MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # 01 Revision date CAS # CALCIUM PHOSPHATE TRIBASIC Product Codes J.T.Baker: 1436 Mallinckrodt: 0118, 3599, 4280, 4282 Synonym(s) Manufacturer Address Customer Service Hour Emergency Chemtrec Tricalcium phosphate; Calcium hydroxy apatite; hydroxyapatite, Precipitated Calcium Phosphate. Avantor Performance Materials, Inc. 222 Red School Lane Phillipsburg, NJ US 2. Hazards Identification Emergency overview OSHA regulatory status Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Chronic effects Signs and symptoms Potential environmental effects WARNING Contact may irritate or burn eyes. Irritating to respiratory system and skin. This product is considered hazardous under 29 CFR (Hazard Communication). Skin contact. Eye contact. Inhalation. Ingestion. Contact will irritate or burn eyes. Eye contact may result in corneal injury. Do not get this material in contact with eyes. Irritating to skin. Avoid contact with the skin. Dust irritates the respiratory system, and may cause coughing and difficulties in breathing. Avoid breathing dust/fume/gas/mist/vapors/spray. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Do not ingest. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Shortness of breath. Coughing. May cause long-term adverse effects in the environment. 3. Composition / Information on Ingredients Components CAS # Percent CALCIUM PHOSPHATE TRIBASIC First Aid Measures First aid procedures Eye contact Skin contact Inhalation Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Immediately flush skin with plenty of water. Take off contaminated clothing and wash before reuse. Get medical attention if irritation develops and persists. If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a physician if symptoms develop or persist. 1 / 5

2 Ingestion General advice 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Protection of firefighters Protective equipment and precautions for firefighters Special protective equipment for fire-fighters If ingestion of a large amount does occur, call a poison control center immediately. Do not induce vomiting without advice from poison control center. Never give anything by mouth to a victim who is unconscious or is having convulsions. Rinse mouth thoroughly. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. The product is not flammable. No unusual fire or explosion hazards noted. Water. Move containers from fire area if you can do so without risk. In the event of fire, cool tanks with water spray. Cool containers exposed to flames with water until well after the fire is out. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for cleaning up Keep unnecessary personnel away. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid contact with eyes and prolonged skin contact. Do not contaminate water. Should not be released into the environment. Small Dry Spills: With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Avoid dust formation. Clean up in accordance with all applicable regulations. Following product recovery, flush area with water. For waste disposal, see section 13 of the MSDS. 7. Handling and Storage Handling Storage Do not get this material in contact with eyes. Avoid contact with skin. Avoid breathing dust/fume/gas/mist/vapors/spray. Minimize dust generation and accumulation. Wear personal protective equipment. Wash thoroughly after handling. Handle and open container with care. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in accordance with local/regional/national/international regulation. 8. Exposure Controls / Personal Protection Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygeine considerations 9. Physical & Chemical Properties Appearance Color Odor Odor threshold Physical state Ensure adequate ventilation, especially in confined areas. Chemical goggles are recommended. Face-shield. Provide eyewash station and safety shower. Do not get in eyes. Wear suitable protective clothing. Avoid contact with the skin. No protection is ordinarily required under normal conditions of use and with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Particulate air-purifying respirator approved for dust or oil mist is recommended. WARNING! Air-purifying respirators do not protect workers in oxygen deficient atmospheres. Do not get in eyes. Avoid contact with skin. Avoid breathing dust. Keep away from food and drink. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. Powder. White. Odorless. Solid. 2 / 5

3 Form ph Melting point Freezing point Boiling point Flash point Evaporation rate Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Solid F (1670 C) Not applicable. Specific gravity 25 C Relative density Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Molecular weight Molecular formula Not available g/mol Ca5-H-O13-P3 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions 11. Toxicological Information Sensitization Local effects Carcinogenicity Skin corrosion/irritation Material is stable under normal conditions. None under normal conditions. Hazardous polymerization does not occur. Not a skin sensitizer. Irritating to eyes. Irritating to skin. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Not classified. Irritating to skin. 12. Ecological Information Ecotoxicity Environmental effects Persistence and degradability Partition coefficient (n-octanol/water) Contains a substance which causes risk of hazardous effects to the environment. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. No data is available on the degradability of this product. Not available 3 / 5

4 13. Disposal Considerations Disposal instructions Contaminated packaging 14. Transport Information DOT IATA IMDG This product, in its present state, when discarded or disposed of, is not a hazardous waste according to Federal regulations (40 CFR (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Do not allow this material to drain into sewers/water supplies. Dispose of contents/container in accordance with local/regional/national/international regulations. Since emptied containers retain product residue, follow label warnings even after container is emptied. 15. Regulatory Information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. CERCLA (Superfund) reportable quantity None CERCLA/SARA Hazardous Substances - Not applicable. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 311 hazardous chemical Inventory status Country(s) or region Australia Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Immediate Hazard - Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Inventory name Australian Inventory of Chemical Substances (AICS) Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory On inventory (yes yes/no no)* *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. No No 4 / 5

5 Saf-T-Data 16. Labeling Info Label Hazard Warning Label Precautions Label First Aid Health: 1 - Slight Flammability: 0 - None Reactivity: 0 - None Contact: 3 - Severe Lab Protective Equip: D - GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Storage Color Code: G - Green (General Storage) WARNING! Contact may irritate or burn eyes. Irritating to respiratory system and skin. Do not get in eyes and avoid contact with skin and clothing. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Immediately flush eyes with plenty of water for at least 15 minutes. Immediately flush skin with plenty of water. If gas/fume/vapor/dust/mist from the material is inhaled, remove the affected person immediately to fresh air. Oxygen or artificial respiration if needed. Get medical attention if irritation develops or persists. If ingestion of a large amount does occur, call a poison control center immediately. Do not induce vomiting without advice from poison control center. 17. Other Information NFPA ratings Health: 2 Flammability: 0 Instability: 0 Disclaimer Issue date The information in the sheet was written based on the best knowledge and experience currently available. Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. 5 / 5