MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # 05 Issue date Revision date Supersedes date CAS # Tough Quench (TM), Quart Mixture Product code Manufacturer information 2. Hazards Identification BROWNELLS, INC. 200 South Front Street Montezuma, Iowa United States (641) hour Emergency Number, Domestic: (800) hour Emergency Number, Foreign: +1(352) INFOTRAC Registrant #79335 Emergency overview OSHA regulatory status Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms Potential environmental effects WARNING Harmful in contact with eyes. Causes serious eye irritation. Irritating to respiratory system and skin. May cause an allergic skin reaction. Cancer hazard. Suspected of causing genetic defects. May cause damage to organs. Prolonged exposure may cause chronic effects. Dangerous for the environment if discharged into watercourses. This product is considered hazardous under 29 CFR (Hazard Communication). Eye contact. Skin contact. Inhalation. Do not get this material in contact with eyes. Contact may cause serious irritation or burn to the eyes. Eye contact may result in corneal injury. Avoid contact with the skin. Prolonged or repeated contact may cause irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. This product may cause an allergic skin reaction. of the product may be absorbed into the body through the skin. Do not breathe dust/fume/gas/mist/vapors/spray. Prolonged inhalation may be harmful. Irritating to respiratory system. May cause cancer by inhalation. Do not ingest. May cause nausea and discomfort. of the product may be absorbed into the body by ingestion. Eyes. Respiratory system, lungs. Skin. Conjunctiva. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Discomfort in the chest. Shortness of breath. Corneal damage. Coughing. Conjunctivitis. Irritation of eyes and mucous membranes. Irritating to mouth, throat, and stomach. Skin irritation. Defatting of the skin. Rash. Sensitization. Prolonged exposure may cause chronic effects. Exposure may cause aggravation to pre-existing conditions of the respiratory system or the skin. May cause long-term adverse effects in the aquatic environment. 3. Composition / Information on Ingredients CAS # Percent PARAFFINIC / 7

2 CAS # Percent PETROLEUM DISTILLATES, SOLVENT DEWAXED LIGHT PARAFFINIC PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES, SOLVENT-REFINED LIGHT PARAFFINIC RESIDUAL OILS (PETROLEUM), SOLVENT REFINED Other components below reportable levels First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion tes to physician General advice Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Continue rinsing. Get medical attention immediately. Remove and isolate contaminated clothing and shoes. Wash off with warm water and soap. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. For minor skin contact, avoid spreading material on unaffected skin. Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention, if needed. Do not induce vomiting. Consult a physician. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. If exposed or concerned: Get medical advice/attention. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Show this material safety data sheet (MSDS) to the doctor in attendance. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Fire fighting equipment/instructions unusual fire or explosion hazards noted. Carbon dioxide (CO2). Dry chemical. Foam. Water. Do not use water jet as an extinguisher, as this will spread the fire. May include oxides of carbon. Move containers from fire area if you can do so without risk. Water runoff can cause environmental damage. Firefighters should wear full protective gear. Treat as an oil fire. 6. Accidental Release Measures Personal precautions Environmental precautions Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate personal protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Avoid inhalation of vapors or mists. Eliminate all ignition sources (no smoking, flares, sparks, motors, or flames in immediate area). Avoid discharge into drains, water courses or onto the ground. Avoid release to the environment. The product is immiscible with water and will spread on the water surface. Do not contaminate water. 2 / 7

3 Methods for containment Methods for cleaning up Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Prevent entry into waterways, sewer, basements or confined areas. Clean up in accordance with all applicable regulations. 7. Handling and Storage Handling Storage 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit s SOLVENT DEWAXED LIGHT ) SOLVENT-RE FINED HEAVY ) SOLVENT-RE FINED LIGHT ) Large Spills: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. For waste disposal, see section 13 of the MSDS. Do not handle until all safety precautions have been read and understood. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Avoid prolonged exposure. Do not breathe dust/mist/vapors. Do not use in areas without adequate ventilation. Avoid contact with eyes, skin, and clothing. Wear personal protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Wash thoroughly after handling. Avoid release to the environment. Do not empty into drains. Handle in accordance with good industrial hygiene and safety practice. CAUTION Store locked up. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store in a closed container when not in use. Store away from incompatible materials. See Section 10 of the MSDS for incompatible materials. Keep away from heat, sparks and open flame. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) HYDROTREAT ED LIGHT ) SOLVENT DEWAXED LIGHT ) SOLVENT-RE FINED HEAVY ) TWA 5 mg/m3 Inhalable fraction. TWA 5 mg/m3 Inhalable fraction. TWA 5 mg/m3 Inhalable fraction mg/m3 500 ppm 3 / 7

4 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) SOLVENT-RE FINED LIGHT ) US. NIOSH: Pocket Guide to Chemical Hazards HYDROTREAT ED LIGHT ) SOLVENT DEWAXED LIGHT ) SOLVENT-RE FINED HEAVY ) SOLVENT-RE FINED LIGHT ) Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations 9. Physical & Chemical Properties Appearance Odor Physical state Color Odor threshold ph Vapor pressure Vapor density Boiling point Melting point/freezing point Solubility (water) Ensure adequate ventilation, especially in confined areas. Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. Provide eyewash station and safety shower. Do not get in eyes. Chemical goggles are recommended. Avoid contact with the skin. Use rubber gloves. Wear appropriate chemical resistant clothing. If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection. Do not get in eyes, on skin, or on clothing. When using, do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Contaminated work clothing should not be allowed out of the workplace. Handle in accordance with good industrial hygiene and safety practice. Liquid. Oil. Clear, dark amber. Bland. > 500 F (> 260 C) Insoluble. Specific gravity Relative density Flash point F ( C) Cleveland Open Cup 4 / 7

5 Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature VOC 8 g/l ASTM Evaporation rate < 1 BuAc 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions 11. Toxicological Information Sensitization Acute effects Local effects Chronic effects Carcinogenicity ACGIH Carcinogens Product is stable when stored in closed container at room temperature under normal storage and handling conditions. Heat, flames and sparks. Strong oxidizer. May include oxides of carbon. Hazardous polymerization will not occur. May cause sensitization by skin contact. Irritating to eyes, respiratory system and skin. Causes eye burns. May cause nausea and discomfort. of the product may be absorbed into the body through the skin or through ingestion. Hazardous by OSHA criteria. Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. Causes damage to organs through prolonged or repeated exposure. Conjunctiva. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Hazardous by OSHA criteria. Cancer hazard ) PETROLEUM DISTILLATES, SOLVENT DEWAXED LIGHT ) PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY ) PETROLEUM DISTILLATES, SOLVENT-REFINED LIGHT ) A4 t classifiable as a human carcinogen. A4 t classifiable as a human carcinogen. A4 t classifiable as a human carcinogen. IARC Monographs. Overall Evaluation of Carcinogenicity ) US NTP Report on Carcinogens: Known carcinogen ) PETROLEUM DISTILLATES, SOLVENT DEWAXED LIGHT ) PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY ) PETROLEUM DISTILLATES, SOLVENT-REFINED LIGHT ) Skin corrosion/irritation Epidemiology Mutagenicity Reproductive effects Irritating to skin. Suspected of causing genetic defects. 1 Carcinogenic to humans. 5 / 7

6 Symptoms and target organs Further information Discomfort in the chest. Shortness of breath. Coughing. Irritant effects. Defatting of the skin. Skin irritation. Rash. Corneal damage. Exposure may cause aggravation to pre-existing conditions of the respiratory system or the skin. Permanent eye damage including blindness could result. 12. Ecological Information Ecotoxicity Environmental effects Aquatic toxicity Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Accumulation in aquatic organisms is expected. May cause long lasting harmful effects to aquatic life. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. May cause long-term adverse effects in the aquatic environment. The product is immiscible with water and will spread on the water surface. 13. Disposal Considerations Disposal instructions Contaminated packaging Dispose of in accordance with current, applicable local, state, and federal regulations. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport Information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. 15. Regulatory Information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR Listed on TSCA Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR (b) and (f)(2) and Chemical Code Number t listed. Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR (c)) DEA Exempt Chemical Mixtures Code Number TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) CERCLA (Superfund) reportable quantity ne Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical Inventory status Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Pressure Hazard - Reactivity Hazard - Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) 6 / 7

7 Country(s) or region Inventory name On inventory (yes/no)* Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations US. Massachusetts RTK - Substance List California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins ) PETROLEUM DISTILLATES, SOLVENT DEWAXED LIGHT ) PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY ) PETROLEUM DISTILLATES, SOLVENT-REFINED LIGHT ) US. Pennsylvania RTK - Hazardous Substances ) PETROLEUM DISTILLATES, SOLVENT DEWAXED LIGHT ) PETROLEUM DISTILLATES, SOLVENT-REFINED LIGHT ) US. Rhode Island RTK 16. Other Information Recommended use Recommended restrictions Further information HMIS ratings Health: 1 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 1 Instability: 0 Disclaimer Listed. Listed. Listed. HMIS is a registered trade and service mark of the NPCA. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Yes 7 / 7