MALLINCKRODT SCIENCE PRODUCTS DIV -- COLLODION, FLEXIBL...- SALICYLIC ACID AND LACTIC ACID IN FLEXIBLE COLLODION

Transcription

1 MALLINCKRODT SCIENCE PRODUCTS DIV -- COLLODION, FLEXIBLE, U.S.P. - SALICYLIC ACID AND LACTIC ACID IN FLEXIBLE COLLODION MATERIAL SAFETY DATA SHEET NSN: Manufacturer's CAGE: Part No. Indicator: A Part Number/Trade Name: COLLODION, FLEXIBLE, U.S.P. General Information Item Name: SALICYLIC ACID AND LACTIC ACID IN FLEXIBLE COLLODION Company's Name: MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION Company's Street: PARIS BYPASS Company's P. O. Box: M Company's City: PARIS Company's State: KY Company's Country: US Company's Zip Code: Company's Emerg Ph #: / Company's Info Ph #: (PRESS 3)/ Record No. For Safety Entry: 006 Tot Safety Entries This Stk#: 008 Status: SM Date MSDS Prepared: 13NOV92 Safety Data Review Date: 26APR94 Supply Item Manager: KX MSDS Serial Number: BTGGL Hazard Characteristic Code: F2 Unit Of Issue: PG Unit Of Issue Container Qty: 12 Type Of Container: PACKAGE Ingredients/Identity Information Ingredient: ETHYL ETHER (SARA III) Ingredient Sequence Number: 01 Percent: 67 NIOSH (RTECS) Number: KI CAS Number: OSHA PEL: 400 PPM/500 STEL ACGIH TLV: 400PPM/500STEL; 9192 Other Recommended Limit: NONE SPECIFI Ingredient: ETHYL ALCOHOL (ETHANOL) Ingredient Sequence Number: 02 Percent: 22 NIOSH (RTECS) Number: KQ CAS Number: OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM; (1 of 5) [9/12/ :14:44 AM]

2 Other Recommended Limit: NONE SPECIFI Ingredient: CAMPHOR, SYNTHETIC Ingredient Sequence Number: 03 Percent: <1 NIOSH (RTECS) Number: EX CAS Number: OSHA PEL: 2 MG/M3 ACGIH TLV: 2 PPM/3 STEL; 9394 Ingredient: CASTOR OIL Ingredient Sequence Number: 04 Percent: <1 NIOSH (RTECS) Number: CA CAS Number: OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED Ingredient: PYROXYLIN, COLLODION (CELLULOSE NITRATE) Ingredient Sequence Number: 05 Percent: 4 NIOSH (RTECS) Number: QW CAS Number: OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED Physical/Chemical Characteristics Appearance And Odor: COLORLESS OR SLIGHTLY YELLOW SYRUPY LIQUID, ETHER- CAMPHOR ODOR. Boiling Point: 95.0F,35.0C Specific Gravity: 0.78 Solubility In Water: SLIGHT Percent Volatiles By Volume: 93.6 Fire and Explosion Hazard Data Flash Point: 0F,-18C Flash Point Method: TCC Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER FOG, FOAM. Special Fire Fighting Proc: USE WATER SPRAY TO COOL FIRE EXPOSED SURFACES AND TO PROTECT PERSONNEL.USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT. (FP N). Unusual Fire And Expl Hazrds: ABOVE F PT EXPLOSIVE VAPOR-AIR MIXTURE MAY BE FORMED. CLOSED CONTAINERS MAY EXPLODEIN HEAT OF FIRE. (2 of 5) [9/12/ :14:44 AM]

3 Reactivity Data Stability: YES Cond To Avoid (Stability): HEAT AND LIGHT. DO NOT ALLOW TO EVAPORATE TO DRYNESS. Materials To Avoid: ACETYL PEROXIDE, LIQUID AIR, BROMOAZIDE, CHLORINE, STRONG OXIDIZING AGENTS, Hazardous Decomp Products: OXIDES OF NITORGEN AND OXYGEN. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NONE Health Hazard Data LD50-LC50 Mixture: ORAL, RAT LD50 FOR ETHER= 1215 MG/KG Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES IRRITATION TO THE RESPIRATORY TRACT, CONTINUED INHALATION MAY LEAD TO RESPIRATORY FAILURE AND DEATH. INGESTION:HARMFUL, INTESTINAL IRRITATION, CNS DEPRESSION. CHRONIC-DERMATITS, LIVER DAMAGE. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Signs/Symptoms Of Overexp: IRRITATION, DIZZINESS, DROWSINESS, HEADACHE, UNCONSCIOUSNESS, RESPIRATORY FAILURE, DEATH. Med Cond Aggravated By Exp: SKIN AND EYE DISODERS, IMPAIRED LIVER, KIDNEY OR RESPIRATORY DISORDERS. Emergency/First Aid Proc: INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/ OXYGEN IF NEEDED. EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL HELP. SKIN CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS PERSIST. INGESTION:INDUCE VOMITING IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER. GET MEDICAL HELP IMMEDIATELY. Precautions for Safe Handling and Use Steps If Matl Released/Spill: SMALL SPILL: WIPE UP WITH RAGS OR TOWELS. LARGE SPILLS: EVACUATE AREA. WEAR NIOSH APPROVED RESPIRATOR. VENTILATE AREA. DIKE TO RETAIN FLUID. PUMP UP FREE LIQUID. RESIDUE WILL EVAPORATE QUICKLY. DO NOT FLUSH TO SEWER OR WATERWAY. Neutralizing Agent: NONE Waste Disposal Method: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Precautions-Handling/Storing: STORE IN A COOL, WELL VENTILATED AREA, AWAY FROM OPEN FLAMES AND SOURCES OF IGNITION. CONTAINERS SHOULD BE BONDED/ GROUNDED FOR TRANSFERS. Other Precautions: EMPTY CONTAINERS RETAIN RESIDUE. DO NOT PRESSURIZE, CUT, WELD OR EXPOSE TO HEAT, FLAME, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY. Control Measures Respiratory Protection: USE NIOSH APPROVED SELF-CONTAINED BREATHING (3 of 5) [9/12/ :14:44 AM]

4 APPARATUS IF TLV IS EXCEEDED OR WHEN SPRAYING OR USING IN CONFINED SPACES. Ventilation: LOCAL OR GENERAL TO KEEP EXPOSURES BELOW TLV. Protective Gloves: PVC Eye Protection: SAFETY GLASSES Other Protective Equipment: APRON, BOOTS. Work Hygienic Practices: DO NOT EAT, DRINK OR SMOKE WHILE WORKING WITH THIS PRODUCT. Suppl. Safety & Health Data: THIS MSDS IS FOR COLLODION FLEXIBLE SOLN. Transportation Data Trans Data Review Date: DOT PSN Code: GJF DOT Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. DOT Class: 3 DOT ID Number: UN1993 DOT Pack Group: I DOT Label: FLAMMABLE LIQUID IMO PSN Code: HIM IMO Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. o IMO Regulations Page Number: 3126 IMO UN Number: 1993 IMO UN Class: 3.1 IMO Subsidiary Risk Label: - IATA PSN Code: MBQ IATA UN ID Number: 1993 IATA Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. * IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID AFI PSN Code: MBQ AFI Prop. Shipping Name: FLAMMABLE LIQUIDS, N.O.S. AFI Class: 3 AFI ID Number: UN1993 AFI Pack Group: I AFI Basic Pac Ref: 7-6 N.O.S. Shipping Name: ETHER, PYROXYLIN. Additional Trans Data: THIS IS NOT A KIT. PART A IS FOR COLLODION SOLUTION ONLY. Disposal Data Label Data Label Required: YES Technical Review Date: 26APR94 Label Status: F Common Name: COLLODION, FLEXIBLE U.S.P. Signal Word: DANGER! Acute Health Hazard-Moderate: X Contact Hazard-Moderate: X Fire Hazard-Severe: X (4 of 5) [9/12/ :14:44 AM]

5 Reactivity Hazard-None: X Special Hazard Precautions: DANGER! FLAMMABLE LIQUID. ACUTE-HARMFUL IF SWALLOWED OR INHALATED. AFFECTS CENTRAL NERVOUS SYSTEM. EYE AND SKIN IRRITANT. CHRONIC-DERMATITS, LIVER DAMAGE. TARGET ORGANS- CNS, LIVER. STORE IN A COOL, WELL VENTILATED AREA, AWAY FROM OPEN FLAMES AND SOURCES OF FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL HELP. SKIN CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS PERSIST. INGESTION:INDUCE VOMITING IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER. GET MEDICAL HELP IMMEDIATELY. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION Label Street: PARIS BYPASS Label P.O. Box: M Label City: PARIS Label State: KY Label Zip Code: Label Country: US Label Emergency Number: / (5 of 5) [9/12/ :14:44 AM]