MSDS for # AKUA STARTER SET. Page 1 of 19. Item Numbers: Page 1 of 19

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4 Page 4 of 19 MATERIAL SAFETY DATA SHEET - NO. 01 AKUA-KOLOR/LIQUID PIGMENT WATER-BASED INKS 1 of 05 DATE PREPARED February 15, 2000 DATE REVISED May 6, 2013 fcmaster SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME PRODUCT CODE CHEMICAL FAMILY CHEMICAL NAME FORMULA AKUA-KOLOR/LIQUID PIGMENT WATER-BASED INKS AKUA EXTENDER cc MANUFACTURER NAME ADDRESS CITY, STATE, ZIP CONTACT PERSON: TITLE INFORMATION TEL: EMERGENCY TEL: CHEMTREC TEL: Speedball Art Products 2301 Speedball Road Statesville Bud Martin Director of R & D NC USA SECTION 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredient Listing CAS No. OSHA PEL ACGIH TLV STEL % COMP PROPRIETARY INGRED MIXTURE N/L N/L N/L The proprietary ingredients in this product are judged to be non-hazardous and are regarded as trade secrets. SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Non hazardous material PHYSICAL DESCRIPTION: Watery colored liquid MAJOR HEALTH HAZARDS: None for usual and ordinary uses of product PHYSICAL HAZARDS: None for usual and ordinary uses of product ROUTES OF ENTRY: INHALATION no SKIN no EYE no INGESTION no POTENTIAL HEALTH EFFECTS: None known for usual and ordinary uses of product INHALATION: SKIN CONTACT: EYE CONTACT: INGESTION: Item Numbers: Page 4 of 19

5 Page 5 of 19 MATERIAL SAFETY DATA SHEET - NO. 01 AKUA-KOLOR/LIQUID PIGMENT WATER-BASED INKS 2 of 05 CARCINOGEN STATUS: NTP not listed Item Numbers: Page 5 of 19

6 Page 6 of 19 MATERIAL SAFETY DATA SHEET - NO. 01 AKUA-KOLOR/LIQUID PIGMENT WATER-BASED INKS 3 of 05 IARC OSHA not listed not listed MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: SECTION 4 FIRST AID MEASURES EYES: Eye contact: carefully flush for 15 minutes. If irritation occurs, contact a physician SKIN: Wash with soap and water INHALATION: Not likely to occur; seek fresh air INGESTION: Drink water or milk to dilute. Do not induce vomiting. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: FIRE AND EXPLOSION HAZARDS: EXTINGUISHING MEDIA: Water, foam carbon dioxide or dry chemical SPECIAL FIRE FIGHTING PROCEDURES: None required for this material SECTION 6 SPILL/LEAK PROCEDURES ACCIDENTAL RELEASE MEASURES Contain spill. Recover as much as possible by mechanical means. Absorb remainder with an inert material. Place into closed container and store to await disposal. Wash area with soap & water. SECTION 7 HANDLING AND STORAGE STORAGE TEMPERATURE (min/max) SHELF LIFE: Store at 70 Deg F. (Min: 50 deg F Max: 100 deg F.) not determined SPECIAL SENSITIVITY: None likely or known HANDLING AND STORAGE:For personal protection and hygiene, wash thoroughly after handling. Wash before eating, smoking or using toilet facilities. PRECAUTIONS: Avoid eye & skin contact. Keep container closed when in use and upright to prevent leakage SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS: None known Item Numbers: Page 6 of 19

7 Page 7 of 19 MATERIAL SAFETY DATA SHEET - NO. 01AKUA-KOLOR/LIQUID PIGMENT WATER-BASED INKS 3 of 05 EYE PROTECTION: SKIN PROTECTION: RESPIRATORY AND VENTILATION: Wear splash goggles where spills or splashing may occur. Not required. Wear approved NIOSH/MSHA respirator if exposure to mist or vapor exceeds applicable PEL/TLV limits. Use in accordance with manufacturer's use suggestions & OSHA standard SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM COLOR ODOR BOILING POINT MELT POINT FREEZE POINT PH SOLUBILITY IN WATER SPECIFIC GRAVITY BULK DENSITY % VOLATILE BY WEIGHT VAPOR PRESSURE VAPOR DENSITY watery liquid various colors no discernible odor 212 DEG. F. N/A 32 DEG. F. N/A miscible liquid N/A N/A N/A equiv to water equiv to water SECTION 10 STABILITY: STABILITY AND REACTIVITY stable POLYMERIZATION: INCOMPATIBILITIES: no avoid strong oxidizing agents DECOMPOSITION PRODUCTS: known CONDITIONS TO AVOID: SECTION 11 TOXICOLOGICAL INFORMATION HEALTH EFFECTS: Heated decomposition products may cause eye and respiratory irritation. INHALATION: Not likely to occur; do not spray apply without source of fresh air. SKIN CONTACT: Prolonged liquid contact with skin may cause irritation or redness. EYE CONTACT: Prolonged liquid contact with eyes may cause irritation or redness ING ESTION: No effects known in usual and ordinary uses of product SECTION 12 ECOLOGICAL INFORMATION None likely; Item Numbers: Page 7 of 19

8 Page 8 of 19 MATERIAL SAFETY DATA SHEET - NO. 01AKUA-KOLOR/LIQUID PIGMENT WATER-BASED INKS 4 of 05 SECTION 13 DISPOSAL CONSIDERATIONS: WASTE DISPOSAL METHOD: Dispose of all federal, state paint wastes. systems waste material in accordance with all applicable and local regulations for the disposal of aqueous Do not flush liquid into public sewer or water SECTION 14 TRANSPORTATION INFORMATION: D.O.T. SHIPPING NAME: TECHNICAL SHIPPING NAME: D.O.T. HAZARD CLASS: U.N./N.A. NUMBER PRODUCT RQ (LBS) D.O.T. LABEL D.O.T.PLACARD FREIGHT CLASS BULK FREIGHT CLASS PACKAGE PRODUCT LABEL SECTION 15 OSHA STATUS TSCA STATUS REGULATORY INFORMATION CERCLA REPORTABLE QUANTITY SARA TITLE III: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES SECTION 311/312 HAZARD CATEGORIES SECTION 313 TOXIC CHEMICALS RCRA STATUS No lead content based on lead test. Other metals have not been tested but do not contain RCRA metals beyond trace quantities and will not exceed TCLP limits STATE REGULATORY INFO COMPONENT NAME & CAS NUMBER CONCENTRATION STATE CODE FHSA STATUS Conforms to ASTM D-4236, LHAMA and FHSA. 16 CFR Item Numbers: Page 8 of 19

9 Page 9 of 19 MATERIAL SAFETY DATA SHEET - NO. 01 AKUA-KOLOR/LIQUID PIGMENT WATER-BASED INKS 5 of 05 ASTM D-4236 STATUS Conforms to ASTM D-4236 SECTION 16 OTHER INFORMATION REASON FOR ISSUE: PREPARED BY: APPROVED BY: TITLE: APPROVAL DATE SUPERCEDES DATE: MSDS NUMBER: RCRA statement Environmental Medicine Incorporated Rudolph J. Jaeger, PhD, DABT, REA President and Principal Scientist 03/31/08 02/15/00 01 MSDS SUMMARY OF CHANGES:... This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Speedball Art Products and The data on this sheet related only to the specific material designated herein. Speedball Art Products and In assumes no legal responsibility f. ọṛ. ụṣẹ. ọṛ. ṛẹḷịạṇc. ẹ. ụp. ọṇ. ṭḥẹṣẹ. ḍạṭạ REVISION DATE 05/06/13 Item Numbers: Page 9 of 19

10 Page 10 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA INTAGLIO - WATER BASED INKS 1 OF 5 DATE PREPARED 02/26/2002 DATE REVISED May 6, 2013 fcmaster1 SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME PRODUCT CODE CHEMICAL FAMILY CHEMICAL NAME FORMULA MANUFACTURER NAME ADDRESS CITY, STATE, ZIP CONTACT PERSON: TITLE INFORMATION TEL: EMERGENCY TEL: CHEMTREC TEL: AKUA INTAGLIO- WATER BASED INKS / AKUA TRANSPARENT BASE / AKUA RELEASE AGENT / AKUA MAG MIX Speedball Art Products 2301 Speedball Road Statesville NC Bud Martin Director of R & D N/A USA cc SECTION 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredient Listing CAS No. OSHA PEL ACGIH TLV STEL % COMP PROPRIETARY INGRED N/L N/L N/L The proprietary ingredients in this product are judged to be non-hazardous and are regarded as trade secrets. SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Non hazardous material PHYSICAL DESCRIPTION: Paste or thick liquid MAJOR HEALTH HAZARDS: None for the usual and ordinary uses of product PHYSICAL HAZARDS: None for the usual and ordinary uses of product ROUTES OF ENTRY: INHALATION no SKIN no EYE INGESTION no POTENTIAL HEALTH EFFECTS: None known for usual and ordinary uses of product. INHALATION: SKIN CONTACT: EYE CONTACT: INGESTION: CARCINOGEN STATUS: NTP not listed IARC not listed OSHA not listed Item Numbers: Page 10 of 19

11 Page 11 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA INTAGLIO - WATER BASED INKS 2 OF 5 MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: SECTION 4 FIRST AID MEASURES EYES: Eye contact: carefully flush for 15 minutes. If irritation occurs, contact a physician. SKIN: Wash with soap and water INHALATION: Not likely to occur; seek fresh air INGESTION: Drink water or milk to dilute. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: None FIRE AND EXPLOSION HAZARDS: None EXTINGUISHING MEDIA: Water, foam, carbon dioxide or dry chemical SPECIAL FIRE FIGHTING PROCEDURES: None required for this material. SECTION 6 ACCIDENTAL RELEASE MEASURES SPILL/LEAK Wash area with soap and water. PROCEDURES SECTION 7 HANDLING AND STORAGE STORAGE TEMPERATURE Store at 70 deg F. (min/max) SHELF LIFE: Not determined (Min 50 deg F Max 100 deg F.) SPECIAL SENSITIVITY: None likely or known HANDLING AND STORAGE:For personal protection and hygiene, wash thoroughly after handling. Wash before eating, smoking or using toilet facilities. Store in a tightly closed container. Store in a cool, dry, place. PRECAUTIONS: Avoid eye & skin contact. Keep container closed when in use and upright to prevent leakage. SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS: None known Item Numbers: Page 11 of 19

12 Page 12 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA INTAGLIO - WATER BASED INKS 3 OF 5 EYE PROTECTION: Wear splash goggles where spills or splashing may occur. SKIN PROTECTION: RESPIRATORY AND VENTILATION: Not required. Not required. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM COLOR ODOR BOILING POINT MELT POINT FREEZE POINT PH SOLUBILITY IN WATER SPECIFIC GRAVITY BULK DENSITY % VOLATILE BY WEIGHT VAPOR PRESSURE VAPOR DENSITY paste or thick liquid various colors no descernible odor 212 deg F 32 deg F. miscible SECTION 10 STABILITY: STABILITY AND REACTIVITY stable POLYMERIZATION: INCOMPATIBILITIES: no known DECOMPOSITION PRODUCTS: known CONDITIONS TO AVOID: SECTION 11 TOXICOLOGICAL INFORMATION HEALTH EFFECTS: INHALATION: SKIN CONTACT: EYE CONTACT: INGESTION: Heated decomposition products may cause eye and respiratory irritation. Not likely to occur; do not spray apply without source of fresh air. Prolonged liquid contact with skin may cause irritation or redness. Prolonged liquid contact with eyes may cause irritation or redness. No effect s known in usual and ordinary uses of product SECTION 12 ECOLOGICAL INFORMATION Item Numbers: Page 12 of 19

13 Page 13 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA INTAGLIO - WATER BASED INKS 4 OF 5 None likely; SECTION 13 DISPOSAL CONSIDERATIONS: WASTE DISPOSAL METHOD: Dispose of all waste material in accordance with all applicable federal, state and local regulations. SECTION 14 TRANSPORTATION INFORMATION: D.O.T. SHIPPING NAME: TECHNICAL SHIPPING NAME: D.O.T. HAZARD CLASS: U.N./N.A. NUMBER PRODUCT RQ (LBS) D.O.T. LABEL D.O.T.PLACARD FREIGHT CLASS BULK FREIGHT CLASS PACKAGE PRODUCT LABEL SECTION 15 OSHA STATUS TSCA STATUS REGULATORY INFORMATION CERCLA REPORTABLE QUANTITY SARA TITLE III: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES SECTION 311/312 HAZARD CATEGORIES SECTION 313 TOXIC CHEMICALS RCRA STATUS STATE REGULATORY INFORMATION No lead content based on lead test. Other metals have not been tested but do not contain RCRA metals beyond trace quantities and will not exceed TCLP limits. COMPONENT NAME & CAS NUMBER CONCENTRATION STATE CODE Item Numbers: Page 13 of 19

14 Page 14 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA INTAGLIO - WATER BASED INKS 5 OF 5 FHSA STATUS Conforms to ASTM D-4236, LHAMA AND FHSA 16 CFR ASTM D-4236 STATUS Conforms to ASTM D-4236 SECTION 16 OTHER INFORMATION REASON FOR ISSUE: PREPARED BY: APPROVED BY: TITLE: APPROVAL DATE SUPERCEDES DATE: MSDS NUMBER: RCRA statement Environmental Medicine Incorporated Rudolph J. Jaeger, PhD, DABT, REA (California) President and Principal Scientist 03/31/ /27/ MSDS SUMMARY OF CHANGES: N/A This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Speedball Art Products and The data on this sheet related only to the specific material designated herein. Speedball Art Products and In assumes no legal responsibility f. ọṛ. ụṣẹ. ọṛ. ṛẹḷịạṇc. ẹ. ụp. ọṇ. ṭḥẹṣẹ. ḍạṭạ REVISION DATE 05/06/2013 Item Numbers: Page 14 of 19

15 Page 15 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA LIQUID PIGMENT BLENDING MEDIUM 1 OF 5 DATE PREPARED 05/29/2013 DATE REVISED SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME PRODUCT CODE CHEMICAL FAMILY CHEMICAL NAME FORMULA MANUFACTURER NAME ADDRESS CITY, STATE, ZIP CONTACT PERSON: TITLE INFORMATION TEL: EMERGENCY TEL: CHEMTREC TEL: AKUA LIQUID PIGMENT BLENDING MEDIUM Speedball Art Products 2301 Speedball Road Statesville NC Bud Martin Director of R & D N/A USA SECTION 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredient Listing CAS No. OSHA PEL ACGIH TLV STEL % COMP PROPRIETARY INGRED The proprietary ingredients in this product are judged to be non-hazardous and are regarded as trade secrets. SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Non hazardous material PHYSICAL DESCRIPTION: Clear liquid MAJOR HEALTH HAZARDS: None for the usual and ordinary uses of product PHYSICAL HAZARDS: None for the usual and ordinary uses of product ROUTES OF ENTRY: INHALATION no SKIN no EYE INGESTION no POTENTIAL HEALTH EFFECTS: None known for usual and ordinary uses of product. INHALATION: SKIN CONTACT: EYE CONTACT: INGESTION: CARCINOGEN STATUS: NTP not listed IARC not listed OSHA not listed Item Numbers: Page 15 of 19

16 Page 16 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA LIQUID PIGMENT BLENDING MEDIUM 2 OF 5 MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: SECTION 4 FIRST AID MEASURES EYES: Eye contact: carefully flush for 15 minutes. If irritation occurs, contact a physician. SKIN: Wash with soap and water INHALATION: Not likely to occur; seek fresh air INGESTION: If large quantity swallowed, give lukewarm water (pint/ ½ litre) if victim completely conscious/alert. Do not induce vomiting. Risk of damage to lungs exceeds poisoning risk. Obtain emergency medical attention. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: 109 C (228.2 F) FIRE AND EXPLOSION HAZARDS: None EXTINGUISHING MEDIA: Water, f o g, foam, carbon dioxide or dry chemical; do not use direct water stream SPECIAL FIRE FIGHTING PROCEDURES: None required for this material. SECTION 6 ACCIDENTAL RELEASE MEASURES SPILL/LEAK Wash area with soap and water. PROCEDURES SECTION 7 HANDLING AND STORAGE STORAGE TEMPERATURE Store at 70 deg F. (min/max) SHELF LIFE: 24 months (Min 50 deg F Max 100 deg F.) SPECIAL SENSITIVITY: None likely or known HANDLING AND STORAGE: For personal protection and hygiene, wash thoroughly after handling. Wash before eating, smoking or using toilet facilities. Store in a tightly closed container. Store in a cool, dry, place. PRECAUTIONS: Avoid eye & skin contact. Keep container closed when in use and upright to prevent leakage. SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS: None known Item Numbers: Page 16 of 19

17 Page 17 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA LIQUID PIGMENT BLENDING MEDIUM 3 OF 5 EYE PROTECTION: Wear splash goggles where spills or splashing may occur. SKIN PROTECTION: RESPIRATORY AND VENTILATION: Not required. Not required. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM COLOR ODOR BOILING POINT MELT POINT FREEZE POINT PH SOLUBILITY IN WATER SPECIFIC GRAVITY BULK DENSITY % VOLATILE BY WEIGHT VAPOR PRESSURE VAPOR DENSITY Clear liquid colorless no descernible odor 370 deg F -76 deg F miscible SECTION 10 STABILITY: STABILITY AND REACTIVITY stable POLYMERIZATION: INCOMPATIBILITIES: no known DECOMPOSITION PRODUCTS: carbon monoxide and other toxic vapors CONDITIONS TO AVOID: SECTION 11 TOXICOLOGICAL INFORMATION HEALTH EFFECTS: INHALATION: SKIN CONTACT: EYE CONTACT: INGESTION: Heated decomposition products may cause eye and respiratory irritation. Not likely to occur; do not spray apply without source of fresh air. Prolonged liquid contact with skin may cause irritation or redness. Prolonged liquid contact with eyes may cause irritation or redness. No effect s known in usual and ordinary uses of product SECTION 12 ECOLOGICAL INFORMATION Item Numbers: Page 17 of 19

18 Page 18 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA LIQUID PIGMENT BLENDING MEDIUM 4 OF 5 Non-hazardous to aquatic species SECTION 13 DISPOSAL CONSIDERATIONS: WASTE DISPOSAL METHOD: Dispose of all waste material in accordance with all applicable federal, state and local regulations. SECTION 14 TRANSPORTATION INFORMATION: D.O.T. SHIPPING NAME: TECHNICAL SHIPPING NAME: D.O.T. HAZARD CLASS: U.N./N.A. NUMBER PRODUCT RQ (LBS) D.O.T. LABEL D.O.T.PLACARD FREIGHT CLASS BULK FREIGHT CLASS PACKAGE PRODUCT LABEL SECTION 15 OSHA STATUS TSCA STATUS REGULATORY INFORMATION CERCLA REPORTABLE QUANTITY SARA TITLE III: SECTION 302 EXTREMELY HAZARDOUS not regulated SUBSTANCES SECTION 311/312 HAZARD CATEGORIES SECTION 313 TOXIC CHEMICALS RCRA STATUS STATE REGULATORY INFORMATION No lead content based on lead test. Other metals have not been tested but do not contain RCRA metals beyond trace quantities and will not exceed TCLP limits. COMPONENT NAME & CAS NUMBER CONCENTRATION STATE CODE Item Numbers: Page 18 of 19

19 Page 19 of 19 MATERIAL SAFETY DATA SHEET - NO 01 AKUA LIQUID PIGMENT BLENDING MEDIUM 5 OF 5 FHSA STATUS Conforms to ASTM D-4236, LHAMA AND FHSA 16 CFR ASTM D-4236 STATUS Conforms to ASTM D-4236 SECTION 16 OTHER INFORMATION REASON FOR ISSUE: PREPARED BY: APPROVED BY: TITLE: APPROVAL DATE SUPERCEDES DATE: MSDS NUMBER: RCRA statement Bud Martin Bud Martin Director of R & D 05/29/ MSDS SUMMARY OF CHANGES: N/A This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Speedball Art Products and The data on this sheet related only to the specific material designated herein. Speedball Art Products and In assumes no legal responsibility f. ọṛ. ụṣẹ. ọṛ. ṛẹḷịạṇc. ẹ. ụp. ọṇ. ṭḥẹṣẹ. ḍạṭạ REVISION DATE 05/29/2013 Item Numbers: Page 19 of 19

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