Safety Data Sheet. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name Product number CFDP8 1.3 Details of the supplier of the safety data sheet Name Address Mercer Milling Company 4698 Crossroads Park Drive Liverpool, New York USA Telephone Fax SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) - Eye damage/irritation (chapter 3.3), Cat. 2, H319 For the full text corresponding to the "H"-codes displayed in this section, refer to Section Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP] Hazard pictograms Signal word Hazard statement(s) H319 Precautionary statement(s) P264 P280 Warning Causes serious eye irritation Wash hands thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Version: 1.0, Date of issue: , p. 1 of 8

2 P305+P351+P338 P337+P313 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. SECTION 3: Composition/information on ingredients 3.2 Mixtures Components Component Calcium Phosphate, Monobasic, Monohydrate (CAS no.: ) CLASSIFICATIONS: HAZARDS: Calcium carbonate (Natural) (CAS no.: ) CLASSIFICATIONS: HAZARDS: Magnesium oxide (CAS no.: ) CLASSIFICATIONS: HAZARDS: Dynamate (CAS no.: ) CLASSIFICATIONS: HAZARDS: Zinc sulfate (CAS no.: ; EC no.: ; Index no.: ) CLASSIFICATIONS: Acute toxicity (chapter 3.1), Cat. 4; Eye damage/irritation (chapter 3.3), Cat. 1; Hazardous to the aquatic environment - acute hazard (chapter 4.1), Cat. 1; Hazardous to the aquatic environment - long-term hazard (chapter 4.1), Cat. 1. HAZARDS: H302 - Harmful if swallowed; H318 - Causes serious eye damage; H400 - Very toxic to aquatic life; H410 - Very toxic to aquatic life with long lasting effects. Manganese (II) Sulfate (CAS no.: ; EC no.: ; Index no.: ) CLASSIFICATIONS: Specific target organ toxicity, repeated exposure (chapter 3.9), Cat. 2; Hazardous to the aquatic environment - long-term hazard (chapter 4.1), Cat. 2. HAZARDS: H373 - May cause damage to organs through prolonged or repeated exposure; H411 - Toxic to aquatic life with long lasting effects. Saccharomyces cerevisiae (CAS no.: ) CLASSIFICATIONS: HAZARDS: White mineral oil, petroleum (CAS no.: ) CLASSIFICATIONS: HAZARDS: D-ALPHA-TOCOPHERYL ACETATE (CAS no.: ) CLASSIFICATIONS: HAZARDS: SECTION 4: First aid measures 4.1 Description of first aid measures Following inhalation Following skin contact Following eye contact Following ingestion Self-protection of the first aider If breathed in, move person into fresh air. Wash off with soap and plenty of water. Continue rinsing eyes during transport to hospital. Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed Version: 1.0, Date of issue: , p. 2 of 8

3 SECTION 5: Firefighting measures 5.1 Extinguishing media Use extinguishing media appropriate for surrounding fire. 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters Further information SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental precautions 6.3 Methods and material for containment and cleaning up 6.4 Reference to other sections SECTION 7: Handling and storage 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1 Control parameters CAS: Magnesium oxide fume - Total Particulate Cal/OSHA: 10 mg/m3 PEL inhalation; NIOSH: See Appendix D REL inhalation; OSHA: 15 mg/m3 PEL inhalation CAS: Calcium Carbonate Cal/OSHA: see PNOR PEL inhalation Calcium Carbonate, Respirable fraction Cal/OSHA: 5 mg/m3 PEL inhalation; NIOSH: 5 mg/m3 REL inhalation; OSHA: 5 mg/m3 PEL inhalation Version: 1.0, Date of issue: , p. 3 of 8

4 Calcium Carbonate, Total dust Cal/OSHA: 10 mg/m3 PEL inhalation; NIOSH: 10 mg/m3 REL inhalation; OSHA: 15 mg/m3 PEL inhalation Limestone Cal/OSHA: see PNOR PEL inhalation Limestone, Respirable fraction Cal/OSHA: 5 mg/m3 PEL inhalation; NIOSH: 5 mg/m3 REL inhalation; OSHA: 5 mg/m3 PEL inhalation Limestone, Total dust Cal/OSHA: 10 mg/m3 PEL inhalation; NIOSH: 10 mg/m3 REL inhalation; OSHA: 15 mg/m3 PEL inhalation Marble Cal/OSHA: See PNOR PEL inhalation Marble, Respirable fraction Cal/OSHA: 5 mg/m3 PEL inhalation; NIOSH: 5 mg/m3 REL inhalation; OSHA: 5 mg/m3 PEL inhalation Marble, Total dust Cal/OSHA: 10 mg/m3 PEL inhalation; NIOSH: 10 mg/m3 REL inhalation; OSHA: 15 mg/m3 PEL inhalation 8.2 Exposure controls Appropriate engineering controls Personal protection equipment Pictograms Eye and face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Body protection Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Thermal hazards Environmental exposure controls SECTION 9: Physical and chemical properties Version: 1.0, Date of issue: , p. 4 of 8

5 9.1 Information on basic physical and chemical properties Appearance Odor Odor threshold ph Melting point / freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limits Upper/lower explosive limits Vapor pressure Vapor density Relative density Solubilit(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties Dry granular powder 9.2 Other information SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials 10.6 Hazardous decomposition products Version: 1.0, Date of issue: , p. 5 of 8

6 SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Summary of evaluation of the CMR properties STOT-single exposure STOT-repeated exposure Aspiration hazard Additional information SECTION 12: Ecological information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential Version: 1.0, Date of issue: , p. 6 of 8

7 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects SECTION 13: Disposal considerations 13.1 Waste treatment methods Disposal of the product Disposal of contaminated packaging Waste treatment Sewage disposal Other disposal recommendations SECTION 14: Transport information DOT (US) Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Massachusetts Right To Know Components Chemical name: Zinc sulfate CAS number: New Jersey Right To Know Components Common name: CALCIUM CARBONATE Version: 1.0, Date of issue: , p. 7 of 8

8 CAS number: Common name: MAGNESIUM OXIDE CAS number: Common name: ZINC SULFATE CAS number: Pennsylvania Right To Know Components Chemical name: Limestone CAS number: Chemical name: Magnesium oxide CAS number: Chemical name: Sulfuric acid, zinc salt (1:1) CAS number: Chemical Safety Assessment SECTION 16: Other information Full text of hazard statements referenced in Section 2 H319 Causes serious eye irritation Further information/disclaimer DISCLAIMER: The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigation to determine the suitability of information for their particular purposes. In no event shall Mercer Milling Company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, whatsoever arising, even if Mercer Milling Company has been advised of the possibility of such damages. Version: 1.0, Date of issue: , p. 8 of 8