MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

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1 MATERIAL SAFETY DATA SHEET Product Name CAS # 1 Product and Company Identification CLEARASIL ULTRA Rapid Action Pads Mixture This MSDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the US Government's Occupational Safety and Health Administration (OSHA) This MSDS is not applicable for consumer use of our products For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation Product Use Distributed by LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 Emergency overview Cleanser Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway PO Box 225 Parsippany, NJ In Case of Emergency: Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: Outside North America: Health / 2 Flammability 3 Physical Hazard 0 Personal Protection 2 Hazards Identification This product is regulated by the US FDA as an over-the-counter, monograph drug Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status Warnings: For external use only Flammable Keep away from extreme heat or open flame When using this product, avoid contact with the eyes If product gets into the eyes rinse thoroughly with water Skin irritation and dryness is more likely to occur if you use another topical acne medication at the same time Limit use to the face and neck Stop use and ask a doctor if skin or eye irritation develops If swallowed, get medical help or contact a Poison Control Center right away KEEP OUT OF REACH OF CHILDREN Eye, Skin contact, Inhalation, Ingestion Avoid contact with eyes Causes eye irritation May cause irritation Not expected to be a skin sensitizer May cause respiratory tract irritation May cause stomach distress, nausea or vomiting Eyes Skin The finished product is not expected to have chronic health effects Symptoms may include redness, edema, drying, defatting and cracking of the skin This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333 #18221 Page 1 of 8 Issue date 29-Nov-2012

2 Potential environmental effects See section 12 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent Alcohol Isoceteth-20 Salicylic Acid First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 4 First Aid Measures Avoid contact with eyes If product gets into the eyes, rinse thoroughly with water Stop use and ask a doctor if eye irritation develops Remove contact lenses if present Flush immediately with large amounts of water, especially under lids for at least 15 minutes If irritation or other effects persist, obtain medical treatment Skin irritation and dryness is more likely to occur if you use another topical acne medication at the same time If irritation occurs, please wash thoroughly with soap and water If symptoms develop move victim to fresh air If symptoms persist, obtain medical attention If swallowed, get medical help or contact a poison control center right away If swallowed in quantity DO NOT INDUCE VOMITING! Rinse mouth thoroughly and seek medical attention immediately Treat patient symptomatically If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Flammable by OSHA criteria Water spray Dry chemical Alcohol foam Carbon dioxide Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Do not discharge into lakes, streams, ponds or public waters Advise authorities if product has penetrated drains, sewers or water pipes Prevent entry into waterways, sewers, basements or confined areas Pick up and discard towel Handling 7 Handling and Storage Ensure adequate ventilation For external use only Avoid contact with eyes When using do not eat or drink #18221 Page 2 of 8 Issue date 29-Nov-2012

3 Storage Keep out of reach of children Store in a closed container away from incompatible materials Keep away from heat, open flames or other sources of ignition Keep container tightly closed Do not freeze Store in a cool, dry, well-ventilated place Allowances for excursions above 30 C: 60 C - Not more than 5 days 50 C - Not more than 5 days 40 C - Not more than 8 weeks Exposure limits Ingredient(s) Alcohol Isoceteth-20 Allowances for excursions below 0 C: Do not store below -20 C 8 Exposure Controls / Personal Protection Exposure Limits ACGIH-TLV TWA: 1000 ppm STEL: 1000 ppm OSHA-PEL TWA: 1000 ppm ACGIH-TLV Not established OSHA-PEL Not established Salicylic Acid Engineering controls Personal protective equipment ACGIH-TLV Not established OSHA-PEL Not established Not normally required if good ventilation is maintained Consult the product label for special protection or precautions that have been identified for using this product under directed consumer use conditions The following recommendations are given for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure Eye / face protection Hand protection Skin and body protection Respiratory protection Not normally required under normal use conditions When handling in large quantities or responding to emergency situations, the use of appropriate eye protection is recommended Not required When handling in large quantities or responding to emergency situations, the use of appropriate skin protection is recommended No special requirements under normal use conditions Not normally required under normal use conditions General hygiene considerations Avoid contact with eyes Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact 9 Physical and Chemical Properties Appearance Liquid saturated on pad Color Clear liquid on white pad Form Liquid saturated on pad Odor perfumed Odor threshold Physical state Solid ph 3-35 #18221 Page 3 of 8 Issue date 29-Nov-2012

4 Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Solubility (H2O) VOC (Weight %) Viscosity Percent volatile 7934 F (263 C) G/mL Pad is not soluble 10 Stability and Reactivity Reactivity This product may react with strong oxidizing agents Possibility of hazardous reactions Hazardous polymerization does not occur Chemical stability Stable under recommended storage conditions Conditions to avoid Do not mix with other chemicals Incompatible materials Caustics Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Component analysis - LC50 Ingredient(s) 11 Toxicological Information LC50 Alcohol Isoceteth-20 Salicylic Acid Component analysis - Oral LD50 Ingredient(s) Alcohol Isoceteth-20 Salicylic Acid Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects ppm rat LD mg/kg mouse; 7060 mg/kg rat Avoid contact with eyes Causes eye irritation May cause irritation Not expected to be a skin sensitizer May cause respiratory tract irritation 891 mg/kg rat; 400 mg/kg cat; 480 mg/kg mouse May cause stomach distress, nausea or vomiting The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects #18221 Page 4 of 8 Issue date 29-Nov-2012

5 Carcinogenicity The finished product is not expected to have chronic health effects Mutagenicity The finished product is not expected to have chronic health effects Reproductive effects The finished product is not expected to have chronic health effects Teratogenicity The finished product is not expected to have chronic health effects Name of Toxicologically Synergistic Products Ecotoxicity 12 Ecological Information Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Fish - Acute Toxicity Data Alcohol Hr LC50 Oncorhynchus mykiss: ml/l [static]; 96 Hr LC50 Pimephales promelas: >100 mg/l [static]; 96 Hr LC50 Pimephales promelas: mg/l Salicylic Acid [flow-through] 48 Hr LC50 Leuciscus idus: 90 mg/l [static] Ecotoxicity - Water Flea - Acute Toxicity Data Alcohol Hr LC50 Daphnia magna: mg/l; 24 Hr EC50 Daphnia magna: mg/l; 48 Hr EC50 Daphnia magna: 2 mg/l [Static] Salicylic Acid Hr EC50 Daphnia magna: 105 mg/l; 48 Hr EC50 Daphnia magna: 870 mg/l [Static] Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information 13 Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging US Department of Transportation (DOT) Review federal, state/provincial, and local government requirements prior to disposal Discard with solid waste Empty container can be disposed of as household trash or rinsed and recycled 14 Transport Information UN 1170, Ethanol Solutions, Class 3, PG III, Limited Quantity #18221 Page 5 of 8 Issue date 29-Nov-2012

6 Transportation of Dangerous Goods (TDG - Canada) UN 1170, Ethanol Solutions, Class 3, PG III, Limited Quantity IMDG (Marine Transport) UN 1170, Ethanol Solutions, Class 3, PG III, Limited Quantity, F/P 263 C IATA/ICAO (Air) UN 1170, Ethanol Solutions, Class 3, PG III, Limited Quantity or ID 8000 Consumer Commodity if acceptable to the airline 15 Regulatory Information Occupational Safety and Health Administration (OSHA) 29 CFR hazardous Yes chemical #18221 Page 6 of 8 Issue date 29-Nov-2012

7 US Federal regulations This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333 All components of this product are either on the TSCA Inventory, or are exempt from TSCA Inventory US - CAA (Clean Air Act) - HON Rule - SOCMI Chemicals Salicylic Acid Group III US - CAA (Clean Air Act) - Reactivity Factors for VOCs in Aerosol Coatings Alcohol G Ozone/g VOC Reactivity Factor US - CAA (Clean Air Act) - Volatile Organic Compounds (VOCs) in SOCMI Alcohol Present Salicylic Acid Present CERCLA (Superfund) reportable quantity Sodium hydroxide: Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Water Act (CWA) Hazardous substance State regulations This product is not subject to warning labeling under the California Proposition 65 regulation US - California - 8 CCR Section Director's List of Hazardous Substances Alcohol Present (refers to solutions >=25% which are not beverage alcohols) US - Massachusetts - Right To Know List Alcohol Teratogen US - Minnesota - Hazardous Substance List Alcohol Present US - New Jersey - Right to Know Hazardous Substance List Alcohol sn 0844 US - Pennsylvania - RTK (Right to Know) List Alcohol Present US - Rhode Island - Hazardous Substance List Alcohol Toxic; Flammable Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer 16 Other Information This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Further information CLEARASIL ULTRA Rapid Action Pads, 90 ct v10 Issue date 29-Nov-2012 Effective date 15-Nov-2012 Prepared by Reckitt Benckiser Regulatory Department #18221 Page 7 of 8 Issue date 29-Nov-2012

8 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #18221 Page 8 of 8 Issue date 29-Nov-2012

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