SAFETY DATA SHEET KITCHEN DEGREASER SACHETS

Transcription

1 Revision Date Revision 1 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. BB Relevant identified uses of the substance or mixture and uses advised against Identified uses Detergent. Cleaning agent Details of the supplier of the safety data sheet Supplier Jangro Ltd Jangro House Worsley Road Farnworth BL4 9LU Tel: Fax: enquiries@jangrohq.net 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Xi;R38, R41. Human health The product is irritating to eyes and skin. Prolonged skin contact may cause redness, irritation and dry skin. Dust may irritate throat and respiratory system and cause coughing Label elements Labelling Irritant Risk Phrases Safety Phrases 2.3. Other hazards R38 R41 Irritating to skin. Risk of serious damage to eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/39 Wear suitable protective clothing and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1 / 7

2 SODIUM CARBONATE 30-60% CAS-No.: EC No.: Registration Number: xxxx Eye Irrit. 2 - H319 Xi;R36 DISODIUM METASILICATE 1-5% CAS-No.: EC No.: Registration Number: xxxx Met. Corr. 1 - H290 Skin Corr. 1B - H314 STOT SE 3 - H335 C;R34 Xi;R37 1-HYDROXYETHLIDENE-1,1-DIPHOSPHONATE 1-5% CAS-No.: EC No.: Not classified. Xi;R41. ALCOHOL ETHOXYLATE 1-5% CAS-No.: EC No.: Acute Tox. 4 - H302 Eye Dam. 1 - H318 Xn;R22. Xi;R41. SODIUM LAURYL SULPHATE 1-5% CAS-No.: EC No.: Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Xi;R38,R41. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information If medical attention is required present a copy of this datasheet to the physician. Inhalation Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion DO NOT INDUCE VOMITING! Rinse mouth thoroughly. Do not give victim anything to drink if he is unconscious. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Give milk instead of water if readily available. Skin contact Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above. Get medical attention promptly if symptoms occur after washing. 2 / 7

3 Eye contact Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed Inhalation. No specific symptoms noted. Ingestion May cause discomfort if swallowed. Skin contact Skin irritation. Prolonged skin contact may cause redness and irritation. Eye contact Irritation and redness followed by blurred vision Indication of any immediate medical attention and special treatment needed No specific first aid measures noted. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media The product is non-combustible. Use fire-extinguishing media appropriate for surrounding materials Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. During fire, toxic gases (CO, CO2) are formed. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures Use water to keep fire exposed containers cool and disperse vapours. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Use protective gloves, goggles and suitable protective clothing. Avoid inhalation of dust Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up GENERAL. Inform Authorities if large amounts are involved. Wash thoroughly after dealing with a spillage. Shovel into dry containers. Cover and move the containers. Flush the area with water Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations. Avoid spilling, skin and eye contact. Avoid handling which leads to dust formation Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Storage Class Chemical storage Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 3 / 7

4 Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective equipment Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment No specific recommendation made, but protection against nuisance dust must be used when the general level exceeds 10 mg/m3. Hand protection Protective gloves should be used if there is a risk of direct contact or splash. Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection Provide eyewash station. Wear appropriate clothing to prevent reasonably probable skin contact. Wear dust masks in dusty areas. Hygiene measures Wash hands at the end of each work shift and before eating, smoking and using the toilet. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility 9.2. Other information Powder, dust Yellow. No characteristic odour. Soluble in water. SECTION 10: STABILITY AND REACTIVITY Reactivity No specific reactivity hazards associated with this product Chemical stability No particular stability concerns Possibility of hazardous reactions Conditions to avoid Avoid contact with oxidisers or reducing agents Incompatible materials Materials To Avoid Strong acids Hazardous decomposition products None under normal conditions. During fire, toxic gases (CO, CO2) are formed. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Toxicological information No information available. Inhalation Dust may irritate respiratory system or lungs. 4 / 7

5 Ingestion May cause discomfort if swallowed. May cause stomach pain or vomiting. Skin contact Irritating to skin. Prolonged or repeated exposure may cause severe irritation. Eye contact Irritating to eyes. Particles in the eyes may cause irritation and smarting. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Not regarded as dangerous for the environment Toxicity Acute Fish Toxicity Not considered toxic to fish Persistence and degradability Degradability The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: The product is soluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods No specific disposal method required. Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General Road Transport Notes Sea Transport Notes The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID). Not Classified Not classified UN number UN proper shipping name Transport hazard class(es) Transport Labels No transport warning sign required Packing group Environmental hazards 5 / 7

6 14.6. Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments Control of Substances Hazardous to Health. The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. National Regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health Regulations 2002 (as amended) The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 ("CDG 2009"), SI 2009 No 1348 The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Abbreviations and acronyms used in the safety data sheet RID: Regulation Concerning the International Transport of Dangerous Goods by Rail. ADR: European Agreement concerning the International Carriage of dangerous Goods by Road. IMDG: International Maritime Code for Dangerous Goods. GHS: Globally Harmonized System of Classification and Labelling of Chemicals. EINECS: European Inventory of Existing Commercial Chemical Substances. CAS: Chemical Abstract Service. DNEL: Derived No-Effect Level. PNEC: Predicted No-Effect Concentration. LD50: Lethal dose, 50 percent. LC50: Lethal concentration, 50 persent. WEL: Workplace Exposure Limit. STEL: Short Term Exposure Limit. TWA: Time Weighted Average. PBT: Persistent Bioaccumulative Toxic. vpvb: Very Persistent and Very Bioaccumulative. Revision Comments The information contained herein is based on known available data believed to be reliable but does not constitute the users own assessment of the work place risk as required by other Health and Safety Legislation. Revision Date Revision 1 Safety Data Sheet Status Approved. Date Risk Phrases In Full R34 R22 R36 R37 R38 R41 Causes burns. Harmful if swallowed. Irritating to eyes. Irritating to respiratory system. Irritating to skin. Risk of serious damage to eyes. 6 / 7

7 Hazard Statements In Full H318 H319 H314 H315 H302 H290 H335 Causes serious eye damage. Causes serious eye irritation. Causes severe skin burns and eye damage. Causes skin irritation. Harmful if swallowed. May be corrosive to metals. May cause respiratory irritation. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 7 / 7