MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification
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1 MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name Clearasil Ultra Acne Solution Kit - Rapid Action Lotion UPC CODES Refer to Section 16 CAS # Product use Distributed by LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 Mixture Topical Skin Preparation Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway PO Box 225 Parsippany, NJ In Case of Emergency: Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: Outside North America: Health / 1 Flammability 0 Physical Hazard 0 Personal Protection Emergency overview 2 Hazards Identification This product is regulated by the US FDA as an over-the-counter, monograph drug Warnings: For external use only When using with other topical acne medications at the same time or immediately following use of the product, increased dryness or irritation may occur Avoid contact with eyes If product gets into the eyes, rinse thoroughly with water Stop use and ask a doctor if skin or eye irritation develops In case of accidental ingestion, get medical help or contact a Poison Control Center immediately Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status Potential environmental effects KEEP OUT OF REACH OF CHILDREN Eye, Skin contact, Inhalation, Ingestion Avoid contact with eyes May cause eye irritation Unlikely to cause skin irritation Not expected to be a skin sensitizer Unlikely to cause irritation due to inhalation Ingestion may cause gastrointestinal irritation Eyes Skin The finished product is not expected to have chronic health effects Symptoms may include redness, edema, drying, defatting and cracking of the skin This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333 Components of this product have been identified as having potential environmental concerns #21931 Page 1 of 8 Issue date 17-Aug-2011
2 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent Glycerol Nonane, 2,2,4,4,6,8,8-heptamethyl- Poly(oxy-1,2-ethanediyl), a-octadecyl-w-hydroxy 1,3-Butanediol Cyclohexasiloxane, dodecamethyl- Cyclopentasiloxane, decamethyl- Lauryl methacrylate, copolymer with Ethylene glycol dimethacrylate Polyethylene glycol First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 4 First Aid Measures If product gets into the eyes, rinse thoroughly with water Stop use and ask a doctor if skin irritation develops Remove to fresh air if inhalation causes eye watering, headaches, dizziness or other discomfort In case of accidental ingestion, get medical help or contact a Poison Control Center immediately Treat patient symptomatically If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Not flammable by OSHA criteria Water spray Foam Dry chemical Sand Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Do not discharge into lakes, streams, ponds or public waters Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills to original containers for re-use #21931 Page 2 of 8 Issue date 17-Aug-2011
3 Handling Storage Exposure limits Ingredient(s) 1,3-Butanediol 7 Handling and Storage For external use only Avoid contact with eyes, lips and mouth When using do not eat or drink Keep out of reach of children Keep in cool, dry, ventilated storage Room temperature - normal conditions Keep from freezing 8 Exposure Controls / Personal Protection Exposure Limits Cyclohexasiloxane, dodecamethyl- Cyclopentasiloxane, decamethyl- Glycerol Lauryl methacrylate, copolymer with Ethylene glycol dimethacrylate Nonane, 2,2,4,4,6,8,8-heptamethyl- Poly(oxy-1,2-ethanediyl), a-octadecyl-w-hydroxy TWA: 10 mg/m3 TWA: 15 mg/m3 Polyethylene glycol Engineering controls Personal protective equipment Eye / face protection Not normally required Not normally required under normal use conditions When handling in large quantities or responding to emergency situations, the use of appropriate eye protection is recommended #21931 Page 3 of 8 Issue date 17-Aug-2011
4 Hand protection Skin and body protection Respiratory protection Not required When handling in large quantities or responding to emergency situations, the use of appropriate eye protection is recommended No special requirements under normal use conditions Not normally required under normal use conditions General hygiene considerations Avoid contact with eyes Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink 9 Physical and Chemical Properties Appearance Glossy cream Color White Form Cream Odor perfumed Odor threshold Physical state Liquid ph Freezing point Boiling point Pour point Evaporation rate Flash point Not tested Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Solubility (H2O) VOC (Weight %) Percent volatile Soluble/Miscible 10 Stability and Reactivity Reactivity This product may react with strong acids Possibility of hazardous reactions Hazardous polymerization does not occur Chemical stability Stable under recommended storage conditions Conditions to avoid Do not mix with other chemicals Incompatible materials Acids Oxidizers Caustics Hazardous decomposition products May include and are not limited to: Oxides of carbon #21931 Page 4 of 8 Issue date 17-Aug-2011
5 Component analysis - LC50 Ingredient(s) 11 Toxicological Information LC50 1,3-Butanediol Cyclohexasiloxane, dodecamethyl- Cyclopentasiloxane, decamethyl- Glycerol Lauryl methacrylate, copolymer with Ethylene glycol dimethacrylate Nonane, 2,2,4,4,6,8,8-heptamethyl- Poly(oxy-1,2-ethanediyl), a-octadecyl-w-hydroxy Polyethylene glycol Component analysis - Oral LD50 Ingredient(s) LD50 1,3-Butanediol Cyclohexasiloxane, dodecamethyl- Cyclopentasiloxane, decamethyl- Glycerol Lauryl methacrylate, copolymer with Ethylene glycol dimethacrylate Nonane, 2,2,4,4,6,8,8-heptamethyl- Poly(oxy-1,2-ethanediyl), a-octadecyl-w-hydroxy mg/kg rat Polyethylene glycol Effects of acute exposure Eye Avoid contact with eyes May cause eye irritation Skin Unlikely to cause skin irritation Not expected to be a skin sensitizer Inhalation Unlikely to cause irritation due to inhalation Ingestion Ingestion may cause gastrointestinal irritation Sensitization The finished product is not expected to have chronic health effects Chronic effects The finished product is not expected to have chronic health effects Carcinogenicity The finished product is not expected to have chronic health effects Mutagenicity The finished product is not expected to have chronic health effects Reproductive effects The finished product is not expected to have chronic health effects Teratogenicity The finished product is not expected to have chronic health effects Name of Toxicologically Synergistic Products Ecotoxicity 12 Ecological Information Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Fish - Acute Toxicity Data Glycerol Hr LC50 Oncorhynchus mykiss: ml/l [static] Polyethylene glycol Hr LC50 Carassius auratus: >5000 mg/l (PEG 200, 400, 800) Ecotoxicity - Water Flea - Acute Toxicity Data Glycerol Hr EC50 Daphnia magna: >500 mg/l Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects #21931 Page 5 of 8 Issue date 17-Aug-2011
6 Aquatic toxicity Partition coefficient Chemical fate information Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Review federal, provincial, and local government requirements prior to disposal 14 Transport Information UN/ID No US Department of Transportation (DOT): Classification: Not regulated Proper shipping name US DOT Hazard Class Subsidiary Risk Packing group DOT RQ (lbs) ERG NO Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Status Packing group #21931 Page 6 of 8 Issue date 17-Aug-2011
7 IMDG (Marine Transport): Classification: Not regulated Proper shipping name Class Subsidiary Risk Packing group IMDG Page Marine pollutant EMS MFAG Maximum Quantity IATA/ICAO (Air): Classification: Not regulated Proper shipping name Class Subsidiary Risk: Packing group Maximum Quantity 15 Regulatory Information Occupational Safety and Health Administration (OSHA) 29 CFR hazardous chemical US Federal regulations Yes This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) #21931 Page 7 of 8 Issue date 17-Aug-2011
8 State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm US - Massachusetts - Right To Know List Glycerol Present (mist) US - Minnesota - Hazardous Substance List Glycerol Present (mist) Polyethylene glycol Present US - New Jersey - Right to Know Hazardous Substance List Glycerol sn 3319 US - Pennsylvania - RTK (Right to Know) List Glycerol Present US - Rhode Island - Hazardous Substance List Glycerol Toxic; Flammable Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer 16 Other Information This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Further information oz - Clearasil Ultra Acne Solution Kit - Rapid Action Lotion Issue date 17-Aug-2011 Effective date 15-Aug-2011 Prepared by Reckitt Benckiser Regulatory Department Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #21931 Page 8 of 8 Issue date 17-Aug-2011
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