Issuing Date: 10-Mar-2015 Revision Date: 10-Mar-2015 Version IDENTIFICATION. Clairol Professional Beautiful Collection Hair Color

Transcription

1 SAFETY DATA SHEET Issuing Date: 10-Mar-2015 Version IDENTIFICATION Product Name Product ID: Product Type: Recommended Use Synonyms Manufacturer Address Emergency Telephone Clairol Professional Beautiful Collection Hair _PROF_NG Finished Product - Professional Use Only Personal Beauty Care Product Clairol Professional Beautiful Collection Semi-Permanent Moisturizing Darkest Brown ( _PROF_NG) Clairol Professional Beautiful Collection Semi-Permanent Moisturizing Dark Warm Brown ( _PROF_NG) Clairol Professional Beautiful Collection Semi-Permanent Moisturizing Jet Black ( _PROF_NG) The Procter & Gamble Company Sharon Woods Innovation Center Reed Hartman Highway Cincinnati OH pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARD IDENTIFICATION This product is classifed under 29CFR (d) and the Canadian Hazardous Products Regulation as follows:. Eye Damage / Irritation Category 2B Skin sensitization Category 1 Signal Word WARNING Hazard Statements Causes eye irritation May cause an allergic skin reaction Hazard pictograms Page 1 / 8

2 Precautionary Statements - Prevention Precautionary Statements - Response Precautionary Statements - Storage Precautionary Statements - Disposal Hazards not otherwise classified (HNOC) Avoid breathing dust/fume/gas/mist/vapors/spray Wash hands thoroughly after handling IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before re-use If skin irritation occurs, get medical advice/attention If skin irritation or rash occurs: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention None Dispose of contents/container in accordance with local regulation None 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR Appendix D and the Canadian Hazardous Products Regulation Chemical Name Synonyms Trade Secret CAS-No Weight % Ethoxydiglycol - No Amino-2-methylpropanol - No Ethanol, 2,2'-[[4-[(2-hydroxyethyl)amino]-3-nitro phenyl]imino]bis- - No First aid measures for different exposure routes 4. FIRST AID MEASURES General advice Eye contact Skin contact Ingestion Inhalation No hazards which require special first aid measures. When symptoms persist or in all cases of doubt seek medical advice. Hair colorants can cause severe allergic reactions. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately if irritation persists. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Hair colorants can cause severe allergic reactions. If skin irritation or rash occurs: Get medical advice/attention. If symptoms persist, call a physician. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of soap and water. Not an expected route of exposure. If swallowed:. Clean mouth with water and afterwards drink plenty of water. Not an expected route of exposure. Page 2 / 8

3 Most important symptoms/effects, acute and delayed None under normal use conditions. May cause sensitization by skin contact. May cause eye irritation. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable Extinguishing Media Special hazard Special protective equipment for fire-fighters Specific hazards arising from the chemical Dry chemical. Carbon dioxide (CO 2). Alcohol-resistant foam. Water spray. Water. None. None known. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. None. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Advice for emergency responders Environmental precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Use personal protective equipment as required. Consumer use:. Do not discharge product into natural waters without pre-treatment or adequate dilution. Workplace:. Should not be released into the environment. Keep out of waterways. Methods and materials for containment and cleaning up Methods for containment Methods for cleaning up Workplace:. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Workplace:. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible products Keep out of reach of children. Keep containers tightly closed in a dry, cool and well-ventilated place. None known. Page 3 / 8

4 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines. Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Ethoxydiglycol TWA: 30 ppm TWA: 165 mg/m 3 No relevant exposure guidelines for other ingredients Exposure controls Engineering Measures Personal Protective Equipment Eye Protection Hand Protection Skin and Body Protection Respiratory Protection Hygiene measures Consumer use: Workplace: Safety glasses with side-shields Manufacturing Sites: Safety glasses with side-shields Distribution, Workplace and Household Settings: Consumer use: Workplace: Protective gloves Manufacturing Sites: Wearprotectivenaturalrubber,nitrilerubber,Neoprene orpvcgloves Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion Distribution, Workplace and Household Settings: Consumer use:. Workplace: Wear suitable protective clothing Manufacturing Sites: Wear protective gloves/clothing Distribution, Workplace and Household Settings: Consumer use: Workplace: When workers are facing concentrations above the exposure limit they must use appropriate certified respirators None under normal use condtions 9. PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor Odor threshold liquid clear yellow red liquid Strong Page 4 / 8

5 Property Values Note ph value Melting/freezing point Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limit Lower Flammability Limit Vapor pressure Vapor density Relative density Water solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity Stability Hazardous polymerization Hazardous Reactions Conditions to Avoid Materials to avoid None under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. None under normal processing. None under normal processing. None in particular. Hazardous Decomposition Products None under normal use. Product Information Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Inhalation Skin contact Ingestion Eye contact May cause sensitization by skin contact. Symptoms may be delayed. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Avoid contact with eyes. Irritating to eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Respiratory sensitization Germ cell mutagenicity Neurological Effects Reproductive toxicity Developmental toxicity Teratogenicity Irritating to eyes. May cause sensitization by skin contact. Page 5 / 8

6 STOT - single exposure STOT - repeated exposure Target Organ Effects Aspiration hazard Carcinogenicity Not applicable. Component Information Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation Ethoxydiglycol >0.025 mg/l (rat) 2-Amino-2-methylpropanol mg/kg bw (Similar to > 2000 mg/kg bw (Similar - OECD 401; standard acute method; rat) to OECD 402; standard acute method; rabbit) Ethanol, 2,2'-[[4-[(2-hydroxyethyl)amino]-3-nit rophenyl]imino]bis >2000 mg/kg (rat) - - Ecotoxicity The product is not expected to be hazardous to the environment. 12. ECOLOGICAL INFORMATION Persistence and degradability Bioaccumulative potential Mobility Other adverse effects DISPOSAL CONSIDERATIONS Waste treatment Waste from Residues / Unused Products Contaminated packaging California Hazardous Waste Codes (non-household setting) Consumer use:. Consumer products ending up down the drain after use. Workplace:. Should not be released into the environment. Dispose of in accordance with local regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations TRANSPORT INFORMATION DOT IMDG IATA Not regulated Not regulated Not regulated U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Page 6 / 8

7 Chemical Name CAS-No SARA Threshold Values % Ethoxydiglycol CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name CAS-No Hazardous Substances RQs Extremely Hazardous Substances RQs CERCLA/SARA 302 TPQ Diethyl phthalate lb - Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following substance(s) which are either listed as hazardous air pollutants (HAPS) or VOC's per the Clean Air Act: Chemical Name CAS-No CAA (Clean Air Act) Hazardous Air Pollutants Ethoxydiglycol X Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Chemical Name CAS-No CWA - Reportable CWA - Toxic CWA - Priority CWA - Hazardous Quantities Pollutants Pollutants Substances Diethyl phthalate X X - California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) Chemical Name CAS-No New Jersey Ethoxydiglycol X 2-Amino-2-methylpropanol X Chemical Name CAS-No Massachusetts 2-Amino-2-methylpropanol X Chemical Name CAS-No Pennsylvania Ethoxydiglycol X 2-Amino-2-methylpropanol X Isopropanol X Dipropylene glycol X Diethyl phthalate X International Inventories United States Product is a personal care product and regulated under FDA. Canada This product is in compliance with CEPA for import by P&G. Page 7 / 8

8 Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act Perfumes contained with the products comply with appropriate IFRA guidance. 16. OTHER INFORMATION Issuing Date: Revision Date: Reason for revision 10-Mar Mar-2015 Initial Release. Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 8 / 8