SAFETY DATA SHEET according to 1907/2006/EC, Article 31

Transcription

1 SAFETY DATA SHEET according to 1907/006/EC, Article 31 Page 1/6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier date Product name Other means of identification DispersiveTitania Paste 1.. Relevant identified uses of the substance or mixture and uses advised against Product Use 1.3. Details of the supplier of the safety data sheet Company Address Web Telephone [SU3] Industrial uses: Uses of substances as such or in preparations at industrial sites; [SU4] Scientific research and development; [PC1] Laboratory chemicals; Greatcell Solar Materials Pty Ltd 8 Faunce Street Queanbeyan NSW 60 Australia (AEST) Fax Emergency telephone number Emergency telephone number SECTION : Hazards identification.1. Classification of the substance or mixture information@greatcellsolar.com (AEST) 9.00 am pm Mon - Fri.1.1. Classification /45/ЕC Main hazards.1.. Classification - EC 17/008.. Label elements Hazard pictograms Xi; R36/37/38 Symbols: Xi: Irritant. Irritating to eyes, respiratory system and skin. Skin Irrit. : H315; STOT SE 3: H335; Signal Word Hazard Statement Prevention Warning Skin Irrit. : H315 - Causes skin irritation. STOT SE 3: H335 - May cause respiratory irritation. P61 - Avoid breathing dust/fume/gas/mist/vapours/spray. P64 - Wash thoroughly after handling. P71 - Use only outdoors or in a well-ventilated area. P80 - Wear protective gloves/protective clothing/eye protection/face protection.

2 date Page /6.. Label elements Response Storage Disposal.3. Other hazards Other hazards P30+P35 - IF ON SKIN: Wash with plenty of soap and water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P31 - Call a POISON CENTER/doctor/physician if you feel unwell. P31 - Specific treatment (see supplemental first aid instructions on this label). P33+P313 - If skin irritation occurs: Get medical advice/attention. P403+P33 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to an approved waste disposal plant None. SECTION 3: Composition/information on ingredients 3.. Mixtures 67/548/EEC / 1999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Terpineol % Xi; R36/37/38 M-factor. Titanium Dioxide % EC 17/008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Terpineol % Skin Irrit. : H315; STOT SE 3: H335; Titanium Dioxide % M-factor. -(-BUTOXYETHOXY) ETHYL % ACETATE Ethyl Cellulose % 4-Hydroxybenzoic acid % Skin Irrit. : H315; Eye Irrit. : H319; STOT SE 3: H335; SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Eye contact Skin contact Ingestion Move the exposed person to fresh air. Seek medical attention. 4.. Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious person. Irritating to respiratory system. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Irritating to eyes. Irritating to skin. Ingestion may cause nausea and vomiting Indication of any immediate medical attention and special treatment needed Inhalation Eye contact Skin contact

3 4.3. Indication of any immediate medical attention and special treatment needed date Page 3/6 Ingestion SECTION 5: Firefighting measures 5.1. Extinguishing media 5.. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Water spray. Alcohol resistant foam. Carbon dioxide (CO). Dry chemical. Carbon oxides. SECTION 6: Accidental release measures Wear suitable respiratory equipment when necessary Personal precautions, protective equipment and emergency procedures 6.. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing dust/fume/gas/mist/vapours/spray. Ensure adequate ventilation of the working area. Wear suitable protective equipment. Evacuate personnel to a safe area. Do not allow product to enter drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. For disposal see section Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Adopt best Manual Handling considerations when handling, carrying and dispensing. Keep container tightly closed and in a well-ventilated place. Keep in a cool place away from light. Research development and manufacture of dye sensitised solar cells Exposure Limit Values Titanium Dioxide WEL 8-hr limit ppm: - WEL 8-hr limit mg/m3: Exposure controls WEL 15 min limit ppm: - WEL 15 min limit mg/m3: - WEL 8-hr limit mg/m3 total 10 WEL 15 min limit mg/m3 total - inhalable dust: inhalable dust: WEL 8-hr limit mg/m3 total 4 WEL 15 min limit mg/m3 total - respirable dust: respirable dust:

4 date Page 4/6 8.. Exposure controls Appropriate engineering controls 8... Individual protection measures Eye / face protection Skin protection - Handprotection Respiratory protection Ensure adequate ventilation of the working area. Handle in accordance with good industrial hygiene and safety practice. Wear chemical protective clothing. Approved safety goggles. Chemical resistant gloves (PVC). Wear suitable respiratory equipment when necessary. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Paste Colour Off white Odour Characteristic Miscible in Alcohol Partition coefficient No data available Autoignition temperature No data available Viscosity No data available Explosive properties No data available Oxidising properties No data available ph No data available Melting point No data available Freezing Point No data available Evaporation rate No data available Flammability (solid, gas) No data available Vapour pressure No data available Vapour density No data available Relative density No data available Water solubility No data available Fat Solubility No data available Initial boiling point > 14 C Flash point 90 C 9.. Other information Conductivity No data available Surface tension No data available Benzene Content No data available Lead content No data available VOC (Volatile organic No data available compounds) Gas group Not applicable. SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability

5 Page 5/6 date 10.. Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects SECTION 1: Ecological information 1.1. Toxicity 1.. Persistence and degradability 1.3. Bioaccumulative potential Stable under normal conditions. Keep away from heat. Strong oxidising agents. Strong reducing agents. In the event of fire: see section 5. No data available Partition coefficient No data available 1.4. Mobility in soil 1.5. Results of PBT and vpvb assessment 1.6. Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Contact a licensed waste disposal company. General information Dispose of in compliance with all local and national regulations. SECTION 14: Transport information UN number 14.. UN proper shipping name

6 Page 6/ Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Further information SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture date Regulations COMMISSION REGULATION (EU) No 453/010 of 0 May 010 amending Regulation (EC) No 1907/006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 000/1/EC Chemical safety assessment SECTION 16: Other information Other information REGULATION (EC) No 1907/006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 000/1/EC. Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 Further information This document differs from the previous version in the following areas:. 1 - Product Use. - Response. - Storage. R36/37/38 - Irritating to eyes, respiratory system and skin. Skin Irrit. : H315 - Causes skin irritation. STOT SE 3: H335 - May cause respiratory irritation. Eye Irrit. : H319 - Causes serious eye irritation. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.