SAFETY DATA SHEET Issuing Date 16-Jun-2016 Revision Date 16-Jun-2016 Revision Number 1

Transcription

1 SAFETY DATA SHEET Issuing Date 16-Jun-2016 Revision Number 1 Product identifier 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name Clorox Disinfecting Wipes1 - Crisp Lemon Other means of identification Synonyms ne EPA Pesticide registration number Recommended use of the chemical and restrictions on use Recommended Use Uses advised against General Purpose Cleaner - n-aerosol information available Details of the supplier of the safety data sheet Supplier Name Supplier Address The Clorox Company 1221 Broadway Oakland CA US Supplier Phone Number Phone: Emergency telephone number Company Emergency Phone Number For Medical Emergencies call: (800) Transportation Emergencies, call Chemtrec: (800) HAZARDS IDENTIFICATION Classification This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ). GHS Label elements, including precautionary statements Emergency Overview. Appearance White Physical state Pre-Moistened Towelette (no free liquids) Odor Lemon Page 1 / 9

2 Precautionary Statements - Prevention ne Precautionary Statements - Response ne Precautionary Statements - Storage ne Precautionary Statements - Disposal ne Hazards not otherwise classified (HNOC) t applicable Unknown Toxicity 21.5 % of the mixture consists of ingredient(s) of unknown toxicity Other information information available Interactions with Other Chemicals. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Weight-% Trade Secret Ethylene glycol monohexyl ether * Quaternary ammonium compounds, * C12-14-alkyl[(ethylphenyl)methyl]dimethyl, chlorides Alkyl C12-18 Dimethylbenzyl Ammonium Chloride * *The exact percentage (concentration) of composition has been withheld as a trade secret First aid measures 4. FIRST AID MEASURES General Advice Eye contact Skin contact Inhalation Ingestion Self-protection of the first aider Show this safety data sheet to the doctor in attendance. If in eyes: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Rinse immediately with plenty of water and seek medical advice. If skin irritation persists, call a physician. Remove to fresh air. If breathing is difficult, (trained personnel should) give oxygen. Call a physician or Poison Control Center immediately. Drink plenty of water. Call a physician or Poison Control Center immediately. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section 8). Page 2 / 9

3 Most important symptoms and effects, both acute and delayed Most Important Symptoms and Effects Irritating. Indication of any immediate medical attention and special treatment needed tes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Hazardous Combustion Products information available Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge.. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers. Page 3 / 9

4 Precautions for safe handling 7. HANDLING AND STORAGE Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Incompatible Products Keep container tightly closed in a dry and well-ventilated place. ne known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethylene glycol monohexyl ether ne ne ne Quaternary ammonium compounds, ne ne ne C12-14-alkyl[(ethylphenyl)methyl]dimethyl, chlorides Alkyl C12-18 Dimethylbenzyl Ammonium Chloride ne ne ne ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health Other Exposure Guidelines Appropriate engineering controls Engineering Measures Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Skin and body protection Respiratory protection Hygiene Measures special protective equipment required. special protective equipment required. protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Handle in accordance with good industrial hygiene and safety practice. Physical and Chemical Properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Pre-Moistened Towelette (no free liquids) Appearance White Odor Lemon Color information available Odor Threshold information available Property Values Remarks Method ph 6-9 (liquid) ne known Melting / freezing point ne known Page 4 / 9

5 Boiling point / boiling range ne known Flash Point ne known Evaporation Rate ne known Flammability (solid, gas) ne known Flammability Limit in Air Upper flammability limit Lower flammability limit Vapor pressure ne known Vapor density ne known Specific Gravity ~1.0 (liquid) ne known Water Solubility Soluble in water ne known Solubility in other solvents ne known Partition coefficient: n-octanol/water ne known Autoignition temperature ne known Decomposition temperature ne known Kinematic viscosity ne known Dynamic viscosity ne known Explosive properties Oxidizing properties Other Information Softening Point VOC Content (%) Particle Size Particle Size Distribution 10. STABILITY AND REACTIVITY Reactivity. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions ne under normal processing. Conditions to avoid ne known based on information supplied. Incompatible materials ne known. Hazardous Decomposition Products ne known. Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Product Information Inhalation Eye contact Skin contact Ingestion Product does not present an acute toxicity hazard based on known or supplied information.. May cause irritation of respiratory tract. May cause slight irritation. Substance may cause slight skin irritation. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal Page 5 / 9

6 Component Information irritation, nausea, vomiting and diarrhea. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Ethylene glycol monohexyl ether 739 mg/kg (Rat) 721 mg/kg (Rabbit) >0.5 mg/l (Rat, 4 h) Information on toxicological effects Symptoms May cause redness and tearing of the eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Mutagenic Effects Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. IARC (International Agency for Research on Cancer) Group 3 - t Classifiable as to Carcinogenicity in Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive toxicity STOT - single exposure STOT - repeated exposure Chronic Toxicity Target Organ Effects Aspiration Hazard known effect based on information supplied. Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 40.1 mg/kg ATEmix (dermal) 59.8 mg/kg Ecotoxicity ne known. Persistence and Degradability Bioaccumulation information available 12. ECOLOGICAL INFORMATION Other adverse effects Page 6 / 9

7 Waste treatment methods 13. DISPOSAL CONSIDERATIONS Disposal methods Contaminated Packaging Dispose of in accordance with federal, state and local regulations. Do not reuse empty containers. Dispose of in accordance with federal, state and local regulations. This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION DOT TDG MEX ICAO IATA IMDG/IMO RID ADR ADN International Inventories TSCA DSL 15. REGULATORY INFORMATION All components are listed on the TSCA Inventory All components are listed either on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name CAS Weight-% SARA Threshold Values % Ethylene glycol monohexyl ether SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden release of pressure hazard Reactive Hazard Page 7 / 9

8 CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain Proposition 65 chemicals. U.S. State Right-to-Know Regulations. Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Ethylene glycol monohexyl ether X X X Isopropyl alcohol X X X X EPA Pesticide Registration Number EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide label CAUTION: Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling. International Regulations Canada WHMIS Hazard Class D2B - Toxic materials 16. OTHER INFORMATION NFPA Health Hazards 0 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazards 0 Flammability 0 Physical Hazard 0 Personal Protection A Prepared By Issuing Date Revision Date Revision te Product Stewardship 23 British American Blvd. Latham, NY Jun Jun-2016 information available Page 8 / 9

9 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 9 / 9