SAFETY DATA SHEET Loctite Corporation

Transcription

1 Loctite Corporation Essentials Maintenance Kit Polyolefin Primer IE EA MSDS_IE This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name 770 Polyolefin Primer Manufacturer/Supplier Loctite UK Address Watchmead, Welwyn Garden City, Herts., AL7IJB. Phone Number Fax Number Emergency Phone Number / / COMPOSITION / INFORMATION ON INGREDIENTS Nature Solvent based activator. Hazardous Components in Product for EC Component Name Concentration R Phrases Classification N-Heptane R11, R38, R65, R67, R50/53 F, Xn, N 3. HAZARD IDENTIFICATION This product is highly flammable. The flash point is -1 C and explosive limits are approximately 1-7%. Irritating to skin. Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES First Aid - Inhalation Remove affected person to fresh air, and if still feeling unwell seek medical attention. First Aid - Skin Wash skin with plenty of soap and water and apply replenishing cream if necessary. First Aid - Eyes Flush eyes with plenty of water for at least 15 minutes. If irritation persists seek medical attention. First Aid - Ingestion Rinse mouth with water then give plenty of water to drink. Do not induce vomiting. Seek medical advice. 5. FIRE FIGHTING MEASURES This product is highly flammable having a flash point of -1 C. Keep unaffected containers cool with water spray. If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Self contained breathing apparatus should be worn when dealing with fire. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Eliminate sources of ignition. Absorb spillage onto inert absorbent material and place in a closed container, which should be partially filled (air space), for disposal. MSDS_IE Page 1 of 24

2 Loctite Corporation Essentials Maintenance Kit Polyolefin Primer IE EA MSDS_IE 7. HANDLING AND STORAGE Handling Avoid sources of ignition - no smoking. Vapours should be extracted to avoid inhalation. Prolonged or repeated skin contact should be avoided. Storage Keep away from sources of ignition. Store away from heat in a cool, well-ventilated area. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits N-Heptane ACGIH: TLV 400ppm 8h TWA. ACGIH: STEL 500ppm 15min TWA. HSA (1999) C.O.P : OEL 400ppm (1600mg/m3) 8h TWA. HSA (1999) C.O.P : OEL 500ppm (2000mg/m3) 15 min exposure limit. In circumstances where there is a potential for prolonged or repeated skin contact, the use of polyvinyl chloride, polyethylene or nitrile rubber gauntlets or equivalent solvent resistant gloves is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid. Colour Almost colourless. Odour Pungent. ph Not determined. Boiling Range/Point ( C) 97 to 99. Flash Point (CC) ( C) -1 Specific Gravity 0.68 at 20 C. Solubility in Water (kg/m³) Immiscible. Solubility in Acetone Miscible Vapour Pressure (mmhg 35 at 20 C) Explosion Limits (%) 1 to STABILITY AND REACTIVITY The product is relatively stable under normal conditions of use. Non reactive to oxidising agents except for peroxides. 11. TOXICOLOGICAL INFORMATION Inhalation Inhalation of vapours may cause headaches or dizziness. Skin Acute dermal LD50 (rabbit) is estimated to be greater than 2000mg/kg. Solvent may remove essential oils from the skin making it susceptible to attack from other chemicals. Irritating to the skin. Eyes May cause mild irritation to the eyes. MSDS_IE Page 2 of 24

3 Loctite Corporation Essentials Maintenance Kit Polyolefin Primer IE EA MSDS_IE 11. TOXICOLOGICAL INFORMATION Ingestion Small amounts of liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or pulmonary oedema. 12. ECOLOGICAL INFORMATION Does not contain substances listed on the Montreal protocol. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. Evaporation and incineration recommended. 14. TRANSPORT INFORMATION UN Number 1206 Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) 15. REGULATORY INFORMATION Contains Labelling Information Harmful Heptanes, Class 3, Flammable liquid, Packaging Grp II Heptanes, Class 3.2, Flammable liquids, Packaging Grp II EmS 3-07 MFAG 310. Heptanes, Class 3, Flammable liquids, Item No. 3 (b) N-Heptane Highly flammable R phrases S phrases Voluntary Labelling 16. OTHER INFORMATION MSDS first issued 10 October 1995 MSDS data revised 11 May 2000 R11 Highly flammable. R65 Harmful: may cause lung damage if swallowed. R38 Irritating to skin. R67 Vapours may cause drowsiness and dizziness. S16 Keep away from sources of ignition - No Smoking. S23 Do not breathe vapour. S28 After contact with skin, wash immediately with plenty of soap and water. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. S51 Use only in well ventilated areas. N/A Prepared by: Dr. Sandra Wade Senior Chemist Health & Regulatory Affairs - Europe Further Information may be obtained from:- Loctite Corporation, MSDS_IE Page 3 of 24

4 Loctite Corporation Essentials Maintenance Kit Polyolefin Primer IE EA MSDS_IE 16. OTHER INFORMATION International Health and Regulatory Affairs, Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: Fax: Formerly Development Product: LID-1213 The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). MSDS_IE Page 4 of 24

5 Loctite Corporation Essentials Maintenance Kit - Prism IE EA MSDS_IE This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name 406 Manufacturer/Supplier Loctite UK Address Watchmead, Welwyn Garden City, Herts., AL7IJB. Phone Number Fax Number Emergency Phone Number / / COMPOSITION / INFORMATION ON INGREDIENTS Nature Cyanoacrylate adhesive. Hazardous Components in Product for EC Component Name Concentration R Phrases Classification Ethyl Cyanoacrylate R36/37/38 Xi 3. HAZARD IDENTIFICATION Irritating to eyes, respiratory system and skin. Bonds skin and eyes in seconds. Highly reactive to water. (See Section 4 on first aid). 4. FIRST AID MEASURES First Aid - Inhalation Remove affected person to fresh air, and if still feeling unwell seek medical attention. First Aid - Skin Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in warm soapy water. Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate enough heat to cause a burn. Burns should be treated normally after the adhesive has been removed from the skin. If lips are accidentally stuck together apply warm water to the lips and encourage maximum wetting and pressure from saliva inside the mouth. Peel or roll lips apart. Do not try to pull the lips apart with direct opposing action. First Aid - Eyes If the eye is bonded closed, release eyelashes with warm water by covering with wet pad. Cyanoacrylate will bond to eye protein causing lachrymatory effect which will help to debond adhesive. Keep eye covered until debonding is complete, usually within 1-3 days. Do not force eye open. Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause any abrasive damage. First Aid - Ingestion Ensure that breathing passages are not obstructed. The product will polymerise immediately in the mouth making it almost impossible to swallow. Saliva will slowly separate the solidified product from the mouth (several hours). 5. FIRE FIGHTING MEASURES Non flammable product (flash point is greater than 80 C (CC)). If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. MSDS_IE Page 5 of 24

6 Loctite Corporation Essentials Maintenance Kit - Prism IE EA MSDS_IE 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Do not use cloths for mopping up. Polymerise with water and scrape off floor. 7. HANDLING AND STORAGE Handling Ventilation (low level) is recommended when using large volumes. Use of dispensing equipment is recommended to minimise the risk of skin or eye contact. Storage For optimum shelf life store in original containers under refrigerated conditions at 2 C to 8 C. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION The TLV for ethyl cyanoacrylate is 0.2ppm(ACGIH, TWA). Polyethylene or polypropylene gloves are recommended when using large volumes. Do not use PVC, rubber, nylon or cotton gloves. Eye protection should be used where there is any risk of splashing. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid. Colour Clear Colourless. Odour Sharp. Characteristic. ph Not applicable. Boiling Range/Point ( C) Boils above 100. Flash Point (CC) ( C) Exceeds 80. Specific Gravity 1.1 at 20 C. Solubility in Water (kg/m³) Immiscible. Solubility in Acetone Not applicable. Vapour Pressure (mmhg Less than 0.5 at 25 C) Explosion Limits (%) Not applicable. 10. STABILITY AND REACTIVITY Polymerisation will occur in the presence of moisture. 11. TOXICOLOGICAL INFORMATION Inhalation Irritating to respiratory system. Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals. In dry atmosphere with < 50% humidity, vapours may irritate the eyes and respiratory system. Skin Irritating to the skin. Bonds skin in seconds. Considered to be of low toxicity: acute dermal LD50 (rabbit)>2000mg/kg. Due to polymerisation at the skin surface allergic reaction is not considered possible. Eyes This product is an irritant to the eyes. Liquid product will bond eyelids. In a dry atmosphere (RH<50%) vapours may cause irritation and lachrymatory effect. MSDS_IE Page 6 of 24

7 Loctite Corporation Essentials Maintenance Kit - Prism IE EA MSDS_IE 11. TOXICOLOGICAL INFORMATION Ingestion Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000mg/kg (rat). It is almost impossible to swallow as it rapidly polymerises in the mouth. 12. ECOLOGICAL INFORMATION Biodegradable product of low ecotoxicity. Does not contain and is not manufactured with any of the substances listed on the Montreal protocol. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. Polymerise by adding slowly to water (10:1). Dispose of as water insoluble non-toxic solid chemical in authorised landfill or incinerate under controlled conditions. 14. TRANSPORT INFORMATION UN Number Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) None Not classified. Not classified. Not classified. 15. REGULATORY INFORMATION Contains Labelling Information Irritant Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. R phrases S phrases Voluntary Labelling 16. OTHER INFORMATION MSDS first issued 7 December 1995 MSDS data revised 9 November 1999 R36/37/38 Irritating to eyes, respiratory system and skin. S23 Do not breathe vapour. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. N/A Prepared by: Dr. Sandra Wade Senior Chemist Health & Regulatory Affairs - Europe Further Information may be obtained from:- Loctite Corporation, International Health and Regulatory Affairs, Tallaght Business Park, MSDS_IE Page 7 of 24

8 Loctite Corporation Essentials Maintenance Kit - Prism IE EA MSDS_IE 16. OTHER INFORMATION Whitestown, Dublin 24, Ireland. Tel: Fax: The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). Supersedes Safety Data Sheet No: dated 17/11/98. MSDS_IE Page 8 of 24

9 Loctite Corporation Essentials Maintenance Kit - Loctite IE EA MSDS_IE This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name Loctite 7063 Cleaner Manufacturer/Supplier Loctite UK Address Watchmead, Welwyn Garden City, Herts., AL7IJB. Phone Number Fax Number Emergency Phone Number / / COMPOSITION / INFORMATION ON INGREDIENTS Nature Solvent based cleaner Hazardous Components in Product for EC Component Name Concentration R Phrases Classification Dimethoxymethane R11 F Ethanol, Denatured R11 F Aliphatic hydrocarbon solvent R11, R38, R51/53, Xn, F, N R65, R67 3. HAZARD IDENTIFICATION This product is highly flammable. Harmful: may cause lung damage if swallowed. Irritating to skin. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES First Aid Inhalation Remove affected person to fresh air, and if still feeling unwell seek medical attention. First Aid - Skin Wash skin with plenty of soap and water and apply replenishing cream if necessary. First Aid - Eyes Flush eyes immediately with plenty of water for at least 15 minutes. Seek medical attention immediately. First Aid - Ingestion Rinse mouth with water then give plenty of water to drink. Do not induce vomiting. Seek medical advice. 5. FIRE FIGHTING MEASURES Self contained breathing apparatus should be worn when dealing with fire. This product is highly flammable having a flash point of -21 C. Keep unaffected containers cool with water spray. If product is involved in fire extinguish with dry powder, foam or carbon dioxide. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Eliminate sources of ignition. Absorb spillage onto inert absorbent material and place in a closed container, which should be partially filled (air space), for disposal. MSDS_IE Page 9 of 24

10 Loctite Corporation Essentials Maintenance Kit - Loctite IE EA MSDS_IE 7. HANDLING AND STORAGE Handling Use in well ventilated area. Avoid sources of ignition - no smoking. Vapours should be extracted to avoid inhalation. Prolonged or repeated skin contact should be avoided. Storage Keep away from sources of ignition. Store away from heat in a cool, well-ventilated area. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits Dimethoxymethane Ethanol, Denatured HSA (1999) C.O.P : OEL 1000ppm (3100mg/m3) 8h TWA. HSA (1999) C.O.P : OEL 1250ppm (3880mg/m3) 15 min exposure limit. ACGIH: TLV 1000ppm 8h TWA. ACGIH: TLV 1000ppm 8h TWA. HSA (1997) C.O.P : OEL 1000ppm (1900mg/m3) 8h TWA. Good industrial hygiene practices should be observed. Use in well ventilated area. Wear suitable protective clothing. Avoid contact with skin and eyes. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid. Colour Clear Colourless. Odour Hydrocarbon. ph Not determined. Boiling Range/Point ( C) 87 to 104. Flash Point (CC) ( C) -21 Specific Gravity Solubility in Water (kg/m³) Immiscible. Solubility in Acetone Miscible Vapour Pressure (mmhg Less than 1.75 Bar at 50 C) Explosion Limits (%) Not determined. 10. STABILITY AND REACTIVITY The product is relatively stable under normal conditions of use. Non reactive to oxidising agents except for peroxides. 11. TOXICOLOGICAL INFORMATION Inhalation Inhalation of vapours may cause headaches or dizziness. Skin Acute dermal LD50 (rabbit) is estimated to be greater than 2000mg/kg. Solvent may remove essential oils from the skin making it susceptible to attack from other chemicals. Eyes May cause mild irritation to the eyes. MSDS_IE Page 10 of 24

11 Loctite Corporation Essentials Maintenance Kit - Loctite IE EA MSDS_IE 11. TOXICOLOGICAL INFORMATION Ingestion Harmful if swallowed. Small amounts of liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or pulmonary oedema. Ingestion of large quantities may cause liver or kidney damage. 12. ECOLOGICAL INFORMATION There should be precautions taken against environmental damage caused by articles containing this product. The product should not go into drains or surface water. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. Evaporation and incineration recommended. 14. TRANSPORT INFORMATION UN Number 1993 Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) 15. REGULATORY INFORMATION Contains Labelling Information Highly flammable Flammable liquid, n.o.s. Class 3, Pkg. Grp. II. Flammable liquid, n.o.s., Class 3.1, Pkg. Grp. II. EmS MFAG 310. Flammable liquid n.o.s., Class 3, Item No.3 (b), label No. 3. Isoparaffinic hydrocarbon Harmful R phrases S phrases Voluntary Labelling 16. OTHER INFORMATION MSDS first issued 17 October 1995 MSDS data revised 12 July 2000 Prepared by: R11 Highly flammable. R65 Harmful: may cause lung damage if swallowed. R38 Irritating to skin. R67 Vapours may cause drowsiness and dizziness. S16 Keep away from sources of ignition - No Smoking. S23 Do not breathe vapour. S28 After contact with skin, wash immediately with plenty of soap and water. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. S51 Use only in well ventilated areas. N/A Caroline Walsh MSc Health & Regulatory Affairs - Europe Further Information may be obtained from:- Loctite Corporation, International Health and Regulatory Affairs, MSDS_IE Page 11 of 24

12 Loctite Corporation Essentials Maintenance Kit - Loctite IE EA MSDS_IE 16. OTHER INFORMATION Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: Fax: The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). Supersedes Safety Data Sheet No: 6 dated 01/02/2000. This safety data sheet was prepared in accordance with Commission Directive 98/98/EC adapting to technical progress for the 25th time Council Directive 67/548/EEC. MSDS_IE Page 12 of 24

13 Loctite Corporation Essentials Maintenance Kit - RETAINER 603 Health & Regulatory Affairs - Europe IE EA MSDS_IE This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name RETAINER 603 Manufacturer/Supplier Loctite UK Address Watchmead, Welwyn Garden City, Herts., AL7IJB. Phone Number Fax Number Emergency Phone Number / / COMPOSITION / INFORMATION ON INGREDIENTS Nature Product based on polyethyleneglycol dimethacrylate. Hazardous Components in Product for EC Component Name Concentration R Phrases Classification 4-T-Butylcyclohexyl Methacrylate R37 Xi Acrylic acid R10, R34 C 1,3 Butylene Glycol Dimethacrylate R36/37/38 Xi Hydroxypropyl Methacrylate R36/38 Xi Surfactant R22, R41 Xn Cumene Hydroperoxide R7, R20/22, R34 C, O 3. HAZARD IDENTIFICATION Irritating to eyes, respiratory system and skin. 4. FIRST AID MEASURES First Aid - Inhalation Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. First Aid - Skin Wash with plenty of soap and water. If irritation persists, seek medical advice. First Aid - Eyes Flush eyes immediately with plenty of water for at least 15 minutes. Seek medical attention immediately. First Aid - Ingestion Give plenty of water to drink. Do not induce vomiting. Obtain medical attention. 5. FIRE FIGHTING MEASURES Non flammable product (flash point is greater than 100 C (CC)). Trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. If product is involved in fire extinguish with dry powder, foam or carbon dioxide. 6. ACCIDENTAL RELEASE MEASURES MSDS_IE Page 13 of 24

14 Loctite Corporation Essentials Maintenance Kit - RETAINER 603 Health & Regulatory Affairs - Europe IE EA MSDS_IE Wear protective clothing and suitable respiratory protection. Contain spillage, and absorb onto an inert absorbent such as sand or multisorb and place in a sealed container for supervised disposal. 7. HANDLING AND STORAGE Handling Use in well ventilated area. Loctite applicators are recommended to minimise skin contact, particularly where workers are handling sharp or threaded parts which might result in microlaceration of sensitive areas of the skin. Avoid contact with skin and eyes. Storage Store in original containers at 8 C-21 C and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Use in well ventilated area. Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour ph Boiling Range/Point ( C) Flash Point (CC) ( C) > 100 Specific Gravity Solubility in Water (kg/m³) Solubility in Acetone Vapour Pressure C) Explosion Limits (%) Liquid. Green. Characteristic. Not determined. Not determined. Immiscible. 10. STABILITY AND REACTIVITY Miscible Less than 3 at 20 C. Not determined. Non reactive to water. Non reactive to oxidising agents except for peroxides. Destabilised by reducing agents. 11. TOXICOLOGICAL INFORMATION Inhalation May cause irritation to respiratory system. Skin Acute dermal LD50 (rabbit) is estimated to be greater than 2000mg/kg. This product is classified as a skin irritant. Eyes This product is an irritant to the eyes. Ingestion This product is considered to be of low toxicity having an acute oral LD50 (rat) >2000mg/kg by analogy to other similar products. MSDS_IE Page 14 of 24

15 Loctite Corporation Essentials Maintenance Kit - RETAINER 603 Health & Regulatory Affairs - Europe IE EA MSDS_IE 12. ECOLOGICAL INFORMATION Does not contain substances listed on the Montreal protocol. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. Standard procedures for water insoluble non-toxic chemicals recommended. 14. TRANSPORT INFORMATION UN Number Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) None Not classified. Not classified. Not classified. 15. REGULATORY INFORMATION Contains Labelling Information Acrylic acid. Irritant R phrases S phrases Voluntary Labelling R36/37/38 Irritating to eyes, respiratory system and skin. S51 Use only in well ventilated areas. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of soap and water. N/A 16. OTHER INFORMATION MSDS first issued 12 February 1996 MSDS data revised 4 November 1998 MSDS_IE Page 15 of 24

16 Loctite Corporation Essentials Maintenance Kit - RETAINER 603 Health & Regulatory Affairs - Europe IE EA MSDS_IE Prepared by: Caroline Walsh MSc Health & Regulatory Affairs - Europe Further Information may be obtained from:- Loctite Corporation, Health and Regulatory Affairs - Europe, Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: Fax: The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). Supersedes Safety Data Sheet No: 2 dated 06/11/97. MSDS_IE Page 16 of 24

17 Loctite Corporation Essentials Maintenance Kit - Loctite Prism IE EA MSDS_IE This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name Loctite Prism 454 Manufacturer/Supplier Loctite UK Address Watchmead, Welwyn Garden City, Herts., AL7IJB. Phone Number Fax Number Emergency Phone Number / / COMPOSITION / INFORMATION ON INGREDIENTS Nature Cyanoacrylate adhesive. Hazardous Components in Product for EC Component Name Concentration R Phrases Classification Ethyl cyanoacrylate R36/37/38 Xi 3. HAZARD IDENTIFICATION Irritating to eyes, respiratory system and skin. Bonds skin and eyes in seconds. Highly reactive to water. (See Section 4 on first aid). 4. FIRST AID MEASURES First Aid - Inhalation Remove affected person to fresh air, and if still feeling unwell seek medical attention. First Aid - Skin Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in warm soapy water. Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate enough heat to cause a burn. Burns should be treated normally after the adhesive has been removed from the skin. If lips are accidentally stuck together apply warm water to the lips and encourage maximum wetting and pressure from saliva inside the mouth. Peel or roll lips apart. Do not try to pull the lips apart with direct opposing action. First Aid - Eyes If the eye is bonded closed, release eyelashes with warm water by covering with wet pad. Cyanoacrylate will bond to eye protein causing lachrymatory effect which will help to debond adhesive. Keep eye covered until debonding is complete, usually within 1-3 days. Do not force eye open. Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause any abrasive damage. First Aid - Ingestion Ensure that breathing passages are not obstructed. The product will polymerise immediately in the mouth making it almost impossible to swallow. Saliva will slowly separate the solidified product from the mouth (several hours). 5. FIRE FIGHTING MEASURES Non flammable product (flash point is greater than 80 C (CC)). If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. MSDS_IE Page 17 of 24

18 Loctite Corporation Essentials Maintenance Kit - Loctite Prism IE EA MSDS_IE 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Do not use cloths for mopping up. Polymerise with water and scrape off floor. 7. HANDLING AND STORAGE Handling Ventilation (low level) is recommended when using large volumes. Use of dispensing equipment is recommended to minimise the risk of skin or eye contact. Storage For optimum shelf life store in original containers under refrigerated conditions at 2 C to 8 C. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits Ethyl cyanoacrylate ACGIH: TLV 0ppm 8h TWA. HSA (1999) C.O.P : OEL 2ppm (8mg/m3) 8h TWA. HSA (1999) C.O.P : OEL 4ppm (16mg/m3) 15 min exposure limit. Polyethylene or polypropylene gloves are recommended when using large volumes. Do not use PVC, rubber, nylon or cotton gloves. Eye protection should be used where there is any risk of splashing. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid. Colour Clear Colourless. Odour Sharp. Characteristic. ph Not applicable. Boiling Range/Point ( C) Boils above 100. Flash Point (CC) ( C) Exceeds 80. Specific Gravity 1.1 at 20 C. Solubility in Water (kg/m³) Immiscible. Solubility in Acetone Not applicable. Vapour Pressure (mmhg Less than 0.5 at 25 C) Explosion Limits (%) Not applicable. 10. STABILITY AND REACTIVITY Polymerisation will occur in the presence of moisture. 11. TOXICOLOGICAL INFORMATION Inhalation Irritating to respiratory system. In dry atmosphere with < 50% humidity, vapours may irritate the eyes and respiratory system. Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals. Skin Irritating to the skin. Bonds skin in seconds. Considered to be of low toxicity: acute dermal LD50 (rabbit)>2000mg/kg. Due to polymerisation at the skin surface allergic reaction is not considered possible. MSDS_IE Page 18 of 24

19 Loctite Corporation Essentials Maintenance Kit - Loctite Prism IE EA MSDS_IE 11. TOXICOLOGICAL INFORMATION Eyes This product is an irritant to the eyes. Liquid product will bond eyelids. In a dry atmosphere (RH<50%) vapours may cause irritation and lachrymatory effect. Ingestion Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000mg/kg (rat). It is almost impossible to swallow as it rapidly polymerises in the mouth. 12. ECOLOGICAL INFORMATION Biodegradable product of low ecotoxicity. Does not contain and is not manufactured with any of the substances listed on the Montreal protocol. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. Polymerise by adding slowly to water (10:1). Dispose of as water insoluble non-toxic solid chemical in authorised landfill or incinerate under controlled conditions. 14. TRANSPORT INFORMATION UN Number Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) None Not classified. Not classified. Not classified. 15. REGULATORY INFORMATION Contains Labelling Information Irritant Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. R phrases R36/37/38 Irritating to eyes, respiratory system and skin. S phrases S23 Do not breathe vapour. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Voluntary Labelling OTHER INFORMATION MSDS first issued 15 December 1995 MSDS data revised 5 November 1999 Prepared by: Caitriona Keane Health & Regulatory Affairs - Europe Further Information may be obtained from:- Loctite Corporation, Health and Regulatory Affairs - Europe, MSDS_IE Page 19 of 24

20 Loctite Corporation Essentials Maintenance Kit - Loctite Prism IE EA MSDS_IE 16. OTHER INFORMATION Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: Fax: The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). MSDS_IE Page 20 of 24

21 Loctite Corporation Essentials Maintenance Kit Loctite IE EA MSDS_IE 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name 3463 Manufacturer/Supplier Address (Fixmaster Metal Magic Steel Stick) Loctite UK Watchmead, Welwyn Garden City, Herts., AL7IJB. Phone Number Fax Number Emergency Phone Number / / COMPOSITION / INFORMATION ON INGREDIENTS Epoxy resin. Nature Hazardous Components in Product for EC Component Name Concentration R Phrases Classification Bisphenol A -epichlorhydrin R36/38, R43, Xi R51/53 Microcrystalline silica ,4,6-tri(Dimethylaminomethyl)phenol R22, R36/38 Xn 3. HAZARD IDENTIFICATION Irritating to eyes and skin. May cause sensitisation by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES First Aid - Inhalation Remove affected person to fresh air, and if still feeling unwell seek medical attention. First Aid - Skin Wash skin with plenty of soap and water. Seek medical advice if irritation develops. First Aid - Eyes Flush eyes with plenty of water for at least 15 minutes. If irritation persists seek medical attention. First Aid - Ingestion Rinse mouth with water then give plenty of water to drink. Do not induce vomiting. Obtain medical attention. 5. FIRE FIGHTING MEASURES Non flammable product (flash point is greater than 100 C (CC)). If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Self contained breathing apparatus should be worn when dealing with fire. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. For large spills absorb onto inert absorbent material and place in sealed container for disposal. For small spills wipe up with paper towel and place in container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. Try to prevent the material from entering drains or water courses. MSDS_IE Page 21 of 24

22 Loctite Corporation Essentials Maintenance Kit Loctite IE EA MSDS_IE 7. HANDLING AND STORAGE Handling Good industrial hygiene practices should be observed. Use in a well ventilated area. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Avoid contact with eyes. Storage Store away from heat in a cool, well-ventilated area. For optimum shelf life store in original containers under refrigerated conditions at 2 C to 8 C. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits Microcrystalline silica UK EH40: OES 0.3mg/m3 8h TWA. Good industrial hygiene practices should be observed. Use in well ventilated area. Avoid contact with skin and eyes. In circumstances where there is a potential for prolonged or repeated skin contact, the use of polyvinyl chloride or nitrile rubber gauntlets or equivalent solvent resistant gloves is recommended. Safety glasses should be worn. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour ph Boiling Range/Point ( C) Flash Point (CC) ( C) Specific Gravity Solubility in Water (kg/m³) Solubility in Acetone Vapour Pressure C) Explosion Limits (%) Paste. Grey. Mild. Not applicable. 390 C. 284 C g/cm3. Negligible Not determined. Not determined. Not applicable. 10. STABILITY AND REACTIVITY The product is relatively stable under normal conditions of use. Exothermic polymerisation at room temperature may occur with amines, mercaptanes and Lewis acids. 11. TOXICOLOGICAL INFORMATION Inhalation Due to the low volatility of the product there are no hazards associated with inhalation under normal conditions of use. Skin It is irritating and sensitising to the skin. Eyes This product is an irritant to the eyes. Ingestion Ingestion of large quantities may cause liver or kidney damage. MSDS_IE Page 22 of 24

23 Loctite Corporation Essentials Maintenance Kit Loctite IE EA MSDS_IE 12. ECOLOGICAL INFORMATION Keep away from drains and open waters. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. When cured, the product is non-hazardous, and may be placed in industrial or municipal landfill. 14. TRANSPORT INFORMATION UN Number Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) None Not classified. Not classified. Not classified. 15. REGULATORY INFORMATION Contains Labelling Information Irritant Contains epoxy constituents. See information supplied by the manufacturer. R phrases S phrases Voluntary Labelling 16. OTHER INFORMATION MSDS first issued 5 January 1999 MSDS data revised 21 May 2002 R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause longterm adverse effects in the aquatic environment. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of soap and water. S37 Wear suitable gloves. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Prepared by: Vanessa Doherty HRA Specialist Health & Regulatory Affairs - Europe Further Information may be obtained from:- Loctite Corporation, Health and Regulatory Affairs - Europe, Tallaght Business Park, Whitestown, Dublin 24, MSDS_IE Page 23 of 24

24 Loctite Corporation Essentials Maintenance Kit Loctite IE EA MSDS_IE 16. OTHER INFORMATION Ireland. Tel: Fax: The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). This safety data sheet was prepared in accordance with Commission Directive 98/98/EC adapting to technical progress for the 25th time Council Directive 67/548/EEC. and Commission Directive 1999/45/EC. MSDS_IE Page 24 of 24