Material Safety Data Sheet

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1 DALER ~ ROWNEY U.S.A. FINE ART & GRAPHIC MATERIALS Daler-Rowney USA, 2 Corporate Drive, Cranbury, New Jersey U.S.A. Tel: Fax: Material Safety Data Sheet 1. IDENTIFICATION OF THE PREPARATION AND COMPANY Product : Intended use: GEORGIAN OIL COLOUR (All colours with the exception of Flake White & OIL COLOUR PAINTING. Underpainting White see separate MSDS s) Manufacturers Name: Daler-Rowney Ltd. Address: 2 Corporate Drive Cranbury New Jersey Emergency telephone Number: Telephone Number for information: Date of Issue: 2 nd November CHEMICAL COMPOSITION/INFORMATION ON INGREDIENTS Substances presenting a health hazard with the meaning of the Dangerous Substances Directive 67/548/EEC. Names: % (wt) Concentration Symbol R Phrases 3. HAZARDS IDENTIFICATION OF PREPARATION Product Type: Georgian Oil Colour. For use in oil painting. Labelling requirements in conformity with ASTM D 4236 Classified as HL Non - Toxic

2 FIRST AID MEASURES. General: Inhalation: In all cases, if symptoms persist, seek medical attention. NEVER give anything by mouth to an unconscious person. Not Applicable. Eye contact: Skin contact: Ingestion: Irrigate eyes with copious amounts of water for at least ten minutes. If irritation Persists, seek medical attention. Wash affected area with plenty of soap and water. DO NOT use solvent. If irritation persists, seek medical attention. DO NOT induce vomiting. Flush mouth with clean water. Seek medical attention. 5. FIRE FIGHTING METHODS Extinguishing media: Dry or Foam Extinguishers. Not to be used: Water jet. Recommendations/other information : 6. ACCIDENTAL RELEASE MEASURES Clean up with absorbent cloth. Any residue can be cleaned up with a cloth dampened with solvent. USE PROTECTIVE GLOVES when using solvents. Ensure good ventilation. Dispose of any soiled rags or waste in a sealed water filled metal container. Dispose of in accordance with local regulations. 7. HANDLING AND STORAGE Handling: Storage: Observe good standards of hygiene. DO NOT eat, drink or smoke whilst using. Wash hands after use. Reseal tube when not in use. Store at room temperature. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSON PROTECTION Wear overalls / smock. DO NOT eat, drink or smoke whilst using. Wash hands before eating, drinking or smoking

3 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Odour: ph of aqueous extract: Melting point: Flash point: Flammability : Explosive properties : Oil colours of buttery consistency. Linseed oil. Not Applicable Greater than C Not Applicable. See 5 above. Not Applicable Specific gravity: Solubility water: Organic solvents: Insoluble. Soluble in White Spirit, Turpentine or Isoparrafin Solvents (eg. Daler-Rowney Low Odour Thinners). 10. STABILITY AND REACTIVITY Conditions to avoid: Materials to avoid: Contains an oxidising oil. Rags, Steel wool or waste soaked with this product may spontaneously catch fire if improperly discarded. Immediately after use, place soiled material in a sealed water filled metal container. None known. Hazardous decomposition products : Nothing below C 11. TOXICOLOGICAL INFORMATION There are no data on the preparation itself. Threshold limit: Ingestion: Not considered to represent a significant health hazard. May cause discomfort. Skin: Prolonged contact may result in a mild reaction in some cases. Eyes: May cause temporary discomfort. Respiratory: Not Applicable. 12. ECOLOGICAL INFORMATION No information available.

4 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local regulations 14. TRANSPORT INFORMATION Transport only in accordance with ADR for roads, RID for Rail, IMDG for sea and ICAO/IATA for air transport ADR/RID: IMG : ICAO/IATA: Not restricted. Not restricted. Not restricted Packaging Group. 15. REGULATORY INFORMATION In accordance with ASTM D 4236 the product is labelled as follows: Danger Classification : HL Non Toxic. 16. OTHER INFORMATION The information on this MSDS is based on the present state of our knowledge, as the users working conditions are beyond our knowledge and control. The product is not to be used for other purposes than specified in section 1 without first seeking our advice. It is always the responsibility of the user to take necessary steps in order to fulfil the demands laid down in the local rules of legislation. The information in this MSDS is meant as a description of the safety requirements of our product: it is not to be considered as a guarantee of the products properties.

5 DALER ~ROWNEY U.S.A. FINE ART & GRAPHIC MATERIALS Daler-Rowney USA, 2 Corporate Drive, Cranbury, New Jersey U.S.A. Tel: Fax: Material Safety Data Sheet SECTION I PRODUCTS & MANUFACTURERS DETAILS Identification of Product (as listed): GEORGIAN OIL COLOUR FLAKE WHITE Manufacturers Name: Address: Daler-Rowney Ltd 2 Corporate Drive Cranbury New Jersey Emergency Telephone Number: Telephone Number for information: Date Prepared: 25 th June 2000 SECTION II HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Product Type: White oil colour for oil painting. Contains lead carbonate pigment. Labelling Requirements Conform to ASTM D-4236 WARNING: May be harmful if swallowed. Cancer agent based on experimental data. Exposure may cause damage to the testes, difficulty with reproduction (child bearing) or harmful to the developing foetus. Exposure may cause nervous system, kidney or bone marrow damage. Contains lead. Precautions: Do not spray apply. Wash hands immediately after use. When using do not eat, drink or smoke. Wear a work apron. Keep in original container. AVOID USING IF PREGNANT OR CONTEMPLATING PREGNANCY. NOT FOR USE IN HEALTH CARE FACILITIES. KEEP OUT OF REACH OF CHILDREN. For further health information contact a poison control center.

6 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Over 300 Solubility in Water: Imiscible Specific Gravity: 2.4 Freezing: Not determined Evaporation Rate: Not applicable Appearance and Odour: White oil colour. Linseed oil. SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point (method used): Over 230 Extinguishing Media: Use dry powder, foam, carbon dioxide or halon extinguisher. Special Fire Fighting Procedures: Never use water since this may boil explosively or may float the burning oil and thus spread the fire. Unusual Fire and Explosion Hazards: Danger of spontaneous combustion if colour is absorbed onto porous material (e.g. clay, cloths and rags, particularly cotton. ) Ensure all porous material is sprayed well with water. SECTION V REACTIVITY DATA Stability: Stable Conditions to Avoid: May auto ignite over 300 C Hazardous Decomposition/byproducts: If heated over 250 will decompose to give complex mixture of aldehydes, lactones and ketones, notably acrolein Hazardous Polymerisation: None known.

7 SECTION VI HEALTH HAZARD DATA Inhalation: Not applicable. Do not spray apply Skin: Not considered hazardous. Wash skin with soap and warm water. Flush eye with water and seek medical advice. Ingestion: May cause nausea and sickness. Exposure may cause nervous system, kidney or bone marrow damage. Exposure may cause damage to the testes, difficulty with reproduction and harm to the developing foetus. If swallowed seek prompt medical attention. Carcinogenicity: Cancer agent based on experimental data. Signs & Symptons of Exposure: Nausea, sickness, abdonimal pain. Medical Conditions aggravated by exposure: Avoid using if pregnant or contemplating pregnancy. Emergency and First Aid Procedure: Seek immediate medical attention. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be taken in case material is released or spilled. Contain the spilll with sand or earth. Spray the earth with water to avoid spontaneous combustion. Any rags or cloths used to clean up the spill should be burnt; if left crumpled in a dustbin there is a risk of spontaneous combustion and any cloths which cannot be burnt should be soaked in water for 5 minutes then placed in a flat bin. Waste Disposal Method. Dispose in accordance with local regulations Precautions to be taken in handling and storing. Store at room temperature. Keep in original container. Avoid using if pregnant or contemplating pregnancy. Not to be used in health care facilities. Keep out of reach of children. Wash hands after use. When using do not eat, smoke or drink. Do not spray apply. SECTION VIII CONTROL MEASURES Respiratory Protection: Not applicable. Do not spray apply

8 Protective Gloves: None Eye Protection: None Other Precautions: Clothing and Equipment: Apron SECTION IX OTHER INFORMATION The information on this MSDS is based on the present state of our knowledge, as the users working conditions are beyond our knowledge and control. The product is not to be used for other purposes than specified in section 11 without first seeking our advice. It is always the responsibility of the user to take necessary steps in order to fulfil the demands laid down in the local rules of legislation. The information in this MSDS is meant as a description of the safety requirements of our product: it is not to be considered as a guarantee of the products properties. gocfw4

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