SUNJIN Catalog2 Micro Beads SINCE 1978

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1 SUNJIN Catalog2 Micro Beads SINCE 1978 THE 10 TH Edition 2 SUNJIN members 3 Company Overview 4 Micro Beads for Skin Care (1) Polymer Beads 6 How to measure softness & elasticity of Micro Beads? 7 Urethane Bead 10 EPU-2X: The most compressible Urethane Acrylate Bead (2) Fusion Powders 37 Fusion Cosmetics: Cross over between skin care and make-ups 39 FP powders FP-Glycerin Active Ingredient Loaded PMMA 19 EPU40 Plus: Soft & Spreadable Urethane Acrylate Bead + Silica 22 SUNPMMA-Plus 24 SUNPMMA-S 27 Porous PMMA Beads 33 Hemi-spherical PMMA SUNPMMA-X (3) Silica Beads 43 Silica Bead Surface Treated Silica Bead 46 Silica Bead for Skin Care : Thickener compatible (4) Soft Focus Agent 48 SH219 : High Refractive Index Bead (5) Instant Whitening Agent 53 SUNSIL T in NaturalWhite(CO) TiO 2 containing Silica Bead April 2012 (6) Skin Brightener 57 JH-Series PMMA coated Pearl Satin Pearl for Skin Care

2 SUNJIN MEMBERS in 2012 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 2

3 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 3 INTRODUCTION COMPANY OVERVIEW TECHNOLOGY OVERVIEW Founded in 1978 Headquartered in Korea Product Category: Cosmetic Raw Materials, Surfactants, Micro bead synthesis Nano powder synthesis Encapsulation & Composition hollow porous nano & micro encapsulation nano & micro Paint & Coating Raw Materials, Plastic, Surface treatment solid Optical Materials ISO 9001 certified Dispersion Organic synthesis Triple composition SUNJIN brings new concepts & new technologies From other industries TO COSMETICS Paint & coating Flat Panel Display: LCD, PDP Plastic

4 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 4 Micro Beads are commonly used in Skin Cares, Why? If you don t use micro beads, Then Cosmetic texture may be too tacky & oily 1) Sensorial Modification Reduce too much tackiness Modification of Texture Elegant feeling Micro Beads can alter tactile qualities of a cosmetic: initial contact, application, after feel 2) Optical Effects Soft Focus effect, optical blurring Matte look 3) Absorption, Release & Delivery Sebum, oil absorption Slow release Loading active ingredients

5 SUNPU-170: Urethane Bead Most Elastic Polymer Bead Cushion Feel Elegant Touch Skin Care for Anti Wrinkle

6 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 6 How to measure SOFTNESS and ELASTICITY of Micro Beads? K value: Measurement of Softness 925 Recovery Rate: Measurement of Elasticity K value Recovery Rate K = (3/2 1/2 )(F)(S -3/2 )(R -1/2 ) S: Sample displacement R: Sample radius One particle of each powder type was exposed to compression. Pressure necessary for 10% deformation of the particle was measured. (Measuring Tool: Shimadzu Micro Compression Testing Machine MCTM-500) The lower K value, the softer Elastic 37.5% The higher recovery rate value, the more elastic Soft Not Elastic 6.0% 8.71% 0% 0% 0% 0% 0%

7 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 7 SUNPU-170, Elastic & Soft Urethane bead Grade Descriptions Avg. Particle size( μm ) Hardness SUNPU-170 Urethane bead 14~20 soft Chemical Name: Hexamethylene Diisocyanate/Trimethylol Hexyllactone Crosspolymer & Silica K value: Softness INCI Name: HDI/Trimethylol Hexyllactone Crosspolymer & Silica Best recommend for SKIN CARE (1) Anti Wrinkle Cream Instantly see up to a 29% reduction in fine, dry lines. Skin is luminous. (2) Eye Care Cream The density, elasticity and firmness of your skin are preserved Fine lines are smoothed out Recovery Rate: Elasticity 0% 0% 37.5% 6.0% 0% 8.71% 0% (3) Moisturizing Lotion ELASTICITY gives moisturizing feel Skin is left feeling velvety smooth (4) Night Cream An intensive action cream, developed to meet the special needs of the skin at night, The density, elasticity and firmness of your skin are preserved Fine lines are smoothed out

8 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 8 Application of Elastic Urethane Bead: Skin Care SJF-0811-Anti Wrinkle Cream-ver.1.0 Urethane Bead is an excellent choice for skin care application due to its unique optical blurring effect and elegant texture Phase No. Trade Name INCI Name % A B 1 D.I. Water Water Adenosine Adenosine Glycerin Glycerin 4 4 KF6100 Polyglyceryl-3Disiloxane Dimethicone Phenoxy Ethanol Phenoxy Ethanol TSF405 Cyclopentasiloxane KSG16 Dimethicone/Vinyl Dimethicone Crosspolymer 26 C 8 Sepigel305 Polyacrylamide/C13-C14 Isoparaffin/Laureth D 9 Tocopheryl Acetate E 10 SUNPU-170 Tocopheryl Acetate 0.2 HDI/Trimethylol Hexyllactone Crosspolymer /Silica 20 Elegant & Elastic Luxurious Texture

9 EPU-2X: Urethane Acrylate Bead The most compressible Micro Bead As compressible as Talc For Eye shadows Pressed Powders

10 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 10 EPU-2X: Upgrade of EPU40, 5X more compressible EPU-2X Particle size: 5um Oil absorption: 0.5cc/g K value: Softness INCI Name: HDI/Trimethylol Hexyllactone Crosspolymer & Polymethyl Methacrylate & Silica The most compressible Polymer Bead 5X more than EPU-40 As compressible as Talc Recovery Rate: Elasticity 0% 0% 37.5% 6.0% 0% 8.71% 0%

11 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 11 5X more compressible? 3g of Tested Samples 1. EPU-2X 2. EPU Ethylene copolymer 4. Nylon 12 Powder 5. Urethane Bead 6. PMMA Bead 7. SILICA Bead 8. TALC Pressing Condition Pressure : 70 kg/cm2 Time : 7 sec Drop Test: Height : 1m, 1~15 times Onto cemented floor Evaluation of Compressibility of Micro Beads?

12 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 12 Dropping Test Results 15 Times Drop EPU 2X, Almost as good as Talc! 5 times better than EPU40 in 2010 TALC EPU-2X 3 Times Force Drop Ethylene Copolymer EPU 40 EPU-2X Time passes Pressed pressed 2 Times Drop Force Nylon Silica Hard to be pressed 1 Time Force Drop PMMA Urethane SILICA Urethane Pressed

13 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 13 EPU-2X, Heat Stable EPU-2X Ethylene Copolymer

14 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 14 Applications of EPU-2X 1 Pearl 40% more eye shadow EPU-2X enables you to make an eye shadow with pearlescent 40% inside 2 Talc Free Premium Pressed Powder It s almost impossible to make pressed powders without talc But if you take out talc, the touch of pressed powder will differ remarkably 3 Baked Powder(Terracotta) If your terracotta breaks up too often, you need HEAT STABLE EPU- 2X to improve compressibility of baked powders 4 Less glazing, better pay off Use less metal soap or oil binder, put more EPU-2X Metal soap free or Oil binder free possible

15 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 15 Eye shadow with Pearlescent 40% possible with EPU-2X SJF_1116_EYE SHADOW with pearl (40%)_VER1.0 Dropping Test Result Trade Name #1 #2 #3 #4 #1 #2 #3 #4 SUNTALC-LL SUNMICA-LL SUNSERI-LL A SUNSIL Aluminum Stearate PMMA-S EPU-2X PMMA-S Ethylene Copolymer Drop Once fail Ethylene Copolymer Yellow # B Ultra marine blue RED CLOISONNE RED FLAMENCO ULTRA SPAKLE FLAMENCO SATINA EPU-2X Drop 7 Times OK Drop 3 Times fail Metal soap Drop 7 Times OK but FLAMENCO RED C DC 200F/100cs Preservatives Total Pearl 40% inside, visually very attractive Excellent compressibility Excellent Pay Off Commercially not valuable because Too Soapy Bad pay off

16 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 16 Talc Free PREMIUM Pressed Powders Customer Needs Why Talc Free Make up? Talc Free means premium with unique texture Most pressed powders in the market have talc by more than 40% So if you use talc, it s very difficult to differentiate the texture of pressed powders So premium pressed powders frequently do not incorporate talc to differentiate texture Problems However, Going Talc Free is not easy, especially for pressed powders Because Without talc, it s very difficult to compress powders Generally speaking, No Talc, No Compressibility So you need very compressible micro beads Solution from SUNJIN But, SUNJIN proposes a solution for Talc Free Make-ups EPU-2X: very Compressible, Very Soft & Creamy

17 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 17 EPU-2X for Talc Free PREMIUM Pressed Powder SJF Talc Free PREMIUM pressed powder-ver 1.0 Trade Name % Magnesium Myristate 8.0 BORONEIGE 602-DMC3 8.0 SUNSERI-LL(P) 30.3 SUNMICA-LL 10.0 A B SUNSIL 130SC 3.0 EPU-2X 20.0 SUNTITAN-LL 7.0 SUNIOR-AS 0.3 SUNIOB-AS 0.1 SUNIOY-AS 1.3 DC-200F-100cs 6.0 DC-200F-10cs 6.0 Talc free formula. EPU-2X is very compressible powder. It gives good spread & softness. LL-coated Fillers are skin-friendly materials. moist feeling & fitness to skin

18 EPU40 Plus: Urethane Acrylate Bead Soft & Spreadable

19 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 19 EPU40 Plus EPU40 Plus Particle size: 7um K value: Softness INCI Name: HDI/Trimethylol Hexyllactone Crosspolymer & Silica Spread Improved Polymer Bead Recovery Rate: Elasticity 0% 0% 37.5% 6.0% 0% 8.71% 0%

20 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 20 EPU40 Plus, a new release in 2011 EPU40 Particle Size: 7um INCI: Urethane Acrylate Bead EPU40 Plus Particle Size: 7um INCI: Urethane Acrylate Bead/ Silica Much Better Spread Skin Adhesion

21 SUNPMMA-Plus: PMMA Bead Much Better Spread

22 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 22 SUNPMMA-Plus, 13um, a new release in 2011 SUNPMMA-S Particle Size: 7um Oil Absorption: 0.45cc/g INCI: Polymethyl methacrylate SUNPMMA-Plus Particle Size: 13um Oil Absorption: 0.45cc/g INCI: Polymethyl methacrylate More Even Spread on skin More Silky

23 SUNPMMA-S: PMMA Bead Classic PMMA Bead

24 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 24 SUNPMMA-S No residual monomer(i.e. no odor), pharmaceutical grade by FDA regulation Grade Descriptions Avg. Particle size( μm ) Oil Absorption (cc/g) SUNPMMA-S PMMA bead 7 0.4~0.6 Remark 1) PMMA-S is PURE & SAFE, of no residual monomer Product MMA content EGDMA content Bad Odor Feel Chemical Resistance Particle size Product "J" 144 ppm 0 ppm Strong Fair Good 7.8 Product "MM" 342ppm n.a. Strong Fair n.a 4.3 Product "M" 44 ppm 0 ppm Little Good Bad 7.0 Product "A" 37 ppm 14 ppm None SUNJIN Lot: ppm 0 ppm None Good Good 8.2 Lot: ppm 0 ppm None Good Good 8.0 Lot: ppm 0 ppm None Good Good 8.3 Chemical Name :Polymethyl Methacrylate 2) PMMA-S is PRICE competitive INCI Name :Polymethyl Methacrylate CAS No. : Custom Tariff No. :

25 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 25 SUNPMMA-Series are the most Economic sensory modifier for Mass Brands Best recommend for (1) W/O emulsion Liquid foundation, skin cover Slightly hydrophobic surface, especially suitable for W/Si or W/O formula such as liquid foundation or sun block lotions (2)O/W emulsion, especially for dry skin As for O/W formula, great formula stability due to lack of interaction with polymeric thickeners(i.e. PMMA bead is polymer so contains no metal ions inside) PMMA bead is not porous so can t absorb moisture on skin. Good for skin cares for dry skin (3) Mass sun care products Good price for mass sun care products Good for O/W sun care, great formula stability due to lack of interaction with polymeric thickeners(i.e. PMMA bead is polymer so contains no metal ions inside) Good for W/O sun care due to slightly hydrophobic surface so easily compatible with W/Si or W/O formula

26 Porous PMMA Beads Selective Sebum Absorption For Men s care For premium pressed powders

27 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 27 SUNJIN offers various grades of POROUS PMMA BEADS Grade INCI Avg. Particle size( μm ) Oil Absorption (cc/g) COCO170, the best feel & Spread among porous PMMA Beads SUNPMMA-COCO130 SUNPMMA-COCO170 Methyl Methacrylate Cross Polymer Methyl Methacrylate Cross Polymer 8 1.2~ ~1.8 SUNPMMA-P Methyl Methacrylate Cross Polymer 8 1.7~2.1 SUNPMMA-PH Methyl Methacrylate Cross Polymer 8 2.1~2.4 Porous PMMA

28 Porous Silica Porous PMMA Pressed Powder with POROUS PMMA WATER D5 LP 3min SJF-0809-Powdery Pressed Powder-ver.1.1 Phase No. Trade Name % 1 SUNTALC-LL HOLLOW PMMA SUNPMMA-H 2 SUNMICA-LL 9.90 Porous PMMA, especially good for pressed powder for excellent feel and spread without skin dryness 3 SH 219 AS 6.93 Porous PMMA does not absorb water A 4 SUNPMMA-P SUNSERI-LL SUNTITAN-LL 6.93 Best recommend for 7 Magnesium Myristate 2.97 (1)Pressed powder WATER D5 LP 3min B 8 SUNIOR-AS SUNIOY-AS SUNIOB-AS Phenoxy Ethanol 0.16 Porous PMMA selectively absorbs oils So it is very good for transparent powdery make up which has sebumabsorbing-long -lasting effect without making skin too dry C 12 DC-200 F-100CS DC Absorbing water & oil very fast Making skin feel dry 14 Fragrance 0.10 D5:Cyclomethicone LP: Liquid Paraffin Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 28

29 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 29 Porous PMMA Beads are of good Media Dispersibility Water/EtOH dispersible porous PMMA Best recommend for (1)Spray products Powder 10%, EtOH 10%, Water 80% 3 Month Later, upside down test Urethane Bead A No Good 2. Urethane Bead B No Good 3. COCO 130(porous) Good 4. Nylon 12 Powder No Good 5. SUSNIL 130NP O.K. 6. SUNPU170 No Good 7. SUNPMMA-S No Good 8. SUNPMMA-PH (porous) Good 9. PE Bead No Good 10. SUNSIL 130H No Good 11. SUNPMMA-P(porous) Good 12. SUNSIL 130 No Good (2)Shaking products Porous PMMA Beads have shown excellent re-dispersibility Skin toner

30 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 30 The best combination for PREMIUM Pressed Powder: EPU-2X + COCO170 Evaluation of Micro Beads for Make-ups Micro Beads Size (um) Oil absorption (cc/g) Compressibility Cushion & Soft Pay Off Skin Adhesion Spread EPU -2X Hybrid ABOC SUNSIL-130L SUNSIL-130LSC COCO170+1,3BG (6:4) PMMA-S PU SUNPMMA-COCO How to make PREMIUM pressed powder? NO TALC Instead Sericite, Boron Nitride, EPU-2X & SUNPMMA-COCO170 SUNSERI-LL(P): Premium Sericite from SUNJIN EPU-2X COCO170 is excellent for pay-off, skin adhesion & spread but not good for compressibility

31 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 31 How to make BB(Blemish Balm) Cream? Challenges in BB cream SJF-1104-Non nano BB Cream-ver2.0 SJF-1117 ZnO Free BB Cream-ver2.0 Normally BB cream formulation is made up of high portion of powders for coverage and silicone oils for light feel Often there may be not be enough polar emollients to solubilize BEMT or BMDBM Phase Ingredients % T-80AS 10.0 SUNTITAN-LL 3.0 SUNPMMA COCO A SUNIOY-AS 0.9 SUNIOR-AS 0.35 SUNIOB-AS 0.1 TEGOSOFT DEC 3.0 In vivo SPF35, PA++ Phase Ingredients % Hybrid Talc(DM) 25.0 SUNTITAN-LL 5.0 A SUNSIL-Tin50AS 2.0 SUNIOY-AS 0.9 SUNIOR-AS 0.3 SUNIOB-AS 0.1 TESGSOFT DEC 3.0 Bentone 38 VCG 0.2 In vivo SPF35, PA++ So it would be difficult to achieve PA+++ without ZnO B Bentone 38 V CG 0.2 DC Parsol MCX 6.0 Abil EM KSG CETIOL CC 2.0 B DC Parsol MCX 6.0 ABIL EM KSG Cetiol CC 2.0 SALACOS KF SALACOS D.I-Water 31.0 KF C 1,3-BG 7.0 D.I. Water NaCl 1.0 C 1,3-BG 7.0 NaCl 1.0 D Phenoxy Ethanol 0.3 Fragrance 0.2 D Phenoxy Ethanol 0.3 Fragrance 0.2

32 SUNPMMA-X: Hemispherical PMMA Bead Cushion Feel Rolling & Skin Adhesion Great pay off Unique Feel & Touch for Make up For premium pressed powders

33 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 33 SUNPMMA-X: Hemi-spherical PMMA Particle size: 9um Oil absorption: 2.9~3.3cc/g INCI: Methyl Methacrylate Crosspolymer Cushion Feel Rolling & Skin Adhesion Great pay off Excellent spread

34 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 34 Pressed Powder with 5% of SUNPMMA-X SJF-1105-Silky Pressed Powder-ver1.0 PRODUCT NAME #1 #2 SUNPMMA-X SUNPMMA-S SUNTALC-AS SUNSERI-AS #1 #2 A SUNMICA-AS SUNTITAN-AS B Aluminum Stearate SUNIOR-AS SUNIOB-AS SUNIOY-AS DC-200F-100cs DC-200F-10cs total 100% 100% Do you feel the difference?

35 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 35 The Differences 1. Cushion Feel 2. Rolling & Adhesion 3. Double Pay off by hemi-spherical shape 4. 6X Pay off by Bulky nature of PMMA-X 5. Better Compressibility due to hemi-spherical shape

36 Fusion Powders Color Cosmetics with Skin Care Efficacy

37 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 37 What is Fusion Cosmetics? Moisturizing Water Glycerin, PG, BG in Water Chitosan in Water Glucan in Water Hyaluronic Acid in Water SUNJIN proposes FUSION cosmetics as a crossover between skin cares and make-ups Fusion make-ups have skin care functions inside Various actives can be loaded in porous PMMA Porous PMMA is a good carrier for its inert nature(no metal ions, no active functional groups) Whitening Arbutin in Water Ascorbic Acid Derivatives Oil-soluble licorice extract Broussonetia Extract Powder Actives loaded in Porous PMMA As a carrier Color Cosmetics with Skin Care Functions inside Anti Wrinkle Adenosine Retinol or Retinol Palmitate Anti Acne Azelaic Acid Tea-Tree Oil Triclosan Porous PMMA containing actives : still very powdery POROUS PMMA CAN LOAD ACTIVES by MORE THAN 40% OF ITS WEIGHT Moisturizing Makeup Moisturizing Lip stick Whitening Powder Makeup Anti inflammatory Portulaca extract Dipotassium glycyrrhezinate Anti Atophy Camellia oil Ceramide-3 FUSION, originates from a Latin word, fuse (mix). It means harmonizing by combining more than two things

38 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 38 FP POWDERS are Porous PMMA with Actives loaded inside Grade INCI Name & composition FP-GLYCERIN Methyl methacrylate crosspolymer 65% Glycerin 35% FP-COLLAGEN Methyl methacrylate crosspolymer 60% Liquefied collagen 40% FP-MENTHOL Methyl methacrylate crosspolymer 80% L-menthol 20% FP-OMC Methyl methacrylate crosspolymer 60% Ethyl hexyl methoxycinnamate 40% FP-ADENOSINE Methyl methacrylate crosspolymer 60% Adenosine 1% Water 39% Why Porous PMMA is better than Porous Silica as an active carrier? Avg. Particle size( μm ) EFFECT & APPLICATION 8 Moisturizing make up, Moisture retention 8 Collagen providing 8 Cooling agent 8 UV protecting High SPF sun care products 8 Anti wrinkle make up Fusion Powders (FP) are Porous highly crosslinked so are insoluble, inert, and of PMMA sufficient strength to stand up to the high shear commonly used in manufacturing of creams, lotions, and powders FPs are spherical PMMA polymer particles which can entrap a wide variety of substances and can be incorporated into a formulation FPs have the capacity to adsorb or load a high degree of active materials into the particle Allow a sustained rate of release of the active ingredients to skin over time This sustained release of actives is an extremely valuable tool to extend the efficacy and lessen the irritation Porous Silica is inorganic so has metal ions inside Porous PMMA is a kind of plastic so has no metals or ions inside Thus porous PMMA is an inert carrier for actives or fragrances which are susceptible for chemical degradation catalyzed by metallic ions FPs are spherical and rigid so enhances the skin feel and elegance of creams and lotions

39 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 39 Applications of FP-Glycerin: Super Moisture Pressed Powder SJF-1107-Super Moisture Pressed Powder-ver1.1 Phase Trade Name % SUNTALC-LL SUNMICA-LL EPU Net Glycerin 5.6% inside formula 16% of FP-Glycerin (Glycerin 35% inside) Water soluble actives can loaded in this formula A FP-GLYCERIN BN powder 3.00 SUNSERI-LL (P) 5.00 SUNTITAN-AS 7.00 Magnesium Myristate 3.00 You can feel the difference! B C SUNIOR-AS 0.60 SUNIOY-AS 1.20 SUNIOB-AS 0.05 Phenoxy Ethanol 0.20 DC-200 F-100CS 7.50 DC Fragrance 0.10 FP-GLYCERIN contains 35% humectants unlike water, Glycerin does not evaporate. So you can easily make Long Lasting Moisturizing formula. It is good for dry skin.

40 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 40 Moisturizing White Part of Skin Cover Brown Part: Make up, skin cover White Part: Skin Care, Whitening Essence You can easily make White Moisturizing Part by incorporating FP-AQUA into waxy oil phase SJF Moisturizing Skin Cover White part-ver1.0 Phase Trade Name % A SUNTITAN - AS 10.0 FP- AQUA 20.0 Formula with Water 8% (=20% * 40%) Long-lasting moisturizing formula as water hardly evaporate (water trapped inside porous PMMA which is again entrapped by waxy mixture) You can make white part not by emulsion but by simple mixing Additives or water soluble actives can loaded in this formula B Candellila wax 8.0 Carnauba wax 1.0 Cosmol 168AR 4.0 Rhedol AO Crodamol TN 16.0 COGNIS SENSOFT 26.9 Cosmol Isononyl isononanoate 5.0 Waglinol MCT 5.0 VIT.E ACETATE 0.10

41 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 41 SUN PROTECT GEL, by using FP-OMC Sun Protect Gel Super light, Very translucent Aristoflex AVC used to thicken water phase No shine, No white casts, No oiliness, No stickiness, nothing! SJF-0905-SUN PROTECT GEL-ver1.0 A B C Trade Name INCI Name % PARSOL EHS Ethylhexyl Salicylate 3.0 PARSOL MCX Ethylhexyl Methoxy cinnamate 3.6 FP-OMC (SUNJIN) HYBRID ABOC (SUNJIN) Methylmethacrylate Crosspolymer & Ethylhexyl Methoxy cinnamate In vivo SPF 21.8, PA 5.0 (++) Polymethyl Methacrylate / Avo Benzone / Octocrylene 3.0 1,3-B.G. 1,3-Butylene Glycol 10.0 D.I. WATER Water ARISTIFLEX AVC Ammonium Acryloyldimethyltaurate / VP Copolymer % Hybrid ABOC provides PA++ No emulsifier No emulsion Process used So translucent Applicable to Skin care formula D FRAGRANCE Fragrance 0.15 Liquid Chemical Filter= 3.0% +3.6% +2.4%(6.0%*40%) =9.0%

42 Silica Beads Natural Bead(ECOCERT) Sensorial Modifier

43 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 43 Silica Beads, SUNSIL series SUNSIL 130 series approved by ECOCERT, Natural Origin Silica Beads Untreated Porous SILICA BEADS Grade Descriptions Avg. Particle size( μm ) Oil Absorption(c c/g) SUNSIL 20 Porous Silica 2 0.9~1.3 SUNSIL 130L Porous Silica 7 0.6~0.9 SUNSIL 130 Porous Silica 7 0.9~1.3 SUNSIL 130H Porous Silica 7 1.3~1.7 SUNSIL 130SH Porous Silica 7 2.1~2.6 SUNSIL 150H Porous Silica ~2.1 Marketing claims of silica beads: Natural Finish Matting Less Oily Not Greasy Powdery Non-Transfer Extra Wear Smooth Full Extension Curving for Mascara Non Porous SILICA BEAD Grade Descriptions size( μm ) (cc/g) SUNSIL 130NP Non Porous Silica 7 0.3~0.6 Very price affordable, only a few $ more expensive than the untreated silica beads Methicone Coated SILICA BEADS Grade Descriptions size( μm ) (cc/g) SUNSIL 130LSC Hydrophobic Silica 6~9 0.6~0.9 SUNSIL 130SC Hydrophobic Silica 6~9 0.9~1.3 SUNSIL 130HSC Hydrophobic Silica 6~9 1.1~1.7 SUNSIL 150HSC Hydrophobic Silica 10~15 1.2~2.0 Hydrophobical coating improves Better Skin adhesion, Better skin spread Better tactile properties More compatiable with oily binder Ease of press Reduce breakage by drop Long lasting

44 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 44 Silica Bead, Natural Micro Bead Customer Needs (1) silica beads seems to disturb viscosity build up of thickeners. Do you have silica beads for o/w skin cares? (2) Polymer micro beads are synthetic. Do you have any natural & ECOCERT grade micro bead? Customers becoming label savvy! Silica, Natural Micro Bead While PMMA bead Nylon bead Urethane bead Silicone bead PE bead Are synthetic, can not be natural micro bead

45 Viscosity Viscosity Viscosity Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 45 Silica Beads for Skin Care Solution from SUNJIN SUNJIN provides Thickener SJF-0805-Sebum compatible Natural Control Silica Essence-ver.1.0 Beads for skin care SJF-0805-Sebum Control Essence_ver1.0 Phase No. Trade Name % 1 DI-Water ,3-B.G A 3 ALLANTOIN ) CARBOPOL 940 2) Sepigel 305 3) ARISTOFLEX AVC 4 TEA ,000 10,500 44,000 45,000 16,000 17,300 5 ARLATONE RHEODOL MS RHEODOL TW S B 8 LANETTE O EMERSOL % in water neutralized by TEA 1% in water 0.4% in water 10 TSF TEGOSOFT DEC 2.00 C 12 CARBOPOL 940 (1%) % 5% SUNSIL 130 0% 5% 130 added 0% 5% 130 added SUNSIL series are highly purified to remove ionic components and not to disturb polymeric thickeners SUNSIL series are natural, i.e. of ECOCERT approval. Polymeric Micro Beads such as nylon bead, urethane bead, PMMA bead, etc are of synthetic polymeric origin so can not be natural D 13 Sepigel E 14 ARBUTIN D.I.WATER F 16 Sodium Hyaluronate (1%) 1.00 G 17 SUNSIL H 18 Phenoxyethanol 0.5

46 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 46 Silica Beads for Body Lotion SJF-1124-Velvet Feel Body Lotion-ver.1.0 Part Camical Name % D.I-Water 59.2 A Carbopol 940 1% sol Marketing claims of Silica Bead in Body Lotion Velvet Feel B C D Glycerin 10.0 Peaster Myristic Acid 2.0 Arlacel DC 200F/10cs 0.5 Finsolv TN 0.8 Arlacel Lanette O 0.5 Vitamin E Acetate 0.1 D.I-Water 1.0 TEA 0.2 Fragrance 0.2 Opitiphen 0.5 SUNSIL Moisturizing feel, surprisingly silica bead enhance moisturizing feel of body lotion a lot

47 SH219 Soft Focus Agent Efficient Optical Blurring Agent Instant anti-wrinkle effect for Skin care and Base make up

48 High Refractive Index Bead with the refractive index of 1.8 5um Silica With 12nm TiO 2 Grade Composition (Silica/TiO 2 ) Refractive Index Surface treatment Silica Bead size / TiO 2 crystal size 12nm TiO 2 SH219 Silica 75% TiO 2 25% 1.8 none 2~7 μm / 12nm SH219-AS Silica 75% TiO 2 25% 1.8 Alkyl silane 2~7 μm / 12nm Refractive Index Of cosmetic powders : Silicone 1.47: Silica 1.49: PMMA 1.51: Glass, CaCO : Urethane 1.53: Alumina: 1.56: Talc, Mica 1.63: BaSO 4 2% 4% 6% 8% SH219 5% 10% 15% 20% Urethane Bead PU170 Looks like 4% of SH219 SH219 RI = 1.8 4X ~ 6X more efficient soft focusing agent as compared to other micro beads due to its high RI ECOCERT : SH : ZnO 5% 10% Silica Bead: 130L 5% 10% PMMA Bead PMMA-S : TiO 2 anatase 2.7: TiO 2 rutile 15% 15% SH219 20% 20% Looks like 3% of SH219 Looks like 5% of SH219 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 48

49 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 49 Theoretical explanation about why SH219 is such an efficient Optical Blurring Agent Soft focus powder possesses the ability to blur skin troubles such as wrinkles. Wrinkles on the skin are perceptible though the contrast of light and dark that accentuates even very subtle creases. Instead of covering the trouble area by highly opaque materials such as TiO 2, soft focus powder diffuses optical light within the structures. Soft focus powder does not produce whiteness, but rather natural translucent finish Hard Focus Soft Focus Rm: Refractive Index of Media Rp: Refractive Index of Powder Light Scattering Table Based on Refractive Index Fresnel Loss When light rays cross the boundary from one medium t another, there is a loss due to reflection at the boundary, this is called Fresnel loss and is calculated with the following expression Fresnel Loss = 100*(Rm-Rp) 2 /(Rm+Rp) 2 At cyclomethicone 100% formula, SH219 is more effective than silicone bead by 160 TIMES! 160X 22.8X 14.5X 8.8X

50 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 50 Application(1): SH219 for Natural Base Make-up Best recommend for SJF-0801-Primer-ver.1.0 Phase No. Trade Name INCI Name % (1)Base Make-up Natural foundation Thin Liquid foundation A 1 D.I. Water Water Glycerin Glycerin KF6100 Polyglyceryl-3Disiloxane Dimethicone 1.00 B 4 Phenoxyethanol Phenoxyethanol TSF405 Cyclopentasiloxane Light diffusing effect is required for natural base make-up. SH219 is 4~5 times efficient optical blurring agent as compared to normal micro beads So SH219 saves formulation cost and offers more room for formulation freedom (2)Primer Primer Transparent foundation Primer 6 KSG16 Dimethicone/Vinyl Dimethicone Crosspolymer C 7 Sepigel305 Polyacrylamide/C13-C14 Isoparaffin/Laureth-7 D 8 SH219 Silica/ Titanium dioxide 7.50 What is Primer? Foundation primer is a relatively new product offered on the market. It creates a barrier between your skin & the foundation and helps the foundation go on smoothly. it actually works much like a moisturizer under your foundation does: they ease the application of foundation and are meant to create a barrier between foundation and skin. Makeup artists swear primers go one step further than moisturizers: They'll even out skin tone, help your makeup stay on longer Marketing Claims of Primers Going make-up free Skin look smoother and more even-toned on my make-up free days Primer primarily meant to mattify Oil free moisturizer 1.00

51 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 51 Application(2): SH219 for Skin Cares & Lip Stick Best recommend for (3)O/W skin care Anti Wrinkle Cream Eye Care (4)Lip Stick Generally, inorganic white pigments such as titanium dioxide and zinc oxide have been used in foundations and lipsticks to provide good finish. Marketing Claims of Soft Focus in Skin Care wrinkles are diminished the eye area looks visibly younger fine lines are reduced and the eye contour looks visibly younger Light diffusers help hind imperfections immediately and visibly smoothed this daily moisturizing lotion visibly reduces fine lines visibly corrects the first signs of aging Instantly see up to a 29% reduction in fine, dry lines. Skin is luminous The look of lines and wrinkles is significantly reduced But there are several problems, such as it s poor dispersion and uneven application color. the composite of porous spherical silica and titanium dioxide bead, can improve these problems and provide a new make-up result. Mass tone & Skin tone same with use of SH219 Skin tone Mass tone

52 SUNSIL-TinNaturalWhite(CO) Instant Whitening Agent Natural Whiteness & Coverage Instant Whitening for Skin care and Base make up

53 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 53 NaturalWhite Bead for Instant Whiteness for Skin Care & Natural Coverage for Color 5um Silica Bead With 200nm TiO 2 by 35% Grade Descriptions Surface Treatment Avg. Particle size( μm ) SEM picture 200nm TiO 2 SUNSIL-T in NaturalWhite(CO) SUNSIL-T in UVAB 200nm TiO 2 35% & Silica 65% 200nm TiO 2 35% & Silica 65% Hydrogen Dimethicone 5 none 5 TiO 2 TiO 2 TiO 2 Silica Bead TiO 2 NaturalWhite TiO 2 Good spread and feel of Silica Bead + Covering power of pigmentary TiO 2 Opaqueness comparison Silica - Very transparent - No covering power Natural White - Natural white looking - Optimum coverage Natural White = Silica + TiO 2 TiO 2 - Draggy, - Chalky, - Gritty, - Rough

54 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 54 Instant Whitening Effect for Whitening Cream SJF-0804-Whitening Cream-ver 1.1 Phase No. Trade Name % Marketing claims of NaturalWhite Bead in Skin Care A 1 D.I-WATER B.G Glycerin Allantoin TEA Rheodol AO Rheodol TW-S Rheodol MS Even skin tone Provide good coverage of skin imperfections, e.g., pores and uneven skin tone, while retaining a natural skin appearance Natural way to milky, translucent skin Can be an opacifying agent to provide a white appearance to the emulsion NaturalWhite does not suffer from unacceptable skin whitening. NaturalWhite TiO 2 9 TEGOSOFT DEC 4.00 B 10 KALCOHL EMERSOL TCG-M TSF C 14 1% CARBOPOL D 15 SEPIGEL E 16 NA-HYALUNOLATE (1%) 2.00 While TiO 2 causes Too much whitening Too harshness TiO 2 settles down(i.e TiO 2 is very difficult to disperse so often cause separation of formula) 10% 10% F G 17 D.I-WATER ARBUTIN FRAGRANCE ` Phenoxyethanol 0.5 H 22 SUNSIL-TinUVAB 3.00

55 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 55 NaturalWhite Bead provides Natural Coverage & Good Spread for Mineral Powder NaturalWhite Bead 100% Silica Bead 65% + TiO 2 35% Mineral Powder with NaturalWhite Bead inside Conventional Mineral Powder with TiO 2 inside EVEN SKIN EVEN SKIN SJF-0802-Mineral Powder-ver.1.1 Phase No. Trade Name % 1 SUNTALC-LL SUNTITAN-LL SUNSIL-Tin Natural White(CO) SUNZNO-NAS LIGHT AS A POWDER EVEN SKIN TONE LIKE A FOUNDATION Flawless coverage Excellent Skin Spread A B 5 SUNSERI-LL(P) SUNIOR-AS SUNIOY-AS SUNIOB-AS Broneige Salacos KF 96-5CS Carnauba Wax DC Silky Elegant Feel LONG LASTING LIKE A FOUNDATION SPF15 ZINC OXIDE FOR SPF AND SKIN HEALING

56 Skin Brightener JH Red for Pinky Healthy Look JH Blue for Asian

57 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 57 Pearlescent acts like a Micro Mirror on skin, making skin sparkling and flashy MARKETING CLAIMS of use of pearlescent in skin care your skin glowing and looking natural bright and radiant instantly brightening the skin The pearl tone provides your skin with a luminous quality runway gleam you will look resplendent in 60 seconds tired skin look awake and alive Pearlescent acts like a mirror on skin, Reflecting lights so Making skin bright but too flashy! Radiance Cream UV moisturizer Pearlescent In Skin Care Whitening Gel Essence Eye Lifting Serum Luster pigment based on titanium dioxide/mica can amplify skin imperfections when applied in cosmetic formulations. This is particularly obvious with wrinkles, where light is reflected at certain angles and the edges of the wrinkles are emphasized Attempts have been made to smooth out these unwanted imperfections with highly refractive conventional pigments. This type of pigmentation leads, however to an unnatural mask appearance. A compromise between two extremes was found with the use of transmitting, light scattering pigments, which lessens the visibility of wrinkles. - Special Effect Pigments, Gerhard Pfaff, page 66 -

58 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 58 PMMA coated SATIN Pearl makes Skin Imperfections Less Noticeable Strong specula reflection Reduced specula reflection NOT Flashy Flashy interference Pearl Luster Pearl Light reflection Amplify skin imperfection Good for Point make-up Satin Pearl Low Luster Pearl Radiance Natural skin tone Light transmitting & scattering Reduce contrast, less visible skin imperfection Reduced color travel with viewing angle Good for skin care & base make-up

59 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 59 JH Series, Lower specula reflection & Less color change on viewing angle Polymethyl Methacrylate (And) Mica (And) Titanium Dioxide Grade Composition Avg. Particle size ( μm ) JH-Red PMMA 40%, Mica/TiO2 60% 20~30 JH-Gold PMMA 40%, Mica/TiO2 60% 20~30 JH-Blue NEW PMMA 40%, Mica/TiO2 60% 20~30 Radiant but not flashy Subtle pearlescent sheen to your skin Radiance without shine Satin Effect with lower specula reflection & less saturated colored reflection

60 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 60 JH RED & BLUE for Skin Brightener JH-BLUE minimizing yellow skin tone Whitening Cream SJF-1125-Moisturizing Essence With JH-Series-ver.1.0 No. Trade Name % % 1 D.I. WATER JH-RED Maximizing vivid pink lively skin tone Radiance Cream A B C D 2 CARBOPOL GLYCERIN ALLANTOIN SODIUM HYALURONATE (1%) D.I. WATER TEA SEPIPLUS PHENOXYETHANOL FRAGRANCE JH-RED JH-BLUE - 3.0

61 Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 61 JH Series: Applications Best recommend for (1) Skin Care natural radiance skin brightening to skin care (2) Sun Care Skin Brightening effect Counter-balance any whitening / dull appearance that can be created by the mineral UV filters. Instant natural glow effect provided by: Gives a more natural looking brightening effect compared to traditional pearls (less shiny) (3) Liquid Foundation satin pearl effect.

62 Memo Copyright 2012 by SUNJIN Chemical Co. LTD ALL RIGHTS RESERVED. 62

63 The information given in this publication is based on our current knowledge and experience, and may be used at your discretion and risk. We do not assume any liability in connection with your product or its use

64 Global Distributors List ASIA & Pacific China TIANJIN XIANGUANG CHEMICAL Jinyu Road, Xiditou Beichen District, Tianjin Tel : Mobile: Contact : Sheng-Fan Piao Japan/ LINDEN CO.,LTD. A202, 3-6-3Watado, Fujimi-Shi, Saitama TEL : (+81) Contact : Kazuyuki Miyadera Australia / New Zealand RPL Trading Allingham Street, Golden Square, VIC 3555, Australia Tel : Contact : Russell McNab Thailand/ GOWELL CO. LTD 8/9 Moo 7, Bangna - Trad Road KM.9, Bangkaew, Bangplee, Samutprakarn 10540, Thailand TEL : Contact : Nutthamol Rattanachaiyaphong Taiwan/ WWRC 5F-A, No. 30, Chung Cheng 2nd Road, Kaohsiung 802, Taiwan, R.O.C. Tel : Contact : Tommy Hu Malaysia/ DCM Personal Care Address : No. 5, Jalan U1/21 Seksyen U1, Hicom-Glenmarie Industrial park, Shah Alam, SelangorDarul Ehsan. Malaysia. Tel : Contact : Kok Leong, KHOO Indonesia/ PT. MEGASETIA AGUNG KIMIA JI. Paradise Timur Raya F21/58, Sunter Agung Podomoro, Jakarta Tel : Contact : Abagail EUROPE France / IMPAG France SAS 6, Boulevard du 21eme Regiment d'aviation NANCY France Tel : +33 (0) Contact : Dominique Cormary Germany/ IMPAG GmbH Fritz-Remy-str.25,63071 offenbach Tel: Fax: Contact : Karin Flach-Zierer Switzerland/ IMPAG AG Feldeggstrasse 26, Postfach, CH-8008 Zü rich TEL: Contact: Peter Alder Italy/ Caldic Italia Srl Via Saronnino, Origgio (VARESE) Italy Tel : +39 (02) Contact : Marcello Baggi UK/ ASTON CHEMICALS 1 Aylesbury Industrial Center Bicester Road, Aylesbury, HP19 8AL Tel: +44 (0) Contact: Louis Moulin Poland/ ASTON CHEMICALS Oddział w Polsce, ul. Mińska Warszawa Tel Contact: Mariusz Siwiński Spain & Portugal / C.E.S.T.I.S.A. Bailen 43 pral, Barcelona Tel : Contact : Laura Mas Turkey/ HD ULUSLARARASI TIC. VE AMBALAJ SAN. LTD.STI. Dilovasi Organize Sanayi Bolgesi 5.Kisim D-5007 Sokak No:2 Ofis No: 11 (Jokey Plastik Fabrikasi ici) TR Dilovasi- Kocaeli Turkey Tel : Contact : Oktay OZTURK AMERICA USA & Canada KOBO PRODUCTS, INC. 690 Montrose Ave. - South Plainfield, NJ Tel : (Ext.6152) Contact : Barbara Scott SUNJIN AMERICA INC Center Ave. (Suite 502) Fort Lee, NJ Tel : Mobile : Contact : Phil Lee MIDDLE EAST Jordan & Syria RIMA AL.SHURAFA & PARTENERS 149 Amman Jordan 8th Circle, Al.Bayader, Randa Complex Building, 2nd Floor, Office, 206 Tel: Mobile: Contact : Firas Shurafa

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