Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Issuing Date: 06Sep2012 Revision Date: 06Sep2012 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product ID: Product Name Product Type Recommended use Uses advised against Synyms Manufacturer Address Emergency telephone Emergency Overview OSHA Regulatory Status WHMIS Principle Routes of Exposure The Art of Shaving After Shave Gel Ocean Kelp Finished Product Consumer (Retail) and Professional Use Personal Beauty Care Product All other uses The Art of Shaving After Shave Gel Madison * The Art of Shaving Post Shave Balm Ocean Kelp * The Art of Shaving Post Shave Balm Madison The Procter & Gamble Company Sharon Woods Invation Center Reed Hartman Highway Cincinnati OH pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARDS IDENTIFICATION Consumer Products as defined by the U.S. Consumer Product Safety Act which are used as intended (typical consumer duration and frequency) are exempt from the OSHA Hazard Communication Standard. When used in a professional setting (at a much higher frequency and duration than a typical consumer) this material would NOT be considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Not subject to WHMIS classification None reasonably foreseeable. General Hazards This is a personal care or cosmetic product that is safe for consumers and other users under rmal and reasonably foreseeable use Page 1 / 8

2 The Art of Shaving After Shave Gel Ocean Kelp Revision Date: 06Sep COMPOSITION/INFORMATION ON INGREDIENTS CASNo Weight % 1,2,3Propanetriol Pyridinecarboxamide Methyl2,4pentandiol (Hexylene glycol) FIRST AID MEASURES General advice Eye contact Skin contact Ingestion Inhalation Protection of Firstaiders Most important symptoms/effects, acute and delayed Notes to physician No hazards which require special first aid measures. When symptoms persist or in all cases of doubt seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. If skin problems occur, discontinue use. If symptoms persist, call a physician. Clean mouth with water and afterwards drink plenty of water. Not an expected route of exposure. Use personal protective equipment. None kwn. Treat symptomatically. 5. FIREFIGHTING MEASURES Flash Point Suitable Extinguishing Media Unsuitable Extinguishing Media Special Hazard Special protective equipment for firefighters Not applicable Dry chemical, CO 2, water spray or alcoholresistant foam.. None kwn based on information supplied As in any fire, wear selfcontained breathing apparatus and full protective gear. Page 2 / 8

3 The Art of Shaving After Shave Gel Ocean Kelp Revision Date: 06Sep ACCIDENTAL RELEASE MEASURES Personal precautions Advice for emergency responders Environmental precautions Methods for Containment Methods for Cleaning up None under rmal use conditions. Use personal protective equipment. Should t be released into the environment HANDLING AND STORAGE Advice on safe handling Technical measures/storage conditions Keep out of the reach of children. Observe label precautions. Keep out of the reach of children. 8. EPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines ACGIH TLV OSHA PEL NIOSH IDLH P&G OEL Mexico OEL 1,2,3Propanetriol TWA: 10 mg/m 3 mist TWA: 15 mg/m 3 mist, Mexico: TWA 10 total particulate TWA: mg/m 3 5 mg/m 3 mist, respirable fraction (vacated) TWA: 10 mg/m 3 mist, total particulate (vacated) TWA: 5 mg/m 3 mist, respirable fraction 2Methyl2,4pentandiol Ceiling: 25 ppm (vacated) Ceiling: 25 Ceiling: 25 ppm Mexico: Ceiling 25 (Hexylene glycol) ppm (vacated) Ceiling: Ceiling: 125 mg/m 3 ppm Mexico: Ceiling 125 mg/m mg/m 3 Alberta Quebec Ontario TWAEV British Columbia 1,2,3Propanetriol TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 3 2Methyl2,4pentandiol (Hexylene glycol) mg/m 3 Ceiling: 25 ppm Ceiling: 121 mg/m 3 Ceiling: 25 ppm Ceiling: 121 mg/m 3 CEV: 25 ppm Ceiling: 25 ppm Engineering Measures Not applicable. Personal Protective Equipment Eye Protection Hand Protection Skin and body protection Respiratory protection Thermal hazards Hygiene measures No special protective equipment required. No special protective equipment required. No special protective equipment required. No special protective equipment required Not applicable. None under rmal use condtions. Page 3 / 8

4 The Art of Shaving After Shave Gel Ocean Kelp Revision Date: 06Sep2012 Environmental Exposure Controls See Section PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor liquid viscous liquid. orange Property Values Note ph VALUE Melting/freezing point Boiling point/boiling range Flash Point Not applicable Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor pressure Vapor density Relative density Water solubility Soluble in water Solubility in other solvents Partition coefficient: noctal/water Autoignition temperature. Decomposition temperature. Viscosity of Product Bulk Density log Pow 1,2,3Propanetriol Methyl2,4pentandiol (Hexylene glycol) <0.14 VOC Content Not applicable 10. STABILITY AND REACTIVITY Reactivity Stability Hazardous Polymerization Hazardous Reactions Conditions to Avoid Materials to Avoid None under rmal use conditions. Stable under rmal conditions. Hazardous polymerization does t occur. None under rmal processing. None under rmal processing. None in particular. Hazardous Decomposition Products None under rmal use. Page 4 / 8

5 The Art of Shaving After Shave Gel Ocean Kelp Revision Date: 06Sep2012 Product Information 11. TOICOLOGICAL INFORMATION Acute Toxicity Inhalation Skin contact Ingestion Eye contact Product does t present an acute toxicity hazard based on kwn or supplied information. No kwn effect based on information supplied. No kwn effect based on information supplied. No kwn effect based on information supplied. No kwn effect based on information supplied. LD50 Oral LD50 Dermal LC50 Inhalation 1,2,3Propanetriol mg/kg (rat) mg/kg ( Rat ) 3Pyridinecarboxamide 3500 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2Methyl2,4pentandiol (Hexylene glycol) 3692 mg/kg ( Rat ) 8560 µl/kg ( Rabbit ) 310 mg/m 3 ( Rat ) 1 h Chronic Toxicity Corrosivity Sensitization Neurological Effects Reproductive Toxicity Mutagenic Effects Developmental Toxicity Teratogenicity Carcigenicity No kwn effect. No kwn effect. No kwn effect. The product contains substances kwn to be hazardous to health in concentrations which need to be taken into account. There are kwn mutagenic chemicals in this product. No kwn effect. No kwn effect. Contains ingredients above reportable quantities listed as a carcigen. Page 5 / 8

6 The Art of Shaving After Shave Gel Ocean Kelp Revision Date: 06Sep2012 Ecotoxicity 12. ECOLOGICAL INFORMATION Acute Toxicity Toxicity to algae Toxicity to fish 1,2,3Propanetriol LC50 96 h ml/l Oncorhynchus mykiss static 3Pyridinecarboxamide LC50 96 h > 1000 mg/l Poecilia reticulata static 2Methyl2,4pentandiol (Hexylene glycol) LC50 96 h mg/l Pimephales promelas flowthrough LC50 96 h = mg/l Lepomis macrochirus static LC50 96 h = 8690 mg/l Pimephales promelas flowthrough LC50 96 h = mg/l Pimephales promelas static Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates EC50 24 h > 500 mg/l Daphnia magna EC50 24 h > 1000 mg/l Daphnia magna EC50 48 h mg/l Daphnia magna Toxicity to other organisms Persistence and degradability Bioaccumulative potential.. Mobility. Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste from Residues / Unused Products Contaminated packaging California Hazardous Waste Codes (nhousehold setting) Dispose of in accordance with local regulations. Dispose of in accordance with local regulations TRANSPORT INFORMATION DOT TDG Page 6 / 8

7 The Art of Shaving After Shave Gel Ocean Kelp Revision Date: 06Sep2012 ME IATA ICAO IMDG/IMO U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: CASNo Weight % SARA 313 Threshold Values % 2Phexyethal SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard CERCLA This material, as supplied, does t contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following substance(s) which are either listed as hazardous air pollutants (HAPS) or VOC's per the Clean Air Act: Volatile Organic Compounds CAA (Clean Air Act) 1990 Hazardous Air Pollutants 2Phexyethal Present Clean Water Act This product does t contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). U.S. State Regulations California Proposition 65 This product is t subject to warning labeling under California Proposition 65 1,2,3Propanetriol 2Methyl2,4pentandiol (Hexylene glycol) New Jersey Massachusetts 1,2,3Propanetriol 2Methyl2,4pentandiol (Hexylene glycol) Page 7 / 8

8 The Art of Shaving After Shave Gel Ocean Kelp Revision Date: 06Sep2012 1,2,3Propanetriol 2Methyl2,4pentandiol (Hexylene glycol) 2Phexyethal Pennsylvania International Regulations Canada WHMIS Hazard Class Not subject to WHMIS classification This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of Health Canada and is therefore exempt from the requirements of CEPA. International Inventories TSCA Product is a personal care product and regulated under FDA DSL Exempt NDSL Exempt Perfumes contained with the products comply with appropriate IFRA guidance. Legend TSCA United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL Canadian Domestic Substances List/NonDomestic Substances List 16. OTHER INFORMATION Issuing Date: Revision Date: 06Sep Sep2012 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our kwledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is t to be considered a warranty or quality specification. The information relates only to the specific material designated and may t be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 8 / 8