-HMIS: Physical state: Liquid HEALTH: Color: Clear to Amber FLAMMABILITY: Odor: Acetone PHYSICAL HAZARD: Personal Protection:
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1 Material Safety Data Sheet Revision Date: 05/24/2007 Issue date: 05/24/2007 Product name: Tak Accelerator Metered Mist Item No. : IIDH No Product type: Accelerator Region: United States Company address: Contact Information: Henkel Corporation Telephone: (860) Trout Brook Crossing Rocky Hill, Connecticut Emergency telephone: (860) Internet: Hazardous comdonents Acetone % ACGIH TLV 500 ppm TWA 750 ppm STEL OSHA PEL 1000 ppm TWA 2400 mglm' TWA OTHER Butane pprn TWA 800 pprn TWA Propane ppm TWA 1000 ppm TWA 1800 mg/m 3 TWA EMERGENCY OVERVIEW -HMIS: Physical state: Liquid HEALTH: Color: Clear to Amber FLAMMABILITY: Odor: Acetone PHYSICAL HAZARD: Personal Protection: DANGER: CONTENTS UNDER PRESSURE. EXTREMELY FLAMMABLE. VAPOR MAY CAUSE FLASH FIRE MAY CAUSE EYE, SKIN AND RESPtRATORY TRACT IRRITATION. ASPIRATION HAZARD IF SWALLOWED See Section 8 Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. Central nervous system depression, including dizziness, drowsiness, fatigue, nausea, headache, unconsciousness. May cause irritation due to defatting of the skin. Redness. Burns. Skin absorption ispossible, but harmful effects are not expected from this route of exposure under normal conditions of handling and use. Non-irritating. Exposure to vapor may cause tearing of the eyes, irritation and burning sensation. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Central nervous system depression, including dizziness, drowsiness, fatigue, nausea, headache, unconsciousness. Liver disorders. Kidney disorders. Lung disorders. See Section 11 for additional toxicological information. Item No. : 18637IIDH No Of4 Product name: Tak Pak@7452(TM) Accelerator Metered Mist
2 Inhalation: Skin contact: Eye contact: Ingestion: Remove to fresh air. Get medical attention immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Remove contaminated clothing and shoes. Wash with soap and water. Wash clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Get medical attention immediately. Do not induce vomiting. Flash point: -109 C (-165 F) (Propellant) Tagliabue closed cup Autoignition temperature: FlammablelExplosive limits-lower %: 2.8 FlammablelExplosive limits-upper %: 12.8 Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Foam, dry chemical or carbon dioxide. Use water spray to keep fire exposed containers cool and disperse vapors. Vapors may accumulate in low or confined areas, travel considerable distance to source of ignition, and flash back. Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Oxides of carbon. Oxides of nitrogen. Environmental precautions: Clean-up methods: Do not contaminate surface water. Do not let product enter drains Remove all sources of ignition. Vapors are heavier than air and may travel along the ground or be moved by ventilation and subsequently ignited by heat, pilot lights or other ignition sources at locations distant from the material handling point. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a closed metal container until ready for disposal. Handling: Storage: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after handling. Wash thoroughly after handling. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. Incompatible products: Refer to Section 10. For information on product shelf life contact Henkel Customer Service at (800) Engineering controls: Respiratory protection: Skin protection: Eyelface protection: Use local ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits. Use NlOSH approved respirator if there is potential to exceed exposure limit(s). Observe OSHA regulations for respiratoly use (29 CFR ). Chemical resistant, impermeable gloves. Goggles. Safety glasses with side-shields. See Section 2 for exposure limits. Item No. : 18637IIDH No f4 Product name: Tak P a m 7452(TM) Accelerator Metered Mist
3 Physical state: Color: Odor: Vapor pressure: ph: Boiling pointlrange: Melting pointlrange: Specific gravity: Vapor density: Evaporation rate: Solubility in water: Partition coefficient (n-octanollwater): VOC content: Liquid Clear to Amber Acetone Approximately 185 C (68" F) Not applicable 57 C (135 F) Approximately (Ether = 1) Soluble. 1.02%; 80 gramslliter Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Conditions to avoid: Stable. Will not occur Strong oxidizing agents No data available Carcinoqen Status Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen Acetone No No No Butane No No No Propane No No No Literature Referenced Taraet Oraan 8 Other Health Effects Hazardous components Acetone Butane Health Effectsnarget Organs Blood, Central nervous system, Irritant, Reproductive Cardiac, Central nervous system, irritant Cardiac, Central nervous system, Irritant Ecological information: Recommended method of disposal: EPA hazardous waste number: Information provided is for unused product only. Dispose of in accordance with Federal, State and local regulations. DO01: Ignitable. I Item No. : 18637IIDH No Product name: Tak Pak@7452(TM) Accelerator Metered Mist 30f4
4 U.S. DeDartment of TransDortation Ground (49 CFR): Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 Identification number: UN 1950 DOT reportable quantity (Ibs): Consumer Commodity ORM-D (Not more than 1 Liter) Acetone (CAS# ) is reportable at 5000 pounds (2270 kg). International Air TransDortation IICAOIIATA): Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 Identification number: UN1950 May Qualify as Consumer Commodity ID8000 (Not more than 500mL) WaterTransDortation IIMOIIMDGI: Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 Identification number: UN 1950 II Marine pollutant: Limited quantity (Not more than 1 L) United States Reaulatorv Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLNSARA Section 302 EHS: CERCLNSARA Section : CERCLNSARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.. above reporting de minimus. Fire, Immediate Health Hazard, Delayed Health Hazard above reporting de minimus. This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Canada Reaulatorv Information CEPA DSLlNDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Domestic Substances List. 8.2, D.2.A, D.2.0 This material safety data sheet contains changes from the previous version in sections: 2, 15 Prepared by: Regulatory Affairs DISCLAIMER The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Item No. : 18637IIDH No Product name: Tak Pak@7452(TM) Accelerator Metered Mist 4 of 4
5 Material Safety Data Sheet Technologies Revision Date: 05/23/2008 Issue date: 05/23/2008 Product name: Loctite(R) 382 Ultra Performance Tak Pak(R) Item No. : IIDH No Instant Adhesive Product type: Cyanoacrylate Reglon: United States Company address: Contact Information: Henkel Corporation Telephone: Trout Brook Crossing Emergency telephone: Rocky Hill, Connecticut Internet: w.loctite.com Hazardous comdonents Ethyl cyanoacrylate YO ACGIH TLV 0.2 ppm TWA OSHA PEL OTHER EMERGENCY OVERVIEW -HMIS: Physical state: Liquid HEALTH: Color: Clear FLAMMABILITY: Odor: Sharp, Irritating PHYSICAL HAZARD: Personal Protection: WARNING: BONDS SKIN IN SECONDS. MAY CAUSE EYE AND RESPIRATORY IRRITATION. COMBUSTIBLE LIQUID AND VAPOR See Section 8 Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Exposure to vapors above the established exposure limit results in respiratory irritation which may lead to difficulty in breathing and tightness in the chest. Bonds skin in seconds. May cause skin irritation. Cyanoacrylates have been reported lo cause allergic reaction but due to rapid polymerization at the skin surface, an allergic response is rare. Cyanoacrylates generate heat on solidification. In rare circumstances a large drop will burn the skin. Cured adhesive does not present a health hazard even if bonded lo the skin. Irritating to eyes. Causes excessive tearing. Eyelids may bond. Not expected to be harmful by ingestion. Rapidly polymerizes (solidifies) and bonds in mouth. It is almost imdossible lo swallow. Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. Item No. : / IDH No Product name: Loctite(R) 382 Ultra Performance Tak Pak(R) Instant Adhesive 1 Of4
6 Inhalation: Skin contact: Eye contact: Remove to fresh air. If discomfort persists seek medical attention. Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart using a blunt instrument. If skin is burned due to the rapid generation of heat by a large drop, seek medical attention. If lips are bonded, apply warm water to the lips and encourage wetting and pressure from saliva in mouth. Peel or roll lips apart. Do not pull lips apart with direct opposing force. Immediately flush with plenty of water for at least 15 minutes. Get medical attention. If eyelids are bonded closed, release eyelashes with warm water by covering with a wet pad. Do not force eye open. Cyanoacrylate will bond to eye protein and will cause a lachrymatory effect which will help to debond the adhesive. Keep eye covered until debonding is complete, usually within 1-3 days. Medical attention should be sought in case solid particles of polymerized cyanoacrylate trapped behind the eyelid caused abrasive damage. Ingestion: Notes to physician: Ensure breathing passages are not obstructed. The product will polymerize rapidly and bond to the mouth making it almost impossible to swallow. Saliva will separate any solidified product in several hours. Prevent the patient from swallowing any separated mass. Surgery is not necessary to separate accidentally bonded tissues. Experience has shown that bonded tissues are best treated by passive, non-surgical first aid. If rapid curing has caused thermal burns they should be treated symptomatically after adhesive is removed. Flash point: Autoignition temperature: FlammablelExplosive limits-lower %: FlammablelExplosive limits-upper %: 8O o C (176'F) to 93.3% (2OOOF) 485 C (905 F) Not determined Not determined Tagliabue closed cup Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Water spray. Dry powder. Foam. Carbon dioxide. Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA). Trace amounts of toxic and/or irritating fumes may be released and the use of breathing apparatus is recommended. Environmental precautions: Clean-up methods: Ventilate area. Prevent product from entering the drains. Do not use cloths for mopping up. Flood with water to complete polymerization and scrape off the floor. Cured material can be disposed of as non-hazardous waste. Handling: Storage: Incompatible products: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after handling. Avoid contact with fabric or paper goods. Contact with these materials may cause rapid polymerization which can generate smoke and strong irritating vapors, and cause thermal burns. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. No special restrictions on storage with other products. For information on product shelf life contact Henkel Customer Service at (800) Item No. : IIDH No Product name: Loctite(R) 382 Ultra Performance Tak Pak(R) Instant Adhesive 2of4
7 Engineering controls: Respiratory protection: Skin protection: Eyelface protection: Use positive down-draft exhaust ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Use nitrile gloves and aprons as necessary to prevent contact. Do not use PVC, nylon or cotton. Chemical splash goggles or safety glasses with side shields. See Section 2 for exposure limits. Physical state: Color: Odor: Vapor pressure: ph: Boiling poinurange: Melting poinurange: Specific gravity: Vapor density: Evaporation rate: Solubility in water: Partition coefficient (n-octanollwater): VOC content: Liquid Clear Sharp, Irritating Less than 0.2 mm Hg Not applicable Greater than 149OC (3OOOF) Not determined 1.05 at 23.9OC (75OF) Approximately 3 Polymerizes in presence of water Not applicable Less than 2%; 20 gll (California SCAQMD Method 3168) (estimated) Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Conditions to avoid: Stable under recommended storage conditions Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols. Water, amines, alkalis and alcohols. Spontaneous polymerization Product toxicity data: Acute oral LD50 >5000mg/kg (rat)(estimated). Acute dermal LD50 >2000mgkg (rabbit)(estimated). Carcinoaen Status Hazardous components NTP Carcinogen IARC Carcinogen Ethyl cyanoacrylate No No OSHA Carcinogen No Literature Referenced Taraet Oraan 8 Other Health Effects Hazardous components Health Effectsnarget Organs Ethyl cyanoacrylate I Allergen, Irritant. Respiratory Ecological information: Not known Item No. : IIDH No Product name: Loctite(R) 382 Ultra Performance Tak Pak(R) Instant Adhesive 3of4
8 Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Dispose of in accordance with Federal, State and local regulations. Not a RCRA hazardous waste. U.S. DeDartment of Transportation Ground (49 CFR): Proper shipping name: Combustible liquids, n.0.s. (Cyanoacrylate ester) Hazard class or division: 3 Identification number: NA 1993 Marine pollutant: (Not more than 450 Liters) Unrestricted International Air TransDortation IICAOIIATAL Proper shipping name: Aviation regulated liquids, n.0.s (Cyanoacrylate ester) Hazard class or division: 9 Identification number: UN 3334 Loctite SHARED FIELD (US/Canada/EU) (Not more than 500ml) Unrestricted WaterTransDortation (IMOIIMDG): Proper shimins name: Hazard class o;division: Identification number: Marine pollutant: Unrestricted United States Requlatorv Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLNSARA Section 302 EHS: CERCLNSARA Section : CERCLNSARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus. Immediate Health Hazard, Delayed Health Hazard, Fire, Reactive above reporting de minimus. No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSLINDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Domestic Substances List. B.3, D.2.B This material safety data sheet contains changes from the previous version in sections: Updated Revision Date Only Prepared by: C.J. Michaels, Manager, Regulatoty Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability ofhenkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Item No. : / IDH No Product name: Loctite(R) 382 Ultra Performance Tak Pak(R) Instant Adhesive 4 of 4
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