HELPING TO BUILD A HEALTHIER ENVIRONMENT THROUGH SUPERIOR GREEN CLEANING

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1 HELPING TO BUILD A HEALTHIER ENVIRONMENT THROUGH SUPERIOR GREEN CLEANING

2 Soap Free Procyon is manufactured by Plus Manufacturing located in the beautiful Pacific Northwest city of Spokane, Washington. For technical questions please call our toll free hotline at PRO-CYON ( ) or visit us on the internet at i

3 For over 30 years, Soap Free Procyon has provided an all natural, environmentally friendly, hypoallergenic, odor free, colorless, non-toxic, high quality cleaner for carpets, upholstery, tile, grout, spot, stain, and general purpose cleaning. Procyon is certified by Green Seal and approved by Indoor Air Quality and the Carpet and Rug Institute. ii

4 Soap Free Procyon does it all and eliminates the need for: ꔷ defoamers ꔷ brighteners ꔷ boosters ꔷ rinsing agents ꔷ neutralizers iii

5 Certifications Pages 1-13 Lab Reports and Assessments Pages Product Information and SDS Pages Carpet Crisis Solutions Pages iv

6 P lus Manufacturing is proud of it s environmental record and many industry approvals and certifications. Soap Free Procyon has more certifications and endorsements than any other product of it s kind. 1

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15 Page Number 1 ATHEY CONSULTING SERVICES Miles Athey, PhD, Director ACS - Indoor Air Quality ACS - Environmental Studies 1007 S. Columbia Ritzville, WA macart44@gmail.com March 11, 2016 Procyon Health and Safety Facts Extensively Researched and Tested Procyon cleaning products are comprised of a proprietary solution of inorganic products. As such, they contain no volatile organic compounds (VOCs) as tested and verified by the analytical forensic testing laboratory, Analytical Chemistry Inc. of Tukwila, WA. In addition, nationally recognized indoor air quality experts, Miles Athey, PhD, toxicology, and Richard Knights, PhD, analytical chemistry, have thoroughly tested and researched the Procyon cleaning products for health and safety concerns and their cleaning effectiveness. No other carpet cleaning products or processes have demonstrated the consistent level of cleaning effectiveness of Procyon in my fifteen years of testing these products in schools and other public facilities. Dr. Miles Athey, ACS, Ritzville, WA. Safe for Asthmatic and Allergy-Sensitive Individuals Extensive research during the past 15 years in numerous schools, medical and other public facilities has demonstrated that Procyon cleaning products are safe for use around asthmatic and allergy sensitive occupants. Preferred by Custodial Professionals Plus Manufacturing Inc. cleaning products, carrying the Procyon label, have been appreciated by hundreds of health conscious custodial professionals nationwide and around the world since their inception in Green Seal Certified Procyon cleaning products were the first carpet and surface cleaning products certified by Green Seal for environmental, human health and safety. Miles Athey, PhD, Toxicology Solutions To Difficult Environmental Problems Indoor Air Quality Toxicological Assessments Environmental Studies Site Planning Design Review Project & Construction Management 10

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29 - 1 - Issue date: June Identification Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03 Product Identifier (Trade name): Procyon Extreme Carpet Pre-Spray Concentrate Recommended Use of Product: Cleaning of carpet and upholstery items. Product Description: this product is a solution comprised of inorganic chemicals and water, therefore does not qualify as a health or environmental hazard. Application of the Product: fabric cleaner Manufacturer/Supplier: Plus Manufacturing Inc 2704 N. Madelia St Spokane, WA PROCYON ( ) Local: Fax: Emergency Telephone Number: Hazard (s) Identification Classification of the Chemical Ingredients: Category 0: Non-hazardous/Non-Toxic Category 0: Non-hazardous/Non-Toxic Hazard Statements: May cause minor skin or eye irritation in extremely hypersensitive individuals. Precautionary Statements: Wear protective gloves and eye protection. Rinse off exposed extremities after handling. If in eyes, rinse with water for several minutes. If skin or eye irritation persists (extremely rare), get medical attention. Unknown Acute Toxicity: No components of this product cause acute toxicity. NFPA ratings (scale 0-4) Health = 0, Fire = 0, Reactivity = 0 HMIS ratings (scale 0-4) Health = 0, Flammability = 0, Physical Hazard = 0, Personal Protection = 0 Hazards not otherwise classified (HNOC): None known.

30 - 2-3 Composition/Information on Ingredients Mixture of Chemical Ingredients: Mixture of chemicals listed below with non-hazardous additions including water. CAS /Component/% of Mixture: Phosphoric Acid 9-11% Sodium Salt 1-3% Silicic Acid 0.2-1% 4 First-aid Measures Inhalation: Not relevant Skin Exposure: Rinse with water. Eye contact: Irrigate eye with running water for several minutes. Ingestion: If nausea occurs consult doctor. 5 Fire-fighting Measures Extinguishing Media: product not flammable. Protective Equipment: product not flammable. Precautions for firefighting: product not flammable. 6 Accidental Release Measures Precautions: none required; product non-hazardous. Protective Equipment: none required but may be preferred by user. Spill Containment/Cleanup Measure: use liquid absorbing material for pickup of product; use squeegee to push spilled product into domestic floor drain if present. 7 Handling & Storage Keep containers tightly sealed in dry environment at standard room temperatures. 8 Exposure Controls/Personal Protection Components with occupational exposure limits: Phosphoric Acid PEL Long-term value: 1 mg/m3 REL: Short-term value: 3 mg/m3 Long-term value: 1 mg/m3 TLV Short-term value:3 mg/m3 Long-term value: 1mg/m3 Protective Measures: Usual precautionary measures for handling of mild nontoxic chemicals should be followed. Avoid excessive contact with skin and eyes. Breathing equipment not required. Protective gloves and eyewear optional.

31 - 3-9 Physical & Chemical Properties Appearance: clear liquid. Odor: odorless. No fragrance added. Odor Threshold: not relevant. ph value: Concentrate 11.0 / working dilution 10.5 / dry 6.5 Melting Point: undetermined. Boiling Point: 100 degrees Centigrade. Flash Point: none. Evaporation Point: not determined. Flammability: non-flammable. Explosive Limits: not relevant. Vapor Pressure/Density: VP is not relevant/density = g/cc Relative Density: not determined. Solubility: not determined. Partition Coefficient: not determined. Viscosity: not determined. Solvent Content: Organic solvents: 0.0% Water: 85-89% Chemical Ingredients: 11-15% 10 Stability & Reactivity Chemical stability: stable under normal/standard conditions. Reactivity: no relevant information. Conditions to avoid: no relevant information. Possibility of hazardous reactions: none. Hazardous decomposition: no dangerous reactions known. Incompatible materials: no relevant information. 11 Toxicological Information: Likely Routes of Exposure: minor likelihood of exposure to skin, lungs, eyes Acute Toxicity: none Description of Symptoms of Exposure: mild irritant to skin of hypersensitive individuals; mild irritant to eyes and mucous membranes of hypersensitive individuals. Carcinogenic Effects of Exposure: IARC: none of the ingredients are listed. NTP: none of the ingredients are listed. OSHA: none of the ingredients are listed. 12 Ecological Information Toxicity: no relevant information available. Persistence and degradability: no relevant information available. Bioaccumulative potential: no relevant information available. Mobility in soil: no relevant information available. Other adverse effects: no relevant information available.

32 Other information: no relevant information available Disposal Considerations Waste treatment methods: no relevant treatment methods are applicable. Regional legislation (waste): not applicable. Waste disposal recommendations: recycle empty containers or dispose of with household trash; liquid product can be washed into domestic waste water and/or sewage systems. 14 Transport Information UN number: DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. UN proper shipping name DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. Environmental hazards: not applicable. Special precautions: not applicable. Air transport: not applicable. UN "Model Regulation": product does not contain regulated materials. 15 Regulatory Information Safety, health and environmental regulations/legislation specific to the substance or mixture: SARA: Section 355 and/or Section 313: none of the ingredients are listed. TSCA: all ingredients are listed. California Proposition 65: not applicable. Chemicals known to cause: cancer: none of the ingredients are listed. reproductive toxicity for females; none of the ingredients are listed. developmental toxicity: none of the ingredients are listed. EPA: none of the ingredients are listed. TLV established by ACGIH: none of the ingredients are listed. NIOSH: none of the ingredients are listed. GHS label elements: product is classified and labeled according to the Globally Harmonized System. See Section 2 of this SDS. Precautionary statements: See Section 2 of this SDS. Chemical safety assessment: not been completed since none of the ingredients are considered a health hazard. 16 Other Information This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not however be construed as guaranteeing any specific property of the product. It is the responsibility of the user to determine applicability of this information and the suitability of the product for any particular purpose. Date of preparation: June, 2015

33 - 1 - Issue date: June Identification Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03 Product Identifier (Trade name): Procyon Carpet & Upholstery Cleaner Recommended Use of Product: Cleaning of carpet and upholstery items. Product Description: this product is a solution comprised of inorganic chemicals and water, therefore does not qualify as a health or environmental hazard. Application of the Product: fabric cleaner Manufacturer/Supplier: Plus Manufacturing Inc 2704 N. Madelia St Spokane, WA PROCYON ( ) Local: Fax: Emergency Telephone Number: Hazard (s) Identification Classification of the Chemical Ingredients: Category 0: Non-hazardous/Non-Toxic Category 0: Non-hazardous/Non-Toxic Hazard Statements: May cause minor skin or eye irritation in extremely hypersensitive individuals. Precautionary Statements: Wear protective gloves and eye protection if appropriate. Rinse off exposed extremities after handling. If in eyes, rinse with water for several minutes. If skin or eye irritation persists (extremely rare), get medical attention. Unknown Acute Toxicity: No components of this product cause acute toxicity. NFPA ratings (scale 0-4) Health = 0, Fire = 0, Reactivity = 0 HMIS ratings (scale 0-4) Health = 0, Flammability = 0, Physical Hazard = 0, Personal Protection = 0 Hazards not otherwise classified (HNOC): None known.

34 3 Composition/Information on Ingredients Mixture of Chemical Ingredients: Mixture of chemicals listed below with non-hazardous additions including water. CAS /Component/% of Mixture: Phosphoric Acid 9-11% Sodium Salt 2-4% 4 First-aid Measures Inhalation: Not relevant Skin Exposure: Rinse with water. Eye contact: Irrigate eye with running water for several minutes. Ingestion: If nausea occurs consult doctor. 5 Fire-fighting Measures Extinguishing Media: product not flammable. Protective Equipment: product not flammable. Precautions for firefighting: product not flammable. 6 Accidental Release Measures Precautions: none required; product non-hazardous. Protective Equipment: none required but may be preferred by user. Spill Containment/Cleanup Measure: use liquid absorbing material for pickup of product; use squeegee to push spilled product into domestic floor drain if present. 7 Handling & Storage Keep containers tightly sealed in dry environment at standard room temperatures. 8 Exposure Controls/Personal Protection Components with occupational exposure limits: Phosphoric Acid PEL Long-term value: 1 mg/m3 REL: Short-term value: 3 mg/m3 Long-term value: 1 mg/m3 TLV Short-term value:3 mg/m3 Long-term value: 1mg/m3 Protective Measures: Usual precautionary measures for handling of mild nontoxic chemicals should be followed. Avoid excessive contact with skin and eyes. Breathing equipment not required. Protective gloves and eyewear optional.

35 9 Physical & Chemical Properties Appearance: clear liquid. Odor: odorless, no fragrance added. Odor Threshold: not relevant. ph value: 9.6 / RTU 9.6 / DRY 8.4 Melting Point: undetermined. Boiling Point: 100 degrees Centigrade. Flash Point: none. Evaporation Point: not determined. Flammability: non-flammable. Explosive Limits: not relevant. Vapor Pressure/Density: VP is not relevant/density = g/cc3 Relative Density: not determined. Solubility: not determined. Partition Coefficient: not determined. Viscosity: not determined. Solvent Content: Organic solvents: 0.0% Water: 85-89% Chemical Ingredients: 11-15% 10 Stability & Reactivity Chemical stability: stable under normal/standard conditions. Reactivity: no relevant information. Conditions to avoid: no relevant information. Possibility of hazardous reactions: none. Hazardous decomposition: no dangerous reactions known. Incompatible materials: no relevant information. 11 Toxicological Information: Likely Routes of Exposure: minor likelihood of exposure to skin, lungs, eyes Acute Toxicity: none Description of Symptoms of Exposure: mild irritant to skin of hypersensitive individuals; mild irritant to eyes and mucous membranes of hypersensitive individuals. Carcinogenic Effects of Exposure: IARC: none of the ingredients are listed. NTP: none of the ingredients are listed. OSHA: none of the ingredients are listed. 12 Ecological Information Toxicity: no relevant information available. Persistence and degradability: no relevant information available. Bioaccumulative potential: no relevant information available. Mobility in soil: no relevant information available. Other adverse effects: no relevant information available.

36 Other information: no relevant information available Disposal Considerations Waste treatment methods: no relevant treatment methods are applicable. Regional legislation (waste): not applicable. Waste disposal recommendations: recycle empty containers or dispose of with household trash; liquid product can be washed into domestic waste water and/or sewage systems. 14 Transport Information UN number: DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. UN proper shipping name DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. Environmental hazards: not applicable. Special precautions: not applicable. Air transport: not applicable. UN "Model Regulation": product does not contain regulated materials. 15 Regulatory Information Safety, health and environmental regulations/legislation specific to the substance or mixture: SARA: Section 355 and/or Section 313: none of the ingredients are listed. TSCA: all ingredients are listed. California Proposition 65: not applicable. Chemicals known to cause: cancer: none of the ingredients are listed. reproductive toxicity for females; none of the ingredients are listed. developmental toxicity: none of the ingredients are listed. EPA: none of the ingredients are listed. TLV established by ACGIH: none of the ingredients are listed. NIOSH: none of the ingredients are listed. GHS label elements: product is classified and labeled according to the Globally Harmonized System. See Section 2 of this SDS. Precautionary statements: See Section 2 of this SDS. Chemical safety assessment: not been completed since none of the ingredients are considered a health hazard. 16 Other Information This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not however be construed as guaranteeing any specific property of the product. It is the responsibility of the user to determine applicability of this information and the suitability of the product for any particular purpose. Date of preparation: June 2015

37 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev Issue date: June Identification Product Identifier (Trade name): Procyon Spot & Stain Cleaner Recommended Use of Product: Cleaning of carpet and upholstery items. Product Description: this product is a solution comprised of inorganic chemicals and water, therefore does not qualify as a health or environmental hazard. Application of the Product: fabric cleaner Manufacturer/Supplier: Plus Manufacturing Inc 2704 N. Madelia St Spokane, WA PROCYON ( ) Local: Fax: Emergency Telephone Number: Hazard (s) Identification Classification of the Chemical Ingredients: Category 0: Non-hazardous/Non-Toxic Category 0: Non-hazardous/Non-Toxic Hazard Statements: May cause minor skin or eye irritation in extremely hypersensitive individuals. Precautionary Statements: Wear protective gloves and eye protection if appropriate. Rinse off exposed extremities after handling. If in eyes, rinse with water for several minutes. If skin or eye irritation persists (extremely rare), get medical attention. Unknown Acute Toxicity: No components of this product cause acute toxicity. NFPA ratings (scale 0-4) Health = 0, Fire = 0, Reactivity = 0 HMIS ratings (scale 0-4) Health = 0, Flammability = 0, Physical Hazard = 0, Personal Protection = 0 Hazards not otherwise classified (HNOC): None known.

38 - 2-3 Composition/Information On Ingredients Mixture of Chemical Ingredients: Mixture of chemicals listed below with non-hazardous additions including water. CAS /Component/% of Mixture: Phosphoric Acid 2-2.5% Sodium Salt % 4 First-aid Measures Inhalation: Not relevant Skin Exposure: Rinse with water. Eye contact: Irrigate eye with running water for several minutes. Ingestion: If nausea occurs consult doctor. 5 Fire-fighting Measures Extinguishing Media: product not flammable. Protective Equipment: product not flammable. Precautions for firefighting: product not flammable. 6 Accidental Release Measures Precautions: none required; product non-hazardous. Protective Equipment: none required but may be preferred by user. Spill Containment/Cleanup Measure: use liquid absorbing material for pickup of product; use squeegee to push spilled product into domestic floor drain if present. 7 Handling & Storage Keep containers tightly sealed in dry environment at standard room temperatures. 8 Exposure Controls/Personal Protection Components with occupational exposure limits: Phosphoric Acid PEL Long-term value: 1 mg/m3 REL: Short-term value: 3 mg/m3 Long-term value: 1 mg/m3 TLV Short-term value:3 mg/m3 Long-term value: 1mg/m3 Protective Measures: Usual precautionary measures for handling of mild nontoxic chemicals should be followed. Avoid excessive contact with skin and eyes. Breathing equipment not required. Protective gloves and eyewear optional.

39 9 Physical & Chemical Properties Appearance: clear liquid. Odor: odorless. No fragrance added. Odor Threshold: not relevant. ph value: 9.4 RTU Melting Point: undetermined. Boiling Point: 100 degrees Centigrade. Flash Point: none. Evaporation Point: not determined. Flammability: non-flammable. Explosive Limits: not relevant. Vapor Pressure/Density: VP is not relevant/density = g/cc3 Relative Density: not determined. Solubility: not determined. Partition Coefficient: not determined. Viscosity: not determined. Solvent Content: Organic solvents: 0.0% Water: 97-98% Chemical Ingredients: 2-3% 10 Stability & Reactivity Chemical stability: stable under normal/standard conditions. Reactivity: no relevant information. Conditions to avoid: no relevant information. Possibility of hazardous reactions: none. Hazardous decomposition: no dangerous reactions known. Incompatible materials: no relevant information. 11 Toxicological Information: Likely Routes of Exposure: minor likelihood of exposure to skin, lungs, eyes Acute Toxicity: none Description of Symptoms of Exposure: mild irritant to skin of hypersensitive individuals; mild irritant to eyes and mucous membranes of hypersensitive individuals. Carcinogenic Effects of Exposure: IARC: none of the ingredients are listed. NTP: none of the ingredients are listed. OSHA: none of the ingredients are listed. 12 Ecological Information Toxicity: no relevant information available. Persistence and degradability: no relevant information available. Bioaccumulative potential: no relevant information available. Mobility in soil: no relevant information available. Other adverse effects: no relevant information available.

40 Other information: no relevant information available Disposal Considerations Waste treatment methods: no relevant treatment methods are applicable. Regional legislation (waste): not applicable. Waste disposal recommendations: recycle empty containers or dispose of with household trash; liquid product can be washed into domestic waste water and/or sewage systems. 14 Transport Information UN number: DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. UN proper shipping name DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. Environmental hazards: not applicable. Special precautions: not applicable. Air transport: not applicable. UN "Model Regulation": product does not contain regulated materials. 15 Regulatory Information Safety, health and environmental regulations/legislation specific to the substance or mixture: SARA: Section 355 and/or Section 313: none of the ingredients are listed. TSCA: all ingredients are listed. California Proposition 65: not applicable. Chemicals known to cause: cancer: none of the ingredients are listed. reproductive toxicity for females; none of the ingredients are listed. developmental toxicity: none of the ingredients are listed. EPA: none of the ingredients are listed. TLV established by ACGIH: none of the ingredients are listed. NIOSH: none of the ingredients are listed. GHS label elements: product is classified and labeled according to the Globally Harmonized System. See Section 2 of this SDS. Precautionary statements: See Section 2 of this SDS. Chemical safety assessment: not been completed since none of the ingredients are considered a health hazard. 16 Other Information This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not however be construed as guaranteeing any specific property of the product. It is the responsibility of the user to determine applicability of this information and the suitability of the product for any particular purpose. Date of preparation: June 2015

41 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev Issue date: June Identification Product Identifier (Trade name): Procyon Plus Powder Recommended Use of Product: Cleaning of carpet and upholstery. Product Description: this product is comprised of inorganic powdered chemicals, therefore does not qualify as a health or environmental hazard. Application of the Product: fabric cleaner Manufacturer/Supplier: Plus Manufacturing Inc 2704 N. Madelia St Spokane, WA US PROCYON ( ) Local: Fax: Emergency Telephone Number: Hazards (s) Identification Classification of the Chemical Ingredients: Category 0: Non-hazardous Category 0: Non-hazardous Hazard Statements: May cause minor skin, eye or lung irritation in extremely hypersensitive individuals. Precautionary Statements: Wear protective gloves, eye protection or filter mask if appropriate. Rinse off exposed extremities after handling. If in eyes, rinse with water for several minutes. If skin or eye irritation persists (extremely rare), get medical attention. Unknown Acute Toxicity: No components of this product cause acute toxicity. NFPA ratings (scale 0-4) Health = 1, Fire = 0, Reactivity = 0 HMIS ratings (scale 0-4) Health = 1, Flammability = 0, Physical Hazard = 0, Personal Protection = 0 Hazards not otherwise classified (HNOC): None known.

42 - 2-3 Composition/Information On Ingredients Mixture of Chemical Ingredients: Mixture of chemicals listed below with non-hazardous additions including water. CAS /Component/% of Mixture: Phosphoric-Acid 22% Sodium Salt 78% 4 First-aid Measures Inhalation: Flush lungs with fresh air via deep breaths and controlled coughing. Skin Exposure: Rinse with water. Eye contact: Irrigate eye with running water for several minutes. Ingestion: If nausea occurs consult doctor. 5 Fire-fighting Measures Extinguishing Media: product not flammable. Protective Equipment: product not flammable. Precautions for firefighting: product not flammable. 6 Accidental Release Measures Precautions: none required; product non-hazardous. Protective Equipment: none required but may be preferred by user. Spill Containment/Cleanup Measure: sweep powder into permissible disposal container. 7 Handling & Storage Keep containers tightly sealed in dry environment at standard room temperatures. 8 Exposure Controls/Personal Protection Components with occupational exposure limits: Phosphoric Acid Anhydrous PEL Long-term value: 1 mg/m3 REL: Short-term value: 3 mg/m3 Long-term value: 1 mg/m3 TLV Short-term value:3 mg/m3 Long-term value: 1mg/m3 Protective Measures: Usual precautionary measures for handling of mild nontoxic chemicals should be followed. Avoid excessive contact with skin and eyes. Breathing equipment not required but facial mask may be preferred in case of accidental spill releasing fine powder particulates into breathing zone. Protective gloves and eyewear optional. 9 Physical & Chemical Properties

43 - 3 - Appearance: dry white granular powder. Odor: odorless. No fragrance added. Odor Threshold: not relevant. ph value: / liquid 9.6. / Dry 8.3 Melting Point: undetermined. Boiling Point: not relevant. Flash Point: none. Evaporation Point: not determined. Flammability: non-flammable. Explosive Limits: not relevant. Vapor Pressure/Density: VP is not relevant/density = g/cc. Relative Density: not determined. Solubility: not determined. Partition Coefficient: not determined. Viscosity: not determined. Solvent Content: Organic solvents: 0.0% Water: 0.0% Chemical Ingredients: 100.0% 10 Stability & Reactivity Chemical stability: stable under normal/standard conditions. Reactivity: no relevant information. Conditions to avoid: no relevant information. Possibility of hazardous reactions: none. Hazardous decomposition: no dangerous reactions known. Incompatible materials: no relevant information. 11 Toxicological Information: Likely Routes of Exposure: minor likelihood of exposure to skin, lungs, eyes Acute Toxicity: none Description of Symptoms of Exposure: mild irritant to skin of hypersensitive individuals; mild irritant to eyes and mucous membranes of hypersensitive individuals. Carcinogenic Effects of Exposure: IARC: none of the ingredients are listed. NTP: none of the ingredients are listed. OSHA: none of the ingredients are listed. 12 Ecological Information Toxicity: no relevant information available. Persistence and degradability: no relevant information available. Bioaccumulative potential: no relevant information available. Mobility in soil: no relevant information available. Other adverse effects: no relevant information available. Other information: no relevant information available.

44 Disposal Considerations Waste treatment methods: no relevant treatment methods are applicable. Regional legislation (waste): not applicable. Waste disposal recommendations: dispose of excess powder in container with household trash. 14 Transport Information UN number: DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. UN proper shipping name DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. Environmental hazards: not applicable. Special precautions: not applicable. Air transport: not applicable. UN "Model Regulation": product does not contain regulated materials. 15 Regulatory Information Safety, health and environmental regulations/legislation specific to the substance or mixture: SARA: Section 355 and/or Section 313: none of the ingredients are listed. TSCA: all ingredients are listed. California Proposition 65: not applicable. Chemicals known to cause: cancer: none of the ingredients are listed. reproductive toxicity for females; none of the ingredients are listed. developmental toxicity: none of the ingredients are listed. EPA: none of the ingredients are listed. TLV established by ACGIH: none of the ingredients are listed. NIOSH: none of the ingredients are listed. GHS label elements: product is classified and labeled according to the Globally Harmonized System. See Section 2 of this SDS. Precautionary statements: See Section 2 of this SDS. Chemical safety assessment: not been completed since none of the ingredients are considered a health hazard. 16 Other Information This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not however be construed as guaranteeing any specific property of the product. It is the responsibility of the user to determine applicability of this information and the suitability of the product for any particular purpose. Date of preparation: June 2015

45 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev Issue date: June Identification Product Identifier (Trade name): Procyon Multi-Purpose Cleaner Concentrate Recommended Use of Product: Cleaning of hard surfaces such as walls, concrete, etc. Product Description: this product is a solution comprised of inorganic chemicals and water, therefore does not qualify as a health or environmental hazard. Application of the Product: hard surface cleaner Manufacturer/Supplier: Plus Manufacturing Inc 2704 N. Madelia St Spokane, WA PROCYON ( ) Local: Fax: Emergency Telephone Number: Hazard (s) Identification Classification of the Chemical Ingredients: Category 0: Non-hazardous/Non-Toxic Category 0: Non-hazardous/Non-Toxic Hazard Statements: May cause minor skin or eye irritation in extremely hypersensitive individuals. Precautionary Statements: Wear protective gloves and eye protection if appropriate. Rinse off exposed extremities after handling. If in eyes, rinse with water for several minutes. If skin or eye irritation persists (extremely rare), get medical attention. Unknown Acute Toxicity: No components of this product cause acute toxicity. NFPA ratings (scale 0-4) Health = 0, Fire = 0, Reactivity = 0 HMIS ratings (scale 0-4) Health = 0, Flammability = 0, Physical Hazard = 0, Personal Protection = 0 Hazards not otherwise classified (HNOC): None known.

46 - 2-3 Composition/Information On Ingredients Mixture of Chemical Ingredients: Mixture of chemicals listed below with non-hazardous additions including water. CAS /Component/% of Mixture: Phosphoric Acid 8-10% Sodium Salt 1-3% 4 First-aid Measures Inhalation: Not relevant Skin Exposure: Rinse with water. Eye contact: Irrigate eye with running water for several minutes. Ingestion: If nausea occurs consult doctor. 5 Fire-fighting Measures Extinguishing Media: product not flammable. Protective Equipment: product not flammable. Precautions for fire fighting: product not flammable. 6 Accidental Release Measures Precautions: none required; product non-hazardous. Protective Equipment: none required but may be preferred by user. Spill Containment/Cleanup Measure: use liquid absorbing material for pickup of product; use squeegee to push spilled product into domestic floor drain if present. 7 Handling & Storage Keep containers tightly sealed in dry environment at standard room temperatures. 8 Exposure Controls/Personal Protection Components with occupational exposure limits: Phosphoric Acid PEL Long-term value: 1 mg/m3 REL: Short-term value: 3 mg/m3 Long-term value: 1 mg/m3 TLV Short-term value:3 mg/m3 Long-term value: 1mg/m3 Protective Measures: Usual precautionary measures for handling of mild nontoxic chemicals should be followed. Avoid excessive contact with skin and eyes. Breathing equipment not required. Protective gloves and eyewear optional.

47 9 Physical & Chemical Properties Appearance: clear liquid. Odor: odorless. No fragrance added. Odor Threshold: not relevant. ph value: 9.3 / RTU 9.0 Melting Point: undetermined. Boiling Point: 100 degrees Centigrade. Flash Point: none. Evaporation Point: not determined. Flammability: non-flammable. Explosive Limits: not relevant. Vapor Pressure/Density: VP is not relevant/density = g/cc3 Relative Density: not determined. Solubility: not determined. Partition Coefficient: not determined. Viscosity: not determined. Solvent Content: Organic solvents: 0.0% Water: 86-90% Chemical Ingredients: 10-14% 10 Stability & Reactivity Chemical stability: stable under normal/standard conditions. Reactivity: no relevant information. Conditions to avoid: no relevant information. Possibility of hazardous reactions: none. Hazardous decomposition: no dangerous reactions known. Incompatible materials: no relevant information. 11 Toxicological Information: Likely Routes of Exposure: minor likelihood of exposure to skin, lungs, eyes Acute Toxicity: none Description of Symptoms of Exposure: mild irritant to skin of hypersensitive individuals; mild irritant to eyes and mucous membranes of hypersensitive individuals. Carcinogenic Effects of Exposure: IARC: none of the ingredients are listed. NTP: none of the ingredients are listed. OSHA: none of the ingredients are listed. 12 Ecological Information Toxicity: no relevant information available. Persistence and degradability: no relevant information available. Bioaccumulative potential: no relevant information available. Mobility in soil: no relevant information available. Other adverse effects: no relevant information available.

48 Other information: no relevant information available Disposal Considerations Waste treatment methods: no relevant treatment methods are applicable. Regional legislation (waste): not applicable. Waste disposal recommendations: recycle empty containers or dispose of with household trash; liquid product can be washed into domestic waste water and/or sewage systems. 14 Transport Information UN number: DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. UN proper shipping name DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. Environmental hazards: not applicable. Special precautions: not applicable. Air transport: not applicable. UN "Model Regulation": product does not contain regulated materials. 15 Regulatory Information Safety, health and environmental regulations/legislation specific to the substance or mixture: SARA: Section 355 and/or Section 313: none of the ingredients are listed. TSCA: all ingredients are listed. California Proposition 65: not applicable. Chemicals known to cause: cancer: none of the ingredients are listed. reproductive toxicity for females; none of the ingredients are listed. developmental toxicity: none of the ingredients are listed. EPA: none of the ingredients are listed. TLV established by ACGIH: none of the ingredients are listed. NIOSH: none of the ingredients are listed. GHS label elements: product is classified and labeled according to the Globally Harmonized System. See Section 2 of this SDS. Precautionary statements: See Section 2 of this SDS. Chemical safety assessment: not been completed since none of the ingredients are considered a health hazard. 16 Other Information This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not however be construed as guaranteeing any specific property of the product. It is the responsibility of the user to determine applicability of this information and the suitability of the product for any particular purpose. Date of preparation: June 2015

49 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev Issue date: June Identification Product Identifier (Trade name): Tile & Grout Cleaner Recommended Use of Product: Cleaning of hard surfaces such as Tile & Grout. Product Description: this product is a solution comprised of inorganic chemicals and water, therefore does not qualify as a health or environmental hazard. Application of the Product: Tile cleaner Manufacturer/Supplier: Plus Manufacturing Inc 2704 N. Madelia St Spokane, WA PROCYON ( ) Local: Fax: Emergency Telephone Number: Hazard (s) Identification Classification of the Chemical Ingredients: Category 0: Non-hazardous/Non-Toxic Category 0: Non-hazardous/Non-Toxic Hazard Statements: May cause minor skin or eye irritation in extremely hypersensitive individuals. Precautionary Statements: Wear protective gloves and eye protection if appropriate. Rinse off exposed extremities after handling. If in eyes, rinse with water for several minutes. If skin or eye irritation persists (extremely rare), get medical attention. Unknown Acute Toxicity: No components of this product cause acute toxicity. NFPA ratings (scale 0-4) Health = 0, Fire = 0, Reactivity = 0 HMIS ratings (scale 0-4) Health = 0, Flammability = 0, Physical Hazard = 0, Personal Protection = 0 Hazards not otherwise classified (HNOC): None known.

50 - 2-3 Composition/Information on Ingredients Mixture of Chemical Ingredients: Mixture of chemicals listed below with non-hazardous additions including water. CAS /Component/% of Mixture: Phosphoric Acid 9-11% Sodium Salt 1-3% Silicic Acid % 4 First-aid Measures Inhalation: Not relevant Skin Exposure: Rinse with water. Eye contact: Irrigate eye with running water for several minutes. Ingestion: If nausea occurs consult doctor. 5 Fire-fighting Measures Extinguishing Media: product not flammable. Protective Equipment: product not flammable. Precautions for firefighting: product not flammable. 6 Accidental Release Measures Precautions: none required; product non-hazardous. Protective Equipment: none required but may be preferred by user. Spill Containment/Cleanup Measure: use liquid absorbing material for pickup of product; use squeegee to push spilled product into domestic floor drain if present. 7 Handling & Storage Keep containers tightly sealed in dry environment at standard room temperatures. 8 Exposure Controls/Personal Protection Components with occupational exposure limits: Phosphoric Acid PEL Long-term value: 1 mg/m3 REL: Short-term value: 3 mg/m3 Long-term value: 1 mg/m3 TLV Short-term value:3 mg/m3 Long-term value: 1mg/m3 Protective Measures: Usual precautionary measures for handling of mild nontoxic chemicals should be followed. Avoid excessive contact with skin and eyes. Breathing equipment not required. Protective gloves and eyewear optional.

51 9 Physical & Chemical Properties Appearance: clear liquid. Odor: odorless. No fragrance added. Odor Threshold: not relevant. ph value: Concentrate 11.0 / RTU 10.7 Melting Point: undetermined. Boiling Point: 100 degrees Centigrade. Flash Point: none. Evaporation Point: not determined. Flammability: non-flammable. Explosive Limits: not relevant. Vapor Pressure/Density: VP is not relevant/density = g/cc Relative Density: not determined. Solubility: not determined. Partition Coefficient: not determined. Viscosity: not determined. Solvent Content: Organic solvents: 0.0% Water: 85-89% Chemical Ingredients: 11-15% 10 Stability & Reactivity Chemical stability: stable under normal/standard conditions. Reactivity: no relevant information. Conditions to avoid: no relevant information. Possibility of hazardous reactions: none. Hazardous decomposition: no dangerous reactions known. Incompatible materials: no relevant information. 11 Toxicological Information: Likely Routes of Exposure: minor likelihood of exposure to skin, lungs, eyes Acute Toxicity: none Description of Symptoms of Exposure: mild irritant to skin of hypersensitive individuals; mild irritant to eyes and mucous membranes of hypersensitive individuals. Carcinogenic Effects of Exposure: IARC: none of the ingredients are listed. NTP: none of the ingredients are listed. OSHA: none of the ingredients are listed. 12 Ecological Information Toxicity: no relevant information available. Persistence and degradability: no relevant information available. Bioaccumulative potential: no relevant information available. Mobility in soil: no relevant information available. Other adverse effects: no relevant information available.

52 Other information: no relevant information available Disposal Considerations Waste treatment methods: no relevant treatment methods are applicable. Regional legislation (waste): not applicable. Waste disposal recommendations: recycle empty containers or dispose of with household trash; liquid product can be washed into domestic waste water and/or sewage systems. 14 Transport Information UN number: DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. UN proper shipping name DOT, ADR, ADN, IMDG, IATA: product does not contain regulated materials. Environmental hazards: not applicable. Special precautions: not applicable. Air transport: not applicable. UN "Model Regulation": product does not contain regulated materials. 15 Regulatory Information Safety, health and environmental regulations/legislation specific to the substance or mixture: SARA: Section 355 and/or Section 313: none of the ingredients are listed. TSCA: all ingredients are listed. California Proposition 65: not applicable. Chemicals known to cause: cancer: none of the ingredients are listed. reproductive toxicity for females; none of the ingredients are listed. developmental toxicity: none of the ingredients are listed. EPA: none of the ingredients are listed. TLV established by ACGIH: none of the ingredients are listed. NIOSH: none of the ingredients are listed. GHS label elements: product is classified and labeled according to the Globally Harmonized System. See Section 2 of this SDS. Precautionary statements: See Section 2 of this SDS. Chemical safety assessment: not been completed since none of the ingredients are considered a health hazard. 16 Other Information This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not however be construed as guaranteeing any specific property of the product. It is the responsibility of the user to determine applicability of this information and the suitability of the product for any particular purpose. Date of preparation: June 2015

53 48

54 Carpet Crisis Solutions Blood/Body Fluids Wear gloves. Using proper blood borne pathogen procedures, apply Spot & Stain Remover, let dwell 10 minutes, agitate then blot dry using a bleach-free white cotton towel. Browning Spots Apply Spot & Stain Remover over browning area, let dwell 10 minutes, agitate then blot dry using a bleachfree white cotton towel. Browning Traffic Lane Mix 3 to 4oz of concentrate to 1 gallon HOT water in spray tank, wetbrowning area, bonnet carpet almost dry using Procyon s 100% cotton bonnet. Duct Tape Mix 3 to 4oz of concentrate to 1 gallon HOT water in spray tank. Spray over adhesive area, let dwell 10 minutes, agitate then bonnet carpet using Procyon s 100% cotton bonnet. Floods Extract as much as possible, then bonnet using Procyon s 100% cotton bonnet to dry fibers. If browning occurs follow directions for browning traffic lane problems. Grease Spray Spot & Stain Remover on area, let dwell 10 minutes, agitate then bonnet using Procyon s 100% cotton bonnet. Ink Mix 3 to 4oz of concentrate to 1 gallon HOT water in spray tank. Spray over area and let dwell 10 to 15 minutes. Using a bone scraper agitate area then blot dry using a bleach-free white cotton towel. (Repeat as necessary.) Oil Spray Spot & Stain Remover on area, let dwell 10 minutes, agitate then blot dry using a bleach-free white cotton towel. Paint Mix 3 to 4oz of concentrate to 1 gallon HOT water in spray tank. Spray over area and let dwell 10 to 15 minutes. Using a bone scraper agitate area then blot dry using a bleach-free white cotton towel. (Repeat as necessary.) Road Tar Mix 3 to 4oz of concentrate to 1 gallon 180 HOT water in spray tank. Spray over area and let dwell 10 to 15 minutes, agitate then bonnet using Procyon s 100% cotton bonnet.(heat water with coffee pot if necessary.) 49

55 School Glue Mix 3 to 4oz of concentrate to 1 gallon HOT water in spray tank. Spray over area and let dwell 10 to 15 minutes, agitate then bonnet using Procyon s 100% cotton bonnet. Smoke Damage Mix 3 to 4oz of concentrate to 1 gallon HOT water in spray tank. Spray over area and let dwell 10 to 15 minutes, extract then bonnet using Procyon s 100% cotton bonnet. Water Stains Mix 3 to 4oz of concentrate to 1 gallon HOT water in spray tank. Spray over area and let dwell 10 to 15 minutes, agitate then bonnet using Procyon s 100% cotton bonnet. Food Scrape excess food from carpet with dull object (such as a spoon). Spray Spot & Stain Remover on area and let dwell for 10 minutes, agitate then blot dry using a bleachfree white cotton towel. Coffee Spray Spot & Stain Remover on area agitate then blot dry using a bleach-free white cotton towel. Gum Mix 3 to 4oz of concentrate to 1 gallon HOT water in spray tank. Spray over gum and let dwell 10 minutes, agitate and remove gum, then bonnet using Procyon s 100% cotton bonnet. Juice Spray Spot & Stain Remover on area, let dwell 10 minutes, agitate then blot dry using a bleach-free white cotton towel. Pop Spray Spot & Stain Remover on area, let dwell 10 minutes, agitate then blot dry using a bleach-free white cotton towel. Tea Spray Spot & Stain Remover on area, let dwell 10 minutes, agitate then blot dry using a bleach-free white cotton towel. NOTE: If you do not have access to hot water, you may use a large coffee pot to heat water. CAUTION: Avoid contact with eyes. If spashed in eyes, immediately remove contact lenses and rinse eyes with plenty of water for 20 minutes. Contact a physician if necessary. PROCYON FACTS: Contains nonionic surfactant and water softening agents. Non-Flammable. Contains no detergents, no enzymes, no bleach and no dyes. Using more is NOT better. Use as directed. Committed to Healthier Cleaning Concepts Plus Manufacturing, Inc. PO Box 7288 Spokane, WA (509) PRO-CYON ( ) Fax (509) sales@soapfreeprocyon.com 50

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