Dentsply Calibra Esthetic Resin Cement - Catalyst Paste
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1 Page 1 of 9 PRODUCT NAME SYNONYMS? PRODUCT USE? Medicine SUPPLIER Company: Dentsply (AUSTRALIA) Pty Ltd Address: Gilby Road Mount Waverley VIC, 3149 Australia Telephone: Telephone: Emergency Tel: (Hrs. Mon.-Fri. 9am-5p Fax: Website: STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. CHEMWATCH HAZARD RATINGS Flammability: 0 Toxicity: 1 Body Contact: 2 Reactivity: 0 Chronic: 2 POISONS SCHEDULE None Min Max Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4 RISK Irritating to eyes, respiratory system and skin. May cause SENSITISATION by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Inhalation may produce health damage*. Cumulative effects may result following exposure*. Limited evidence of a carcinogenic effect*. Possible respiratory sensitiser*. SAFETY Do not breathe dust. Avoid contact with skin. Avoid contact with eyes. Wear suitable gloves. Wear eye/ face protection. Use only in well ventilated areas. Keep container in a well ventilated place.
2 Page 2 of 9 Avoid exposure - obtain special instructions before May possibly affect fertility*. use. * (limited evidence). Do not empty into drains. To clean the floor and all objects contaminated by this material, use water and detergent. This material and its container must be disposed of in a safe way. In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre. If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre (show this container or label). Use appropriate container to avoid environment contamination. Avoid release to the environment. Refer to special instructions/ safety data sheets. In case of accident by inhalation: remove casualty to fresh air and keep at rest. NAME CAS RN % frits chemical >60 bisphenol A glycidylmethacrylate <15 triethylene glycol dimethacrylate <10 2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane <15 silica, dimethylsiloxane treated <5 titanium dioxide <5 dibenzoyl peroxide <2 SWALLOWED For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. EYE If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. SKIN If skin contact occurs: Immediately remove all contaminated clothing, including footwear.
3 Page 3 of 9 Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. INHALED If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary. NOTES TO PHYSICIAN Treat symptomatically. EXTINGUISHING MEDIA Water spray or fog. Foam. Dry chemical powder. BCF (where regulations permit). FIRE FIGHTING Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Consider evacuation (or protect in place). Use water delivered as a fine spray to control fire and cool adjacent area. FIRE/EXPLOSION HAZARD Non combustible. Not considered a significant fire risk, however containers may burn. Decomposition may produce toxic fumes of:. carbon dioxide (CO2). sulfur oxides (SOx). metal oxides. other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes. HAZCHEM None MINOR SPILLS Clean up all spills immediately. Avoid breathing vapours/ aerosols/ or dusts and avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. MAJOR SPILLS Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Personal Protective Equipment advice is contained in Section 8 of the MSDS. PROCEDURE FOR HANDLING Limit all unnecessary personal contact. Wear protective clothing when risk of exposure occurs.
4 Page 4 of 9 Use in a well-ventilated area. When handling DO NOT eat, drink or smoke. SUITABLE CONTAINER Polyethylene or polypropylene container. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks. STORAGE INCOMPATIBILITY amines STORAGE REQUIREMENTS Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. EXPOSURE CONTROLS Source Australia Exposure Standards Material titanium dioxide (Titanium dioxide (a)) TWA ppm TWA mg/m³ 10 STEL ppm STEL mg/m³ Australia dibenzoyl Exposure peroxide (Benzoyl 5 Standards peroxide) The following materials had no OELs on our records frits chemical: CAS: bisphenol A glycidylmethacrylate: CAS: triethylene glycol dimethacrylate: CAS: ,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane: CAS: silica, dimethylsiloxane treated: CAS: Peak ppm Peak mg/m³ TWA F/CC Notes (see Chapter 14) PERSONAL PROTECTION RESPIRATOR Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) EYE Chemical goggles. Full face shield may be required for supplementary but never for primary protection of eyes Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the
5 Page 5 of 9 first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent] HANDS/FEET Wear protective gloves, eg. PVC. NOTE: The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. OTHER Overalls. P.V.C. apron. Barrier cream. Skin cleansing cream. ENGINEERING CONTROLS Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. APPEARANCE Creamy off white paste with sweet acrylic ester odour; does not mix PHYSICAL PROPERTIES Does not mix with water. Sinks in water. State Free-flowing Molecular Weight Not Applicable Melting Range ( C) Not Available Viscosity Not Available Boiling Range ( C) Not Applicable Solubility in water (g/l) Immiscible Flash Point ( C) Not Applicable ph (1% solution) Not Available Decomposition Temp ( C) Not Available ph (as supplied) Autoignition Temp ( C) Not Available Vapour Pressure (kpa) Not Applicable Upper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.8 approx. Lower Explosive Limit (%) Not Applicable Relative Vapour Density (air=1) Not Applicable Volatile Component (%vol) Not Available Evaporation Rate Not Applicable CONDITIONS CONTRIBUTING TO INSTABILITY Presence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur. For incompatible materials - refer to Section 7 - Handling and Storage.
6 Page 6 of 9 POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual, following ingestion, especially where pre-existing organ (eg. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities is not thought to be cause for concern. EYE There is some evidence to suggest that this material can cause eye irritation and damage in some persons. SKIN There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons. Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. INHALED Not normally a hazard due to physical form of product. Not normally a hazard due to non-volatile nature of product. The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models). Nevertheless inhalation of the material, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress. CHRONIC HEALTH EFFECTS Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population. Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. There is some evidence from animal testing that exposure to this material may result in toxic effects to the unborn baby. Bisphenol A may have effects similar to female sex hormones and when administered to pregnant women, may damage the foetus. It may also damage male reproductive organs and sperm. Sensitisation may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitised persons should not be allowed to work in situations where exposure may occur. TOXICITY AND IRRITATION Not available. Refer to individual constituents. CARCINOGEN Titanium dioxide Benzoyl peroxide SENSITISER triethylene glycol dimethacrylate International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs Australia Final Report on Hazard Classification of Common Skin Sensitisers Group Group 3 Recommended for Hazard Classification (R43) 2B No Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
7 Page 7 of 9 Avoid release to the environment. Refer to special instructions/ safety data sheets. Ecotoxicity Ingredient Persistence: Water/Soil Persistence: Air Bioaccumulation Mobility frits chemical No Data Available No Data Available bisphenol A glycidylmethacrylate No Data Available No Data Available triethylene glycol dimethacrylate LOW No Data Available LOW HIGH 2,2-bis[4-(2-methacryloxy)ethoxy) phenyl]propane No Data Available No Data Available silica, dimethylsiloxane treated No Data Available No Data Available titanium dioxide HIGH No Data Available LOW HIGH dibenzoyl peroxide LOW HIGH LOW MED Consult State Land Waste Management Authority for disposal. Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible. Otherwise: If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. Where possible retain label warnings and MSDS and observe all notices pertaining to the product. HAZCHEM: None (ADG7) NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG POISONS SCHEDULE None REGULATIONS Regulations for ingredients frits chemical (CAS: ) is found on the following regulatory lists; "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix C", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix I", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6", "OECD List of High Production Volume (HPV) Chemicals", "United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments"
8 Page 8 of 9 bisphenol A glycidylmethacrylate (CAS: ) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)" triethylene glycol dimethacrylate (CAS: ) is found on the following regulatory lists; "Australia Final Report on Hazard Classification of Common Skin Sensitisers", "Australia Inventory of Chemical Substances (AICS)", "International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List of High Production Volume (HPV) Chemicals" 2, 2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane (CAS: ) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)" silica, dimethylsiloxane treated (CAS: ) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix C", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4", "OSPAR National List of Candidates for Substitution Norway" titanium dioxide (CAS: , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , ) is found on the following regulatory lists; "Australia Exposure Standards", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", "Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines", "Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products", "CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "International Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals" dibenzoyl peroxide (CAS: ) is found on the following regulatory lists; "Australia - South Australia Controlled Substances (Poisons) Regulations - Schedule E: Schedule 2 poisons authorised to be sold by holder of a medicine sellers licence", "Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2", "Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported", "Australia Dangerous Goods Code (ADG Code) - List of Currently Assigned Organic Peroxides in Packagings", "Australia Exposure Standards", "Australia Hazardous Substances", "Australia Inventory of Chemical Substances (AICS)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 2", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "International Air Transport Association (IATA) Dangerous Goods Regulations", "International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List", "OECD List of High Production Volume (HPV) Chemicals", "United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments" No data for (CW: ) Denmark Advisory list for selfclassification of dangerous substances Substance CAS Suggested codes bisphenol A glycidylmethacrylate Xi; R38 N; R50/53 triethylene glycol dimethacrylate R43 2, 2- bis[4- ( Xi; R38 N; methacryloxy)ethoxy)phenyl] R50/53
9 Page 9 of 9 propane Ingredients with multiple CAS Nos Ingredient CAS Name titanium dioxide , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) Print Date:24-Jul-2012
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Page 1 of 9 PRODUCT NAME PRODUCT USE Dental restoration. SUPPLIER Company: Dentsply (AUSTRALIA) Pty Ltd Address: 11-21 Gilby Road Mount Waverley VIC, 3149 Australia Telephone: +61 3 9538 8240 Telephone:
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