MSDS. SECTION 1 Chemical Product and Company Identification. SECTION 2 Hazard Identification. SECTION 3 Composition, Information or Ingredients

Transcription

1 Cream Hardener.doc Print Date: 1/8/2009 Page 1 of 5 MSDS SECTION 1 Chemical Product and Company Identification CATALYST SYSTEMS U S Chemical & Plastics Alco Industries Companies PO Box 88 CHEMTREC: Zimmerman Rd SE CANUTEC: Gnadenhutten, OH (For Canada call collect) PH: PRODUCT NAME: CREAM HARDENER PRODUCT CODE: 27640/White, 27641/Red, 27642/Green, 27643/Blue, 28050/Black, 28070/Lt. Red Additional Product Codes on Page 5. SYNONYM/CROSS REFERENCE: Polyester Cream Hardener/Polyester Catalyst, Benzoyl Peroxide Paste SCHEDULE B NUMBER: SECTION 2 Hazard Identification OVEREXPOSURE EFFECTS ACUTE EFFECTS: EYES: Contact with eyes can cause irritation, redness, tearing, blurred vision, and/or swelling. SKIN: Contact with skin can cause irritation, (minor itching, burning, and/or redness), dermatitis, defatting may be readily absorbed through the skin. INHALATION: Inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness, fatigue, nausea, headache, possible unconsciousness, and/or asphyxiation. Aspiration of material into lungs may result in chemical pneumonitis which can be fatal. INGESTION: Ingestion can cause gastro-intestinal irritation, nausea, vomiting, diarrhea. PRIMARY ROUTES OF EXPOSURE: Skin, inhalation SECTION 3 Composition, Information or Ingredients INGREDIENTS WGT% CAS # Benzoyl Peroxide SECTION 4 First Aid Measures INHALATION: If inhaled, remove victim from exposure to a well-ventilated area. Make them comfortably warm, but not hot. Use oxygen or artificial respiration as required. Consult a physician. SKIN: For skin contact, wash promptly with soap and excess water. EYES: For eye contact, flush promptly with excess water for at least fifteen minutes. Consult a physician. INGESTION: If ingested, do not induce vomiting. Give victim a glass of water. Call a physician immediately. SECTION 5 Fire-Fighting Measures FIRE EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, foam SPECIAL FIRE FIGHTING PROCEDURES: Fight like a fuel oil fire. Cool fire exposed containers with water spray. Firefighter should wear OSHA/NIOSH approved self-contained breathing apparatus.

2 MSDS UNUSUAL FIRE AND EXPLOSION HAZARD: Closed containers exposed to high temperatures, such as fire conditions may rupture. SECTION 6 Accidental Release Measures SPILLS, LEAK OR RELEASE: Ventilate area. Remove all possible sources of ignition. Avoid prolonged breathing of vapor. Contain spill with inert absorbent. SECTION 7 Handling and Storage STORAGE AND HANDLING: Use with adequate ventilation. Avoid contact with eyes and skin. Avoid breathing vapors. Do not store the product above 100 F/38 C. Do not flame, cut, braze weld or melt empty containers. Keep the product away from heat, open flame, and other sources of ignition. Avoid contact with strong acids, alkalis, and oxidizers. SECTION 8 Exposure Controls and Personal Protection INGREDIENTS CAS # TLV/PEL Benzoyl Peroxide Combustible when dry: TLV 5 mg/m 3 * *Refer to 29 CFR , subpart Z. Also see TLV for Chemical Substances and Physical Agents in the Work Environment (ACGIH). RESPIRATORY PROTECTION: If component TLV limits are exceeded, use NIOSH/MSHA approved respirator to remove vapors. Use an air-supplied respirator if necessary. VENTILATION: Use adequate ventilation in volume and pattern to keep TLV/PEL below recommended levels. Explosion-proof ventilation may be necessary. PROTECTIVE GLOVES: To prevent prolonged exposure use rubber gloves; solvents may be absorbed through the skin. EYE PROTECTION: Safety Glasses or goggles with splash guards or side shields. OTHER PROTECTIVE EQUIPMENT: Wear protective clothing as required to prevent skin contact. SECTION 9 Physical and Chemical Properties APPEARANCE: Red, white, blue, green, or light red paste SPECIFIC GRAVITY: 1.20 VAPOR PRESSURE (mmhg): N/E BOILING POINT: Decomposes VAPOR DENSITY: (Air=1) >1 EVAPORATION RATE (Ethyl Ether = 1): <1 VOLATILES BY WEIGHT: 10-20% SOLUBILITY IN WATER: Insoluble FLASH POINT: 184 F/84 C LOWER FLAMMABLE LIMIT %: N/E UPPER FLAMMABLE LIMIT %: N/E VOC: Grams/Liter = Nil Lbs/Gallon = Nil Cream Hardener.doc Print Date: 1/8/2009 Page 2 of 5

3 MSDS SECTION 10 Stability and Reactivity STABILITY: Stable CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge. INCOMPATIBILITY MATERIALS TO AVOID: Strong acids, alkalis, oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide, and Carbon. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Toxicological Information CHRONIC EFFECTS: Overexposure to this material has apparently been known to cause the following effects in lab animals: skin damage and tumors. CARCINOGEN: YES NO X TERATOGEN: YES NO X MUTAGEN: YES NO X Benzoyl Peroxide has caused tumorogenic effects in laboratory animals. SECTION 12 Ecological Information None. SECTION 13 Disposal Considerations WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations. SECTION 14 Transport Information For Ground Transport: In USA In inner containers less than 500 grams each: Consumer Commodity ORM-D. In large containers, UN3108, Organic Peroxide Type E, Solid ( 52% Dibenzoyl Peroxide as a paste), 5.2, PG II. For Air Transport: Must be re-boxed to UN specified packaging. UN3108, Organic Peroxide Type E, Solid ( 52% Dibenzoyl Peroxide as a paste), 5.2, Packaging Instruction 510 or 513. For Ocean Transport: UN3108, Organic Peroxide Type E, Solid, 5.2, EMS#F-J, S-R (the activator is 52% Dibenzoyl Peroxide as a paste). Limited quantity if inner containers are less than 500 grams each. SECTION 15 Regulatory Information CALIFORNIA PROPOSITION 65: This product does not contain chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm. SECTION 313 SUPPLIER NOTIFICATION: Cream Hardener.doc Print Date: 1/8/2009 Page 3 of 5

4 MSDS This product contains the following toxic chemicals subject to the reporting requirements of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR 372: CHEMICAL NAME CAS % BY WGT Benzoyl Peroxide % This information must be included in all MSDS that are copied and distributed for this chemical. SECTION 16 Other Information HMIS RATING: Health 2 4 = Extreme Fire 2 3 = High Reactivity 2 2 = Moderate 1 = Slight 0 = Insignificant Personal Protection - See Section VIII NOTE: ADDITIONAL PART NUMBERS: Bulk Red , 27027, 27110, 27120, 27121, 27125, 27169, 27170, 27172, 27173, 27174, 27607, 27604, 27607, 27610, 27616, 27626, 27632, 27644, 27649, 27663, 27673, 27690, , 27697, 27750, 27751, 28015, 28016, 28028, 28139, 28144, 28149, 28164, Bulk Lt. Red/Red Raspberry , 27034, 27111, 27128, 27171, 27633, 27656, 28071, 28143, 28148, Bulk Light Blue , Bulk Blue , 27022, 27041, 27112, 27115, 27122, 27160, 27619, 27622, 27628, 27634, 27646, 27665, 27675, 27676, 27677, 27678, 27679, 28029, 28030, 28136, 28141, 28146, 28151, 28156, 28159, 28163, 28165, Bulk White , 27024, 27036, 27038, 27114, 27124, 27132, 27168, 27201, 27211, 27621, 27627, 27647, 27648, 27664, 27674, 28025, 28031, 28042, 28043, 28059, 28145, 28150, 28171, 28184, Bulk Black , 27035, 27037, 27624, 27669, 28032, 28052, 28183, Bulk Green , 28038, Bulk Yellow , ABBREVIATIONS IARC = International Agency for Research on Cancer ACGIH = American Conference of Governmental Industrial Hygienists NIOSH = National Institute of Occupational Safety and Health TLV = Threshold Limit Value PEL = Permissible Emission Level DOT = Department of Transportation Cream Hardener.doc Print Date: 1/8/2009 Page 4 of 5

5 NTP N/AV N/AP N/E N/D = National Toxicology Program = Not Available = Not Applicable = Not Established = Not Determined MSDS PREPARED BY: CATALYST SYSTEMS U S Chemical & Plastics Alco Industries Companies PO Box Zimmerman Rd SE Gnadenhutten, OH PH: DATE REVIEWED: January 8, 2009 DATE REVISED: January 8, 2009 REVISION: Section 14 The information in the Material Safety Data Sheet has been compiled from our experience and from data presented in various technical publications. It is the user s responsibility to determine the suitability of this information for the adoption of the safety precautions as may be necessary. We reserve the right to revise Material Safety Data Sheets from time to time as new technical information becomes available. The user has the responsibility to contact the Company to make sure that the MSDS is the latest one issued. Cream Hardener.doc Print Date: 1/8/2009 Page 5 of 5

6 MSDS SECTION 1 Chemical Product and Company Identification U S CHEMICAL & PLASTICS For Chemical Emergency: An Alco Industries Company CHEMTREC: Nova Drive SE Massillon, OH PH FAX PRODUCT NAME: Easy White Tack Free PRODUCT CODE: (10005), 10010, 10020, 10030, 10055, SYNONYM/CROSS REFERENCE: Polyester Paste SCHEDULE B NUMBER: SECTION 2 Hazard Identification OVEREXPOSURE EFFECTS: ACUTE EFFECTS: EYES: Contact with eyes can cause irritation, redness, tearing, blurred vision, and/or swelling. SKIN: Contact with skin can cause irritation, (minor itching, burning and/or redness), Dermatitis, defatting may be readily absorbed through the skin. INHALATION: Inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness, fatigue, nausea, headache, possible unconsciousness and/or asphyxiation. Aspiration of material into lungs may result in chemical pneumonitis which can be fatal. INGESTION: Ingestion can cause gastrointestinal irritation, nausea, vomiting, diarrhea. PRIMARY ROUTES OF EXPOSURE: skin, inhalation, eyes SECTION 3 Composition, Information or Ingredients INGREDIENTS WGT% CAS # Styrene 15-20% Non-Fibrous Talc 40-50% Calcium Carbonate 10-20% , SECTION 4 First Aid Measures INHALATION: If inhaled, remove victim from exposure to a well-ventilated area. Make them comfortably warm, but not hot. Use oxygen or artificial respiration as required. Consult a physician. SKIN: For skin contact, wash promptly with soap and excess water. EYES: For eye contact, flush promptly with excess water for at least fifteen minutes. Consult a physician. INGESTION: If ingested, do not induce vomiting. Give victim a glass of water. Call a physician immediately. Easy White Tack Free doc Print Date: 5/31/2011 Page 1 of 5

7 MSDS SECTION 5 Fire-Fighting Measures FIRE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Fight like a fuel oil fire. Cool fire exposed containers with water spray. Firefighter should wear OSHA/NIOSH approved self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: Closed containers exposed to high temperatures, such as fire conditions may rupture. SECTION 6 Accidental Release Measures SPILLS, LEAK OR RELEASE: Ventilate area. Remove all possible sources of ignition. Avoid prolonged breathing of vapor. Contain spill with inert absorbent. SECTION 7 Handling and Storage STORAGE AND HANDLING: Use with adequate ventilation. Avoid contact with eyes and skin. Avoid breathing vapors. Do not store the product above 100 F/38 C. Do not flame, cut, braze weld or melt empty containers. Keep the product away from heat, open flame, and other sources of ignition. Avoid contact with strong acids, alkalis, and oxidizers. SECTION 8 Exposure Controls and Personal Protection RESPIRATORY PROTECTION: If component TLV limits are exceeded, use NIOSH/MSHA approved respirator to remove vapors. Use an air-supplied respirator if necessary. VENTILATION: Use adequate ventilation in volume and pattern to keep TLV/PEL below recommended levels. Explosion-proof ventilation may be necessary. PROTECTIVE GLOVES: To prevent prolonged exposure use rubber gloves; solvents may be absorbed through the skin. EYE PROTECTION: Safety Glasses or goggles with splash guards or side shields. OTHER PROTECTIVE EQUIPMENT: Wear protective clothing as required to prevent skin contact. INGREDIENTS CAS # TLV/PEL Styrene ACGIH TLV 20 ppm STEL 40 ppm OSHA PEL 100 ppm CPEL 200 ppm Non-Fibrous Talc ACGIH TWA 2 mg/m 3 OSHA TLV 20 mppcf Calcium Carbonate ACGIH TWA 10 mg/m Easy White Tack Free doc Print Date: 5/31/2011 Page 2 of 5

8 MSDS SECTION 9 Physical and Chemical Properties APPEARANCE: Smooth paste SPECIFIC GRAVITY: 1.73 FLASH POINT: 93 F/34 C Seta Flash Closed cup LOWER FLAMMABLE LIMIT %: N/E UPPER FLAMMABLE LIMIT %: N/E VAPOR PRESSURE (mmhg): Heavier than air BOILING POINT: N/Av VAPOR DENSITY: Heavier than air EVAPORATION RATE (Ethyl Ether = 1): Slower than Ethyl Ether VOLATILES BY WEIGHT: 15-20% SOLUBILITY IN WATER: None VOC: Grams/Litre = less exempts 249 loss upon curing 0.9 g/l SECTION 10 Stability and Reactivity STABILITY: Stable CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge. INCOMPATIBILITY MATERIALS TO AVOID: Strong acids, alkalis, oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide, and Carbon. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 Toxicological Information CHRONIC EFFECTS: Overexposure to this material has apparently been known to cause the following effects in lab animals: Eye, skin, lung, and central nervous system damage. CARCINOGEN: YES NO X TERATOGEN: YES NO X MUTAGEN: YES NO X STYRENE CARCINOGENICITY Styrene is listed by IARC to be a possible carcinogen. Styrene studies have shown that Styrene causes cancer in certain laboratory animals. However, there is insufficient evidence to conclude that Styrene is a human carcinogen. SECTION 12 Ecological Information N/E SECTION 13 Disposal Considerations WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations. Easy White Tack Free doc Print Date: 5/31/2011 Page 3 of 5

9 MSDS SECTION 14 Transport Information For Ground Transport: In USA Consumer Commodity ORM-D or Limited Quantity For Air Transport: Must be re-boxed to UN specified packaging in quantities of no more than 5 kg per fiberboard box UN3269, Polyester Resin Kit, 3, PGIII Packing Instruction 370 For Ocean Transport: UN3269, Polyester Resin Kit, 3, PGIII, F/P 34 C EMS # F-E, S-D, in limited quantity SECTION 15 Regulatory Information CALIFORNIA PROPOSITION 65: Trace amounts of some chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm may be present in this product. SECTION 313 SUPPLIER NOTIFICATION: This product contains the following toxic chemicals subject to the reporting requirements of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR 372: CHEMICAL NAME CAS % BY WGT Styrene % This information must be included in all MSDS that are copied and distributed for this chemical. SECTION 16 Other Information HMIS RATING: Health 2 4 = Extreme Fire 3 3 = High Reactivity 1 2 = Moderate 1 = Slight 0 = Insignificant Personal Protection - See Section VIII Easy White Tack Free doc Print Date: 5/31/2011 Page 4 of 5

10 MSDS ABBREVIATIONS IARC = International Agency for Research on Cancer ACGIH = American Conference of Governmental Industrial Hygienists NIOSH = National Institute of Occupational Safety and Health TLV = Threshold Limit Value PEL = Permissible Emission Level DOT = Department of Transportation NTP = National Toxicology Program N/AV = Not Available N/AP = Not Applicable N/E = Not Established N/D = Not Determined PREPARED BY: U S CHEMICAL & PLASTICS An Alco Industries Company 600 NOVA DRIVE SE MASSILLON, OH TELEPHONE NBR: FAX NBR: DATE REVIEWED: January 28, 2011 DATE REVISED: May 17, 2011 REVISION: Section 14 The information in the Material Safety Data Sheet has been compiled from our experience and from data presented in various technical publications. It is the user s responsibility to determine the suitability of this information for the adoption of the safety precautions as may be necessary. We reserve the right to revise Material Safety Data Sheets from time to time as new technical information becomes available. The user has the responsibility to contact the Company to make sure that the MSDS is the latest one issued. Easy White Tack Free doc Print Date: 5/31/2011 Page 5 of 5

11 RZ Issued to : Multi-Tech Products Corp Cherry Street Murrieta CA Attention: : Material Safety Data Sheet Coordinator The attached Material Safety Data Sheet relates potential hazards and recommended practices for safe handling of the product. We urge you and your employees to review the entire MSDS prior to handling, use or disposal of the product. You are required to keep this MSDS on file for reference by company employees or government regulatory officials. If you resell or distribute this product, you must furnish a copy of the MSDS to your customer. SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION CHEMICAL PRODUCT IDENTIFICATION: PRODUCT CODE.... : PRODUCT NAME... : PORCELAIN ENAMEL REPAIR SPRAY PLUMBING WHITE PRODUCT CLASS... : Aerosol Product MSDS PREPARATION DATE : 11/30/2010 MANUFACTURER IDENTIFICATION: RAABE COMPANY PO BOX 1090 CUSTOMER IDENTIFICATION: Multi-Tech Products Corp Cherry Street MENOMONEE FALLS WI Murrieta CA EMERGENCY TELEPHONE NUMBERS: 24 HOURS A DAY - CALL CHEMTREC : INTERNATIONAL CALLS TO CHEMTREC : AM TO 4:30 PM CENTRAL TIME : SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS 1 ETHYLBENZENE CAS# ETHYLBENZENE PCT BY WT:.4300 VAPOR PRESSURE: F LEL ppm ACGIH TLV-STEL 125 ppm 100 ppm OSHA PEL-STEL 125 ppm OTHER IARC (2B), CALIFORNIA PROP 65 (Cancer 6/11/2004) LD50(ORAL) 3500 mg/kg (rat) LD50(DERMAL) mg/kg (rabbit) LC mg/m3 (rat) PROP 65-Cancer,listed 6/11/04 EINECS PENTANONE CAS# PENTANONE PCT BY WT: LEL 1.50 Page 1

12 RZ ppm ACGIH TLV-STEL 250 ppm 200 ppm COMPANY 3 N-BUTANE CAS# N-BUTANE PCT BY WT: VAPOR PRESSURE: F LEL ppm ACGIH TLV-STEL NO INFO 800 ppm COMPANY LD50(ORAL) N.A. LD50(DERMAL) N.A. LC mg/m3 (rat) EINECS PROPANE CAS# PROPANE PCT BY WT: VAPOR PRESSURE: F LEL ppm ACGIH TLV-STEL NO INFORMATION LD50(ORAL) NOT APPLICABLE LD50(DERMAL) NOT APPLICABLE LC50 NO INFORMATION EINECS TITANIUM DIOXIDE CAS# TITANIUM DIOXIDE PCT BY WT: mg/m3 ACGIH TLV-STEL NO INFO 10 mg/m3 COMPANY LD50(ORAL) > mg/kg (rat) LC50 > 6820 mg/m3 (rat) EINECS XYLENE CAS# XYLENE PCT BY WT: VAPOR PRESSURE: F LEL ppm ACGIH TLV-STEL 150 ppm 100 ppm OSHA PEL-STEL 150 ppm COMPANY LD50(ORAL) 4300 mg/kg (rat) LD50(DERMAL) 1700 mg/kg (rabbit) LC mg/m3 (rat) EINECS ACRYLIC POLYMER CAS# Poly(Methyl Methacrylate/n-Butyl Methacrylate/Methacrylic Acid) PCT BY WT: ACGIH TLV-STEL COMPANY Page 2

13 RZ BUTYL BENZYL PHTHALATE CAS# BUTYL BENZYL PHTHALATE PCT BY WT: LEL.30 5 mg/m3 ACGIH TLV-STEL 5 mg/m3 OTHER CALIFORNIA PROP 65-Developmental(listed 12/2/05) EINECS ACETONE CAS# ACETONE PCT BY WT: VAPOR PRESSURE: F LEL ppm ACGIH TLV-STEL 1000 ppm 750 ppm OSHA PEL-STEL 1000 ppm COMPANY LD50(ORAL) 5340 mg/kg (rabbit) LD50(DERMAL) mg/kg (rabbit) LC mg/m3 (rat) EINECS ETHYLENE GLYCOL MONOPROPYL ETH CAS# ETHYLENE GLYCOL MONOPROPYL ETHER PCT BY WT: VAPOR PRESSURE: F LEL 1.30 NO INFO ACGIH TLV-STEL NO INFO 11 ETHYL 3-ETHOXYPROPIONATE CAS# ETHYL 3-ETHOXYPROPIONATE PCT BY WT: VAPOR PRESSURE: F LEL ppm ACGIH TLV-STEL NONE EST. 50 ppm COMPANY EINECS GLYCOL ETHER PM ACETATE CAS# PROPYLENE GLYCOL METHYL ETHER ACETATE PCT BY WT: VAPOR PRESSURE: F LEL 1.30 NOT ESTABLISHED ACGIH TLV-STEL NOT ESTABLISHED LD50(ORAL) 8500 mg/kg (rat) LD50(DERMAL) 5000 mg/kg (rat) LC mg/m3 (rat) EINECS *************************************************************************** This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. *************************************************************************** *************************************************************************** This substance is classified as a hazardous air pollutant. *************************************************************************** SECTION 3 - HAZARDS IDENTIFICATION Page 3

14 RZ EMERGENCY OVERVIEW: Harmful if swallowed. Harmful if inhaled. Causes eye irritation. Causes skin irritation. Vapors irritating to eyes and respiratory tract. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Extremely flammable aerosol. Contents under pressure. EYE: May cause severe eye irritation. SKIN: May cause skin irritation. Prolonged contact with the skin can cause chemical burns. Product contains a component which can be absorbed through the skin. Excessive exposure may cause hemolysis (red blood cell damage) which can impair the blood's ability to transport oxygen. Skin contact may aggravate an existing dermatitis. INHALATION: Exposure to high concentrations of vapors may cause dizziness, breathing difficulty, headaches or respiratory irritation. Extremely high concentrations may cause drowsiness, staggering, confusion, unconsciousness, coma or death. Excessive inhalation of vapors can cause nasal and respiratory irritation. Liquid or vapor may be irritating to skin, eyes, throat or lungs. Breathing of mist can cause irritation of nasal and respiratory passages. Intentional misuse by deliberately concentrating and inhaling the contents of this product can be harmful or fatal. INGESTION: Moderately toxic. May cause stomach discomfort, nause, vomiting, diarrhea, and narcosis. Aspiration of material into the lungs if swallowed or if vomiting occurs can cause chemical pneumonitis which can be fatal. May cause nausea, vomiting and diarrhea. CHRONIC EFFECTS: Chronic overexposure to a component or components in this material has been found to cause the following effects in laboratory animals: Kidney damage Eye damage Liver damage Anemia Chronic overexposure to a component or components is this product has been suggested as a cause of the following effects in humans: Cardiac abnormalities Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Contains butyl benzyl phthalate which has been shown to cause cancer in at least one study in laboratory animals. Butyl benzyl phthalate is listed by the National Toxicoloty Program (NTP) as producing significant maternal and developmental toxicity. Rats exposed to titanium dioxide dust at 250 mg/m3 developed lung cancer, however, such exposure levels are not attainable in the workplace with this material. In February 2000 the International Agency for Research on Cancer (IARC) classified ethylbenzene as possibly carcinogenic to humans (Group 2B) on the basis of sufficient evidence for carcinogenicity in experimental animals but inadequate evidence for cancer in humans. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Immediately flush eyes with plenty of water. Get medical attention, if irritation persists. Flush with large quantities of water for 15 minutes. SKIN CONTACT: Immediately flush skin with plenty of water. Remove clothing. Get medical attention immediately. Wash clothing separately before reuse. Wash thoroughly with soap and water and seek medical attention if irritation persists. Remove contaminated clothing. Launder contaminated clothing before reuse. Page 4

15 RZ INHALATION: For inhalation overexposure move person to fresh air. If breathing stops, apply artificial respiration and seek medical attention. INGESTION: Since this product may contain materials which can cause lung damage if aspirated into the lungs, the decision whether to induce vomiting or not must be made by a physician after careful consideration of all materials ingested. SECTION 5 - FIRE FIGHTING MEASURES FIRE AND EXPLOSIVE PROPERTIES OF THE PRODUCT: Flashpoint : Less Than -25 øf Explosion Level : Low (LEL) -.3 High (UEL) EXTINGUISHING MEDIA: Use Dry Chemical, Carbon Dioxide or Chemical Foam. FIRE-FIGHTING PROCEDURES AND EQUIPMENT: Keep containers tightly closed. Isolate from heat, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Contents under pressure. Do not use or store near sources of heat, sparks or open flame. Keep away from any source of heat such as sunlight, heaters or stoves that could cause the container to burst. Do not puncture or incinerate. Do not crush or place in a garbage compactor. Do not store above 120 degrees F. Aerosol containers may explode when exposed to extreme heat. Product vapors are heavier than air and may travel a long distance to a source of ignition and flash back. Full protective equipment including self-contained breathing apparatus to avoid inhalation of vapors should be used. Water spray should not be used except to keep down vapors or cool closed containers to prevent build-up of pressure. If water is used, fog nozzles are preferred. SECTION 6 - ACCIDENTAL RELEASE MEASURES CLEAN-UP AND CONTAINMENT: Remove all sources of ignition. Avoid heat, sparks, flames and anything which could cause fire. Ventilate area of spill and adjacent low lying areas. Avoid breathing solvent vapors. Remove with inert absorbent materials and non-sparking tools. SECTION 7 - HANDLING AND STORAGE HANDLING: Wash hands thoroughly after handling. This product contains chemical(s) which are listed on California's proposition 65 list. If the product is to be sold or used in California a clear and reasonable warning must be provided such as: Warning! This product contains a chemical or chemicals known to the State of California to cause cancer. STORAGE: Store in a cool dry area with ventilation suitable for storing materials shown in section 2. Keep away from heat, sparks and flame. Store in a cool place away from direct sunlight or any source of ignition. Do not store at temperatures above 120 degrees F. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ENGINEERING CONTROLS: Sufficient ventilation, in volume and pattern, should be provided to keep air contamination below current applicable OSHA permissible exposure limit or ACGIH's TLV limit. RESPIRATORY PROTECTION: If workplace exposure limits are exceeded for any component(see section 2 for hazardous components and exposure limits), a NIOSH/OSHA approved respirator suitable for components listed is recommended. SKIN PROTECTION: Chemical resistant plastic or rubber gloves recommended for prolonged or repeated contact. Page 5

16 RZ EYE PROTECTION: Chemical goggles with side shields or face shield recommended if contact with the eyes is likely. OTHER PROTECTIVE EQUIPMENT: Appropriate impervious clothing is recommended if prolonged or repeated contact is likely. HYGIENIC PRACTICES: Wash hands before eating or smoking. Smoke in designated areas only. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure : mm 20 C Vapor Density : 3.70 Boiling Range : Lower øf Higher øf Specific Gravity :.741 Formula Weight per Volume : LB/GL VOC (Calculated, LB/GAL) : VOC (Calculated, GM/L) : Percent Volatile by Weight : Percent Volatile by Volume..... : Evaporation Rate : (n-butyl Acetate = 1) Viscosity : -N/A SECTION 10 - STABILITY AND REACTIVITY CONDITIONS TO AVOID: Avoid contact with heat, sparks, and open flame. Product may explode if heated. Keep cool, avoid exposure to heat. INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION: Thermal decomposition may produce carbon dioxide, carbon monoxide, and unidentifiable organic materials. POLYMERIZATION: No hazardous polymerization will occur under normal conditions. STABILITY: The product is stable under normal storage conditions. SECTION 11 - TOXICOLOGICAL INFORMATION No specific information is available. Please refer to Section 2 and 3 for available information on exposure limits and hazards identification. SECTION 12 - ECOLOGICAL INFORMATION No specific ecological information is available for this product. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Place in closed containers. Dispose of product in accordance with local, county, state, and federal regulations. SECTION 14 - TRANSPORT INFORMATION Ground shipment of limited or excepted quantities of aerosols or liquid paint in containers of 1 quart or less: CONSUMER COMMODITY, ORM-D Ground shipment of liquid paint in containers more than 1 quart: PAINT, FLAMMABLE LIQUID, UN1263, CLASS 3, GROUP II (Regulatory sources: DOT 49CFR ) Air shipment of limited or excepted quantities of aerosols or liquid paint in containers of 1 quart or less: CONSUMER COMMODITY, ID 8000, CLASS 9 MISCELLANEOUS LABEL (Regulatory sources: IATA Quantity Exemptions - Table 2.8.4, 2.7.A, 2.7.5, Packaging Instruction: 910) OR AEROSOLS, FLAMMABLE, UN1950, CLASS 2.1 LABEL (Regulatory sources: IATA Quantity Exemptions - Table 2.8.1, 2.8.4, Packaging Instruction: Y203) Page 6

17 RZ SECTION 15 - REGULATORY INFORMATION SARA 313 INFORMATION: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: ETHYLBENZENE CAS# PCT BY WT:.4300 XYLENE CAS# PCT BY WT: ETHYLENE GLYCOL MONOPROPYL ETHER CAS# PCT BY WT: FEDERAL REGULATIONS: TOXIC SUBSTANCES CONTROL ACT: The chemical substances in this product are listed on the TSCA Section 8 inventory. STATE REGULATIONS: This product contains chemical(s) which are listed on California's proposition 65 list. If the product is to be sold or used in California a clear and reasonable warning must be provided such as: Warning! This product contains a chemical or chemicals known to the State of California to cause cancer. Warning! This product contains a chemical or chemicals known to the State of California to cause birth defects or other reproductive harm. NEW JERSEY RIGHT-TO-KNOW No non-hazardous ingredients are among the top five ingredients PENNSYLVANIA RIGHT-TO-KNOW The following non-hazardous ingredients are present in the product at greater than 3 % CHEMICAL NAME CAS NUMBER Cellulose Acetate Butyrate INTERNATIONAL REGULATIONS: CANADA: The chemical substances in this product are listed on the Canadian Domestic Substances List. SECTION 16 - OTHER INFORMATION The information contained on this MSDS is believed to be reliable and accurate. Due to the changing nature of government information, it is impossible to guarantee the accuracy of the information contained herein. Since the conditions of handling and use are beyond our control, we make no guarantee of results and assume no liability for damages incurred by the use of this material. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. For questions relating to specific aspects of the requirements and regulations consult the proper regulatory agency. HMIS RATINGS: HEALTH: 2* FLAMMABILITY: 4 REACTIVITY: 0 PERSONAL PROTECTION: G Page 7