Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS PPE Transport Symbol Issuing Date 09-Jan-2007 Revision Date Revision Number 0 1. PRODUCT AND COMPANY IDENTIFICATION Product Name 91% Isopropyl Alcohol 804 Recommended Use Personal care Supplier Address Vi-Jon One Swan Drive, Smyrna, Tennessee, US Phone: Fax: Contact:Cathy M. Crabtree Contact Phone: Emergency Phone: Company Emergency Phone Number WARNING! 2. HAZARDS IDENTIFICATION Emergency Overview FLAMMABLE LIQUID AND VAPOR Irritating to eyes. Vapors may be irritating to eyes, nose, throat, and lungs. May cause drowsiness and dizziness. Appearance Clear Colorless Physical State Liquid Odor Alcohol Potential Health Effects Principle Routes of Exposure Acute Toxicity Eyes Inhalation, Skin contact, Eye contact. Moderately irritating to the eyes. Contact with eyes may cause irritation. Page 1 / 9

2 Skin Inhalation Ingestion Chronic Effects Aggravated Medical Conditions Environmental Hazard May cause eye/skin irritation. May cause irritation of respiratory tract. Avoid breathing vapors or mists. May cause drowsiness and dizziness. Ingestion may cause irritation to mucous membranes. Potential for aspiration if swallowed. May cause additional affects as listed under "Inhalation". Avoid repeated exposure. Preexisting eye disorders. Skin disorders. Respiratory disorders. See Section 12 for additional Ecological information 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Isopropyl alcohol Water FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Notes to Physician Protection of First-aiders Show this safety data sheet to the doctor in attendance. If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. Wash off with warm water and soap. If skin irritation persists, call a physician. Move to fresh air in case of accidental inhalation of vapors. If symptoms persist, call a physician. If breathing is irregular or stopped, administer artificial respiration. Call a physician or Poison Control Center immediately. Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Consult a physician. Treat symptomatically. Remove all sources of ignition. Use personal protective equipment. 5. FIRE-FIGHTING MEASURES Flammable Properties Flammable; may be ignited by heat, sparks or flames. Flash Point Suitable Extinguishing Media Uniform Fire Code Unsuitable Extinguishing Media Hazardous Combustion Products 12.2Â C / 54Â F Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. CO2, dry chemical, dry sand, alcohol-resistant foam. Flammable Liquid: I-B Irritant: Liquid Other Health Hazard: Target Organ Toxin--Liquid Do not use a solid water stream as it may scatter and spread fire. Carbon oxides Page 2 / 9

3 Explosion Data Sensitivity to mechanical impact Sensitivity to static discharge Not sensitive Yes Specific Hazards Arising from the Chemical Flammable. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear NFPA Health Hazard 1 Flammability 3 Stability 0 Physical and Chemical Hazards - 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Methods for Containment Methods for Cleaning Up Remove all sources of ignition. Take precautionary measures against static discharges. Evacuate personnel to safe areas. Ensure adequate ventilation. Use personal protective equipment. Keep people away from and upwind of spill/leak. Prevent further leakage or spillage if safe to do so. Cover with water, sand or earth. Shovel into metal container and keep material under water. Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. 7. HANDLING AND STORAGE Handling Storage Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Use only in area provided with appropriate exhaust ventilation. Wear personal protective equipment. Avoid breathing vapors or mists. Avoid contact with eyes. Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat and sources of ignition. Do not store in aluminum > 120 F 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Isopropyl alcohol TWA: 200 ppm TWA: 400 ppm 2000 ppm STEL: 400 ppm NIOSH IDLH: Immediately Dangerous to Life or Health Engineering Measures Showers Eyewash stations Ventilation systems Page 3 / 9

4 Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Tightly fitting safety goggles. Antistatic boots. Wear fire/flame resistant/retardant clothing. Impervious gloves. Long sleeved clothing. Apron. No protective equipment is needed under normal use conditions. NIOSH approved respiratory protection required when above PEL/TWA When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing. After working with this product, be sure to wash before eating, drinking, smoking or applying cosmetics. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Clear Colorless Odor Alcohol Odor Threshold No information available Physical State Liquid ph UNKNOWN Flash Point 12.2Â C / 54Â F Autoignition Temperature Not applicable Decomposition temperature No data available Boiling Point/Range 82Â C / 180Â F Melting Point/Range No data available Flammability Limits in Air No data available Explosion Limits No data available Specific Gravity Water Solubility Miscible with water Solubility No data available Evaporation Rate No data available Vapor Pressure 68 F Vapor Density No data available VOC Content 91% Partition Coefficient (noctanol/water) 10. STABILITY AND REACTIVITY Stability Conditions to Avoid Incompatible Products Hazardous Decomposition Products Hazardous Polymerization Stable under recommended storage conditions. Heating in air. Sparks, Open Flames. Strong bases. Amines. Ammonia. Strong oxidizing agents. Chlorinated compounds. Acetaldehyde. Ethylene Oxide. Acids. Isocyanates. Carbon oxides. Hazardous polymerization does not occur 11. TOXICOLOGICAL INFORMATION Acute Toxicity Page 4 / 9

5 Product Information. LD50 Oral VALUE (mg/kg) 4831 mg/kg (rat) estimated Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Isopropyl alcohol 4396 mg/kg ( Rat ) mg/kg ( Rabbit ) mg/kg ( Rat ) 72.6 mg/l ( Rat ) 4 h Subchronic Toxicity (28 days) Chronic Toxicity Chronic Toxicity Carcinogenicity Avoid repeated exposure. There are no known carcinogenic chemicals in this product Chemical Name ACGIH IARC NTP OSHA Isopropyl alcohol Mutagenicity Reproductive Toxicity Target Organ Effects Endocrine Disruptor Information Not indicated. This product does not contain any known or suspected reproductive hazards. Eyes, Respiratory system, Skin. This product does not contain any known or suspected endocrine disruptors. 12. ECOLOGICAL INFORMATION Ecotoxicity Ecotoxicity effects. Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea) Isopropyl alcohol EC50 > 1000 mg/l 72 h EC50 = mg/l 5 min EC50 = mg/l 48 h Chemical Name Log Pow Isopropyl alcohol DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated Packaging US EPA Waste Number Dispose of in accordance with local regulations D001 Chemical Name Isopropyl alcohol California Hazardous Waste Status Toxic, Ignitable 14. TRANSPORT INFORMATION Page 5 / 9

6 DOT Proper Shipping Name Hazard Class 14. TRANSPORT INFORMATION Consumer commodity (Solution) ORM-D Consumer commodity (Solution),ORM-D, TDG MEX ICAO IATA Proper Shipping Name Isopropanol (Solution) ISOPROPANOL,3,,PG,Solution Proper Shipping Name Isopropanol (Solution) Isopropanol,3,,Solution Proper Shipping Name Isopropyl alcohol (Solution) Isopropyl alcohol,3,,pg,solution Proper Shipping Name Isopropyl alcohol (Solution) ERG Code 3L,Isopropyl alcohol,3,pg,solution IMDG/IMO Proper Shipping Name Isopropanol (Isopropyl alcohol) (Solution) EmS No. F-E, S-D, Isopropanol (Isopropyl alcohol),3,pg,solution RID ADR Proper Shipping Name Isopropanol (Isopropyl alcohol) (Solution) Classification Code F1 Isopropanol (Isopropyl alcohol),3,,rid,solution ADR/RID-Labels 3 Proper Shipping Name Isopropanol (Isopropyl alcohol) (Solution) Page 6 / 9

7 14. TRANSPORT INFORMATION Classification Code F1 ADR/RID-Labels 3 ADN Proper Shipping Name Isopropanol (Solution) Classification Code F1 Isopropanol,3, Hazard Labels 3 Limited Quantity 1 L Page 7 / 9

8 15. REGULATORY INFORMATION International Inventories TSCA DSL NDSL EINECS ELINCS ENCS CHINA KECL PICCS AICS U.S. Federal Regulations SARA 313 Section 313 of Title I of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight % SARA Threshold Values Isopropyl alcohol SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes No Yes No No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Pesticide Information. Chemical Name FIFRA - Restricted Use FIFRA - Pesticide Product Other Ingredients FIFRA - Listing of Pesticide Chemicals Isopropyl alcohol List 4B - Inert Ingredients X Water List 4A - Minimum Risk Inerts California Pesticides - Restricted Materials U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. Page 8 / 9

9 U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Isopropyl alcohol X X X X Water International Regulations Mexico - Grade Serious risk, Grade 3 Canada Chemical Name Carcinogen Status Exposure Limits Isopropyl alcohol Mexico: TWA= 980 mg/m 3 Mexico: TWA= 400 ppm Mexico: STEL= 1225 mg/m 3 Mexico: STEL= 500 ppm This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class B2 Flammable liquid Chemical Name Isopropyl alcohol NPRI X Legend NPRI - National Pollutant Release Inventory 16. OTHER INFORMATION Issuing Date 09-Jan-2007 Revision Date Revision Note No information available Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 9 / 9