SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE AND THE COMPANY. Uses other than those identified on the product label are not recommended.

Transcription

1 SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE AND THE COMPANY Date Issued: Supersedes: Product Name: Product Number: Brand: Recommended use: Uses advised against: 67 Carpet Spotter (Ready-to-Use) SEB B Sustainable Earth by Staples Carpet cleaner Uses other than those identified on the product label are not recommended. Supplier Name: Staples Contract & Commercial, Inc. Supplier Address: 500 Staples Drive Framingham MA USA Supplier Phone Number: SDS Internet Address: Emergency telephone number: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) and Canadian Hazardous Products Regulations (HPR) (WHMIS 2015-GHS). Classification for the Undiluted Product Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Acute toxicity - Inhalation (vapors) Category 4 GHS Label elements, including precautionary statements Emergency Overview: 2. HAZARDS IDENTIFICATION Signal word: Hazard Statements: Precautionary Statements Prevention: IF IN EYES: IF ON SKIN: IF INHALED: Danger Causes severe skin burns and eye damage. Harmful if inhaled. Avoid breathing mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing immediately. Call a poison center or doctor/physician. Wash with plenty of soap and water. If skin irritation occurs, get medical advice/attention. Take off contaminated clothing and wash before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell.

2 Hazards not otherwise classified (HNOC): t applicable Other information: Interactions with Other Chemicals: Harmful to aquatic life with long lasting effects. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Weight-% Hydrogen peroxide Dipropylene glycol butyl ether Ethoxylated surfactants Trade secret 1-5 Sodium hydroxide Balance is water and similar non-hazardous ingredients. fragrance added. General Advice First aid measures: Eye Contact Skin Contact Inhalation Ingestion Self-protection of the first aider required: 4. FIRST AID MEASURES Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and easy to do. Continue rinsing. Do not rub affected area. Seek immediate medical attention/advice. Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists. Remove to fresh air. Get medical attention immediately if symptoms occur. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician. Avoid contact with skin, eyes or clothing. Use personal protective equipment. Most Important Symptoms and Effects: Burning sensation. Coughing and/or wheezing. Difficulty in breathing. tes to Physician: Treat symptomatically. Suitable Extinguishing Media: Unsuitable extinguishing media: 5. FIRE-FIGHTING MEASURES Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical: Uniform Fire Code: Uniform Fire Code: Hazardous Combustion Products: Irritant: Liquid Irritant: Liquid Carbon oxides. Explosion Data Sensitivity to Mechanical Impact:. Sensitivity to Static Discharge:. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 2 of 7

3 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: Methods for Containment: Methods for cleaning up: Handling: Storage: Incompatible Products: Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Avoid breathing vapors or mists. Prevent from entering soil, ditches, sewers, waterways and/or ground water. Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Avoid breathing vapors or mists. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up. Store away from incompatible material. Keep out of the reach of children. Strong acids. Strong oxidizing agents. Strong bases. Control parameters 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name / CAS ACGIH TLV OSHA PEL NIOSH IDLH Hydrogen peroxide TWA: 1 ppm TWA: 1 ppm TWA: 1.4 mg/m 3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH National Institute for Occupational Safety and Health - Immediately Dangerous to Life or Health IDLH: 75 ppm TWA: 1 ppm TWA: 1.4 mg/m 3 Engineering Measures: General ventilation normally adequate. Individual protection measures, such as personal protective equipment Eye / Face Protection: Skin and Body Protection: Respiratory Protection: Wear splash-proof, chemical-resistant goggles. Wear chemical-resistant gloves and long sleeved clothing. protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures:. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Physical State Appearance: Liquid Odor: Sweet Color: Colorless Odor Threshold: information available Property Values ph (as is) Melting / freezing point Boiling point /boiling range Flash Point Evaporation Rate Flammability Lower flammability limit Vapor density Specific Gravity PHYSICAL AND CHEMICAL PROPERTIES Page 3 of 7

4 Water Solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Softening Point VOC Content (by wt) Particle Size Particle Size Distribution Soluble in water <0.0% (0 g/l) This product is compliant with California Air Resources Board (CARB) regulations on Volatile Organic Compounds (VOC). Reactivity. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions ne under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid ne known based on information supplied. Incompatible Materials Strong acids. Strong oxidizing agents. Strong bases. Hazardous Decomposition Products Carbon oxides. Information on likely routes of exposure Product Information. 10. STABILITY AND REACTIVITY 11. TOXICOLOGICAL INFORMATION Inhalation Eye Contact Skin Contact Ingestion Component Information Specific test data for this product is not available. May cause irritation of respiratory tract. Harmful by inhalation (based on components). Specific test data for the substance or mixture is not available. Expected to be an irritant based on components. Severely irritating to eyes. Causes serious eye damage. May cause burns. May cause irreversible damage to eyes. Specific test data for the substance or mixture is not available. Expected to be an irritant based on components. Irritating to skin. Prolonged contact may cause redness and irritation. Specific test data for the substance or mixture is not available. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chemical Name / CAS# Oral LD50 Dermal LD50 Inhalation LC50 Hydrogen peroxide = 801 mg/kg ( Rat ) = 4060 mg/kg ( Rat ) = 2 g/m 3 ( Rat ) 4 h = 2000 mg/kg ( Rabbit ) Dipropylene glycol butyl ether >2.04 mg/l (Rat) 4 H = 42.1 ppm (Rat) 4 H Information on toxicological effects Symptoms Erythema (skin redness). May cause redness and tearing of the eyes. May cause blindness. Burning. Coughing and/or wheezing. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Mutagenic Effects Page 4 of 7

5 Carcinogenicity Chemical Name / CAS ACGIH IARC NTP OSHA Hydrogen peroxide A3 Group 3 ACGIH (American Conference of Governmental Industrial Hygienists): A3 - Animal Carcinogen IARC (International Agency for Research on Cancer): Group 3 - t Classifiable as to Carcinogenicity in Humans Reproductive Toxicity STOT - single exposure STOT - repeated exposure Chronic Toxicity known effect. Target Organ Effects Respiratory system. Eyes. Skin. Blood. Lungs. Aspiration Hazard Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral): 12, mg/kg ATEmix (dermal): 65, mg/kg (ATE) ATEmix (inhalation-dust/mist): mg/l ATEmix (inhalation-vapor): ATEmix Ecotoxicity Harmful to aquatic life with long lasting effects.. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna Microorganisms (Water Flea) Hydrogen Peroxide h EC50: = 2.5 mg/l (Chlorella vulgaris) 12. ECOLOGICAL INFORMATION 96h LC50:= mg/l (Oncorhynchus mykiss) 96h LC50:= mg/l (Lepomis macrochirus) 96h LC50: = 16.4 mg/l (Pimephales promelas) 48h EC50:= mg/l 24h EC50: = 7.7 mg/l Dipropylene glycol butyl ether h LC50: = 841 mg/l (Poecilia reticulata) Persistence and Degradability: Bioaccumulation: Other adverse effects: 13. DISPOSAL CONSIDERATIONS Disposal methods: This material is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Contaminated Packaging Dispose of contents/containers in accordance with local regulations. California Hazardous Waste Codes 331 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Hydrogen peroxide Toxic / Corrosive / Ignitable / Reactive 24-HR EMERGENCY PHONE: DOT/ TDG/ MEX/ ICAO/ IATA/ IMDG/IMO: t Regulated 14. TRANSPORT INFORMATION Page 5 of 7

6 International Inventories TSCA (US) Complies DSL (Canada) All components are listed either on the DSL or NDSL. US Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden release of pressure hazard Reactive Hazard Yes CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances Hydrogen peroxide X X X X CERCLA This material contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name / CAS Hazardous Substances RQs Extremely Hazardous Substances RQs Hydrogen peroxide lb RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Hydrogen peroxide X X X X Sodium hydroxide X X X X International Regulations Canada Page 6 of 7

7 16. OTHER INFORMATION NFPA Health Hazards 2 Flammability 0 Instability 0 Physical & chemical Hazards Personal protection X HMIS Health Hazards 2 Flammability 0 Physical Hazard 0 Prepared By: Regulatory Specialist, Staples Brand Group, (508) Always follow label directions carefully when using this or any other chemical product. If information about this product is required, please contact Staples at or visit our website at Keep Safety Data Sheets filed and organized in an area accessible to workers according to all applicable regulations. All information contained in this SDS is provided to the best of Staples Contract & Commercial Inc s knowledge. warranty is made with respect to this information expressed or implied, including warranties of merchantability or fitness for a particular purpose. Users are responsible for verifying the information under their own operating conditions to determine whether the products listed in the SDS are suitable for their intended use. Users are responsible for compliance with all laws and regulations as may be required by their receipt of the information and use of the products provided with this SDS. Page 7 of 7