SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 SAFETY DATA SHEET 1. Product and Company Identification Product Name 3V Product Number 550 Product Type Mixture Product Use Manual cleaner for pots and pans, glassware and silverware. Manufacturer/Supplier National Purity, LLC Shingle Creek Parkway, Suite #23 Brooklyn Center, MN Company Contact Emergency Telephone Number Hazards Identification GHS Classification in accordance with 29 CFR 1910 OSHA HCS Acute toxicity, Oral (Category 5) H303, Eye damage/irritation, (Category 2B) H320 Acute aquatic toxicity, (Category 3) H402 Chronic aquatic toxicity, (Category 3) H412 GHS Label elements, including precautionary statements Pictogram Signal word None required Warning Hazard Statements H303 May be harmful if swallowed. H320 Causes eye irritation. H402 Harmful to aquatic life. H412 Harmful to aquatic life with long lasting effects Precautionary Statements Prevention P264 Wash hands thoroughly after handling. P273 Avoid release to the environment. Response P312 Call a POISON CENTER/doctor if ingested and feeling unwell. P305+P351+P337+P313 IF IN EYES, rinse cautiously for several minutes. Remove contact lenses if present. Continue rinsing. If eye irritation persists, Get medical advice and attention Storage/Disposal P501 Dispose of contents/container in accordance with local/regional/federal regulations. 3/7/2015 Page 1 of 6

2 .3. Composition/Information on Ingredients The criteria for listing components in this section are: Ingredients that meet the criteria for carcinogenic, toxic to reproduction, or specific target organ toxicity and components otherwise considered hazardous according to OSHA which exceed the cut off limits for SDS specified by the criteria for mixtures are listed. Non hazardous components are not listed. This is not a composition disclosure. Exact percentages are considered proprietary and a trade secret. Hazardous Components CAS# Classification % Dodecylbenzene sulfonic acid H301, H314, H318, H % Sodium (C14-C16) Olefin sulfonate H316, H % (Nonylphenoxy) polyethylene oxide H313, H320, H % Sodium hydroxide H314, H % Description of First Aid Procedures General Advice In Case of Eye Contact In Case of Skin Contact If Ingested If Inhaled Notes to Physician General advice Flammable properties Extinguishing media Protection of firefighters Hazardous combustion products Unusual Fire, Explosion hazards Personal precautions Methods for containment Methods for cleaning up Environmental precautions Precautions for Safe Handling Conditions for Safe Storage 4. First Aid Measures Consult a physician. Show this SDS to the doctor. Flush with cool running water for 15 minutes. Remove contact lenses if present. Get immediate medical attention. Rinse thoroughly with cool running water. Remove contaminated clothing. Get medical attention if irritation occurs or persists. Rinse mouth with water. Do not induce vomiting. Obtain medical attention if feeling unwell. Move person to fresh air. If breathing difficulty persists, consult a physician. Symptoms may be delayed. Seek medical attention if feeling unwell. Show the SDS to the physician in attendance. 5. Fire-fighting Measures None Use methods appropriate to the source of the fire. Firefighters should wear protective clothing including self contained breathing apparatus. May include and not limited to oxides of carbon, sulfur, and nitrogen. Containers may melt or rupture from heat of fire. May form combustible mixtures with air when heated. 6. Accidental Release Measures Keep unnecessary personal away. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers. Before attempting clean up, refer to hazard data given above. Small spills, may be mopped up and rinsed. Large spills, dike area to prevent from spreading. Absorb with non reactive absorbent and place in suitable, covered, and labeled container. Rinse area with water. Never return spill to original container. Avoid spills. Keep out of waterways. 7. Handling and Storage Use good industrial hygiene practices when handling this material. Avoid contact with eyes. Keep container closed when not in use. 3/7/2015 Page 2 of 6

3 8. Exposure Controls and Personal Protection Exposure Limits Ingredients CAS# OSHA PEL ACGIH TLV Dodecylbenzene sulfonic acid Sodium (C14-C16) olefin sulfonate (Nonylphenol) Polyethylene oxide Sodium hydroxide mg/m 3 PEL 2 mg/m 3 Ceiling Engineering controls Personal protective equipment Eye/Face protection Hand protection Skin and body Respiratory protection General hygiene considerations General ventilation normally adequate. Wear goggles or safety glasses with side shields if splash conditions exist. Have suitable eye wash water available. None required. Not required with normal use. Use a NIOSH approved respirator when exposure guidelines are exceeded. Handle in accordance with good industrial hygiene practices. Do not eat or drink when using product. Rinse hands well before breaks and immediately after handling the product. 9. Physical and Chemical Properties Information on basic physical and chemical properties Appearance/form Clear liquid Color Blue/green Odor Floral fragrance Odor threshold Not established ph (concentrate) Melting/freezing point Not established Initial Boiling point 212º F. ( 100º C.) Flash point > 200º F. (93º C.) CC Evaporation rate < 1 (butyl acetate = 1) Flammability Not flammable Upper/lower flammability or Not applicable Explosive limits Vapor pressure Not established Vapor density Not established Specific gravity/density Not established Solubility in water Complete VOC < 1% % Volatile Approx 75% Other Safety Information Reactivity Chemical Stability Hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Hazardous polymerization 10. Stability and Reactivity Not known to be reactive. Stable under normal storage conditions. None known. Do not mix with other chemicals. Strong acids, alkalais, strong oxidizing agents. May include but not limited to oxides of carbon, sulfur, and nitrogen. Will not occur. 3/7/2015 Page 3 of 6

4 11. Toxicological Information Ingredients Dodecylbenzene sulfonic acid Sodium (C14-C16) olefin sulfonate (Nonylphenoxy) polyethylene oxide Sodium hydroxide Ingredients Dodecylbenzene sulfonic acid Sodium (C14-C16) olefin sulfonate (Nonylphenoxy) polyethylene oxide Sodium hydroxide LC mg/l Acute inhalation LD mg/kg (Acute oral-rat) 2310 mg/kg (Oral-rat), 6300 mg/kg (Oral-rabbit) mg/kg (Oral-rat) Eye Causes eye irritation. Skin Not expected to be an irritant under normal use. Ingestion May be harmful if swallowed. I halation Not expected to be a normal route of entry. Sensitization Chronic effects of short and long Prolonged exposure to skin may cause drying, defatting and irritation. Term exposure Carcinogenicity Does not contain ingredients considered carcinogenic by NTP, or OSHA. Mutagenicity Reproductive effects Teratogenicity 12. Ecological Information Eco-toxicity Ecological effects for this product have not been analyzed. However, if spilled this products ingredients are harmful to aquatic life and may have long lasting effects. Aquatic toxicity Doodecylbenzene sulfonic acid LC50 Fish: 4200 mg/l -96 hour estimated (Nonylphenoxy) polyethylene oxidelc50 Fish: 10 mg/l- 96 hours Environmental effects Persistence and Degradability Bioaccumulation/accumulation Partition coefficient Mobility in environmental media Chemical fate information Other adverse effects Waste codes Disposal instructions Wastes from residues/unused product Contaminated packaging Hazard can not be excluded if product is misused or released to the environment Disposal Considerations Not Available Dispose in accordance with local, state, and federal regulations Containerize. Rinse area with water. Keep out of storm sewer/waterways. Dispose in accordance with all applicable regulations. 3/7/2015 Page 4 of 6

5 Basic shipping requirements: Proper shipping name: Hazard class UN number Packing group Special provisions Packaging exceptions 14. Transport Information Not DOT regulated 15. Regulatory Information U.S federal regulations TSCA This product has been classified in accordance with the Occupational Safety and Health Administration hazard criteria and the SDS contains all of the information required by OSHA. HCS 2012 All ingredients are listed on the Toxic Substances Control Act CERCLA Super Fund 40CFR Product contains a material with a Reportable Quantity (RQ) Dodecylbenzene sulfonic acid RQ = 1000 Lbs. SARA Title III Section 311&312 SARA Title III Section 313 States Right to Know Immediate (Acute) Health Hazard Ingredients are not subject to the reporting requirements of section 313 of Title III SARA. Reportable chemicals: Dodecylbenzene sulfonic acid, Sodium hydroxide California Proposition 65 This product contains chemicals known to the state of California to cause cancer : Sodium sulfate <0.02%, Inventory Status Countries Inventory Name On Inventory (Yes/No)* U.S. CIL Yes Canada DSL Yes A Yes indicates that all of the components of this product comply with the inventory requirements administered by the governing country(s) listed. HMIS RATING HMIS Legend 16. Other Information Severe 4 Health 1Health3Health- Serious 3 Flammability 0 FlammabilityF Moderate 2 Reactivity 0 Slight 1 Personal Protection 0 Minimal 0 3/7/2015 Page 5 of 6

6 Disclaimer To the best of our knowledge, the information included herein is accurate. However, neither the above named supplier nor any of its subsidiaries assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Issue date March 7, 2015 Supersedes date Previous issues Reason for update Conform to GHS OSHA HCS 2012 Expiration date March 7, /7/2015 Page 6 of 6