Safety Data Sheet in conformity with Regulation (EC) No 1907/2006

Size: px

Start display at page:

Download "Safety Data Sheet in conformity with Regulation (EC) No 1907/2006"

Phillip Watson
5 years ago
Views:

1 1 IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY Trade name Use of the product Use area and type of use LIQUID ACID HYGIENE OF MILKING EQUIPMENT Company identification Manufacturer HYPRED S.A. 55, Boulevard Jules Verger B.P DINARD Cedex - FRANCE Tél : +33 (0) Fax : +33 (0) hypred@hypred.fr HYPRED GmbH Marie-Curie Strasse, Bornheim - Sechtem Tel : Fax : hypred.de@roullier.com Distributor HYPRED UK LTD. Clifton Down House, Beauforts Buildings Clifton - BRISTOL BS8 4AN Tel: Fax: Emergency phone number Call your medical practitionner LONDON (Information available at the National Poison Unit - Guy's Hospital) - 1/13 -

2 - 2/13 -

3 2 HAZARDS INDENTIFICATION The product is considered as a hazardous preparation according to 1999/45/EC Directive. Hazard symbol(s) : O : OXIDIZING, C : CORROSIVE Main risks : Causes burns. Contact with combustible material may cause fire. Environmental risks : No dangerous environmental effect when instructions for use are followed. 3 COMPOSITION / INFORMATION ON INGREDIENTS CHEMICAL NATURE OF THE PRODUCT : LIQUID ACID a - Substance(s) contributing to the hazard(s): 5% <= Peracetic acid < 10% + 8%<= Hydrogen peroxide < 35% b - Other hazardous substance(s) according to 1999/45/EC Directive : 10% <= acetic acid < 25% c - Substance(s) not already included under points a and b for which there are workplace exposure limits : Not concerned Substance(s) / CAS number(s) / EINECS number(s) : acetic acid / / Hydrogen peroxide / / Peracetic acid / / Symbole(s)- R Phrase(s) : acetic acid : C, R10;R35 Hydrogen peroxide : C;O, R20/22;R35;R5;R8 Peracetic acid : C;N;O, R10;R20/21/22;R35;R50;R7-3/13 -

4 4 FIRST AID MEASURES Skin contact : Take off immediately all contaminated clothing. Wash immediately with plenty of water for 15 minutes at least. Consult a dermatologist. Eye contact : Rinse at once with a soft stream of water for at least 15 minutes, eyes wide open. Immediately consult an ophtalmologist, even in the absence of apparent damages. Ingestion : Rinse the mouth. Do not induce vomiting. Send to hospital. Inhalation : Bring to fresh air. Put into practice respiratory help procedure if needed and get medical advice immediately. 5 FIRE-FIGHTING MEASURES Specific risks : is non-flammable but may contribute to fire. Oxygen release resulting in burning. Recommended extinguishing media : Water, agents compatible with other products involved into fire. Extinguishing media to be avoided: None from our knowledge. Protective equipment : Wear independent respiratory equipment and protective suit. 6 ACCIDENTAL RELEASE MEASURES Personal precautions : Respect protective measures presented at heading 5. Respect protective measures presented at heading 8. Environmental precautions : Intervention limited to trained staff. Do not discharge the product directly to sewer or to environment. - 4/13 -

5 Take as soon as possible all incompatible materials away. Method(s) for cleaning up : Small spillage : Wash with plenty of water. Large spillage : Mark out, dyke up with an inert absorbant and pump in an emergency tank. Do not use: textiles, sawdust, flammable substances. 7 HANDLING AND STORAGE Handling : Avoid discharge when using. Take off immediately all contaminated clothing. Keep away from incompatible matters (see heading 10). Storage : Keep only in the original container. Keep in a clean, cool and well-ventilated place away from sources of heat and intense light. Keep away from incompatible matters (see heading 10). Keep container closed. Packaging materials : High density polyethylene recommended. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limit values : D - Hydrogen peroxide (100%) - MAK : 1 ppm - Category : I MAK - Kommission D - Hydrogen peroxide (100%) - MAK : 1,4 mg/m3 - Category : I MAK - Kommission F - Hydrogen peroxide (100%) - VME : 1 ppm - INRS F - Hydrogen peroxide (100%) - VME : 1,5 mg/m3 - INRS GB - Hydrogen peroxide (100%) - OES (8h) : 1,5 mg/m3 - Health & safety commission GB - Hydrogen peroxide (100%) - OES (8h) : 1 ppm - Health & safety commission GB - Hydrogen peroxide (100%) - OES (15 min) : 3 mg/m3 - Health & safety commission GB - Hydrogen peroxide (100%) - OES (15 min) : 2 ppm - Health & safety commission NL - Hydrogen peroxide (100%) - MAC - 15 min : 2,8 mg/m3 - IUCLID USA - Hydrogen peroxide (100%) - TLV-TWA : 1 ppm - ACGIH USA - Hydrogen peroxide (100%) - TLV-TWA : 1,4 mg/m3 - ACGIH F - Peracetic acid (100%) - VLE : 1,6 mg/m3 - INRS - proposed value F - Peracetic acid (100%) - VME : 0,6 mg/m3 - INRS - proposed value D - acetic acid (100%) - MAK : 25 mg/m3 - Category : I MAK - Kommission - 5/13 -

6 D - acetic acid (100%) - MAK : 10 ppm - Category : I MAK - Kommission F - acetic acid (100%) - VME : 10 mg/m3 - European Regulation F - acetic acid (100%) - VME : 25 ppm - European Regulation F - acetic acid (100%) - VLE : 10 ppm - INRS F - acetic acid (100%) - VLE : 25 mg/m3 - INRS GB - acetic acid (100%) - OES (15 min) : 37 mg/m3 - Health & safety commission GB - acetic acid (100%) - OES (15 min) : 15 ppm - Health & safety commission GB - acetic acid (100%) - OES (8h) : 25 mg/m3 - Health & safety commission GB - acetic acid (100%) - OES (8h) : 10 ppm - Health & safety commission USA - acetic acid (100%) - TLV-STEL : 15 ppm - ACGIH USA - acetic acid (100%) - TLV-STEL : 37 mg/m3 - ACGIH USA - acetic acid (100%) - TLV-TWA : 10 ppm - ACGIH USA - acetic acid (100%) - TLV-TWA : 25 mg/m3 - ACGIH Personal protection equipment : Hand protection : Wear protective gloves with chemical resistance (PVC, neopren, rubber type). Eye/face protection : Wear protective glasses. For certain applications, the use of a breathing protection equipment in a ventilated place or a ventilation equipment in suffocating place is recommended. Skin/body protection : Wear boots and a protective cloth with chemical resistance. Specific hygiene measures : Safety shower and eye wash fountain near to workplace. After using, wash systematically all personal protective equipment. - 6/13 -

7 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance : Clear liquid Colour : Colourless Odour : Pungent Freezing point : -25 C Flash point : 84 C Solubility : Soluble in water in all proportions Pure ph : 0,8+/- 0,2 ph value at 10 g/l: 3+/- 0,5 Mass density : 1,09+/- 0,01 g/cm3 10 STABILITY AND REACTIVITY Hazardous reaction(s) : Avoid the contact with the basis, metals, reducing agents, organic and inflammable matters. Condition(s) to avoid : Light, heat. Material(s) to avoid : Basis. Organic matters. Metals. Flammable substances. Reducing agents. Hazardous decomposition products : Release of oxygen. These data are given for the concentrated product. The use of the product under its diluted form must be performed in conformity with data given by the technical data sheet and the technical adviser. - 7/13 -

8 11 TOXICOLOGICAL INFORMATION Toxicological data relating to hazardous substances : ACUTE TOXICITY acetic acid (74%) : LC 50 - inhalation - 4h (rat) : 40 mg/l - MSDS supplier Peracetic acid (2%) : LD 50 - dermal (rat) : > mg/kg bw - IUCLID (H2O2 : 7%; HOAc : 19%) Hydrogen peroxide (35%) : LD 50 - oral (rat) : 1200 mg/kg - MSDS supplier Peracetic acid (5,6%) : LD 50 - oral (rat) : 3622 mg/kg - ECETOC (H2O2 : 26,9%; HOAc : 7,6%) acetic acid (74%) : LD 50 - oral (rat) : 3310 mg/kg - MSDS supplier acetic acid (74%) : Inhalation : : Irritating to respiratory system. - MSDS supplier acetic acid (74%) : Skin irritation : Corrosive. - MSDS supplier Hydrogen peroxide (35%) : Skin irritation : Irritating - MSDS supplier Hydrogen peroxide (35%) : Respiratory tracts irritation : Irritating to respiratory system. - MSDS supplier acetic acid (74%) : Respiratory tracts irritation : Corrosive. - MSDS supplier acetic acid (74%) : Eye irritation : Corrosive. - MSDS supplier Hydrogen peroxide (35%) : Eye irritation : Serious damage to eyes - MSDS supplier Hydrogen peroxide (35%) : Skin sensitisation (guinea-pig) : Not sensitising - MSDS supplier Peracetic acid (2%) : Sensitisation (guinea-pig) : Not sensitising - IUCLID (H2O2 : 7%; HOAc : 19%) CHRONIC TOXICITY Hydrogen peroxide (35%) : Dermal route (mouse) : Not carcinogenic - MSDS supplier Hydrogen peroxide (35%) : Oral route (rat) : Not carcinogenic - MSDS supplier CARCINOGENESIS acetic acid (74%) : Not carcinogenic - MSDS supplier MUTAGENESIS acetic acid (74%) : Chromosomal aberration test : Not mutagenic - MSDS supplier acetic acid (74%) : Ames test : Not mutagenic - MSDS supplier GENETIC TOXICITY IN VITRO Hydrogen peroxide (35%) : With metabolic activation : Not mutagenic - MSDS supplier GENETIC TOXICITY IN VIVO Hydrogen peroxide (35%) : Not mutagenic - MSDS supplier TOXICITY FOR THE REPRODUCTION Hydrogen peroxide (35%) : No effect on reproduction - MSDS supplier acetic acid (74%) : Teratogenicity : Not teratogenic - MSDS supplier According to acute toxicity results of dangerous substance(s) and 1999/45/EC Directive : is not considered as : - harmful preparation by contact with skin. - harmful preparation if swallowed. - harmful preparation by inhalation, but it has corrosive properties whose local effects are presented below. - 8/13 -

9 Local effects Skin contact : Corrosive : Causes burns. Eye contact : Corrosive : Causes burns. Risk of serious damage to eyes if not treated immediately. Ingestion : Causes burns in mouth and digestive tract. Inhalation : May cause a severe inflammation of the nose, throat and respiratory system. 12 ECOLOGICAL INFORMATION Ecotoxicological data relating to hazardous substances : ACUTE TOXICITY Hydrogen peroxide (35%) : EC 50-48h (daphnia) : 2,4-7,7 mg/l - MSDS supplier Peracetic acid (4,5%) : EC 50-48h (daphnia)(daphnia magna) : 1,1 mg/l - ECETOC (H2O2 : 27,5%) Hydrogen peroxide (35%) : EC à 96h (algae) : 3,7-160 mg/l - MSDS supplier acetic acid (74%) : EC 50-24h (daphnia)(daphnia magna) : 95 mg/l - MSDS supplier Peracetic acid (5,2%) : LC 50-96h (fishes)(oncorhynchus mykiss) : 1,6 mg/l - ECETOC (H2O2 : 20%) Hydrogen peroxide (35%) : LC 50-96h (fishes)(pimephales promelas) : 16,4 mg/l - MSDS supplier acetic acid (74%) : LC 50-96h (fishes)(lepomis macrochirus) : 75 mg/l - MSDS supplier DEGRADABILITY Hydrogen peroxide (35%) : Aerobic biodegradability, half time fresh water : 0,3-5 jour(s) Fast and important biodegradation - MSDS supplier Peracetic acid () : Biodegradability : (aerobic) : Inherently biodegradable (OECD 301 E) - IUCLID acetic acid (74%) : Biodegradability : : Easily biodegradable. - MSDS supplier BEHAVIOUR IN ENVIRONMENT Hydrogen peroxide (35%) : : No toxicity of degradation products (H2O + O2) - MSDS supplier BIOACCUMULATION acetic acid (74%) : : Not bioaccumulative - MSDS supplier Hydrogen peroxide (35%) : : Not bioaccumulative - MSDS supplier Peracetic acid () : Log Pow : 0,3 +/- 0,13 Not bioaccumulative (EPA) - ECETOC Conclusion : According to acute ecotoxicity results of dangerous substance(s) and 2006/8EC Directive : is not considered as : - dangerous preparation regarding to environment. Other indications : - 9/13 -

10 13 DISPOSAL CONSIDERATIONS Waste treatment : Elimination must be disposed of in accordance with local, regional or national regulations. Do not discharge the product directly to sewer or to environment. Packaging treatment : Rinse thoroughly the packaging with water and treat the effluent like wastes. Packagings do not be reused (excepted in case of exemption and in accordance with the regulations in force). - 10/13 -

11 14 TRANSPORT INFORMATION ROAD TRANSPORT : Rail/Road (RID/ADR) Transport denomination :HYDROGEN PEROXIDE AND PEROXYACETIC ACID IN STABILIZED MIXTURE (Peracetic acid) Class: 5.1 UN no :3149 Packaging group : II Hazard code :58 Label : 5.1 SEA TRANSPORT : IMDG Transport denomination :HYDROGEN PEROXIDE AND PEROXYACETIC ACID IN STABILIZED MIXTURE (Peracetic acid) Class : 5.1 UN no :3149 Packaging group : II EmS no: F-H, S-Q Marine pollutant : 15 REGULATORY INFORMATION The product is considered as a hazardous preparation according to 1999/45/EC Directive. Hazard symbol(s) : O : OXIDIZING, C : CORROSIVE Substance(s) leading to the classification of the product : 5% <= Peracetic acid < 10% + 8%<= Hydrogen peroxide < 35% R Phrase(s) - S Phrase(s) : R34 : Causes burns. R8 : Contact with combustible material may cause fire. S14b : Keep out of catalist of decomposition, alkalins, reducing agents and flammable materials. S23b : Do not breathe vapour. S23d : Do not breathe spray. S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S3/7 : Keep container tightly closed in a cool place. S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection. S45 : In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S51 : Use only in well-ventilated areas. - 11/13 -

12 16 OTHER INFORMATION The safety data sheet is additional to the technical data sheet but does not replace it. The information given here in is to the best of our knowledge correct and is given in good faith. We must also draw the user's attention on potential risks of the product is used for other purposes for which the product is known. In no way does it exempt users from being aware of and complying with regulations applicable to their activity. It is their sole responsibility to take all necessary precautions in accordance to the usage of the product they are aware of. Regulations are only stated in order to help users fulfill the duties involved in the use of the product. This description should not be considered as exhaustive. It does not exempt users from ensuring if other demands need to be complied with-according to other laws than the ones hereby stated and applicable to holding and usage of the product-demands for which they will remain sole responsibility. Updated heading(s) since the previous version : 3 COMPOSITION / INFORMATION ON COMPONENTS; List of relevant R phrases under headings 2 and 3 : R10 : Flammable. R20/21/22 : Harmful by inhalation, in contact with skin and if swallowed. R20/22 : Harmful by inhalation and if swallowed. R34 : Causes burns. R35 : Causes severe burns. R5 : Heating may cause an explosion. R50 : Very toxic to aquatic organisms. R7 : May cause fire. R8 : Contact with combustible material may cause fire. Sources of key data used to compile the data sheet : ACGIH European Regulation ECETOC ECETOC (H2O2 : 20%) ECETOC (H2O2 : 26,9%; HOAc : 7,6%) ECETOC (H2O2 : 27,5%) MSDS supplier Health & safety commission INRS INRS - proposed value IUCLID IUCLID (H2O2 : 7%; HOAc : 19%) MAK - Kommission - 12/13 -

13 Historical : Version : 3.1 Cancels and replaces previous version /13 -

Safety Data Sheet Sunspot ph Minus/Dry Acid

Safety Data Sheet Sunspot ph Minus/Dry Acid Revision DATE SDS REVISED 26 th April 2005 SDS Ref: SOL1000 Supercedes SDS dated March 2003 Revision Number: 3 rd Edition 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION