Storage Store in tightly closed original container in a dry, cool and well-ventilated place.

4 MSc Wash Page 4 of Specific end use(s) Recommendations Keep out of reach of children. Specific use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure controls / personal protection 8.1. Control parameters Substance Identification Value TWA Year Sodium hydroxide CAS No.: OEL short term value Value: 2 mg/m3 Sodium carbonate CAS No.: Sodium dodecyl sulphate (SDS) 8.2. Exposure controls Safety signs CAS No.: TWA Year: 2011 Eye / face protection Suitable eye protection Wear tight-fitting goggles or face shield. Hand protection Suitable gloves type Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent change is advisable. Skin protection Suitable protective clothing Special work clothing should be used. Respiratory protection Recommended type of equipment Chemical respirator with specific cartridge providing protection against the compound of concern. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Solid. ph Value: > 11, Other information Other physical and chemical properties Comments SECTION 10: Stability and reactivity Reactivity

5 MSc Wash Page 5 of Reactivity Reactivity Chemical stability Stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Possibility of hazardous reactions None known Conditions to avoid Conditions to avoid None known Incompatible materials Materials to avoid Avoid contact with metals. Acids, oxidising Hazardous decomposition products Hazardous decomposition products None under normal conditions. SECTION 11: Toxicological information Information on toxicological effects Other information regarding health hazards Inhalation Skin contact Eye contact Ingestion Inhalation is corrosive to the upper airways. Causes a burning sensation in the nose, mouth and throat, together with sneezing, coughing, breathing difficulties and chest pain. Has a corrosive effect and causes burning pain, reddening, blisters and burns. May cause severe burns, pain, tearing and cramp of the eyelids. Risk of serious damage to eyes and loss of vision. May cause burns to mouth, gullet and stomach. Pains in mouth, throat and stomach. Difficulty in swallowing, indisposition and bloody vomit. Brown spots and burns may appear in and around the mouth. Symptoms of exposure Comments SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability, comments There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. No data recorded.

6 MSc Wash Page 6 of Mobility in soil Mobility No data recorded Results of PBT and vpvb assessment PBT assessment results Not Classified as PBT/vPvB by current EU criteria Other adverse effects Other adverse effects, comments SECTION 13: Disposal considerations Waste treatment methods Specify the appropriate methods of disposal EWC waste code National waste group Waste is classified as hazardous waste. EWC waste code: laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals Classified as hazardous waste: Yes X SECTION 14: Transport information Dangerous goods Yes UN number ADR / RID / ADN 1823 IMDG 1823 ICAO / IATA UN proper shipping name Proper shipping name english ADR / RID / ADN ADR / RID / ADN IMDG ICAO / IATA Transport hazard class(es) ADR / RID / ADN 8 Classificaton code ADR / RID / ADN IMDG 8 ICAO / IATA Packing group C6 ADR / RID / ADN IMDG II II

7 MSc Wash Page 7 of 8 ICAO / IATA II Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Product name Additional information ADR / RID / ADN hazard label 8 IMDG Hazard label 8 ICAO / IATA Hazard label 8 ADR / RID - Other information Tunnel restriction code E Transport category 2 Hazard No. 80 RID other applicable information 80 IMDG / ICAO / IATA Other information EmS F-A, S-B SECTION 15: Regulatory information Safety, health and environmental regulations / legislation specific for the substance or mixture National regulations As a general rule, persons under 18 years of age are not allowed to work with this product. Users must be carefully instructed in the proper work procedure, the dangerous properties of the product and the necessary safety instructions Chemical safety assessment Chemical safety assessment performed No SECTION 16: Other information List of relevant H-phrases (Section 2 and 3) Classification according to Regulation (EC) No 1272/2008 [CLP / GHS] Additional information H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes Serious eye damage. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. Skin Corr 1A; H314 The user must be instructed in the proper work procedure and be familiar with the contents of

8 MSc Wash Page 8 of 8 Key literature references and sources for data Version 3 these instructions. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. 2001/118/EC: Commission Decision of 16 January 2001 amending Decision 2000/532/EC as regards the list of wastes. Directives 67/548/EEC on dangerous substances and 1999/45/EC on dangerous preparations, including amendments. Council directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to chemical agents at work, wtih ammendments. 2001/118/EC: Commission Decision of 16 January 2001 amending Decision 2000/532/EC as regards the list of wastes.