1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product name : Stearic acid
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1 SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Version 4.0 Revision Date Print Date GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product name : Stearic acid Product Number : Brand : Sigma-Aldrich Company : Sigma-Aldrich (M) Sdn. Bhd. A-07-11, Empire Office, Empire Subang Jalan SS16/1, SS SUBANG JAYA-SELANGOR DARUL EHSAN MALAYSIA Telephone : +60 (603) Fax : +60 (603) Emergency Phone # : 2. HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Skin irritation (Category 2) According to European Directive 67/548/EEC as amended. Label elements Pictogram Signal word Hazard statement(s) H315 Precautionary statement(s) Hazard symbol(s) Xi R-phrase(s) R38 S-phrase(s) Other hazards - none Warning Causes skin irritation. none Irritant none 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms : Octadecanoic acid Formula : C 18 H 36 O 2 Molecular Weight : 284,48 g/mol CAS-No. EC-No. Index-No. Classification Concentration Sigma-Aldrich Page 1 of 5
2 Stearic acid Skin Irrit. 2; H315 Xi, R38 For the full text of the H-Statements mentioned in this Section, see Section FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. Conditions for safe storage Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Sigma-Aldrich Page 2 of 5
3 Eye protection Safety glasses with side-shields conforming to EN166 Skin and body protection Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Safety data ph Melting point Boiling point Flash point Ignition temperature Lower explosion limit Upper explosion limit solid C - lit. 361 C - lit. 113 C - closed cup Vapour pressure 1 hpa at 173,7 C Density Water solubility 0,845 g/cm3 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid Materials to avoid Bases, Oxidizing agents, Reducing agents Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides 11. TOXICOLOGICAL INFORMATION Acute toxicity LD50 Oral - rat - > mg/kg LD50 Dermal - rabbit - > mg/kg Skin corrosion/irritation Skin - rabbit - Skin irritation - 24 h - Draize Test Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Sigma-Aldrich Page 3 of 5
4 Carcinogenicity Carcinogenicity - mouse - Implant Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Kidney, Ureter, Bladder:Tumors. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. Causes skin irritation. May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: WI ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil PBT and vpvb assessment Other adverse effects 13. DISPOSAL CONSIDERATIONS Product Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION ADR/RID Sigma-Aldrich Page 4 of 5
5 IMDG IATA 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/ OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 H315 Skin Irrit. Xi R38 Causes skin irritation. Skin irritation Irritant Further information Copyright 2010 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Co., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Sigma-Aldrich Page 5 of 5
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