Kit Summary. Vidal Sassoon Pro Series Hair Color Kits

Transcription

1 Kit Summary Product Name Vidal Sassoon Pro Series Hair Color Kits Kit Comment SHADES Black 3/ Dark Copper Red 6/ Dark Brown 4/ Medium Golden Brown 5/ Medium Cool Brown 5/ Medium Brown 5/ Light Auburn 7/ WITH DEVELOPER AND CONDITIONER SHADES Medium Chocolate Brown 6/ Light Golden Brown 6/ Light Brown 6/ Lightest Brown 7/ Dark Cool Blonde 7/ Medium Golden Blonde 8/ Medium Blonde 8/ Light Blonde 9/ Extra Light Cool Blonde 10/ Extra Light Blonde 10/ WITH DEVELOPER and CONDITIONER

2 Material Safety Data Sheet Issuing Date: 02-Apr-2012 Version PRODUCT AND COMPANY IDENTIFICATION Product ID: Product Name Product Type Uses advised against Vidal Sasoon Pro Series Shade 6R Light Auburn 7/47 ( ) Finished Product - Consumer (Retail) Use Only All other uses Synonyms Light Auburn ( ) * Medium Brown ( ) * Medium Cool Brown ( ) * Medium Golden Brown ( ) * Dark Brown ( ) * Dark Copper Red ( ) * Black ( ) * Extra Light Blonde ( ) * Extra Light Cool Blonde ( ) * Light Blonde ( ) * Medium Blonde ( ) * Medium Golden Blonde ( ) * Dark Cool Blonde ( ) * Lightest Brown ( ) * Light Brown ( ) * Light Golden Brown ( ) * Medium Chocolate Brown ( ) * Medium Vibrant Red ( ) Address Emergency telephone Emergency Overview Irritating to eyes and skin pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARDS IDENTIFICATION OSHA Regulatory Status WHMIS Principle Routes of Exposure Consumer Products as defined by the U.S. Consumer Product Safety Act which are used as intended (typical consumer duration and frequency) are exempt from the OSHA Hazard Communication Standard. WHMIS hazardous composition: ingredients are hazardous according to the CPR criteria. ne reasonably foreseeable.

3 Vidal Sasoon Pro Series Shade 6R Light Auburn 7/47 ( ) 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS- Weight % Ammonia solution Laureth Resorcinol Phenol, 4-amino-3-methyl Aminoethanol Sodium hydroxide Phenol, 2-amino-6-chloro-4-nitro FIRST AID MEASURES General advice Eye contact Skin contact Ingestion Inhalation Protection of First-aiders Most important symptoms/effects, acute and delayed tes to physician Immediate medical attention is not required. When symptoms persist or in all cases of doubt seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. If symptoms persist, call a physician. If skin problems occur, discontinue use. If symptoms persist, call a physician. In the case of skin irritation or allergic reactions see a physician. Rinse mouth with water and afterwards drink plenty of water or milk. Do NOT induce vomiting. May produce an allergic reaction. Move to fresh air. If symptoms persist, call a physician. Consult a physician. Hair colorants can cause severe allergic reactions. Use personal protective equipment.. May cause sensitization of susceptible persons. 5. FIRE-FIGHTING MEASURES Flash Point Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Extinguishing media which shall not be used for safety reasons Special Hazard Special protective equipment for fire-fighters ne known based on information supplied As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapors. May cause sensitization by inhalation and skin contact. Page 3 / 31

4 Vidal Sasoon Pro Series Shade 6R Light Auburn 7/47 ( ) 6. ACCIDENTAL RELEASE MEASURES Personal precautions Advice for emergency responders Environmental precautions Methods for Containment Methods for Cleaning up Avoid contact with skin, eyes and clothing. Use personal protective equipment. Should not be released into the environment HANDLING AND STORAGE Advice on safe handling Technical measures/storage conditions Observe label precautions. Avoid contact with skin, eyes and clothing. Keep out of the reach of children. Keep container tightly closed in a dry and well-ventilated place. 8. EPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures t applicable. Personal Protective Equipment Eye Protection Hand Protection Skin and body protection Respiratory protection Thermal hazards Hygiene measures Avoid contact with eyes. Protective gloves. Wear protective gloves/clothing. special protective equipment required t applicable. Handle in accordance with good industrial hygiene and safety practice. Environmental Exposure Controls See Section 6. Page 4 / 31

5 Vidal Sasoon Pro Series Shade 6R Light Auburn 7/47 ( ) 9. PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor liquid viscous liquid. beige. orange. cream. Perfume Property Values te ph VALUE Melting/freezing point Boiling point/boiling range Flash Point Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor pressure Vapor density Relative density > 100 Water solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product Bulk Density Oxidizing Properties 10. STABILITY AND REACTIVITY Reactivity Stability Hazardous Polymerization Hazardous Reactions Conditions to Avoid Materials to Avoid ne under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. ne under normal processing. ne under normal processing. ne in particular. Hazardous Decomposition Products ne under normal use. Page 5 / 31

6 Vidal Sasoon Pro Series Shade 6R Light Auburn 7/47 ( ) Product Information 11. TOICOLOGICAL INFORMATION Acute toxicity Inhalation Skin contact Ingestion Eye contact Product does not present an acute toxicity hazard based on known or supplied information. known effect based on information supplied. Irritating to skin. known effect based on information supplied. Irritating to eyes. Chronic Toxicity Corrosivity Sensitization Neurological Effects Reproductive toxicity Mutagenic Effects Developmental Toxicity Teratogenicity Carcinogenicity The product contains no substances known to be hazardous to health in concentrations which need to be taken into account. There are no known mutagenic chemicals in this product. Contains no ingredients above reportable quantities listed as a carcinogen. 12. ECOLOGICAL INFORMATION Ecotoxicity Acute toxicity Toxicity to algae Toxicity to fish Toxicity to microorganisms Resorcinol 97 mg/l (OECD 201, Pseudokirchnerella subcapitata, static, growth rate, 72 h) Persistence and degradability LOEC (mortality and total embryotoxicity): 320 mg/l; LOEC (length): 100 mg/l and LOEC (weight): 32 mg/l (OECD Guide-line draft "Early Life Stage Test (ELS-Test)", Oncorhynchus mykiss, freshwater). Toxicity to daphnia and other aquatic invertebrates >=0.172 mg/l EC50 Daphnia magna 21d (OECD 211) Toxicity to other organisms Bioaccumulative potential. Mobility. Other adverse effects Page 6 / 31

7 Vidal Sasoon Pro Series Shade 6R Light Auburn 7/47 ( ) 13. DISPOSAL CONSIDERATIONS Waste from Residues / Unused Products Contaminated packaging Dispose of in accordance with local regulations. Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT TDG ME IATA ICAO IMDG/IMO U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: CAS- Weight % SARA Threshold Values % Ammonia solution SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Ammonia solution 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ Resorcinol 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ Sodium hydroxide 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of Page 7 / 31

8 Vidal Sasoon Pro Series Shade 6R Light Auburn 7/47 ( ) Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Ammonia solution Resorcinol Sodium hydroxide U.S. State Regulations CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances 1000 lb lb lb - - California Proposition 65 This product is not subject to warning labeling under California Proposition 65 Ammonia solution Ammonia solution Ammonia solution Resorcinol Sodium hydroxide Sulfuric acid sodium salt (1:2) New Jersey Massachusetts Pennsylvania International Regulations Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. International Inventories TSCA All intentionally-added components of this product(s) are listed on the US TSCA Inventory DSL Complies NDSL Complies Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List Page 8 / 31

9 Vidal Sasoon Pro Series Shade 6R Light Auburn 7/47 ( ) 16. OTHER INFORMATION Issuing Date: Revision Date: 02-Apr Jan-2013 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 9 / 31

10 Material Safety Data Sheet Issuing Date: 02-Apr-2012 Version PRODUCT AND COMPANY IDENTIFICATION Product ID: Product Name Product Type Recommended use Uses advised against Synonyms Manufacturer Address Emergency telephone Emergency Overview Irritating to eyes and skin Vidal Sassoon PrecisionMixÔ Developer Creme 6% Finished Product - Consumer (Retail) and Professional Use Personal Beauty Care Product All other uses The Procter & Gamble Company Sharon Woods Innovation Center Reed Hartman Highway Cincinnati OH pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARDS IDENTIFICATION OSHA Regulatory Status WHMIS Principle Routes of Exposure General Hazards Consumer Products as defined by the U.S. Consumer Product Safety Act which are used as intended (typical consumer duration and frequency) are exempt from the OSHA Hazard Communication Standard. When used in a professional setting (at a much higher frequency and duration than a typical consumer) this material would be considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). WHMIS hazardous composition: ingredients are hazardous according to the CPR criteria. Skin contact. Eye contact. This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use

11 Vidal Sassoon PrecisionMixÔ Developer Creme 6% 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients CAS- Weight % Hydrogen peroxide solution...% Sulfuric acid monododecyl ester sodium salt (1:1) Salicylic acid FIRST AID MEASURES General advice Eye contact Skin contact Ingestion Inhalation Protection of First-aiders Most important symptoms/effects, acute and delayed tes to physician hazards which require special first aid measures. When symptoms persist or in all cases of doubt seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. If symptoms persist, call a physician. If skin problems occur, discontinue use. If skin irritation persists, call a physician. Rinse mouth. Drink plenty of water. Do NOT induce vomiting. t an expected route of exposure. Use personal protective equipment. ne known. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flash Point Suitable Extinguishing Media t applicable Dry chemical, CO 2, water spray or alcohol-resistant foam. Extinguishing media which shall not be used for safety reasons Special Hazard Special protective equipment for fire-fighters Hazardous Combustion Products This is a strong oxidizer and will react vigorously or explosively with many materials including fuels As in any fire, wear self-contained breathing apparatus and full protective gear. The release of the following substances is possible in a fire:. Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Nitrogen oxides (NOx). Page 11 / 31

12 Vidal Sassoon PrecisionMixÔ Developer Creme 6% 6. ACCIDENTAL RELEASE MEASURES Personal precautions Advice for emergency responders Environmental precautions Methods for Containment Methods for Cleaning up Avoid contact with eyes. Use personal protective equipment. Should not be released into the environment HANDLING AND STORAGE Advice on safe handling Technical measures/storage conditions Keep out of the reach of children. Observe label precautions. Avoid contact with skin, eyes and clothing. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. 8. EPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Engineering Measures t applicable. Personal Protective Equipment Eye Protection Hand Protection Skin and body protection Respiratory protection Thermal hazards Hygiene measures Environmental Exposure Controls Avoid contact with eyes. Protective gloves. Wear protective gloves/clothing. special protective equipment required t applicable. When using, do not eat, drink or smoke. Remove and wash contaminated clothing before re-use. Do not allow material to contaminate ground water system. Page 12 / 31

13 Vidal Sassoon PrecisionMixÔ Developer Creme 6% 9. PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor liquid viscous liquid. Milky light beige emulsion. Property Values te ph VALUE Melting/freezing point t applicable Boiling point/boiling range Flash Point t applicable Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor pressure Vapor density Relative density > 1.00 Water solubility Slightly insoluble Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product Bulk Density Oxidizing Properties 10. STABILITY AND REACTIVITY Reactivity Stability Hazardous Polymerization Hazardous Reactions Conditions to Avoid Materials to Avoid ne under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. ne under normal processing. Heat, flames and sparks. Protect from light. ne in particular. Hazardous Decomposition Products Oxygen. Page 13 / 31

14 Vidal Sassoon PrecisionMixÔ Developer Creme 6% Product Information 11. TOICOLOGICAL INFORMATION Acute toxicity Principle Routes of Exposure Inhalation Skin contact Ingestion Eye contact Irritating to eyes and skin Skin contact. Eye contact. t an expected route of exposure. Irritating to skin. known effect based on information supplied. Irritating to eyes. Chronic Toxicity Corrosivity Sensitization Neurological Effects Reproductive toxicity Mutagenic Effects Developmental Toxicity Teratogenicity Carcinogenicity The product contains no substances known to be hazardous to health in concentrations which need to be taken into account. There are no known mutagenic chemicals in this product. Contains no ingredients above reportable quantities listed as a carcinogen. 12. ECOLOGICAL INFORMATION Ecotoxicity Acute toxicity Persistence and degradability Bioaccumulative potential.. Mobility. Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste from Residues / Unused Products Contaminated packaging Dispose of in accordance with local regulations. Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION Page 14 / 31

15 Vidal Sassoon PrecisionMixÔ Developer Creme 6% DOT TDG ME IATA ICAO IMDG/IMO U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard yes CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Hydrogen peroxide solution...% lb - Phosphoric acid, sodium salt 5000 lb - RQ 5000 lb final RQ RQ 2270 (1:2) kg final RQ Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any HAPs. Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Phosphoric acid, sodium salt (1:2) U.S. State Regulations CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances 5000 lb - - California Proposition 65 This product is not subject to warning labeling under California Proposition 65 U.S. State Regulations Page 15 / 31

16 Vidal Sassoon PrecisionMixÔ Developer Creme 6% Hydrogen peroxide solution...% Hydrogen peroxide solution...% Hydrogen peroxide solution...% Phosphoric acid, sodium salt (1:2) Hydrogen peroxide solution...% New Jersey Massachusetts Pennsylvania Rhode Island International Regulations Canada WHMIS Hazard Class t subject to WHMIS classification This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of Health Canada and is therefore exempt from the requirements of CEPA. International Inventories TSCA Exempt DSL Exempt NDSL Exempt Perfumes contained with the products comply with appropriate IFRA guidance. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List 16. OTHER INFORMATION Issuing Date: Revision Date: 02-Apr Jan-2013 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 16 / 31

17 Material Safety Data Sheet Issuing Date: 02-Apr-2012 Version PRODUCT AND COMPANY IDENTIFICATION Product ID: Product Name Product Type Recommended use Uses advised against Synonyms Manufacturer Address Emergency telephone Emergency Overview Irritating to eyes and skin Vidal Sassoon PrecisionMixÔ Developer Creme 9% Finished Product - Consumer (Retail) and Professional Use Personal Beauty Care Product All other uses The Procter & Gamble Company Sharon Woods Innovation Center Reed Hartman Highway Cincinnati OH pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARDS IDENTIFICATION OSHA Regulatory Status WHMIS Principle Routes of Exposure General Hazards Consumer Products as defined by the U.S. Consumer Product Safety Act which are used as intended (typical consumer duration and frequency) are exempt from the OSHA Hazard Communication Standard. When used in a professional setting (at a much higher frequency and duration than a typical consumer) this material would be considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). WHMIS hazardous composition: ingredients are hazardous according to the CPR criteria. Skin contact. Eye contact. This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use

18 Vidal Sassoon PrecisionMixÔ Developer Creme 9% 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients CAS- Weight % Hydrogen peroxide solution...% Sulfuric acid monododecyl ester sodium salt (1:1) Salicylic acid FIRST AID MEASURES General advice Eye contact Skin contact Ingestion Inhalation Protection of First-aiders Most important symptoms/effects, acute and delayed tes to physician hazards which require special first aid measures. When symptoms persist or in all cases of doubt seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. If symptoms persist, call a physician. If skin problems occur, discontinue use. If skin irritation persists, call a physician. Rinse mouth. Drink plenty of water. Do NOT induce vomiting. t an expected route of exposure. Use personal protective equipment. ne known. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flash Point Suitable Extinguishing Media t applicable Dry chemical, CO 2, water spray or alcohol-resistant foam. Extinguishing media which shall not be used for safety reasons Special Hazard Special protective equipment for fire-fighters Hazardous Combustion Products This is a strong oxidizer and will react vigorously or explosively with many materials including fuels As in any fire, wear self-contained breathing apparatus and full protective gear. The release of the following substances is possible in a fire:. Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Nitrogen oxides (NOx). Page 18 / 31

19 Vidal Sassoon PrecisionMixÔ Developer Creme 9% 6. ACCIDENTAL RELEASE MEASURES Personal precautions Advice for emergency responders Environmental precautions Methods for Containment Methods for Cleaning up Avoid contact with the skin and the eyes. Use personal protective equipment. Should not be released into the environment HANDLING AND STORAGE Advice on safe handling Technical measures/storage conditions Keep out of the reach of children. Observe label precautions. Avoid contact with skin, eyes and clothing. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. 8. EPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Engineering Measures t applicable. Personal Protective Equipment Eye Protection Hand Protection Skin and body protection Respiratory protection Thermal hazards Hygiene measures Environmental Exposure Controls Avoid contact with eyes. Protective gloves. Wear protective gloves/clothing. special protective equipment required t applicable. When using, do not eat, drink or smoke. Remove and wash contaminated clothing before re-use. Do not allow material to contaminate ground water system. Page 19 / 31

20 Vidal Sassoon PrecisionMixÔ Developer Creme 9% 9. PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor liquid viscous liquid. Milky light beige emulsion. Property Values te ph VALUE Melting/freezing point t applicable Boiling point/boiling range Flash Point t applicable Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor pressure Vapor density Relative density > 1.00 Water solubility Slightly insoluble Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product Bulk Density Oxidizing Properties 10. STABILITY AND REACTIVITY Reactivity Stability Hazardous Polymerization Hazardous Reactions Conditions to Avoid Materials to Avoid ne under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. ne under normal processing. Heat, flames and sparks. Protect from light. ne in particular. Hazardous Decomposition Products Oxygen. Page 20 / 31

21 Vidal Sassoon PrecisionMixÔ Developer Creme 9% Product Information 11. TOICOLOGICAL INFORMATION Acute toxicity Principle Routes of Exposure Inhalation Skin contact Ingestion Eye contact Irritating to eyes and skin Skin contact. Eye contact. t an expected route of exposure. Irritating to skin. known effect based on information supplied. Irritating to eyes. Chronic Toxicity Corrosivity Sensitization Neurological Effects Reproductive toxicity Mutagenic Effects Developmental Toxicity Teratogenicity Carcinogenicity The product contains no substances known to be hazardous to health in concentrations which need to be taken into account. There are no known mutagenic chemicals in this product. Contains no ingredients above reportable quantities listed as a carcinogen. 12. ECOLOGICAL INFORMATION Ecotoxicity Acute toxicity Persistence and degradability Bioaccumulative potential.. Mobility. Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste from Residues / Unused Products Contaminated packaging Dispose of in accordance with local regulations. Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION Page 21 / 31

22 Vidal Sassoon PrecisionMixÔ Developer Creme 9% DOT UN/ID Proper shipping name Hazard class Packing Group Reportable Quantity (RQ) Description Emergency Response Guide Number UN2984 Hydrogen peroxide, aqueous solutions 5.1 III Sodium phosphate dibasic: RQ(kg)=1.816 UN2984, Hydrogen peroxide, aqueous solutions, 5.1, III 140 TDG UN/ID UN2984 Proper shipping name Hydrogen peroxide, aqueous solution Hazard class 5.1 Packing Group III Description UN2984, Hydrogen peroxide, aqueous solution, 5.1, III ME UN/ID Proper shipping name Hazard class Packing Group Description UN2984 Hydrogen peroxide, aqueous solution 5.1 III UN2984, Hydrogen peroxide, aqueous solution, 5.1, III IATA UN/ID UN2984 Proper shipping name Hydrogen peroxide, aqueous solution Hazard class 5.1 Packing Group III ERG Code 5L Description UN2984, Hydrogen peroxide, aqueous solution, 5.1, III ICAO UN/ID UN2984 Proper shipping name Hydrogen peroxide, aqueous solution Hazard class 5.1 Packing Group III Description UN2984, Hydrogen peroxide, aqueous solution, 5.1, III IMDG/IMO UN/ID UN2984 Proper shipping name Hydrogen peroxide, aqueous solution Hazard class 5.1 Packing Group III EmS. F-H, S-Q Description UN2984, Hydrogen peroxide, aqueous solution, 5.1, III U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Page 22 / 31

23 Vidal Sassoon PrecisionMixÔ Developer Creme 9% Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard yes CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Hazardous Substances RQs Extremely Hazardous RQ Substances RQs Hydrogen peroxide solution...% lb - Phosphoric acid, sodium salt 5000 lb - RQ 5000 lb final RQ RQ 2270 (1:2) kg final RQ Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following substance(s) which are either listed as hazardous air pollutants (HAPS) or VOC's per the Clean Air Act: Volatile Organic Compounds CAA (Clean Air Act) Hazardous Air Pollutants Salicylic acid Present - Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). Phosphoric acid, sodium salt (1:2) U.S. State Regulations CWA - Reportable Quantities 5000 lb CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances - - California Proposition 65 This product is not subject to warning labeling under California Proposition 65 U.S. State Regulations Hydrogen peroxide solution...% Hydrogen peroxide solution...% Hydrogen peroxide solution...% Phosphoric acid, sodium salt (1:2) Hydrogen peroxide solution...% New Jersey Massachusetts Pennsylvania Rhode Island International Regulations Page 23 / 31

24 Vidal Sassoon PrecisionMixÔ Developer Creme 9% Canada WHMIS Hazard Class t subject to WHMIS classification This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of Health Canada and is therefore exempt from the requirements of CEPA. International Inventories TSCA Exempt DSL Exempt NDSL Exempt Perfumes contained with the products comply with appropriate IFRA guidance. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List 16. OTHER INFORMATION Issuing Date: Revision Date: 02-Apr Jan-2013 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 24 / 31

25 Material Safety Data Sheet Issuing Date: 02-Apr-2012 Version 3.02 Product ID: PRODUCT AND COMPANY IDENTIFICATION Product Name Product Type Recommended use Uses advised against Synonyms Manufacturer Address Emergency telephone Emergency Overview OSHA Regulatory Status WHMIS Principle Routes of Exposure General Hazards Vidal Sassoon HydraBlock TM Color Preserving Conditoner Finished Product - Consumer (Retail) Use Only Personal Beauty Care Product All other uses The Procter & Gamble Company Sharon Woods Innovation Center Reed Hartman Highway Cincinnati OH pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARDS IDENTIFICATION Consumer Products as defined by the U.S. Consumer Product Safety Act which are used as intended (typical consumer duration and frequency) are exempt from the OSHA Hazard Communication Standard. WHMIS hazardous composition: ingredients are hazardous according to the CPR criteria. Skin contact. Eye contact. This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use Page 25 / 31

26 Vidal Sassoon HydraBlock TM Color Preserving Conditoner 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients ne 4. FIRST AID MEASURES General advice Eye contact Skin contact Ingestion Inhalation Protection of First-aiders Most important symptoms/effects, acute and delayed tes to physician hazards which require special first aid measures. When symptoms persist or in all cases of doubt seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. If symptoms persist, call a physician. If skin problems occur, discontinue use. If symptoms persist, call a physician. t an expected route of exposure. If swallowed. Clean mouth with water and afterwards drink plenty of water. t an expected route of exposure. Use personal protective equipment. ne known. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flash Point Suitable Extinguishing Media t applicable Dry chemical, CO 2, water spray or alcohol-resistant foam. Extinguishing media which shall not be used for safety reasons Special Hazard Special protective equipment for fire-fighters ne known based on information supplied As in any fire, wear self-contained breathing apparatus and full protective gear. Page 26 / 31

27 Vidal Sassoon HydraBlock TM Color Preserving Conditoner 6. ACCIDENTAL RELEASE MEASURES Personal precautions Advice for emergency responders Environmental precautions Methods for Containment Methods for Cleaning up ne under normal use conditions. Use personal protective equipment. Should not be released into the environment HANDLING AND STORAGE Advice on safe handling Technical measures/storage conditions Keep out of the reach of children. Observe label precautions. Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures t applicable. Personal Protective Equipment Eye Protection Hand Protection Skin and body protection Respiratory protection Thermal hazards Hygiene measures special protective equipment required. special protective equipment required. special protective equipment required. special protective equipment required t applicable. ne under normal use condtions. Environmental Exposure Controls See Section 6. Page 27 / 31

28 Vidal Sassoon HydraBlock TM Color Preserving Conditoner 9. PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor liquid viscous liquid. Pale yellow. white. cream. Characteristic Property Values te ph VALUE Melting/freezing point t applicable Boiling point/boiling range > 100 C / 212 F Flash Point t applicable Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor pressure Vapor density Relative density > 0.95 Water solubility Slightly insoluble Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product Bulk Density Oxidizing Properties 10. STABILITY AND REACTIVITY Reactivity Stability Hazardous Polymerization Hazardous Reactions Conditions to Avoid Materials to Avoid ne under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. ne under normal processing. ne under normal processing. ne in particular. Hazardous Decomposition Products ne under normal use. Page 28 / 31

29 Vidal Sassoon HydraBlock TM Color Preserving Conditoner Product Information 11. TOICOLOGICAL INFORMATION Acute toxicity Principle Routes of Exposure Inhalation Skin contact Ingestion Eye contact Product does not present an acute toxicity hazard based on known or supplied information. Skin contact. Eye contact. known effect based on information supplied. known effect based on information supplied. known effect based on information supplied. known effect based on information supplied. Chronic Toxicity Corrosivity Sensitization Neurological Effects Reproductive toxicity Mutagenic Effects Developmental Toxicity Teratogenicity Carcinogenicity The product contains no substances known to be hazardous to health in concentrations which need to be taken into account. There are no known mutagenic chemicals in this product. Contains no ingredients above reportable quantities listed as a carcinogen. 12. ECOLOGICAL INFORMATION Ecotoxicity Acute toxicity Persistence and degradability Bioaccumulative potential.. Mobility. Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste from Residues / Unused Products Contaminated packaging Dispose of in accordance with local regulations. Dispose of in accordance with local regulations. Page 29 / 31

30 Vidal Sassoon HydraBlock TM Color Preserving Conditoner 14. TRANSPORT INFORMATION DOT TDG ME IATA ICAO IMDG/IMO U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Edetic acid 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Edetic acid 5000 lb - - U.S. State Regulations California Proposition 65 This product is not subject to warning labeling under California Proposition 65 Page 30 / 31

31 Vidal Sassoon HydraBlock TM Color Preserving Conditoner U.S. State Regulations Edetic acid Pennsylvania International Regulations Canada WHMIS Hazard Class t subject to WHMIS classification This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of Health Canada and is therefore exempt from the requirements of CEPA. International Inventories TSCA Exempt DSL Exempt NDSL Exempt Perfumes contained with the products comply with appropriate IFRA guidance. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List 16. OTHER INFORMATION Issuing Date: Revision Date: 02-Apr Jan-2013 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 31 / 31