MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # 02 Issue date Revision date Supersedes date CAS # ACRAGLAS RELEASE AGENT (60900), 3 oz. Mixture Product code Manufacturer information 2. Hazards Identification BROWNELLS, INC. 200 South Front Street MONTEZUMA, IOWA United States (641) hour Emergency Number, Call Collect: +1(352) Emergency overview OSHA regulatory status Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms Will be easily ignited by heat, spark or flames. Harmful in contact with eyes. Irritating to skin. Prolonged exposure may cause chronic effects. This product is considered hazardous under 29 CFR (Hazard Communication). Inhalation. Ingestion. Skin contact. Eye contact. Contact may irritate or burn eyes. Eye contact may result in corneal injury. Do not get this material in contact with eyes. Irritating to skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Avoid contact with the skin. Avoid breathing dust/fume/gas/mist/vapors/spray. of the product may be absorbed into the body by ingestion. Do not ingest. Eyes. Gastro-intestinal tract. Respiratory system. Skin. Central nervous system. Conjunctiva. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Corneal damage. Narcosis. Decrease in motor functions. Behavioral changes. Conjunctivitis. Defatting of the skin. Skin irritation. Rash. 3. Composition / Information on Ingredients CAS # Percent N-PROPYL ALCOHOL First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Remove and isolate contaminated clothing and shoes. Wash off with warm water and soap. Get medical attention if irritation develops and persists. If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. If ingestion of a large amount does occur, call a poison control center immediately. 1 / 6

2 tes to physician General advice 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Fire fighting equipment/instructions Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Flammable by OSHA criteria. Water. Water spray. Foam. Dry powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire may produce irritating, corrosive and/or toxic gases. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up 7. Handling and Storage Handling Storage 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values N-PROPYL ALCOHOL (CAS ) Keep unnecessary personnel away. Keep upwind. Prevent further leakage or spillage if safe to do so. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Prevent entry into waterways, sewer, basements or confined areas. Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Do not smoke. Do not get this material in contact with eyes. Avoid contact with skin. Do not use in areas without adequate ventilation. Wash thoroughly after handling. Keep away from heat and sources of ignition. Store in cool place. Store in a well-ventilated place. Keep container tightly closed. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. Use care in handling/storage. Type TWA US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Type N-PROPYL ALCOHOL (CAS ) PEL US. NIOSH: Pocket Guide to Chemical Hazards Type N-PROPYL ALCOHOL (CAS ) Engineering controls STEL TWA Value 100 ppm Value 500 mg/m3 200 ppm Value Ensure adequate ventilation, especially in confined areas. 625 mg/m3 250 ppm 500 mg/m3 200 ppm 2 / 6

3 Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations 9. Physical & Chemical Properties Appearance Physical state Form Color Odor Odor threshold ph Vapor pressure Vapor density Boiling point Solubility (water) Do not get in eyes. Chemical goggles are recommended. Avoid contact with the skin. Wear appropriate chemical resistant clothing. Chemical resistant gloves. personal respiratory protective equipment normally required. When using do not smoke. Do not get in eyes. Avoid contact with skin. Keep away from food and drink. Handle in accordance with good industrial hygiene and safety practice. White. Liquid. Liquid. White. Alcohol hpa estimated 207 F (97.22 C) Specific gravity Relative density Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature VOC Other data Flammability class F (34.44 C) 13.5 % estimated 2.1 % estimated 775 F ( C) estimated 45 % estimated Flammable IC estimated 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Risk of ignition. Heat, flames and sparks. Strong oxidizing agents. hazardous decomposition products are known. Hazardous polymerization does not occur. 11. Toxicological Information Toxicological data Product ACRAGLAS RELEASE AGENT (60900), 3 oz. (CAS Mixture) Acute Oral LD50 Mouse Rabbit Rat mg/kg g/kg g/kg 3 / 6

4 Acute Oral LD50 Mouse Rabbit Rat 6800 mg/kg 2.8 g/kg 1.87 g/kg Local effects Chronic effects Carcinogenicity ACGIH Carcinogens Further information 12. Ecological Information Ecotoxicological data Product of the product may be absorbed into the body through the skin. Irritating to skin. Contact may irritate or burn eyes. Hazardous by OSHA criteria. Repeated absorption may cause disorder of central nervous system, liver, kidneys and blood. Prolonged exposure may cause chronic effects. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Symptoms may be delayed. ACRAGLAS RELEASE AGENT (60900), 3 oz. (CAS Mixture) Crustacea Fish Aquatic Crustacea Fish Ecotoxicity Environmental effects Persistence and degradability EC50 LC50 LC50 LC50 Bioaccumulation / Accumulation Daphnia Fish Water flea (Daphnia magna) A4 t classifiable as a human carcinogen. Fathead minnow (Pimephales promelas) 9198 mg/l, 48 hours 9133 mg/l, 96 hours 6300 mg/l, 48 hours 4450 mg/l, 24 hours mg/l, 24 hours 5000 mg/l, 48 hours mg/l, 96 hours Contains a substance which causes risk of hazardous effects to the environment. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Bioaccumulative potential Octanol/water partition coefficient log Kow N-PROPYL ALCOHOL 0.25 Partition coefficient N-PROPYL ALCOHOL Disposal Considerations Disposal instructions 14. Transport Information Dispose of in accordance with current, applicable local, state, and federal regulations. DOT Basic shipping requirements: UN number UN1987 Proper shipping name Alcohol solution, n.o.s. (N-PROPYL ALCOHOL RQ = 222 LBS) Hazard class 3 Packing group III 4 / 6

5 IATA UN number UN proper shipping name Transport hazard class(es) Packing group IMDG UN number UN proper shipping name Transport hazard class(es) Packing group DOT UN1987 Alcohol solution, n.o.s (N-PROPYL ALCOHOL) 3 III UN1987 Alcohol solution, n.o.s. (N-PROPYL ALCOHOL) 3 III IATA; IMDG 15. Regulatory Information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. CERCLA/SARA Hazardous Substances - t applicable. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR (b) and (f)(2) and Chemical Code Number t listed. Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR (c)) t regulated. DEA Exempt Chemical Mixtures Code Number t regulated. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. CERCLA (Superfund) reportable quantity N-PROPYL ALCOHOL: 100 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 302 Extremely hazardous substance Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - 5 / 6

6 SARA 311/312 Hazardous chemical Inventory status Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations US - New Jersey RTK - Substances: Listed substance US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK 16. Other Information Further information HMIS ratings Health: 1* Flammability: 3 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 3 Instability: 0 Disclaimer This data sheet contains changes from the previous version in section(s): This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Listed. Listed. HMIS is a registered trade and service mark of the NPCA. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Fire Fighting Measures: Flammable properties Fire Fighting Measures: Specific methods Physical & Chemical Properties: Multiple Properties Toxicological Information: Epidemiology Toxicological Information: Neurological effects Disposal Considerations: Disposal instructions Other Information: Disclaimer 6 / 6