Ethnic Care Formulary No. 930

Transcription

1 Minerals Ethnic Care Formulary No. 90

2 Minerals Ethnic Care Formulary No. 90 Specialties Department No. 90(rev) ETHNIC SKIN & HAIR CARE FORMULARY VANATURAL entonite Clay VEEGUM Magnesium Aluminum Silicate VANZAN Xanthan Gum VANATURAL entonite Clay (INCI Name: entonite) and VEEGUM Magnesium Aluminum Silicate (INCI Name: Magnesium Aluminum Silicate) are natural water-washed smectite clays that reliably stabilize personal care and pharmaceutical emulsions and suspensions. VANATURAL bentonite is in full compliance with the rules established by the USDA National Organic Program (NOP). The NOP provides regulations and guidance for raw materials used in products claimed as organic or that contain organic ingredients (7CFR through ). entonite is listed as an allowed component in such products. VANATURAL bentonite is therefore recommended for use in organic personal care products. VANZAN Xanthan Gum (INCI Name: Xanthan Gum) is a natural high molecular weight, exocellular polysaccharide derived from Xanthomonas campestris. ecause of its protective function in nature, it is more resistant than are most gums to shear, heat, bacterial, enzyme, and UV degradation. VANZAN products are efficient thickeners as well as emulsion and suspension stabilizers. They also provide useful synergism with VANATURAL and VEEGUM clays. USING VANATURAL AND VEEGUM CLAYS VANATURAL and VEEGUM products must be properly dispersed in water to provide their best performance. No other materials should be present in the water, because they can interfere with the proper hydration of the clay and the formation of the colloidal structure. The degree of clay hydration is directly proportional to the amount of energy used to disperse the product. The degree of hydration therefore increases as mixing time, mixing intensity or water temperature increase. One grade, VEEGUM Ultra, is relatively unaffected by changes in these mixing factors; adequate hydration can be achieved quickly, using room temperature water and a simple, slow-speed propeller mixer. The following table provides suggested minimum mixing times for the hydration of VANATURAL and VEEGUM products. Actual hydration times, in the laboratory or in production, will depend on the particular combination of batch size, mixer shear, and water temperature used. Whichever mixing conditions are used, it is very important that they be carefully controlled to achieve reproducible results in the final formulation. Minimum Suggested Mixing Time VANATURAL Water Temp. Mixer Type Mixer Speed, rpm VEEGUM R VEEGUM HS VEEGUM Ultra 5 C Propeller min. 0 min. 5 min. 75 C Propeller min. 0 min. 0 min. 5 C Homogenizer min. 0 min. 0 min. 75 C Homogenizer min. 0 min. 0 min. USING VANZAN XANTHAN GUM VANZAN products are soluble in both cold and warm water. To dissolve quickly and completely, they must first be properly dispersed so that individual gum particles are surrounded by the aqueous medium. The individual particles then hydrate and dissolve. Good dispersion is promoted by high shear mixing, blending the gum particles into a water-miscible non-solvent such as glycol or alcohol before addition to the aqueous phase, or dry blending with other formula ingredients such as co-thickeners, salts, acids, abrasives or pigments before addition to the aqueous phase. RECOMMENDED GRADES FOR SKIN AND HAIR CARE FORMULATIONS Smectite Clays: VANATURAL Rapidly hydrating high purity bentonite clay. VEEGUM Ultra A unique acidic smectite clay that is especially easy to hydrate. VEEGUM R The standard grade for a wide range of applications. VEEGUM HS A fast hydrating grade with maximum electrolyte stability. Xanthan Gum: VANZAN NF The standard personal care grade.

3 Minerals Ethnic Care Formulary No. 90 FORMULARY SKIN CARE All Natural Shea utter/cocoa utter Lotion No. 589 Soothing Organic Skin Lotion with Calendula Extract No. 595 Rejuvenating Lotion No. 574 Intensive AHA Moisturizing Cream No. 484 Vitamin-Enriched Skin Cream With Natural Moisturizers No. 545 Conditioning Skin Cream with Jojoba Oil No. 57 Oatmeal Lotion No. 586 Oatmeal & Macadamia Cream No. 588 Rich ody utter Plus Sunscreen No. 60 Moisturizing Lotion with Sunscreen No. 567 Moisturizing Cream with Sunscreen No. 568 Wash-Off Resistant Sunscreen Cream No. 55 Green Tea Instant Facial No. 54 AHA Clay Mask No. 487 Moisturizing Gel for Oily Skin, Containing Tea Tree Oil No. 554 HAIR CARE Thioglycolate Relaxer No. 77 Hydroxide Relaxer No. 80 isulfite Relaxer No. 8 Relaxer/Waving Lotion No. 85 Pearlescent No Residue Conditioning Shampoo No. 488 Zinc Pyrithione Lotion Shampoo No. 64 GROOMING Depilatory Cream No. 64 Depilatory Lotion No. 86 Washing Cream for Sensitive Skin No. 505 Extra Mild Facial Cleanser No. 55 Aerosol Shave Cream for Sensitive Skin No. 50 After Shaving alm No. 558 Licorice Extract Fade Lotion No. 604 Fade Cream No. 8 otanical Fade Lotion No. 49 5% enzoyl Peroxide Acne Treatment Lotion No. 56 Salicylic Acid Acne Treatment Cream No. 60 Instant Sulfur Acne Treatment Mask No. 590 Sulfur and Salicylic Acid Wash No. 58 Cleansing ar No. 08 Natural Exfoliant Scrub No. 576

4 All Natural Shea utter/cocoa utter Lotion No. 589 VANATURAL entonite Clay.5 A VANZAN NF Xanthan Gum 0.5 Water 78.0 Cetearyl Wheat Straw Glycosides (and) Cetearyl Alcohol (Xyliance TM ) 5.0 Orbignya Oleifera Seed Oil (Cropure abassu ) 5.0 Simmondsia Chinensis (jojoba) seed oil (Jojoba Oil Golden ) 5.0 utyrospermum Parkii (Shea) utter (Tomasa Shea utter 4 ).0 Theobroma Cacao (cocoa) seed butter (Cocoa utter NF 5 ).0 C Preservative Procedure: While heating the water to C, slowly add the VANATURAL and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Maintain the water phase at C. lend the Part oil phase ingredients and heat to C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; add Part C when the emulsion is <0 C. Actives International, Allendale, NJ Croda Inc., Edison, NJ Desert Whale Jojoba Co., Inc., Tucson, AZ 4 Tri-K Industries, Inc., Northvale, NJ 5 RITA Corporation, Crystal Lake, IL VANATURAL and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Cropure is a registered trademark of Croda, Inc. Xyliance is a trademark of Soliance. rev0//0

5 Soothing Organic Skin Lotion with Calendula Extract No. 595 Wt.% VANATURAL entonite Clay.50 A VANZAN NF Xanthan Gum 0.50 Water 7.0 Cetearyl Wheat Straw Glycosides (and) Cetearyl Alcohol (Xyliance TM ) 5.0 utyrospermum Parkii (Shea) utter (Shea utter-ultra Refined TM Certified.5 Organic ) Theobroma Cacao (cocoa) seed butter (Cocoa utter-ultra Natural TM Certified.5 Organic ) Persea Gratissima (Avocado) Oil (Avocado Oil Certified Organic ) 6.0 Simmondsia Chinensis (Jojoba) Seed Oil (Jojoba Oil- Natural Golden-Certified.0 Organic ) C Glycerin (and) Water (and) Calendula Officinalis Flower Extract (Certified Organic Calendula Extract ) Preservative 5.0 Procedure: While heating the water to 75 C, slowly add the VANATURAL and VANZAN NF (sequentially or as a dry blend) while mixing at maximum available shear. Mix until fully hydrated.. Maintain the water phase temperature at 75 C. Combine Part ingredients and heat to 75 C. Add Part oil phase to Part A water phase and mix thoroughly. Cool with mixing; add Part C ingredients when the emulsion is <0 C and mix thoroughly. Actives International, Allendale, NJ iochemica Int l, Inc., Melbourne, FL io-otanica Inc., Hauppauge, NY VANATURAL and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Ultra Natural & Ultra Refined are trademarks of iochemica International, Inc. Xyliance is a trademark of Soliance. rev0//0

6 Rejuvenating Lotion No. 574 VANATURAL entonite Clay.0 A VANZAN NF Xanthan Gum 0.5 Water.5 utylene Glycol.0 Cyclomethicone (and) Dimethicone (and) Petrolatum (Gel ase SM-PT ) 7.0 C-5 Alkyl enzoate (Finsolv TN ) 4.0 Cetearyl Alcohol.0 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 VEG ) 5.0 C Water (and) Aloe arbedensis Leaf Extract (and) Yeast (Sacchromyces) Extract (etavera ) Preservative, Fragrance 5.0 Procedure: While heating the water to C, slowly add the VANATURAL and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Add the butylene glycol, mixing until uniform. Maintain the water phase at C. lend the Part oil phase ingredients and heat to C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; add the Part C ingredients in order when the emulsion is <0 o C. Arch Personal Care Products L.P., South Plainfield, NJ Innospec Active Chemicals, Edison, NJ Croda Inc., Edison, NJ VANATURAL and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Arlacel is a registered trademark of Uniqema Americas LLC. etavera is a registered trademark of Arch Personal Care Products L.P. Finsolv is a registered trademark of Innospec Performance Chemicals Company. rev0/0/

7 Intensive AHA Moisturizing Cream No. 484 Wt.% VEEGUM Ultra Magnesium Aluminum Silicate.5 A VANZAN NF Xanthan Gum 0. Deionized Water 56.6 C D Glycerin.4 utylene Glycol.0 Cetyl Alcohol 0.5 Glyceryl Monostearate SE.0 Petrolatum 0.0 Mineral Oil.0 Caprylic/Capric Triglyceride (Neobee M-5 ).0 C -5 Octanoate (Finester TM EH-5 ).0 Dimethicone (XIAMETER PMX-00 Silicone Fluid 50cs ).0 Steareth- (rij S 4 ).5 Steareth- (rij S7 4 ).5 Isosorbide Laurate (Arlamol ISML 4 ) 0.5 Lactic Acid USP, 88 %.6 Sodium Lactate (PATLAC NAL 5 ).6 Glycolic Acid, 70 %.0 Triethanolamine (to ph.75 ± 0.5).0 E Preservative, Fragrance Procedure: egin heating the water to 80 C. Dry blend the VEEGUM Ultra and VANZAN NF; add to the water slowly, mixing with maximum available shear until fully hydrated. Add the remaining water phase ingredients from Part, mixing until uniform. Maintain the water phase at 80 C. lend the Part C oil phase ingredients and heat to 80 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool while mixing. Add the Part D and Part E ingredients when the emulsion is <40 o C. Adjust as necessary to ph.75 ± 0.5. Stepan Company, Northfield, IL Innospec Active Chemicals, Edison, NJ Dow Corning, Midland, MI 4 Croda Inc., Edison, NJ 5 RITA Corporation, Crystal Lake, IL VEEGUM and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Arlamol and rij are registered trademarks of Uniqema Americas LLC. Finester is a trademark of Innospec Performance Chemicals Company. Neobee is a registered trademark of Stepan Company. Xiameter is a registered trademark of Dow Corning Corporation. rev0//0

8 Vitamin-Enriched Skin Cream With Natural Moisturizers No. 545 VEEGUM R Magnesium Aluminum Silicate.00 A VANZAN NF Xanthan Gum 0.5 Water C utylene Glycol 5.00 Disodium EDTA 0.0 D- Panthenol USP 0.0 Macadamia Ternifolia Nut Oil (Australian Macadamia Nut Oil Cosmetic Grade ) 4.50 Polyglyceryl- Distearate (Cremophor GS ).00 Ceteareth-5 (Cremophor A5 ).50 Cetearyl alcohol.00 Tocopherol Acetate (Vitamin E Acetate Oil USP, FCC ) 0.50 D Retinyl Palmitate (Vitamin A Palmitate ) 0.0 E Hyaluronic Acid (and) Water (Lipo Hyaluronic Acid % solution ).00 Preservative Procedure: While heating the water to C, slowly add the VEEGUM R and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Add Part and mix until uniform. Maintain the water phase at C. lend the Part C oil phase ingredients and heat to C. Add Part C to Part A/ with good agitation. Cool with mixing. At C add Part D. At 0 C add Part E. Adjust as necessary to ph 6.5 ± 0.5. Southern Cross otanical PTY Ltd, Lennox Head, NSW, Australia ASF Corporation, Florham Park, NJ Lipo Chemicals, Paterson, NJ VEEGUM and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Cremophor is a registered trademark of ASF Aktiengesellschaft. rev0//0

9 Conditioning Skin Cream with Jojoba Oil No. 57 VANATURAL entonite Clay.0 A Water 7.0 utylene Glycol 5.0 is-peg/ppg-6/6 PEG/PPG-6/6 dimethicone; Caprylic/capric triglyceride.5 (Abil Care 85 ) Cetyl Alcohol (and) Glyceryl Stearate (and) PEG-75 stearate (and) Ceteth (and) Steareth-0 (Emulium Delta ) Cetyl Rinoleate (Tegosoft CR ).0 Simmondsia Chinesis (Jojoba) Seed Oil (Jojoba Oil Golden ) 6.0 Cyclomethicone (XIAMETER PMX-045 Cyclosiloxane lend 4 ) 6.0 C Preservative, Fragrance Procedure: While heating the water to 75 o C, slowly add the VANATURAL while mixing at maximum available shear. Mix until fully hydrated. Add the butylene glycol, mixing until uniform. Maintain the water phase at 75 o C. lend the Part oil phase ingredients and heat to C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; add Part C when the emulsion is <0 o C. Evonik Goldschmidt Chemical Company, Hopewell, VA Gatefosse Corporation, Paramus, NJ Desert Whale Jojoba Co., Inc., Tucson, AZ 4 Dow Corning Corporation, Midland, MI VANATURAL is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Abil is a registered trademark of Goldschmidt GmbH Corporation. Emulium is a registered trademark of Gattefosse SAS. Tegosoft is a registered trademark of Goldschmidt GmbH. Xiameter is a registered trademark of Dow Corning Corporation. rev0//0

10 Oatmeal Lotion No. 586 VANATURAL entonite Clay.50 Water 7.5 Avena Sativa (Oat) Kernel Flour (Tech-O #-070 Oat Flour ).00 A VANZAN NF Xanthan Gum 0.5 Sucrose Stearate (Surfhope SE Cosme C-8 ).75 Sodium PCA (Ajidew NL-50 ).00 Glycerin, 96% 5.00 C Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 VEG 4 ).00 Hydrogenated Polyisobutylene (Parleam 5 ) 4.00 Mineral Oil (and) Lanolin Alcohol (Vilvanolin L-0 6 ).00 Cetyl Alcohol.00 Isopropyl Myristate.00 D Preservative Citric Acid, 0% Procedure: While heating the water to C, sift the VANATURAL into the water agitated at maximum available shear. Once dispersed, slowly sift in the oat flour. Mix until the VANATURAL is fully hydrated and the oat flour is well dispersed. Add the VANZAN NF and mix until dissolved. Add the sucrose stearate and mix until uniform. Add Part ingredients and mix thoroughly. Maintain the water phase at C. lend the Part C oil phase ingredients and heat to C. Add the oil phase to the water phase with good agitation; mix until uniform. Avoid incorporating air. Cool with mixing; add the preservative when the emulsion is <5 o C. Adjust ph to 5.5 ± 0.5 with citric acid. eacon CMP Corporation, Kenilworth, NJ Arch Personal Care Products L.P., South Plainfield, NJ Ajinimoto USA, Inc., Fort Lee, NJ 4 Croda Inc., Edison, NJ 5 Rossow Cosmetiques-USA, Matawan, NJ 6 Lubrizol Advanced Materials, Inc., Cleveland, OH VANATURAL is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Ajidew is a registered trademark of Ajinomoto Company, Inc. Arlacel is a registered trademark of Uniqema Americas LLC. Parleam is a registered trademark of Etablissements. Rossow et Cie. Surfhope is a registered trademark of Mitsubishi Chemical Corporation. Tech-O is a registered trademark of eacon CMP Corporation. Vilvanolin is a trademark of Lubrizol Advanced Materials, Inc. rev0//0

11 Oatmeal & Macadamia Cream No. 588 Wt.% VANATURAL entonite Clay.50 Water 8.5 Avena Sativa (Oat) Kernel Flour.00 A (Tech-O #-070 Oat Flour ) VANZAN NF Xanthan Gum 0.50 Sucrose Stearate (Surfhope SE Cosme C-8 ).5 utylene Glycol 5.00 C Macadamia Ternifolia Seed Oil (SC Macadamia Oil ) 4.50 Cetearyl Alcohol.00 D Preservative Procedure: While heating the water to C, slowly add the VANATURAL while mixing at maximum available shear. Once dispersed, slowly sift in the oat flour. Mix until the VANATURAL is fully hydrated and the oat flour is well dispersed. Add the VANZAN NF and mix until dissolved. Add the sucrose stearate and mix until uniform. Add the butylene glycol and mix thoroughly. Maintain the water phase at C. lend the Part C oil phase ingredients and heat to C. Add the oil phase to the water phase with good agitation; mix until uniform. Avoid incorporating air. Cool with mixing; add Part D when the emulsion is <0 o C. eacon CMP Corporation, Kenilworth, NJ Arch Personal Care Products L.P., South Plainfield, NJ Southern Cross otanicals PTY Ltd., Lennox Head, NSW Australia Registered and pending trademarks appearing printed in bold in these materials are those of Vanderbilt Minerals, LLC. For a complete listing, please visit Trademark Listing. Surfhope is a registered trademark of Mitsubishi Chemical Corporation. Tech-O is a registered trademark of eacon CMP Corporation. rev/5/04 information is not intended to be all-inclusive, because the manner and conditions of use, handling, storage and other factors may involve other or additional safety to the use, handling or further processing of any such material. No suggestion for use is intended as, and nothing herein shall be construed as, a recommendation

12 Rich ody utter Plus Sunscreen No. 60 Wt.% VEEGUM Ultra Magnesium Aluminum Silicate.0 VANZAN NF Xanthan Gum 0.5 A Water 58.5 Glycerine.0 Sorbeth-0.0 C - 5 Alkyl enzoate (Finsolv TN ).0 Dimethicone (Xiameter PMX-00 Silicone Fluid 50cs ).0 Glycine Soja (Soybean) Oil (Super Refined Soybean Oil ).5 utyrospermum Parkii (Shea) utter (Tomasa Shea utter 4 ).5 Isopropyl Myristate (and) Glycine Soja (Soybean) Oil (and) Retinyl Palmitate.0 (and) Carthamus Tinctorius (Safflower) Seed Oil (and) Linoleic Acid (and) Tocopherol (Vitamin Complex AEF OS ) Stearyl Alcohol (Lanette 8 5 ) 5.0 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 ) 5.0 C - 5 Alkyl enzoate (and) Titanium Dioxide (and) Polyhydroxystearic Acid (and) Aluminum Stearate (and) Alumina (Solaveil CT-00 ) 5.0 C Preservative Procedure: While heating the water to C, slowly add the VEEGUM Ultra and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Add the remaining water phase ingredients, mixing until uniform. Maintain the water phase at C. Combine Part ingredients and heat to 70-75ºC. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; add the Part C ingredients when the emulsion is <0 o C. If necessary, adjust the ph to Innospec Active Chemicals, Edison, NJ Dow Corning Corporation, Midland, MI Croda Inc., Edison, NJ 4 Tri-K Industries, Inc., Northvale, NJ 5 Cognis Corporation, Ambler, PA VEEGUM and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Arlacel is a registered trademark of Uniqema Americas LLC. Finsolv is a registered trademark of Innospec Performance Chemicals Company. Lanette is a registered trademark of Cognis IP Management GmbH. Solaveil is a registered trademark of Croda International PLC. Xiameter is a registered trademark of Dow Corning Corporation. rev0//0

13 Moisturizing Lotion with Sunscreen No. 567 Wt.% VEEGUM Ultra Magnesium Aluminum Silicate.0 Water 77. A Glycerin, 96%.7 Zinc Oxide (Zinc Oxide Neutral ).0 Glyceryl Stearate (and) Ceteareth-0 (and) Ceteareth- (and) Cetearyl Alcohol (and) 6.0 Cetyl Palmitate (Emulgade SE-PF ) Glyceryl Stearate (Kessco GMS Pure ).0 Caprylic/Capric Triglyceride (Neobee M-5 ) 5.0 Mineral Oil, USP/NF Grade.0 Octyl Methoxycinnamate (Neo Heliopan AV ).0 C Preservative, Fragrance Procedure: While heating the water to 85 o C, slowly add the VEEGUM Ultra while mixing at maximum available shear. Mix until fully hydrated. Add the remaining water phase ingredients, mixing until the zinc oxide is uniformly dispersed. Maintain the water phase at 85 C. lend the Part oil phase ingredients and heat to 85ºC. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; add the Part C ingredients when the emulsion is <0 o C. Symrise, Teterboro, NJ Cognis Corporation, Ambler, PA Stepan Company, Northfield, IL VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Emulgade is a registered trademark of Cognis GmbH Corporation. Kessco and Neobee are registered trademarks of Stepan Company. Neo Heliopan is a registered trademark of Haarmann & Reimer GmbH. rev0//0

14 Moisturizing Cream with Sunscreen No. 568 Wt.% VEEGUM Ultra Magnesium Aluminum Silicate.5 Water 74.5 A Glycerin, 96% 4.0 Zinc Oxide (Zinc Oxide Neutral ).0 Emulsifying Wax NF (Polawax ).0 PPG- Myristyl Ether Propionate (Crodamol PMP ) 4.0 Octyl Methoxycinnamate (Neo Heliopan AV ).0 C Preservative Procedure: While heating the water to o C, slowly add the VEEGUM Ultra while mixing at maximum available shear. Mix until fully hydrated. Add the remaining water phase ingredients, mixing until the zinc oxide is uniformly dispersed. Maintain the water phase at o C. lend the Part oil phase ingredients and heat to o C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; add Part C when the emulsion is <0 o C. Symrise, Teterboro, NJ Croda Inc., Edison, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Crodamol and Polawax are trademarks of Croda, Inc. Neo Heliopan is a registered trademark of Haarmann & Reimer GmbH. rev0//0

15 Wash-Off Resistant Sunscreen Cream No. 55 Note: The combination of TiO and Avobenzone is not approved for use in the USA. Wt.% VEEGUM Ultra, Magnesium Aluminum Silicate.0 A Carbomer (Ultrez TM 0 ) 0. Water 47.8 Polysorbate 0 (Tween 0 ).0 Titanium Dioxide (and) Alumina (and) Silica (and) Sodium Polyacrylate.5 (Tioveil AQ-G ) utylene Glycol.0 C Cetyl Alcohol 0.5 Isosorbide Laurate (Arlamol ISML ).0 Caprylic/Capric Triglyceride (Neobee M-5 ) 5.0 Glyceryl Monostearate SE (Cutina GMS SE 4 ).0 C -5 Octanoate (Finester TM EH-5 5 ).0 Octylmethoxycinnamate (Parsol MCX 6 ) 7.0 Avobenzone (Parsol ).0 Octyl Salicylate (Dermoblock OS 7 ).0 Castor Oil Polyurethane (Polyderm PPI-CO 7 ).0 Phenyl Dimethicone (DC 556 Fluid 8 ).0 Dimethicone (XIAMETER PMX-00 Silicone Fluid 50cs 8 ).0 Laureth- (rij L ) 0.5 Steareth- (rij S ). Steareth- (rij S7 ). D Etidronic Acid 0. E Triethanolamine (to ph ) qs Preservative Procedure: While heating the water to 80 C, slowly add the VEEGUM Ultra and carbomer (sequentially or as a dry blend) while mixing at maximum available shear. Mix until fully hydrated. Add the remaining water phase ingredients from Part, mixing until uniform. Maintain the water phase at 80 C. lend the Part C oil phase ingredients and heat to 85 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; add the Part D and Part E ingredients when the emulsion is <45 o C. Adjust as necessary to ph Lubrizol Advanced Materials, Inc., Cleveland, OH Croda Inc., Edison, NJ Stepan Company, Northfield, IL 4 Cognis Corporation, Ambler, PA 5 Innospec Active Chemicals, Edison, NJ 6 Givaudan Corporation, Teaneck, NJ 7 Alzo International Inc., Sayreville, NJ 8 Dow Corning Corporation, Midland, MI VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlamol, rij and Tween are registered trademarks of Uniqema Americas LLC. Cutina is a registered trademark of Cognis IP Management GmbH. Dermoblock is a trademark of Alzo International, Inc. Finester is a trademark of Innospec Performance Chemicals Company. Neobee is a registered trademark of Stepan Company. Parsol is a registered trademark of Givaudan Corporation. Polyderm is a trademark of Alzo Investments. Tioveil is a registered trademark of Acma Limited Corporation. Ultrez is a trademark of Noveon IP Holdings. Xiameter is a registered trademark of Dow Corning Corporation. rev0//0 Vanderbilt Minerals, LLC, Winfi eld Street, P.O. ox 550, Norwalk, CT

16 Green Tea Instant Facial No. 54 Wt.% VEEGUM F Magnesium Aluminum Silicate 5.0 Kaolin Clay, Cosmetic Grade 67.0 Zinc Oxide or Calamine, USP 0.0 Polyvinylpyrrolidone (PVP K-0) 5.0 Allantoin.0 Green Tea Extract.0 Procedure: Mix powders until uniformly blended. Use: Mix powder with sufficient water, milk, witch hazel or warmed honey to make a spreadable paste. International Specialty Products, Wayne, NJ Greentech USA, Yarmouth, ME VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its rev0//0

17 AHA Clay Mask No. 487 Wt.% A VEEGUM Ultra Magnesium Aluminum Silicate 5.0 Water 8.9 Glycerin 5.0 utylene Glycol.0 Cosmetic Kaolin clay 0.0 Cosmetic Talc 5.0 Sodium Lauroyl Sarcosinate, 0% 5.0 Glycolic Acid, 70% 5.0 d-panthenol 0.5 Vitamin E Acetate 0. Vitamin A Palmitate 0. Triethanolamine.4 C Preservative Procedure: Slowly add the VEEGUM Ultra to the water agitated at maximum available shear. Mix until fully hydrated. Add the Part ingredients in order, mixing after each addition until smooth. VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its rev0//0

18 Moisturizing Gel for Oily Skin, Containing Tea Tree Oil No. 554 Wt.% Water 64. A Sodium Hyaluronate (Lipo Hyaluronic Acid, % solution ).00 Disodium EDTA 0.05 utylene Glycol (and) Water (and) Equisetum Hyemale Extract (Actiphtye of Horsetail G50P ) utylene Glycol (and) Water (and) Hydrastis Canadensis (Golden Seal) Extract (Actiphtye of Goldenseal G50P ) utylene Glycol (and) Water (and) Cymbopogon Schoenanthus Extract (Actiphtye of Lemongrass G50P ) utylene Glycol (and) Water (and) Hamamelis Virginiana (Witch Hazel) Extract (Actiphtye of Witch Hazel G50P ) utylene Glycol (and) Water (and) Humulus Lupulus (Hops) Extract (Actiphtye of Hops G50P ) C Water (and) Polysorbate 0 (and) PEG-40 Hydrogenated Castor Oil (and) 9.70 Melaleuca Alternifolia (Tea Tree) Leaf Oil (Water-Soluble Tea Tree Oil ) VANZAN NF-C Xanthan Gum (Xanthan Gum).00 D Preservative E Triethanolamine 0.04 Procedure: Add Part A ingredients separately and mix thoroughly. Pre-blend Part ingredients, add to the batch and mix until homogeneous. Add Part C ingredients separately, in the order shown. Sift the VANZAN NF-C into an established vortex and mix until completely dissolved. The batch will thicken at this point. Add Part D and mix until homogeneous. Adjust ph to 6.5 ± 0.5 with triethanolamine. Lipo Chemicals, Paterson, NJ Active Organics, Lewisville, TX Southern Cross otanicals PTY Ltd, Lennox Head, NSW 478, Australia VANZAN is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Actiphyte is a registered trademark of Active Organics, LP. Lipo is a registered trademark of Lipo Chemicals, Inc. rev0/05/0

19 Thioglycolate Relaxer No. 77 A VEEGUM HS Magnesium Aluminum Silicate.0 Water 5.0 C Cetyl Alcohol 5.0 Petrolatum 5.0 Mineral oil 8.0 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 VEG ) 5.0 Ammonium Thioglycolate, 60%.0 Ammonium Hydroxide.0 D Preservative Procedure: While heating the water to o C, slowly add the VEEGUM HS while agitating at maximum available shear. Continue mixing until fully hydrated. lend the Part oil phase ingredients and heat to 70 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; combine Part C ingredients and slowly add when the emulsion is 5 o C; mix until uniform. Add Part D. Croda Inc., Edison, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlacel is a registered trademark of Uniqema Americas LLC. rev0//0

20 Hydroxide Relaxer No. 80 A VEEGUM HS Magnesium Aluminum Silicate.0 Water 55.0 Cetyl Alcohol 5.0 Petrolatum 5.0 Mineral oil 8.0 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 VEG ) 5.0 C Sodium Hydroxide, 0% 0.0 D Preservative Procedure: While heating the water to o C, slowly add the VEEGUM HS while agitating at maximum available shear. Continue mixing until fully hydrated. lend the Part oil phase ingredients and heat to 70 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing. Slowly add Part C when the emulsion is 40 o C; mix until uniform. Add Part D; mix until uniform. Croda Inc., Edison, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlacel is a registered trademark of Uniqema Americas LLC. rev0//0

21 isulfite Relaxer No. 8 A VEEGUM HS Magnesium Aluminum Silicate.0 Water 57.0 C Cetyl Alcohol 0.0 Petrolatum 5.0 Mineral oil 5.0 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 VEG ) 5.0 Ammonium Carbonate 4.0 Water 0.0 Sodium isulfite.0 D Preservative Procedure: While heating the water to o C, slowly add the VEEGUM HS while agitating at maximum available shear. Continue mixing until fully hydrated. lend the Part oil phase ingredients and heat to 70 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing. Prepare Part C by dissolving the ammonium carbonate in the water and slowly adding the sodium bisulfite (it will foam & bubble). Stir gently until the solution is clear. Slowly add Part C when the emulsion is 40 o C; mix until uniform. Add Part D. Croda Inc., Edison, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlacel is a registered trademark of Uniqema Americas LLC. rev0//0

22 Relaxer/Waving Lotion No. 85 A VEEGUM HS Magnesium Aluminum Silicate.0 Water 69.0 C Cetyl Alcohol.0 Mineral Oil (and) Lanolin Alcohol (Vilvanolin L-0 ) 5.0 Polysorbate 80 (and) Cetyl Acetate (and) Acetylated Lanolin Alcohol (Solulan 98 ).0 Mineral oil 5.0 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 VEG ).0 Ammonium Thioglycolate, 60%.0 Ammonium Hydroxide.0 D Preservative Procedure: While heating the water to o C, slowly add the VEEGUM HS while agitating at maximum available shear. Continue mixing until fully hydrated. lend the Part oil phase ingredients and heat to 75 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing. Combine Part C and slowly add when the emulsion is 5 o C; mix until uniform. Add Part D. Lubrizol Advanced Materials, Inc., Cleveland, OH Croda Inc., Edison, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlacel is a registered trademark of Uniqema Americas LLC. Solulan is a registered trademark of The Lubrizol Corporation. Vilvanolin is a trademark of Lubrizol Advanced Materials, Inc. rev0//0

23 Pearlescent No Residue Conditioning Shampoo No. 488 Wt.% A VEEGUM Ultra Magnesium Aluminum Silicate.00 Deionized Water 6.5 Mica (and) Titanium Dioxide (Timiron MP-00 ) 0.50 C Sodium Laureth Sulfate (Steol CS-0 ) 5.00 Lauramide DEA (Monamid 76 ) 7.50 Cocoyl Sarcosine.75 D Preservative Procedure: Slowly add the VEEGUM Ultra to the water while mixing at maximum available shear. Mix until fully hydrated. Add Part and mix until uniform. At reduced mixing speed, add the Part C ingredients in the order shown, mixing after each addition until uniform. Adjust as necessary to ph 5.0 ± 0.5. Add Part D. EMD Chemicals Inc./RONA, Gibbstown, NJ Rhodia Inc., Cranbury, NJ Stepan Company, Northfield, IL VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Monamid is a registered trademark of Mona Industries, Inc. Steol is a registered trademark of Stepan Company. Timiron is a registered trademark of EM Industries, Inc. rev0//0

24 Zinc Pyrithione Lotion Shampoo No. 64 VEEGUM R Magnesium Aluminum Silicate 0.5 A Water 5. Hydroxypropyl Guar (Jaguar HP-60 ) 0.5 Ammonium Lauryl Sulfate (Rhodapon TM L- ) 40.0 PPG-5-Ceteth-0 Phosphate (Crodafos SG ).8 Lauramide DEA (Monamid 76 ) 4.0 C Zinc Pyrithione, 48% (Zinc Omadine ). Preservative qs Procedure: Slowly add the VEEGUM R to the water agitated at maximum available shear. Mix until fully hydrated. Add the hydroxypropyl guar and mix until uniformly dispersed. With slow stirring add the Part ingredients in order. Add the phosphate slowly, mixing until the guar gum is totally dissolved. Add the Part C ingredients in the order listed, agitating slowly. Mix until smooth and uniform. Avoid incorporation of air. Adjust as necessary to ph 7.. Rhodia Inc., Cranbury, NJ Croda Inc., Inc., Edison, NJ Arch Personal Care Products L.P., South Plainfield, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Crodafos is a trademark of Croda, Inc. Monamid is a registered trademark of Mona Industries, Inc. Omadine is a registered trademark of Arch Chemicals, Inc. Rhodapon is a trademark of Rhodia, Inc. rev0//0

25 Depilatory Cream No. 64 Wt.% Deionized Water 75.0 VEEGUM CH Magnesium Aluminum Silicate (Magnesium Aluminum.0 A Silicate) Hydroxyethyl Cellulose (Cellosize HEC QP-4400-H (Cosmetic Grade) ).0 Sodium Gluceptate (Sodium Glucoheptonate) (chelating agent),-butanediol (utylene Glycol) 5.0 Cetearyl Alcohol (and) Ceteareth-0 (Hallstar NCD-0 ).0 C -5 Alkyl enzoate (Finsolv TN ).5 Crambe Abyssinica Seed Oil (Fancor Abyssinian Oil 4 ).5 C Calcium Thioglycolate Trihydrate Calcium Hydroxide (Calcium Hydroxide 80 USP 6 ).5 Procedure: egin heating the water to 55-60ºC. Sift the VEEGUM CH into an established vortex in the water. Mix until fully hydrated. Sift in the hydroxyethyl cellulose and mix until dissolved. Then add in the rest of Part A ingredients and, if necessary, adjust the batch temperature to 55-60ºC. Combine Part ingredients and heat to 55-60ºC. When Part A and Part are both at 55-60ºC, add Part to Part A slowly with adequate mixing to emulsify. Cool with mixing to ~0ºC. Then, slowly add Part C ingredients and mix thoroughly after each. Dow Chemical, Midland, MI HallStar, Chicago, IL Innospec Active Chemicals, Edison, NJ 4 Elementis Specialties, Hightstown, NJ 5 runo ock, Marschacht, Germany 6 renntag Specialties, Inc., South Plainfield, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Cellosize is a registered trademark of Union Carbide Chemicals & Plastics Technology Corporation. Fancor is a registered trademark of Elementis Specialties, Inc. Finsolv is a registered trademark of Innospec Performance Chemicals Company. Hallstar is a registered trademark of Hallstar Innovations Corporation. 04/0/0

26 Depilatory Lotion No. 86 VEEGUM HS Magnesium Aluminum Silicate.0 A Water 74.0 Propylene Glycol 5.0 Mineral Oil (and) Lanolin Alcohol (Vilvanolin L-0 ) 5.0 Polysorbate 80 (and) Cetyl Acetate (and) Acetylated Lanolin Alcohol (Solulan 98 ).0 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 VEG ).0 C Calcium Thioglycolate 5.0 Calcium Hydroxide 6.0 D Preservative Procedure: While heating the water to o C, slowly add the VEEGUM HS while agitating at maximum available shear. Continue mixing until fully hydrated. Add the propylene glycol. Maintain temperature at o C. lend the Part oil phase ingredients and heat to 70 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing. Slowly add Part C ingredients individually when the emulsion is 5 o C; mix until uniform after each. Add Part D. Lubrizol Advanced Materials, Inc., Cleveland, OH Croda Inc., Edison, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlacel is a registered trademark of Uniqema Americas LLC. Solulan is a registered trademark of the Lubrizol Corporation. Vilvanolin is a trademark of Lubrizol Advanced Materials, Inc. rev0//0

27 Washing Cream for Sensitive Skin No. 505 A VEEGUM Ultra Magnesium Aluminum Silicate.0 Water 6.0 Sodium Cocoyl Isethionate (Pureact I-78 ) 5.0 Cocamidopropyl Hydroxysultaine (Mirataine CS ) 0.0 C Preservative Procedure: While heating the water to o C, slowly add the VEEGUM Ultra while agitating at maximum available shear. Continue mixing until fully hydrated. Maintaining temperature, slowly add Part ingredients in the order shown, mixing after each addition until smooth and uniform. Cool with mixing to < 45 o C and then add Part C. Adjust as necessary to ph 5.5 ± 0.5. Innospec Active Chemicals, Edison, NJ Rhodia Inc., Cranbury, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Mirataine is a registered trademark of Rhone-Poulenc, Inc. Pureact is a trademark of Innospec Performance Chemicals Company. rev0//0

28 Extra Mild Facial Cleanser No. 55 A VANZAN NF Xanthan Gum.0 Water 76. C-5 Alkyl enzoate (Finsolv TN ) 5.0 PEG-4 dimethicone (Dow Corning 9 ). C Cocamidopropyl etaine (Amphosol CA ) 0.0 Decyl Glucoside (Plantaren 000N 4 ) 6.6 D Preservative Procedure: Sift the VANZAN NF into the water agitated at maximum available shear. Mix until completely dissolved. lend Part ingredients, then add to Part A and mix thoroughly. Add Part C ingredients separately and mix thoroughly after each addition. Avoid air entrapment. Add the preservative and mix until uniform. Innospec Active Chemicals, Edison, NJ Dow Corning Corporation, Midland, MI Stepan Chemical Co., Northfield, IL 4 Cognis Corporation, Ambler, PA VANZAN is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Amphosol is a registered trademark of Stepan Company. Dow Corning is a registered trademark of Dow Corning Corporation. Finsolv is a registered trademark of Innospec Performance Chemicals Company. Plantaren is a registered trademark of Cognis GmbH Corporation. rev0//0

29 Aerosol Shave Cream for Sensitive Skin No. 50 Wt.% VEEGUM Ultra Magnesium Aluminum Silicate.5 A VANZAN NF Xanthan Gum 0. Deionized Water 67. C D E Glycerin.0 utylene Glycol.0 Stearic Acid XXX.0 Coconut Acid.0 Safflower Oil 0. Soybean Oil 0. Cetyl Alcohol.0 Dimethicone (XIAMETER PMX-00 Silicone Fluid 50cs ).0 Lanolin Alcohol 0. Isosorbide Laurate (Arlamol ISML ).0 Mineral Oil.0 Sodium Cocoyl Sarcosinate, 0% 0.0 Panthenol 0.5 Aloe Vera 0.5 Triethanolamine.5 Preservative Procedure: While heating the water to 75 C, slowly add the VEEGUM Ultra and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Add the remaining water phase ingredients from Part, mixing until uniform. Maintain the water phase at 75 C. lend the Part C oil phase ingredients and heat to 75 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool while mixing. Add the Part D ingredients when the emulsion is <40 o C. Add the Part E ingredients when the emulsion is <5 o C. Adjust as necessary to ph 7.5 ± 0.5. Dow Corning Corporation, Midland, MI Croda Inc., Edison, NJ VEEGUM and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Arlamol is a registered trademark of Uniqema Americas LLC. Xiameter is a registered trademark of Dow Corning Corporation. rev0//0

30 After Shaving alm No. 558 VEEGUM R Magnesium Aluminum Silicate.0 A VANZAN NF Xanthan Gum 0.5 Water. Water (and) Triticum Vulgare (Wheat ) Germ Extract (and) Saccharomyces 4.0 Cerevisiae Extract (and) Sodium Hyaluronate (Eashave ) isabolol ((±)-alpha-isabolol Synthetic ) 0. Aloe arbadensis Leaf Juice (Aloe Vera Gel Regular 40X-AG046 ).0 Allantoin 0. C Preservative qs Procedure: Slowly add the VEEGUM R and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Add the Part ingredients in the order listed and mix until uniform. Add Part C and mix until uniform. Adjust as necessary to ph 6.5 ± 0.5. Pentapharm Ltd., asel, Switzerland/Centerchem, Inc., Norwalk, CT ASF Corporation, Florham Park, NJ Terry Laboratories Inc., Melbourne, FL VEEGUM and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Eashave is a trademark of Pentapharm Ltd. rev0//0

31 Licorice Extract Fade Lotion No. 604 VEEGUM Ultra Magnesium Aluminum Silicate.5 Water 65.8 A Propanediol (Zemea Propanediol ) 5.0 Disodium EDTA 0. Panthenol and Propylene Glycol (D-Panthenol 50-P ) 0.4 White Petrolatum 5.0 Dimethicone (Xiameter PMX-00 Silicone Fluid 50cs ).0 Polyglyceryl- distearate (Cremophor GS ).0 Ceteareth-5 (Cremophor A 5 ).5 Cetearyl alcohol.0 Tocopherol Acetate (Vitamin E Acetate USP/EP/ FCC ) 0.5 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 4 ).0 Ethyl Hexyl Methoxycinnamate (Neo Heliopan AV 5 ) 7.5 C Glycyrrhizza Glabra (Licorice) Root Extract (Licorice Extract CG 4%6 ) 0.5 Ethanol, USP.0 D Retinyl Palmitate (Vitamin A Palmitate PH. EUR/USP/FCC ) 0. E Preservative Triethanolamine, 99% Procedure: While heating the water to 70-75ºC, slowly add the VEEGUM Ultra while agitating at maximum available shear. Mix until fully hydrated. Add the remaining Part A water phase ingredients. Maintain the water phase at 70-75ºC. Combine the Part oil phase ingredients and heat to 70-75ºC. Add the oil phase to the water phase with good agitation; mix until uniform. Cool while mixing to o C. Dissolve the licorice extract in the ethanol under agitation and then add Part C to the emulsion; mix until uniform. Warm the retinyl palmitate to liquefy and make uniform prior to weighing out. Add the retinyl palmitate and the preservative in order to the emulsion, mixing after each addition until uniform. Adjust as necessary to ph DuPont Tate & Lyle io Products Company, LLC, Wilmington, DE ASF Corporation, Florham Park, NJ Dow Corning Corporation, Midland, MI 4 Croda, Inc., Edison, NJ 5 Symrise, Teterboro, NJ 6 Sabinsa Corporation, Piscataway, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlacel is a registered trademark of Uniqema Americas LLC. Cremophor is a registered trademark of ASF Aktiengesellschaft. Neo Heliopan is a registered trademark of Haarmann & Reimer GmbH. Xiameter is a registered trademark of Dow Corning Corporation. Zemea is a registered trademark of DuPont Tate & Lyle io Products Company, LLC rev0//0

32 Fade Cream No. 8 VEEGUM K Magnesium Aluminum Silicate.00 A Water C D Glycerin 4.00 Triethanolamine.00 Stearic acid.00 Cetyl alcohol 4.00 Isopropyl myristate.00 Mineral Oil (and) Lanolin Alcohol (Vilvanolin L-0 ) 0.00 Glyceryl Stearate (and) PEG-00 Stearate (Arlacel 65 VEG ).00 Citric acid 0.0 Hydroquinone*.00 Sodium sulfite 0.40 Sodium metabisulfite 0.5 E Preservative Procedure: While heating the water to 75 o C, slowly add the VEEGUM K while agitating at maximum available shear. Continue mixing until fully hydrated. Add Part and maintain temperature at 75 o C. lend the Part C oil phase ingredients and heat to 70 C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool with mixing; add the citric acid at 65 o C, the hydroquinone at 55 o C, and the sodium sulfite and sodium metabisulfite at 45 o C. Mix until cool and uniform. *Consult local regulations concerning the use of hydroquinone Lubrizol Advanced Materials, Inc., Cleveland, OH Croda Inc., Edison, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlacel is a registered trademark of Uniqema Americas LLC. Vilvanolin is a trademark of Lubrizol Advanced Materials, Inc. rev0//0

33 otanical Fade Lotion No. 49 Wt.% VEEGUM Ultra, Magnesium Aluminum Silicate.0 A Water 69.8 Carbomer (Carbopol 94 ) 0. Polysorbate 0 (Tween 0 ) 0.6 Glycerin.0 utylene Glycol.0 C D Cetyl Alcohol 0.5 Isosorbide Laurate (Arlamol ISML ).0 Laureth- (rij L ) 0.7 Steareth- (rij S ). Steareth- (rij S7 ). Caprylic/Capric Triglyceride (Neobee M-5 ) 5.0 Glyceryl Monostearate SE (Cutina GMS SE 4 ).0 C -5 Octanoate (Finester EH-5 5 ).0 Dimethicone (XIAMETER PMX-00 Silicone Fluid 50cs 6 ).0 Triethanolamine (ph to ).0 Saxifraga Sarmentosa Extract (and) Grape Extract (and) utylene Glycol (and) Water.0 (and) Mulberry Root Extract (and) Scultellaria aicalensis Extract (and) Na EDTA (iowhite 7 ) E Preservative, Chelating Agent Procedure: egin heating the water to C. Slowly add the VEEGUM Ultra and Carbopol 94 sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Add the water phase ingredients from Part, mixing until uniform. Maintain the water phase at C. lend the Part C oil phase ingredients and heat to C. Add the oil phase to the water phase with good agitation; mix until uniform. Cool while mixing; when the emulsion is <45 o C add the Part D and Part E ingredients in the order listed, mixing after each addition until smooth and uniform. Adjust as necessary to ph Lubrizol Advanced Materials, Inc., Cleveland, OH Croda Inc., Edison, NJ Stepan Company, Northfield, IL 4 Cognis Corporation, Ambler, PA 5 Innospec Active Chemicals, Edison, NJ 6 Dow Corning Corporation, Midland, MI 7 ASF Corporation, Florham Park, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Arlamol, rij and Tween are registered trademarks of Uniqema Americas LLC. Carbopol is a trademark of Lubrizol Advanced Materials, Inc. Cutina is a registered trademark of Cognis IP Management GmbH. Finester is a trademark of Innospec Performance Chemicals Company. Neobee is registered trademark of Stepan Company. Xiameter is a registered trademark of Dow Corning Corporation. rev0//0

34 5% enzoyl Peroxide Acne Treatment Lotion No. 56 Wt.% VEEGUM R Magnesium Aluminum Silicate 0.90 A VANZAN NF Xanthan Gum 0.40 Water Propylene Glycol 6.00 enzoyl Peroxide, 70% Powder 7.5 C Laureth-4 (rij L4 ) 5.00 Acetylated Lanolin Alcohol (Acetulan ) 5.00 D Preservative Procedure: Slowly add the VEEGUM R and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Mill Part to a smooth paste. lend Part with Part C. Add this blend to Part A and mix until uniform. Croda Inc., Edison, NJ Lubrizol Advanced Materials, Inc., Cleveland, OH VEEGUM and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Acetulan is a registered trademark of The Lubrizol Corporation. rij is a registered trademark of Uniqema Americas LLC. rev0//0

35 Salicylic Acid Acne Treatment Cream No. 60 VEEGUM Ultra Magnesium Aluminum Silicate.5 VANZAN NF Xanthan Gum 0.5 Water 7.4 A Etidronic Acid 0. Propanediol (Zemea propanediol ) 5.0 C Salicylic Acid - USP.0 Steareth- ( RIJ S7-SO ).5 Steareth- (RIJ S-SO ).5 Cetearyl Alcohol (Protachem CS-50 ).5 Stearic Acid (Pristerene ).0 PPG-5 Stearyl Ether (Arlamol PS5E ) 8.0 Dimethicone (DC 00 Fluid, 50cSt 5 ).0 Preservative Triethanolamine (Adj. ph to.8 0.) Procedure: While heating the water to 80-85ºC, slowly add the VEEGUM Ultra and VANZAN NF sequentially or as a dry blend while mixing at maximum available shear. Continue mixing until fully hydrated. Add the etidronic acid and propanediol in order, mixing after each addition until uniform. Maintain the water phase at 80-85ºC. Combine the Part oil phase ingredients and heat to 80-85ºC. Add Part to Part A slowly with adequate mixing; homogenize. Cool gradually while mixing. Add the preservative when the emulsion is <0 o C, then adjust the ph to with triethanolamine. DuPont Tate & Lyle io Products Company, LLC, Wilmington, DE Croda Inc., Edison, NJ Protameen, Totowa, NJ 4 Uniquema, New Castle, DE 5 Dow Corning Corporation, Midland, MI VEEGUM and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Arlamol and rij are registered trademarks of Uniqema Americas LLC. Pristerene is a registered trademark of Unichema Chemie.V. Protachem is a trademark Protameen Chemicals, Inc. Zemea is a registered trademark of DuPont Tate & Lyle io Products Company, LLC. rev0//0

36 Instant Sulfur Acne Treatment Mask No. 590 VEEGUM HS Magnesium Aluminum Silicate 5 Kaolin USP 60 Sodium icarbonate 5 Avena Sativa (Oat ) Kernel Flour (Tech-O #-070 Oat Flour ) 5 Precipitated Sulfur USP 5 Procedure: Dry blend all ingredients. Use: y volume, mix about part water or witch hazel into 4.5 parts of poultice powder and mix to form a smooth paste. eacon CMP Corporation, Kenilworth, NJ VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Tech-O is a registered trademark of eacon CMP Corporation. rev0//0

37 Sulfur and Salicylic Acid Wash No. 58 Wt.% VEEGUM HS Magnesium Aluminum Silicate.00 A VANZAN NF Xanthan Gum 0.50 Water Sucrose Stearate (Surfhope SE Cosme C-8 ).5 Cetyl Alcohol.0 C D Glycerin 4.0 Sulfur (Yellow Jacket Wettable Sulfur II ).0 Sodium Laureth Sulfate 0.0 Salicylic Acid, USP.0 Preservative Sodium Hydroxide, 50% Procedure: While heating the water to 65 C, slowly add the VEEGUM HS and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Maintaining temperature at 65 C, add Part ingredients in order, mixing after each addition until uniform. Cool with stirring to ambient temperature. Slowly add the Part C and Part D ingredients in the order listed, mixing after each addition until uniform. Avoid the incorporation of air. Adjust to approximately ph 4.5 with sodium hydroxide solution. Arch Personal Care Products L.P., South Plainfield, NJ Georgia Gulf Sulfur Corporation, Valdosta, Georgia VEEGUM and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Surfhope is a registered trademark of Mitsubishi Chemical Corporation. Yellow Jacket is a registered trademark of Georgia Gulf Sulfur Corporation. rev0//0.

38 Cleansing ar No. 08 A VEEGUM F Magnesium Aluminum Silicate.0 Sodium Cocoyl Isethionate (Pureact I-78 ) 58. Cetyl Alcohol.0 Glyceral Monostearate A.S. 5.5 Stearyl Alcohol 7.5 Acetylated Lanolin (Modulan ).0 PEG Citric Acid 0.7 Water 9.0 C Preservative or iocide Procedure: lend the Part A ingredients. Heat Part to o C. Mix part A into Part until uniform. Press into mold and cool. Innospec Active Chemicals, Edison, NJ Lubrizol Advanced Materials, Inc., Cleveland, OH VEEGUM is a registered trademark of R.T. Vanderbilt Holding Company, Inc. or its Modulan is a registered trademark of The Lubrizol Corporation. Pureact is a registered trademark of Innospec Performance Chemicals Company. rev0//0

39 Natural Exfoliant Scrub No. 576 VANATURAL entonite Clay.00 A VANZAN NF Xanthan Gum 0.75 Water Decyl Glucoside (Plantaren 000N ) 7.00 C Cocamidopropyl betaine (Amphosol CA ).00 Propylene Glycol (and) Water (and) Mentha Piperita (Peppermint) Leaf Extract.00 (and) Mentha Piperita (Peppermint) Oil (Aromaphyte of Peppermint ) Water (and) Melaleuca Oil (and) Ethoxylated Castor Oil (and) Polysorbate 0.50 (Water-Soluble Tea Tree Oil 4 ) D Zea Mays (Corn) Cob Powder (Processed Corn Cob (60/00)) E Cocamide DEA (Ninol 40-CO ).00 F Preservative qs Procedure: Slowly add the VANATURAL and VANZAN NF sequentially or as a dry blend to the water agitated at maximum available shear. Mix until fully hydrated. Slowly add Parts, C, D, E and F in order, mixing after each until smooth while avoiding air entrapment and foaming. Cognis Corporation, Ambler, PA Stepan Company, Northfield, IL Active Organics Inc., Lewisville, TX 4 Southern Cross otanicals PTY Ltd, Lennox Head, NSW, Australia 5 Mt. Pulaski Products, Inc., Mt. Pulaski, IL VANATURAL and VANZAN are registered trademarks of R.T. Vanderbilt Holding Company, Inc. and/or its Amphosol and Ninol are registered trademarks of Stepan Company. Plantaren is a registered trademark of Cognis GmbH. rev0//0