Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 2 0 Health Hazard Fire Hazard 2 0 See Section 5. Section. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Tergitol TMN-0(90% Aqueous) SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA Tergitol TMN-0 (90% AQ) Polyethylene glycol trimethylnonyl ether; Secondary Alcohol Ethoxylate 2,6,8-Trimethyl-4-Nonyloxypolyethyleneoxyethanol Catalog Number(s). CAS# RTECS TSCA CI# T WZ IN CASE OF EMERGENCY CHEMTREC (24hr) Page Number: TSCA 8(b) inventory: All components are TSCA listed Chemical Family Chemical Formula Supplier Alcohol Ethoxylates SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA CALL (30) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight ) 4-Nonanol, 2,6,8-trimethyl <2 2) Polyethylene glycol <3 3) Water ) Polyethylene glycol trimethylnonyl ether >87 5) This product may contain trace amounts of the following: Acetaldehyde (<=0.0006%),4-Dioxane (<=0.0005%) Formaldehyde (<=0.0004%) Ethylene Oxide (<0.0020%) Toxicological Data on Ingredients Tergitol TMN-0(90% Aqueous): ORAL (LD50): Acute: 5650 mg/kg [Rat].

2 Tergitol TMN-0(90% Aqueous) Page Number: 2 Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: Repeated or prolonged exposure is not known to aggravate medical condition. Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 5 minutes. Cold water may be used. Get medical attention. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used. Inhalation Serious Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion Serious Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances May be combustible at high temperature. These products are carbon oxides (CO, CO2). Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

3 Tergitol TMN-0(90% Aqueous) Page Number: 3 Section 6. Accidental Release Measures Small Spill Large Spill Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids, alkalis. Keep container tightly closed. Keep container in a cool, well-ventilated area. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Safety glasses or Splash goggles. Lab coat or Synthetic apron. Gloves (impervious). Respiratory protection is normally not required for usual industrial handling. Respiratory protection is needed if ventilation is inadequate and exposure limits are exceeded and if handling of material produces mist/aerosol or vapor. Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Polyethylene Glycol: TWA: 0 (mg/m 3 ) from AIHA (WEELs) [United States] Inhalation Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical state and appearance Liquid. Odor Pungent. (Slight.) Molecular Weight ph (% soln/water) approximately 683 g/mole Taste Color Clear Yellow. (Light.) Boiling Point >00 C (22 F) Melting Point -7.2 C (9 F) Critical Temperature Specific Gravity.044 (Water = ) Vapor Pressure 2 kpa (@ 20 C) Vapor Density < (Air = ) Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties See solubility in water. Solubility Soluble in cold water, hot water.

4 Tergitol TMN-0(90% Aqueous) Page Number: 4 Section 0. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Excess heat, incompatible materials Reactive with oxidizing agents, acids, alkalis. Corrosivity Polymerization Normally unreactive. However avoid strong bases at high temperatures, strong acids, stron oxidizing agents and materials reactive with hydroxyl compounds Will not occur. Section. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Absorbed through skin. Eye contact. Acute oral toxicity (LD50): 5650 mg/kg [Rat]. Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation. LD50 [Rabbit] - Route: Skin; Dose: 4780 ul/kg This product may contain trace amounts of the following which may cause cancer: Acetaldehyde,4-Dioxane Formaldehyde Ethylene Oxide This product may contain trace amounts of the following which may cause reproductive harm: Ethylene Oxide Acute Potential Health Effects: Skin: May cause skin irritation. It may be absorbed through the skin, but no evidence of harmful effects was found from available information. Eyes: Causes severe eye irritation with possible chemical burns and conjunctivitis. Corneal injury may be severe, extensive, and if not treated promptly, could result in impairment of vision. Inhalation: May cause respiratory tract irritation. Short-term harmful health effects are not expected from vapor generated at ambient temperature. Ingestion: May cause irritation of the digestive tract (mouth, throat, esophagus, and stomach) with pain or discomfort in the mouth, throat, and chest and abdomen, nausea, vomiting, diarrhea, thrist. May also affect behavior and respiration. Symptoms may include dizziness, drowsiness, sluggishness, unsteady gait, weakness, and rapid breathing. Aspiration into the lungs may occur during ingestion or vomiting, resulting in lung injury. Chronic Potential Health Effects: Skin: Repeated or prolonged skin contact may cause dermatits. Prolonged contact may also cause more severe irritation and possible tissue destruction.

5 Tergitol TMN-0(90% Aqueous) Page Number: 5 Section 2. Ecological Information Ecotoxicity BOD5 and COD Ecotoxicity in water (LC50): 64.9 mg/l 48 hours [Daphnia]. 03 mg/l 96 hours [Fathead Minnow]. Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Section 3. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 4. Transport Information DOT Classification Identification Not a DOT controlled material (United States). Not applicable. Special Provisions for Transport Not applicable. DOT Section 5. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Ethylene Oxide; Acetaldehyde;,4-Dioxane; Formaldehyde. cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide cause birth defects which would require a warning under the statute: No products were found. cause cancer which would require a warning under the statute: Ethylene Oxide; Acetaldehyde;,4-Dioxane; Formaldehyde. TSCA 8(b) inventory: Polyethylene glycol trimethylnonyl ether; water; Polyethylene Glycol; 4-Nonanol, 2,6,8-trimethyl- Pennsylvania (Right to Know), and Massachusetts(Right to Know ): 4-Nonanol, 2,6,8-trimethyl- Minnesota: Polyethylene Glycols California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Acetaldehyde;,4-Dioxane; Formaldehyde; Ethylene Oxide California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. Other Regulations

6 Tergitol TMN-0(90% Aqueous) Page Number: 6 CAS no can be found on the following Lists: Canada: Domestic Substances List (DSL) Australia: National Inventory (AICS) China Inventory Korea: National Inventory (KECI) Philippines: National Inventory (PICCS) CAS no can be found on the following lists: Canada: Domestic Substances List (DSL) European EINECS Inventory Australia: National Inventory (AICS) China Inventory Japan: National Inventory (ENCS) Korea: National Inventory (KECI) Philippines: National Inventory (PICCS) CAS no can be found on the following lists: Australia: National Inventory (AICS) China Inventory Japan: National Inventory (ENCS) Korea: National Inventory (KECI) Philippines: National Inventory (PICCS) Other Classifications WHMIS (Canada) WHMIS Classification is unavailable. However, it might be classifed as: CLASS D-2B: Material causing other toxic effects (TOXIC). DSCL (EEC) R36- Irritating to eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 2 0 j National Fire Protection Association (U.S.A.) Health 2 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment Gloves (impervious).

7 Tergitol TMN-0(90% Aqueous) Page Number: 7 Lab coat. Not applicable. Safety glasses. Section 6. Other Information MSDS Code References Other Special Considerations T36 Validated by Sonia Owen on 8//2006. Verified by Sonia Owen. Printed 9/4/2006. CALL (30) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.