SAFETY DATA SHEET. 1. Product and Company Identification. 2. Hazards Identification

Transcription

1 SAFETY DATA SHEET 1. Product and Company Identification Product identifier Other means of identification Recommended use Recommended restrictions Manufacturer information Supplier Alkylate Blending component None known. Irving Oil Refining G.P. Box 1260 Saint John, NB E2L 4H6 CA Phone: (506) Refinery: (506) See above. Physical hazards Health hazards Environmental hazards WHMIS 2015 defined hazards Label elements 2. Hazards Identification Gases under pressure Skin corrosion/irritation Specific target organ toxicity, single exposure Aspiration hazard Not classified. Not classified Liquefied gas Category 2 Category 3 narcotic effects Category 1 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal WHMIS 2015: Health Hazard(s) not otherwise classified (HHNOC) WHMIS 2015: Physical Hazard(s) not otherwise classified (PHNOC) Hazard(s) not otherwise classified (HNOC) Danger Extremely flammable liquid and vapor. Causes skin irritation. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Avoid breathing mist or vapor. Use only outdoors or in a well-ventilated area. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use appropriate media to extinguish. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Specific treatment (see information on this label). IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. None known None known None known. #21017 Page: 1 of 20 Issue date 23-January-2017

2 Supplemental information None. Mixture 3. Composition/Information on Ingredients Hazardous components Chemical name Common name and synonyms CAS number % Isooctane Pentane, 2,3,3-trimethyl Pentane, 2,3,4-trimethyl Butane, 2-methyl ,3-Dimethylbutane ,3-Dimethylhexane ,4-Dimethylhexane ,4-Dimethylpentane Methyl-1-butene (technical) Hexane, 2,2,5-trimethyl Isohexane Pentane, 2,2,3-trimethyl ,2,3-trimethylbutane ,2,4-Trimethylhexane ,3,4-trimethylhexane Methylhexane Methylheptane Benzene, 1,2-dimethyl Butyl benzene Nonane p-diethyl benzene Pentane, 3-methyl All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First Aid Measures Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Specific treatment (see information on this label). Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Direct contact with eyes may cause temporary irritation. Skin irritation. May cause redness and pain. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. Keep away from sources of ignition. No smoking. Avoid contact with eyes and skin. Wear rubber gloves and safety glasses with side shields. Keep out of reach of children. 5. Fire Fighting Measures Suitable extinguishing media Unsuitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide.. #21017 Page: 2 of 20 Issue date 23-January-2017

3 Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Hazardous combustion products During fire, gases hazardous to health may be formed. Vapors may form explosive mixtures with air. Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back. Firefighters should wear full protective clothing including self contained breathing apparatus. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. Extremely flammable liquid and vapor. May include and are not limited to: Aromatic hydrocarbons. Oxides of carbon. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid breathing mist or vapor. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Never return spills in original containers for re-use. Following product recovery, flush area with water. Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewers, basements or confined areas. Do not discharge into lakes, streams, ponds or public waters. 7. Handling and Storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Avoid contact with eyes, skin, and clothing. Wear appropriate personal protective equipment. Avoid breathing mist or vapor. Use only with adequate ventilation. Avoid prolonged exposure. Observe good industrial hygiene practices. Wash thoroughly after handling. When handling, do not eat, drink or smoke. Store locked up. Keep away from heat, sparks and open flame. Store in a cool, dry, well-ventilated place. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of reach of children. Occupational exposure limits 8. Exposure Controls/Personal Protection Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylbutane (CAS ) 2,3-Dimethylhexane (CAS ) 2050 mg/m mg/m mg/m mg/m3 #21017 Page: 3 of 20 Issue date 23-January-2017

4 Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) 2,4-Dimethylhexane (CAS ) 2,4-Dimethylpentane (CAS ) 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) 4-Methylheptane (CAS ) Benzene, 1,2-dimethyl- (CAS ) Butane, 2-methyl- (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) 2050 mg/m mg/m mg/m mg/m3 651 mg/m3 150 ppm 434 mg/m mg/m3 600 ppm 3500 mg/m mg/m mg/m mg/m3 #21017 Page: 4 of 20 Issue date 23-January-2017

5 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) 2,2,3-trimethylbutane (CAS ) 2,3-Dimethylbutane (CAS ) 2,4-Dimethylpentane (CAS ) 3-Methylhexane (CAS ) Benzene, 1,2-dimethyl- (CAS ) Butane, 2-methyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) 150 ppm 600 ppm Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylbutane (CAS ) 2,4-Dimethylpentane (CAS ) 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) Benzene, 1,2-dimethyl- (CAS ) Butane, 2-methyl- (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) 150 ppm #21017 Page: 5 of 20 Issue date 23-January-2017

6 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) 2,2,3-trimethylbutane (CAS ) 2,3-Dimethylbutane (CAS ) 2,4-Dimethylpentane (CAS ) 3-Methylhexane (CAS ) Benzene, 1,2-dimethyl- (CAS ) Butane, 2-methyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) 150 ppm 600 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylbutane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 3,3,4-trimethylhexane (CAS ) 4-Methylheptane (CAS ) Benzene, 1,2-dimethyl- (CAS ) 3500 mg/m mg/m mg/m3 375 ppm 1750 mg/m3 375 ppm 1750 mg/m3 375 ppm 651 mg/m3 150 ppm #21017 Page: 6 of 20 Issue date 23-January-2017

7 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Hexane, 2,2,5-trimethyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) 434 mg/m mg/m mg/m mg/m3 375 ppm 1750 mg/m3 375 ppm 1750 mg/m3 375 ppm 1750 mg/m3 375 ppm 3500 mg/m mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 4-Methylheptane (CAS ) Benzene, 1,2-dimethyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) PEL PEL PEL PEL PEL PEL PEL PEL 2350 mg/m mg/m mg/m3 435 mg/m mg/m mg/m mg/m mg/m3 #21017 Page: 7 of 20 Issue date 23-January-2017

8 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) US. ACGIH Threshold Limit Values 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylbutane (CAS ) 2,4-Dimethylpentane (CAS ) 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) Benzene, 1,2-dimethyl- (CAS ) Butane, 2-methyl- (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) 150 ppm US. NIOSH: Pocket Guide to Chemical Hazards 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylbutane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 3,3,4-trimethylhexane (CAS ) 4-Methylheptane (CAS ) Ceiling Ceiling Ceiling Ceiling 1800 mg/m3 510 ppm 350 mg/m mg/m3 385 ppm 350 mg/m3 75 ppm 1800 mg/m3 385 ppm 350 mg/m3 75 ppm 1800 mg/m3 #21017 Page: 8 of 20 Issue date 23-January-2017

9 US. NIOSH: Pocket Guide to Chemical Hazards Benzene, 1,2-dimethyl- (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) Ceiling Ceiling Ceiling Ceiling Ceiling Ceiling 385 ppm 350 mg/m3 75 ppm 655 mg/m3 150 ppm 435 mg/m mg/m3 510 ppm 350 mg/m mg/m3 385 ppm 350 mg/m3 75 ppm 1800 mg/m3 385 ppm 350 mg/m3 75 ppm 1800 mg/m3 385 ppm 350 mg/m3 75 ppm 1800 mg/m3 385 ppm 350 mg/m3 75 ppm 1800 mg/m3 510 ppm 350 mg/m3 US. AIHA Workplace Environmental Exposure Level (WEEL) Guides p-diethyl benzene (CAS ) Biological limit values 5 ppm ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Benzene, 1,2-dimethyl- (CAS ) 1.5 g/g Methylhippuric acids * - For sampling details, please see the source document. Appropriate engineering controls Ensure adequate ventilation. Individual protection measures, such as personal protective equipment Face shield or chemical goggles. Eye/face protection Creatinine in urine * #21017 Page: 9 of 20 Issue date 23-January-2017

10 Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Impervious gloves. Confirm with reputable supplier first. Coveralls to prevent skin contact. If clothing or footwear becomes contaminated with the product, remove it and completely decontaminate it before re-use, or discard it. For confined spaces, wear a NIOSH-approved (or equivalent) full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Respirator should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR ), CAN/CSA-Z94.4 and ANSI's standard for respiratory protection (Z88.2). Not applicable. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. When using, do not eat, drink or smoke. Appearance Physical state Form Color Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Pour point Specific gravity Partition coefficient (n-octanol/water) Flash point Evaporation rate Flammability (solid, gas) Liquid Liquid. 9. Physical and Chemical Properties Liquid or Vapor Clear Petroleum. Not applicable <= -58 F (<= -50 C) F ( C). ~ F (-45.0 C) Closed Cup ~ 4 (BuAc=1) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower > 1.4 % (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Auto-ignition temperature Decomposition temperature Viscosity Other information Explosive properties Oxidizing properties < 7.6 % C 20 C. Insoluble F (456 C).. Not explosive. Not oxidizing. 10. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials May react with incompatible materials. Hazardous polymerization does not occur. Stable under recommended storage conditions. Avoid heat, sparks, open flames and other ignition sources. Do not mix with other chemicals. Acids. Strong oxidizing agents. #21017 Page: 10 of 20 Issue date 23-January-2017

11 Hazardous decomposition products May include and are not limited to: Aromatic hydrocarbons. Oxides of carbon. 11. Toxicological Information Routes of exposure. Ingestion. Skin contact. Eye contact. Eye, Skin contact, Skin absorption,, Ingestion. Eye, Skin contact,, Ingestion. Information on likely routes of exposure Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. May cause stomach distress, nausea or vomiting. Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Causes skin irritation. Direct contact with eyes may cause temporary irritation. Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Skin irritation. May cause redness and pain. Information on toxicological effects toxicity May be fatal if swallowed and enters airways. Narcotic effects. Components Species Test Results 1,1,2-Trimethylcyclohexane (CAS ) 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 3, 4 Hours 3200 mg/l, 4 Hours 2,3-Dimethylhexane (CAS ) Dermal 2,4-Dimethylhexane (CAS ) Dermal 118 mg/l, 4 Hours #21017 Page: 11 of 20 Issue date 23-January-2017

12 Components Species Test Results 2,4-Dimethylpentane (CAS ) 2-Methyl-1-butene (technical) (CAS ) Dermal 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) 4-Methylheptane (CAS ) Dermal Rabbit Mouse Mouse 118 mg/l, 4 Hours 3, 4 Hours 118 mg/l, 4 Hours mg/kg 4600 ppm, 6 Hours 6350 ppm, 4 Hours 5000 mg/l/4h 2180 ppm 1590 mg/kg 3608 mg/kg Mouse ppm 1000 mg/l, 1 Hours 450 mg/l, 2 Hours > 25.3 mg/l, 4 Hours #21017 Page: 12 of 20 Issue date 23-January-2017

13 Components Species Test Results Butyl benzene (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) > 2000 mg/kg 3200 mg/l, 4 Hours. Dermal Isopropylcyclohexane (CAS ) Nonane, 5-methyl- (CAS ) p-diethyl benzene (CAS ) Mouse 3, 4 Hours 118 mg/l, 4 Hours 3, 4 Hours >= mg/kg mg/m mg/kg #21017 Page: 13 of 20 Issue date 23-January-2017

14 Components Species Test Results Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Dermal Pentane, 2,3,4-trimethyl- (CAS ) Dermal Pentane, 3-methyl- (CAS ) Skin corrosion/irritation Exposure minutes Erythema value Oedema value Serious eye damage/eye irritation Corneal opacity value Iris lesion value Conjunctival reddening value Conjunctival oedema value Recover days Respiratory or skin sensitization Canada - Alberta OELs: Irritant Causes skin irritation.... Direct contact with eyes may cause temporary irritation ,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 4-Methylheptane (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) Respiratory sensitization Skin sensitization Mutagenicity Carcinogenicity Not a respiratory sensitizer. Irritant Irritant Irritant Irritant Irritant Irritant Irritant This product is not expected to cause skin sensitization. Not classified. See below. Canada - Manitoba OELs: carcinogenicity XYLENE (O, M AND P ISOMERS) (CAS ) 118 mg/l, 4 Hours 118 mg/l, 4 Hours 118 mg/l, 4 Hours Not classifiable as a human carcinogen. #21017 Page: 14 of 20 Issue date 23-January-2017

15 IARC Monographs. Overall Evaluation of Carcinogenicity Volume 47, Volume 71-3 Not classifiable as to carcinogenicity to humans. US. OSHA Specifically Regulated Substances (29 CFR ) Not listed. Reproductive toxicity Teratogenicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Ecotoxicity Ecotoxicological data Components Algae Crustacea Aquatic Crustacea Fish Crustacea Butyl benzene (CAS ) Aquatic Crustacea Persistence and degradability Bioaccumulative potential Mobility in soil Mobility in general Other adverse effects Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Transport of Dangerous Goods (TDG) Proof of Classification This product is not expected to cause reproductive or developmental effects. Non-hazardous by WHMIS/OSHA criteria. Non-hazardous by WHMIS/OSHA criteria. May cause drowsiness and dizziness. Not classified. May be fatal if swallowed and enters airways. Prolonged inhalation may be harmful. Blood and nervous system disorders may occur after prolonged skin contact. See below IC50 EC50 EC Ecological Information Species Algae Daphnia Water flea (Daphnia magna) Rainbow trout,donaldson trout (Oncorhynchus mykiss) Test Results 4.2 mg/l, 72 Hours 3.2 mg/l, 48 Hours mg/l, 48 hours mg/l, 96 hours EC50 Daphnia 2.3 mg/l, 48 Hours EC50 Water flea (Daphnia magna) mg/l, 48 hours Non-persistent/ Group 1 No data available.. Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: UN number Proper shipping name Hazard class Packing group No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal Considerations Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport Information In accordance with Part (SOR/ ) of the Transportation of Dangerous Goods Regulations, we certify that the classification of this product is correct as of the SDS date of issue. UN1203 GASOLINE 3 II #21017 Page: 15 of 20 Issue date 23-January-2017

16 TDG Special provisions 17, 88, 91, 98, 150 Canadian federal regulations 15. Regulatory Information This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations (SOR/ ) and the SDS contains all the information required by the HPR. Canada NPRI VOCs with Additional Reporting Requirements: Mass reporting threshold/identification Number 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 2,4-Dimethylpentane (CAS ) 2- Methyl-1-butene (technical) (CAS ) 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) 4- Methylheptane (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) Nonane, 5-methyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) Export Control List (CEPA 1999, Schedule 3) Not listed. Greenhouse Gases Not listed. Precursor Control Regulations WHMIS 2015 Not regulated. Exemptions US federal regulations Not applicable This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) 2,2,4-Trimethylhexane (CAS ) 3,3,4-trimethylhexane (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) CERCLA Hazardous Substance List (40 CFR 302.4) 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 2,4-Dimethylpentane (CAS ) 2- Methyl-1-butene (technical) (CAS ) 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) 4- Methylheptane (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) 1.0 % One-Time Export Notification only. 1.0 % One-Time Export Notification only. 1.0 % One-Time Export Notification only. 1.0 % One-Time Export Notification only. #21017 Page: 16 of 20 Issue date 23-January-2017

17 Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) US. OSHA Specifically Regulated Substances (29 CFR ) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations No No Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) 2-Methyl-1-butene (technical) (CAS ) US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. See below US - California Hazardous Substances (Director's): Listed substance 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 3,3,4-trimethylhexane (CAS ) 4-Methylheptane (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) US - Illinois Chemical Safety Act: Listed substance 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 2,4-Dimethylpentane (CAS ) 2- Methyl-1-butene (technical) (CAS ) 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) 4- Methylheptane (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) #21017 Page: 17 of 20 Issue date 23-January-2017

18 Pentane, 3-methyl- (CAS ) US - Louisiana Spill Reporting: Listed substance 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 2,4-Dimethylpentane (CAS ) 2- Methyl-1-butene (technical) (CAS ) 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) 4- Methylheptane (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) US - Pentane, Michigan 3-methyl- Critical Materials (CAS ) Register: Parameter number US - Minnesota Haz Subs: Listed substance Nonane, 5-methyl- (CAS ) Pentane, 3-methyl- (CAS ) US - New Jersey RTK - Substances: Listed substance 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 2,4-Dimethylpentane (CAS ) 2-Methyl-1-butene (technical) (CAS ) 3-Methylhexane (CAS ) 4-Methylheptane (CAS ) Butyl benzene (CAS ) p-diethyl benzene (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) US - North Carolina Toxic Air Pollutants: Listed substance Pentane, 3-methyl- (CAS ) US - Texas Effects Screening Levels: Listed substance 2,2,3-trimethylbutane (CAS ) 2,4-Dimethylpentane (CAS ) 3- Methylhexane (CAS ) 4- Methylheptane (CAS ) Benzene, 1,2-dimethyl- (CAS ) Butane, 2-methyl- (CAS ) Butyl benzene (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) p-diethyl benzene (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) XYLENE (ALL ISOMERS) #21017 Page: 18 of 20 Issue date 23-January-2017

19 Pentane, 3-methyl- (CAS ) US. Massachusetts RTK - Substance List 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 2,4-Dimethylpentane (CAS ) 2- Methyl-1-butene (technical) (CAS ) 3,3,4-trimethylhexane (CAS ) 3-Methylhexane (CAS ) 4- Methylheptane (CAS ) Butyl benzene (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) p-diethyl benzene (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 2,3,4-trimethyl- (CAS ) US. New Pentane, Jersey 3-methyl- Worker (CAS and ) Community Right-to-Know Act 2-Methyl-1-butene (technical) (CAS ) US. Pennsylvania Worker and Community Right-to-Know Law 2,2,3-trimethylbutane (CAS ) 2,2,4-Trimethylhexane (CAS ) 2,3-Dimethylhexane (CAS ) 2,4-Dimethylhexane (CAS ) 2,4-Dimethylpentane (CAS ) 2- Methyl-1-butene (technical) (CAS ) 3,3,4-trimethylhexane (CAS ) 3- Methylhexane (CAS ) Butyl benzene (CAS ) Hexane, 2,2,5-trimethyl- (CAS ) p-diethyl benzene (CAS ) Pentane, 2,2,3-trimethyl- (CAS ) Pentane, 2,3,3-trimethyl- (CAS ) Pentane, 3-methyl- (CAS ) US. Rhode Island RTK 2-Methyl-1-butene (technical) (CAS ) US. California Proposition 65 Not Inventory status Country(s) or region Canada Canada United States & Puerto Rico Inventory name Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory On inventory (yes/no)* No *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) No No #21017 Page: 19 of 20 Issue date 23-January-2017

20 16. Other Information LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 HEALTH * FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION X Disclaimer Issue date Version # Effective date Prepared by Other information The information contained in this form is based on data from sources considered to be reliable but Irving Oil Refining G.P. does not guarantee the accuracy or completeness thereof. The information is provided as a service to the persons purchasing or using the material to which it refers and Irving Oil Refining G.P. expressly disclaims all liability for loss or damage including consequential loss or for injury to persons including death. The information shall not be reproduced, published or distributed in any manner without prior consent in writing of Irving Oil Refining G.P. 23-January January-2017 Dell Tech Laboratories, Ltd. Phone: (519) This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations (SOR/ ) and the SDS contains all the information required by the HPR. For an updated SDS, please contact the supplier/manufacturer listed on the first page of the document. #21017 Page: 20 of 20 Issue date 23-January-2017