MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification. 2. Hazards Identification
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1 MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name UPC Code Formula Number Product use Distributed by CLEARASIL DailyClear Daily Pore Cleansing Pads CLEARASIL DailyClear Daily Pore Cleansing Pads - 90 ct Cleanser Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway PO Box 225 Parsippany, NJ In Case of Emergency: Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: Outside North America: Emergency overview 2 Hazards Identification This product is regulated by the US FDA as an over-the-counter, monograph drug Warnings: For external use only Flammable until dry, keep away from extreme heat or open flame When using this product: Use with other topical acne medications, at the same time or immediately following use of this product, may increase dryness or irritation of the skin If this occurs, only one acne medication should be used unless directed by your doctor Avoid contact with the eyes Stop use and ask a doctor if skin irritation occurs In case of accidental ingestion, get medical help or contact a Poison Control Center immediately Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status Potential environmental effects KEEP OUT OF REACH OF CHILDREN Eye, Skin contact, Inhalation, Ingestion Avoid contact with eyes May cause eye irritation upon direct contact with eyes Prolonged skin contact may cause skin irritation Not expected to be a skin sensitizer There are no hazards associated with this product in normal use Ingestion may cause gastrointestinal irritation Eyes Skin The finished product is not expected to have chronic health effects Symptoms may include redness, edema, drying, defatting and cracking of the skin This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333 Components of this product have been identified as having potential environmental concerns 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent Poly(oxy-1,2-ethanediyl), alpha-isohexadecyl-omega-hydroxy First aid procedures Eye contact 4 First Aid Measures If product gets into the eyes, rinse thoroughly with water Stop use and ask a doctor if eye irritation develops #18222 Page 1 of 7 Issue date 22-Nov-2010
2 Skin contact Inhalation Ingestion Notes to physician General advice Stop use and ask a doctor if skin irritation develops Remove to fresh air In case of accidental ingestion, get medical help or contact a Poison Control Center immediately Treat patient symptomatically If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Flammable by OSHA criteria Dry chemical Foam Carbon dioxide Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Prevent entry into waterways, sewers, basements or confined areas Pick up and discard towel Handling Storage 7 Handling and Storage For external use only Avoid contact with eyes, lips and mouth When using do not eat or drink Keep out of reach of children Store in a cool, dry, well-ventilated place Keep away from heat, open flames or other sources of ignition #18222 Page 2 of 7 Issue date 22-Nov-2010
3 Exposure limits Ingredient(s) 8 Exposure Controls / Personal Protection Exposure Limits ACGIH-TLV TWA: 1000 ppm STEL: 1000 ppm OSHA-PEL TWA: 1000 ppm Poly(oxy-1,2-ethanediyl), alpha-isohexadecyl-omega-hydroxy ACGIH-TLV OSHA-PEL Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection ACGIH-TLV OSHA-PEL Not normally required if good ventilation is maintained Not normally required under normal use conditions When handling in large quantities or responding to emergency situations, the use of appropriate eye protection is recommended Not required When handling in large quantities or responding to emergency situations, the use of appropriate eye protection is recommended No special requirements under normal use conditions Not normally required under normal use conditions General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact 9 Physical and Chemical Properties Appearance Liquid on pad Color Clear, colorless liquid on pad Form Liquid saturated on pad Odor Clean Fresh Odor threshold Physical state Solid ph 4-5 Melting point Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity 8780 F (31 C) (Liquid) G/mL #18222 Page 3 of 7 Issue date 22-Nov-2010
4 Octanol/water coefficient Solubility (H2O) VOC (Weight %) Viscosity Percent volatile 10 Stability and Reactivity Reactivity Reacts vigorously with acids Possibility of hazardous reactions Hazardous polymerization does not occur Chemical stability Stable under recommended storage conditions Conditions to avoid Do not mix with other chemicals Incompatible materials Caustics Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Component analysis - LC50 Ingredient(s) 11 Toxicological Information LC50 Poly(oxy-1,2-ethanediyl), alpha-isohexadecyl-omega-hydroxy Component analysis - Oral LD50 Ingredient(s) ppm rat LD50 Poly(oxy-1,2-ethanediyl), alpha-isohexadecyl-omega-hydroxy Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects Carcinogenicity 3450 mg/kg mouse; 7060 mg/kg rat 891 mg/kg rat; 400 mg/kg cat; 480 mg/kg mouse Avoid contact with eyes May cause eye irritation upon direct contact with eyes Prolonged skin contact may cause skin irritation Not expected to be a skin sensitizer There are no hazards associated with this product in normal use Ingestion may cause gastrointestinal irritation The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects ACGIH - Threshold Limit Values - Carcinogens A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans Mutagenicity The finished product is not expected to have chronic health effects Reproductive effects The finished product is not expected to have chronic health effects Teratogenicity The finished product is not expected to have chronic health effects Name of Toxicologically Synergistic Products #18222 Page 4 of 7 Issue date 22-Nov-2010
5 12 Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Fish - Acute Toxicity Data Hr LC50 Oncorhynchus mykiss: ml/l [static]; 96 Hr LC50 Pimephales promelas: >100 mg/l [static]; 96 Hr LC50 Pimephales promelas: mg/l [flow-through] 48 Hr LC50 Leuciscus idus: 90 mg/l [static] Ecotoxicity - Water Flea - Acute Toxicity Data Hr LC50 Daphnia magna: mg/l; 24 Hr EC50 Daphnia magna: mg/l; 48 Hr EC50 Daphnia magna: 2 mg/l [Static] Hr EC50 Daphnia magna: 105 mg/l; 48 Hr EC50 Daphnia magna: 870 mg/l [Static] Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information 13 Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Review federal, state/provincial, and local government requirements prior to disposal Discard with solid waste 14 Transport Information US Department of Transportation (DOT) UN 1170, Solution, Class 3, PG III Limited Quantity Re-classed as Consumer Commodity ORM-D Transportation of Dangerous Goods (TDG - Canada) UN 1170, Solution, Class 3 PG III Limited Quantity Re-classed as Consumer Commodity / Limited Quantity #18222 Page 5 of 7 Issue date 22-Nov-2010
6 IMDG (Marine Transport) UN 1170, Solution, Class 3 PG III Limited Quantity (F/P 31 C) IATA/ICAO (Air) UN 1170, Solution, Class 3 PG III Consumer Commodity, ID 8000 if acceptable to air carrier 15 Regulatory Information Occupational Safety and Health Administration (OSHA) 29 CFR hazardous chemical US Federal regulations Yes This acne product is in compliance with Title 21 of the Code of Federal Regulations, Part 207 and meets the regulatory requirements outlined in the OTC Monograph under 21 CFR Part 333 Product Registration: NDC Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No No Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) #18222 Page 6 of 7 Issue date 22-Nov-2010
7 State regulations See below US - Massachusetts - Right To Know List Teratogen US - Minnesota - Hazardous Substance List Present US - New Jersey - Right to Know Hazardous Substance List sn 0844 US - Pennsylvania - RTK (Right to Know) List Present US - Rhode Island - Hazardous Substance List Toxic; Flammable Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) LEGEND HMIS/NFPA Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 Disclaimer 16 Other Information Health / 1 Flammability 3 Physical Hazard 0 Personal Protection This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist 22-Nov-2010 Issue date Effective date 15-Nov-2010 Prepared by Reckitt Benckiser Regulatory Department Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #18222 Page 7 of 7 Issue date 22-Nov-2010
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