Material Safety Data Sheet

Transcription

1 Product name Manufacturer Validation date In case of emergency Material Safety Data Sheet Design Freedom Plus Alkaline Perm Neutralizer 1. Product and company identification Telephone number Transportation Emergency Product type Design Freedom Plus Alkaline Perm Neutralizer Zotos International, INC 1 Tokeneke Road, Darien, CT /12/212. (8) [24 Hours] (23) [83 a.m. 5 p.m.] Contact CHEMTREC [US/ 24 Hours] Liquid. 2. Hazards identification Emergency overview NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. Additional information on toxicological endpoints is available from the supplier upon request Color Odor Hazard statements Precautionary measures OSHA/HCS status Potential acute health effects Inhalation Ingestion Skin Eyes Potential chronic health effects Chronic effects Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Overexposure signs/symptoms Medical conditions aggravated by overexposure Offwhite. Fragrant. See toxicological information (Section 11) HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. Do not breathe vapor or mist. Do not ingest. Do not eat, drink or smoke when using this product. Avoid contact with eyes. Wash thoroughly after handling. None. None known. Mild irritant Prolonged exposure may result in skin burns and ulcerations. Prolonged or repeated contact with skin or mucous membrane may result in irritation symptoms, such as redness, blistering, dermatitis etc. Contains material that may cause target organ damage, based on animal data. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. None identified. None. 4127D 1/9

2 Design Freedom Plus Alkaline Perm Neutralizer 3. Composition/information on ingredients Name CAS number % hydrogen peroxide Name CAS number % hydrogen peroxide Name CAS number UN number hydrogen peroxide UN ppm 2 % Classification IDLH H F R Special There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Eye contact Skin contact Inhalation Ingestion Protection of firstaiders Notes to physician 5. Firefighting measures Flammability of the product Extinguishing media Special exposure hazards Special firefighting procedures Hazardous thermal decomposition products Special protective equipment for firefighters Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention if you feel unwell. Wash the contaminated skin gently and thoroughly with running water and nonabrasive soap. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if you feel unwell. Call physician immediately. Have conscious person drink several glasses of water or milk. Do not induce vomiting. Get medical attention. Use suitable protective equipment (section 8). Avoid exposure. Treat symptomatically. Extinguish fire using an agent suitable for the surrounding fire. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Decomposition products may include the following materials carbon dioxide carbon monoxide nitrogen oxides halogenated compounds None. None known. None. In a fire, decomposition may produce toxic gases/fumes. Wear suitable protective clothing. 4127D 2/9

3 Design Freedom Plus Alkaline Perm Neutralizer 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up 7. Handling and storage Rubber gloves. Store in a cool, wellventilated, dry place. NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Place spilled material in an appropriate container for disposal. After contact with skin, wash immediately with plenty of water. Handling Avoid contact with skin and eyes. Store in a dry, cool and wellventilated area, away Storage from incompatible materials (see Section 1). Store in a cool, wellventilated, dry place. Store in a dry place at low temperature away from ignition and heat sources. Avoid increased storage temperature. 8. Exposure controls/personal protection Ingredient hydrogen peroxide ACGIH TLV (, 3/212). TWA 1 ppm 8 hour(s). TWA 1.4 mg/m³ 8 hour(s). OSHA PEL 1989 (, 3/1989). TWA 1 ppm 8 hour(s). TWA 1.4 mg/m³ 8 hour(s). NIOSH REL (, 6/29). TWA 1 ppm 1 hour(s). TWA 1.4 mg/m³ 1 hour(s). OSHA PEL (, 6/21). TWA 1 ppm 8 hour(s). TWA 1.4 mg/m³ 8 hour(s). Exposure limits Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations hydrogen peroxide US ACGIH 3/ AB 4/ [3] BC 9/211 1 ON 7/ QC 9/ [3]Skin sensitization Occupational exposure limits Ingredient hydrogen peroxide NOM1STPS (, 9/2). LMPEPPT 1 ppm 8 hour(s). LMPEPPT 1.5 mg/m³ 8 hour(s). LMPECT 3 mg/m³ 15 minute(s). LMPECT 2 ppm 15 minute(s). Consult local authorities for acceptable exposure limits. Recommended monitoring procedures Engineering measures Hygiene measures Personal protection Exposure limits If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. In case of insufficient ventilation, wear suitable respiratory equipment. When using do not eat, drink or smoke. 4127D 3/9

4 Design Freedom Plus Alkaline Perm Neutralizer 8. Exposure controls/personal protection Respiratory Hands Eyes Skin Environmental exposure controls Other protection Wear suitable protective clothing. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. In case of insufficient ventilation, wear suitable respiratory equipment. Chemical splash goggles. Protective clothing must be worn. None. None. Not available. 9. Physical and chemical properties Physical state Flash point Color Odor ph Boiling/condensation point Relative density Solubility Liquid. [Viscous liquid.] Closed cup Not applicable. Offwhite. Fragrant. 3 to 4 >1 C (>212 F) 1.4 to 1.1 Soluble in the following materials cold water. 1. Stability and reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Hazardous polymerization Not available. Not available. Reducing agents metals Contaminated product generates oxygen gas pressure buildup Not available. Not available. Will not occur. 11. Toxicological information Acute toxicity Product/ingredient name Result Dose Exposure hydrogen peroxide LC5 Inhalation Vapor 2 g/m3 4 hours LD5 Dermal 3 g/kg LD5 Oral 376 mg/kg Chronic toxicity Irritation/Corrosion Product/ingredient name Result Score Exposure Observation hydrogen peroxide Eyes Severe irritant 1 milligrams Sensitizer Carcinogenicity No carcinogenic effect. 4127D 4/9

5 Design Freedom Plus Alkaline Perm Neutralizer 11. Toxicological information Classification Product/ingredient name ACGIH IARC EPA NIOSH NTP hydrogen peroxide A3 3 OSHA Mutagenicity Teratogenicity Reproductive toxicity Acute toxicity Product/ingredient name Result Dose Exposure hydrogen peroxide LC5 Inhalation Vapor 2 g/m3 4 hours LD5 Dermal 3 g/kg LD5 Oral 376 mg/kg Chronic toxicity Irritation/Corrosion Product/ingredient name Result Score Exposure Observation hydrogen peroxide Eyes Severe irritant 1 milligrams Sensitizer Carcinogenicity Classification Product/ingredient name ACGIH IARC EPA NIOSH NTP hydrogen peroxide A3 3 OSHA Mutagenicity Teratogenicity Reproductive toxicity Acute toxicity Product/ingredient name Result Dose Exposure hydrogen peroxide LC5 Inhalation Vapor 2 g/m3 4 hours LD5 Dermal 3 g/kg LD5 Oral 376 mg/kg Chronic toxicity Irritation/Corrosion 4127D 5/9

6 Design Freedom Plus Alkaline Perm Neutralizer 11. Toxicological information Product/ingredient name Result Score Exposure Observation hydrogen peroxide Eyes Severe irritant 1 milligrams Sensitizer Carcinogenicity Classification Mutagenicity Teratogenicity Reproductive toxicity Product/ingredient name ACGIH IARC EPA NIOSH NTP hydrogen peroxide A Ecological information Ecotoxicity Aquatic ecotoxicity Product/ingredient name No known significant effects or critical hazards. Result Species hydrogen peroxide Acute EC5 1.2 mg/l Marine water Algae Dunaliella tertiolecta Exponential growth phase Acute EC mg/l Fresh water Algae Pseudokirchneriella subcapitata Acute EC5 232 ug/l Fresh water Daphnia Daphnia magna Neonate <24 hours Acute LC5 22 ppm Fresh water Fish Oncorhynchus mykiss Juvenile (Fledgling, Hatchling, Weanling) Persistence/degradability Aquatic ecotoxicity hydrogen peroxide Acute EC5 1.2 mg/l Marine water Algae Dunaliella tertiolecta Exponential growth phase Acute EC mg/l Fresh water Algae Pseudokirchneriella subcapitata Acute EC5 232 ug/l Fresh water Daphnia Daphnia magna Neonate <24 hours Acute LC5 22 ppm Fresh water Fish Oncorhynchus mykiss Juvenile (Fledgling, Hatchling, Weanling) OSHA THE FOLLOWING DATA IN THIS SECTION IS SOURCED FROM PUBLICLY AVAILABLE DATABASES AND NOT THE REPRESENTATION OF ANY DATA COLLECTED BY ZOTOS INTERNATIONAL OR ITS AFFILIATES. Product/ingredient name Result Species Exposure 72 hours 96 hours 48 hours 96 hours Exposure 72 hours 96 hours 48 hours 96 hours 4127D 6/9

7 Design Freedom Plus Alkaline Perm Neutralizer 12. Ecological information Persistence/degradability Aquatic ecotoxicity Product/ingredient name Result Species hydrogen peroxide Acute EC5 1.2 mg/l Marine water Algae Dunaliella tertiolecta Exponential growth phase Acute EC mg/l Fresh water Algae Pseudokirchneriella subcapitata Acute EC5 232 ug/l Fresh water Daphnia Daphnia magna Neonate <24 hours Acute LC5 22 ppm Fresh water Fish Oncorhynchus mykiss Juvenile (Fledgling, Hatchling, Weanling) Exposure 72 hours 96 hours 48 hours 96 hours Persistence/degradability Other adverse effects 13. Disposal considerations Waste disposal Contaminated packaging Waste residues information No known significant effects or critical hazards. Dispose of according to all federal, state and local applicable regulations. Waste must be disposed of according to applicable regulations. This material and its container must be disposed of as hazardous waste. Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. 14. Transport information Regulatory information UN number Proper shipping name Classes PG* Label Additional information DOT Classification TDG Classification Not Classification ADR/RID Class Not IMDG Class Not IATADGR Class Not PG* Packing group Not Not 4127D 7/9

8 Design Freedom Plus Alkaline Perm Neutralizer 15. Regulatory information HCS Classification U.S. Federal regulations Toxic material Irritating material Target organ effects TSCA Exempt SARA 32/34/311/312 extremely hazardous substances hydrogen peroxide SARA 32/34 emergency planning and notification hydrogen peroxide SARA 32/34/311/312 hazardous chemicals hydrogen peroxide SARA 311/312 MSDS distribution chemical inventory hazard identification hydrogen peroxide Fire hazard, reactive, Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Water Act (CWA) 311 disodium hydrogenorthophosphate; Phosphoric acid Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 62 Class I Substances Clean Air Act Section 62 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) Not listed Not listed Not listed Not listed Not listed State regulations Massachusetts New York New Jersey Pennsylvania California Prop. 65 WHMIS () The following components are listed HYDROGEN PEROXIDE CALIFORNIA PROPOSITION 65 The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of This product is not known to the State of California to cause cancer. inventory Not determined. (TSCA 8b) Canadian lists Class D1B Material causing immediate and serious toxic effects (Toxic). Class E Corrosive material Canadian NPRI None of the components are listed. CEPA Toxic substances None of the components are listed. inventory All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Classification The following components are listed Hydrogen peroxide The following components are listed HYDROGEN PEROXIDE The following components are listed HYDROGEN PEROXIDE (CONC > 52 PERCENT) Health 2 Flammability Reactivity Special International regulations 4127D 8/9

9 Design Freedom Plus Alkaline Perm Neutralizer 15. Regulatory information Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule III Chemicals 16. Other information Not listed Not listed Not listed Hazardous Material Information System (U.S.A.) Health 2 Flammability Physical hazards Caution HMIS ratings are based on a 4 rating scale, with representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR , the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (8) The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health 2 Flammability Instability/Reactivity Special Reprinted with permission from NFPA 7421, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 21, National Fire Protection Association, Quincy, MA This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 74 systems to classify chemicals does so at their own risk. Date of printing Date of issue Date of previous issue Version Prepared by Notice to reader 9/9/213. 9/12/212. No previous validation. 4 Regulatory Affairs Group Indicates information that has changed from previously issued version. To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 4127D 9/9

10 Product name Manufacturer Validation date In case of emergency Material Safety Data Sheet Design Freedom Plus Alkaline Perm PreTreatment Conditioner 1. Product and company identification Telephone number Transportation Emergency Product type Design Freedom Plus Alkaline Perm PreTreatment Conditioner Zotos International, INC 1 Tokeneke Road, Darien, CT /12/212. (8) [24 Hours] (23) [83 a.m. 5 p.m.] Contact CHEMTREC [US/ 24 Hours] Liquid. 2. Hazards identification Emergency overview NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. Color White. Offwhite. Odor Fragrancelike. Hazard statements MAY CAUSE EYE AND SKIN IRRITATION. Precautionary measures OSHA/HCS status None. Potential acute health effects Inhalation Ingestion Skin Chronic effects Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Overexposure signs/symptoms See toxicological information (Section 11) Do not breathe vapor or mist. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. No known significant effects or critical hazards. No known significant effects or critical hazards. Moderately irritating to the skin. Eyes Moderately irritating to eyes. Potential chronic health effects Medical conditions aggravated by overexposure Contains material that may cause target organ damage, based on animal data. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. None identified. None. 3. Composition/information on ingredients Name CAS number % glycerol propane1,2diol Decacyclopentasiloxane D 1/8

11 Design Freedom Plus Alkaline Perm PreTreatment Conditioner 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Eye contact Skin contact Inhalation Ingestion Protection of firstaiders Notes to physician 5. Firefighting measures Flammability of the product Extinguishing media Special exposure hazards Special firefighting procedures Hazardous thermal decomposition products Special protective equipment for firefighters In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. May cause eye irritation. Prolonged or repeated contact with skin or mucous membrane may result in irritation symptoms, such as redness, blistering, dermatitis etc. Discontinue use of product Apply cold compresses to affected areas to relieve any discomfort Seek medical attention if irritation persists. Move affected person to fresh air. Have conscious person drink several glasses of water or milk. Do not induce vomiting. Get medical attention if adverse health effects persist or are severe. Use suitable protective equipment (section 8). Treat symptomatically. In a fire or if heated, a pressure increase will occur and the container may burst. Extinguish fire using an agent suitable for the surrounding fire. Dike liquid for later disposal. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. None. 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up 7. Handling and storage Handling Storage Decomposition products may include the following materials carbon dioxide carbon monoxide metal oxide/oxides Noncombustible. No special recommendations. Do not touch or walk through spilled material. Keep container closed. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Place spilled material in an appropriate container for disposal. After contact with skin, wash immediately with plenty of water. Avoid contact with skin and eyes. Store in a dry, cool and wellventilated area, away from incompatible materials (see Section 1). Keep container tightly closed. Store in a dry place. 412D 2/8

12 Design Freedom Plus Alkaline Perm PreTreatment Conditioner 8. Exposure controls/personal protection Ingredient glycerol ACGIH TLV (, 2/21). TWA 1 mg/m³ 8 hour(s). Form Inhalable fraction OSHA PEL 1989 (, 3/1989). TWA 5 mg/m³ 8 hour(s). Form Respirable fraction TWA 1 mg/m³ 8 hour(s). Form Total dust OSHA PEL (, 6/21). TWA 5 mg/m³ 8 hour(s). Form Respirable fraction TWA 15 mg/m³ 8 hour(s). Form Total dust propane1,2diol AIHA WEEL (, 5/21). TWA 1 mg/m³ 8 hour(s). Occupational exposure limits No exposure limit value known. Occupational exposure limits No exposure limit value known. Consult local authorities for acceptable exposure limits. Recommended monitoring procedures Engineering measures Hygiene measures Personal protection Respiratory Hands Eyes Skin Environmental exposure controls Other protection If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Exposure limits In case of insufficient ventilation, wear suitable respiratory equipment. Use a properly fitted, airpurifying or airfed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Wear suitable gloves. Not available. 9. Physical and chemical properties Physical state Flash point Color Liquid. [Viscous liquid.] Closed cup Not applicable. White. Offwhite. Odor ph Fragrancelike. 3 to D 3/8

13 Design Freedom Plus Alkaline Perm PreTreatment Conditioner 9. Physical and chemical properties Boiling/condensation point Relative density >1 C (>212 F).99 to Stability and reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Stable under recommended storage and handling conditions (see section 7). No specific data. No specific data. 11. Toxicological information Acute toxicity Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous reactions will not occur. Product/ingredient name Result Dose Exposure glycerol LD5 Oral 126 mg/kg propane1,2diol LD5 Dermal 28 mg/kg LD5 Oral 2 g/kg Decacyclopentasiloxane LD5 Oral >24134 mg/kg Chronic toxicity Irritation/Corrosion Carcinogenicity Mutagenicity Product/ingredient name Result Score Exposure Observation glycerol Eyes Mild irritant 24 hours 5 milligrams Skin Mild irritant 24 hours 5 milligrams propane1,2diol Eyes Mild irritant 24 hours 5 milligrams Eyes Mild irritant 1 milligrams Skin Moderate irritant 96 hours 3 Percent continuous Skin Mild irritant 168 hours 5 milligrams Skin Moderate irritant 72 hours 14 milligrams Intermittent Skin Mild irritant 96 hours 3 Percent Decacyclopentasiloxane Eyes Mild irritant 24 hours 5 milligrams Skin Mild irritant 24 hours 5 milligrams Sensitizer No carcinogenic effect. 412D 4/8

14 Design Freedom Plus Alkaline Perm PreTreatment Conditioner 11. Toxicological information Teratogenicity Reproductive toxicity Acute toxicity Chronic toxicity Irritation/Corrosion Sensitizer Carcinogenicity Mutagenicity Teratogenicity Reproductive toxicity Acute toxicity Chronic toxicity Irritation/Corrosion Sensitizer Carcinogenicity Mutagenicity Teratogenicity Reproductive toxicity 12. Ecological information THE FOLLOWING DATA IN THIS SECTION IS SOURCED FROM PUBLICLY AVAILABLE DATABASES AND NOT THE REPRESENTATION OF ANY DATA COLLECTED BY ZOTOS INTERNATIONAL OR ITS AFFILIATES. Ecotoxicity Aquatic ecotoxicity No known significant effects or critical hazards. 412D 5/8

15 Design Freedom Plus Alkaline Perm PreTreatment Conditioner 12. Ecological information Product/ingredient name Result Species glycerol Acute LC5 54 ml/l Fresh water Fish Oncorhynchus mykiss.9 g propane1,2diol Acute EC5 >1 mg/l Fresh water Daphnia Daphnia magna <24 hours Acute LC5 12 ug/l Fresh water Crustaceans Ceriodaphnia dubia <=24 hours Acute LC5 71 ug/l Fresh water Fish Pimephales promelas <=7 days Exposure 96 hours 48 hours 48 hours 96 hours Persistence/degradability Aquatic ecotoxicity Persistence/degradability Aquatic ecotoxicity Persistence/degradability Other adverse effects 13. Disposal considerations Waste disposal Contaminated packaging Waste residues information No known significant effects or critical hazards. Dispose of according to all federal, state and local applicable regulations. Waste must be disposed of according to applicable regulations. This material and its container must be disposed of as hazardous waste. Waste must be disposed of according to applicable regulations. This material and its container must be disposed of as hazardous waste. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. 14. Transport information Regulatory information UN number Proper shipping name Classes PG* Label Additional information DOT Classification TDG Classification Not Classification Not Not ADR/RID Class Not IMDG Class Not IATADGR Class Not 412D 6/8

16 Design Freedom Plus Alkaline Perm PreTreatment Conditioner 14. Transport information PG* Packing group 15. Regulatory information HCS Classification U.S. Federal regulations Irritating material Target organ effects TSCA Exempt SARA 32/34/311/312 extremely hazardous substances No products were found. SARA 32/34 emergency planning and notification No products were found. SARA 32/34/311/312 hazardous chemicals propane1,2diol; glycerol; propane1,2 diol SARA 311/312 MSDS distribution chemical inventory hazard identification propane1,2diol Immediate (acute) health hazard, Delayed (chronic) health hazard; glycerol Immediate (acute) health hazard, Delayed (chronic) health hazard; propane 1,2diol Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 62 Class I Substances Clean Air Act Section 62 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) Not listed Not listed Not listed Not listed Not listed State regulations Massachusetts New York California Prop. 65 Classification The following components are listed GLYCERINE MIST None of the components are listed. New Jersey The following components are listed GLYCERIN; 1,2,3PROPANETRIOL; PROPYLENE GLYCOL; 1,2PROPANEDIOL; PROPYLENE GLYCOL; 1,2PROPANEDIOL Pennsylvania The following components are listed 1,2,3PROPANETRIOL; 1,2PROPANEDIOL; 1,2 PROPANEDIOL CALIFORNIA PROPOSITION 65 The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of This product is not known to the State of California to cause cancer. Canadian lists inventory Not determined. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Flammability Health Reactivity Special International regulations 412D 7/8

17 Design Freedom Plus Alkaline Perm PreTreatment Conditioner 15. Regulatory information Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule III Chemicals 16. Other information Not listed Not listed Not listed Hazardous Material Information System (U.S.A.) Health 2 Flammability Physical hazards Caution HMIS ratings are based on a 4 rating scale, with representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR , the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (8) The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health 2 Flammability Instability/Reactivity Special Reprinted with permission from NFPA 7421, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 21, National Fire Protection Association, Quincy, MA This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 74 systems to classify chemicals does so at their own risk. Date of printing Date of issue Date of previous issue Version Notice to reader 9/3/213. 9/12/212. No previous validation. 1 Prepared by Regulatory Affairs Group Indicates information that has changed from previously issued version. To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 412D 8/8

18 Product name Manufacturer Validation date In case of emergency Material Safety Data Sheet Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion 1. Product and company identification Telephone number Transportation Emergency Product type Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion Zotos International, INC 1 Tokeneke Road, Darien, CT /12/212. (8) [24 Hours] (23) [83 a.m. 5 p.m.] Contact CHEMTREC [US/ 24 Hours] Liquid. 2. Hazards identification Emergency overview NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. Color Clear. Odor Fragrant. Hazard statements CAUSES EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. Precautionary measures OSHA/HCS status Potential acute health effects Inhalation Ingestion Skin Eyes Potential chronic health effects Chronic effects Carcinogenicity Mutagenicity Teratogenicity Developmental effects This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Mild irritant May cause sensitization by skin contact. Prolonged or repeated contact with skin or mucous membrane may result in irritation symptoms, such as redness, blistering, dermatitis etc. Contains material that may cause target organ damage, based on animal data. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Overexposure signs/symptoms Inhalation Ingestion Skin Eyes Do not breathe vapor or mist. Do not ingest. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. MAY CAUSE RESPIRATORY TRACT IRRITATION. No specific data. No specific data. Adverse symptoms may include the following irritation redness Adverse symptoms may include the following pain or irritation watering redness Medical conditions aggravated by overexposure Preexisting disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by overexposure to this product. 4124A 1/8

19 Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion 2. Hazards identification See toxicological information (Section 11) 3. Composition/information on ingredients Name CAS number % Monoethanolamine There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Eye contact Skin contact Inhalation Ingestion Protection of firstaiders Notes to physician Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention if you feel unwell. Wash contaminated skin with soap and water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if you feel unwell. Get medical attention immediately. Use suitable protective equipment (section 8). Avoid exposure. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. 5. Firefighting measures Flammability of the product Extinguishing media Special exposure hazards Special firefighting procedures Hazardous thermal decomposition products Special protective equipment for firefighters In a fire or if heated, a pressure increase will occur and the container may burst. Extinguish fire using an agent suitable for the surrounding fire. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. None. 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up 7. Handling and storage Handling Storage Decomposition products may include the following materials carbon dioxide carbon monoxide nitrogen oxides sulfur oxides In a fire, decomposition may produce toxic gases/fumes. Wear suitable protective clothing. Wear protective gloves. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Use a water rinse for final cleanup. Avoid contact with skin and eyes. Store in a dry, cool and wellventilated area, away from incompatible materials (see Section 1). Avoid increased storage temperature. 4124A 2/8

20 Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion 8. Exposure controls/personal protection Ingredient Monoethanolamine ACGIH TLV (, 2/21). TWA 3 ppm 8 hour(s). TWA 7.5 mg/m³ 8 hour(s). STEL 6 ppm 15 minute(s). STEL 15 mg/m³ 15 minute(s). OSHA PEL 1989 (, 3/1989). TWA 3 ppm 8 hour(s). TWA 8 mg/m³ 8 hour(s). STEL 6 ppm 15 minute(s). STEL 15 mg/m³ 15 minute(s). NIOSH REL (, 6/29). TWA 3 ppm 1 hour(s). TWA 8 mg/m³ 1 hour(s). STEL 6 ppm 15 minute(s). STEL 15 mg/m³ 15 minute(s). OSHA PEL (, 6/21). TWA 3 ppm 8 hour(s). TWA 6 mg/m³ 8 hour(s). Occupational exposure limits No exposure limit value known. Occupational exposure limits No exposure limit value known. Consult local authorities for acceptable exposure limits. Recommended monitoring procedures Engineering measures Hygiene measures Personal protection Respiratory Hands Eyes Skin Environmental exposure controls Other protection Exposure limits If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. In case of insufficient ventilation, wear suitable respiratory equipment. When using do not eat, drink or smoke. Wear suitable protective clothing. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. In case of insufficient ventilation, wear suitable respiratory equipment. Wear suitable gloves. Safety glasses. Not available. 9. Physical and chemical properties Physical state Flash point Color Odor ph Boiling/condensation point Relative density Liquid. [Viscous liquid.] Closed cup Not applicable. Clear. Fragrant. 8.4 to 9.3 >1 C (>212 F) 1.6 to A 3/8

21 Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion 1. Stability and reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Stable under recommended storage and handling conditions (see section 7). No specific data. No specific data. Ammonia. sulfur oxides Not available. 11. Toxicological information Acute toxicity Product/ingredient name Result Dose Exposure Monoethanolamine LD5 Oral 172 mg/kg Chronic toxicity Irritation/Corrosion Carcinogenicity Mutagenicity Teratogenicity Reproductive toxicity Acute toxicity Chronic toxicity Carcinogenicity Mutagenicity Product/ingredient name Result Score Exposure Observation Monoethanolamine Eyes Severe irritant 25 Micrograms Skin Moderate irritant 55 milligrams Sensitizer Irritation/Corrosion Sensitizer Teratogenicity No carcinogenic effect. 4124A 4/8

22 Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion 11. Toxicological information Reproductive toxicity Acute toxicity Chronic toxicity Irritation/Corrosion Sensitizer Carcinogenicity Mutagenicity Teratogenicity Reproductive toxicity 12. Ecological information THE FOLLOWING DATA IN THIS SECTION IS SOURCED FROM PUBLICLY AVAILABLE DATABASES AND NOT THE REPRESENTATION OF ANY DATA COLLECTED BY ZOTOS INTERNATIONAL OR ITS AFFILIATES. Ecotoxicity Aquatic ecotoxicity Product/ingredient name Aquatic ecotoxicity No known significant effects or critical hazards. Result Species Exposure Monoethanolamine Acute EC5 8 ug/l Fresh water Algae Isochrysis galbana 96 hours Acute LC5 >1 ug/l Marine water Crustaceans Crangon crangon 48 hours Adult Acute LC5 15 mg/l Fresh water Fish Oncorhynchus mykiss Yolksac fry 96 hours Persistence/degradability Persistence/degradability Aquatic ecotoxicity Persistence/degradability Other adverse effects No known significant effects or critical hazards. 4124A 5/8

23 Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion 13. Disposal considerations Waste disposal Dispose of according to all federal, state and local applicable regulations. Contaminated packaging Waste must be disposed of according to applicable regulations. This material and its container must be disposed of as hazardous waste. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. 14. Transport information Regulatory information DOT Classification UN number Proper shipping name Classes PG* Label Additional information TDG Classification Not Classification Not Not ADR/RID Class Not IMDG Class Not IATADGR Class Not PG* Packing group 15. Regulatory information HCS Classification U.S. Federal regulations Irritating material Target organ effects TSCA Exempt SARA 32/34/311/312 extremely hazardous substances No products were found. SARA 32/34 emergency planning and notification No products were found. SARA 32/34/311/312 hazardous chemicals Monoethanolamine SARA 311/312 MSDS distribution chemical inventory hazard identification Monoethanolamine Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 62 Class I Substances Clean Air Act Section 62 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) Not listed Not listed Not listed Not listed Not listed 4124A 6/8

24 Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion 15. Regulatory information State regulations Massachusetts New York New Jersey Pennsylvania California Prop. 65 The following components are listed ETHANOLAMINE CALIFORNIA PROPOSITION 65 The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of This product is not known to the State of California to cause cancer. Canadian lists inventory Not determined. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Classification None of the components are listed. The following components are listed ETHANOLAMINE; ETHANOL, 2AMINO The following components are listed ETHANOL, 2AMINO Health Flammability Reactivity Special International regulations Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule III Chemicals 16. Other information Not listed Not listed Not listed Hazardous Material Information System (U.S.A.) Health 2 Flammability Physical hazards Caution HMIS ratings are based on a 4 rating scale, with representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR , the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (8) The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health 2 Flammability Instability/Reactivity Special 4124A 7/8

25 Design Freedom Plus Alkaline Perm For Normal & Tinted Hair Waving Lotion 16. Other information Reprinted with permission from NFPA 7421, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 21, National Fire Protection Association, Quincy, MA This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 74 systems to classify chemicals does so at their own risk. Date of printing Date of issue Date of previous issue Version Prepared by Notice to reader 9/3/213. 9/12/212. No previous validation..2 Regulatory Affairs Group Indicates information that has changed from previously issued version. To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 4124A 8/8