Report Date : 03/06/2013 1 / 9 SAFETY DATA SHEET WILLIAMS F1 LIQUID POLISH SDS No. 101614 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name WILLIAMS F1 LIQUID POLISH Product No. 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Vehicle Cleaner 1.3. Details of the supplier of the safety data sheet Supplier Assured Products Limited Sharston House Fortyfoot Road Leatherhead Surrey KT22 8RN +44 (0)844 879 7504 (Mon - Fri 8am to 5pm) info@assured-products.co.uk 1.4. Emergency telephone number +44 (0)844 879 7504 (Mon - Fri 8am to 5pm) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) 2.2. Label elements Risk Phrases Safety Phrases NC S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S37/39 Wear suitable gloves and eye/face protection. Contains 5-15% Aliphatic hydrocarbon < 5% Non-ionic surfactants. Perfume Preservative CIT/MIT/TMAD SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures
Report Date : 03/06/2013 2 / 9 1,2,3-Propanetriol < 1 CAS-No.: 56-81-5 Aliphatic cycloparaffinic hydrocarbon 5-15 CAS-No.: 64742-47-8 265-149-8 EUH066 Asp. Tox. 1 - H304 Xn;R65. R66. Amyl Salicylate-N < 0.01 CAS-No.: 2050-08-0 218-080-2 Aquatic Chronic 2 - H411 N;R51/53. COCONUT DIETHANOLAMIDE < 1 CAS-No.: 68603-42-9 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Xi;R38 R41 DIETHANOLAMINE < 0.01 CAS-No.: 111-42-2 203-868-0 Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Xn;R22,R48/22 Xi;R38,R41
Report Date : 03/06/2013 3 / 9 DIMETHYLPOLYSILOXANE 1-5 CAS-No.: METHYL-2H or METHYL-4 (3:1) Mixture of EC NO 220-239-6 < 1 CAS-No.: 55965-84-9 Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 3 - H331 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 T;R23/24/25 C;R34 R43 MUSCOMER S900P < 0.01 Eye Irrit. 2 - H319 Xi;R36. C 9-11 Alcohol Ethoxylate 2.5-5 moles EO < 1 CAS-No.: 68439-46-3 Eye Dam 1 - H318 Xi;R41 C 9-11 Alcohol Ethoxylate 6 8 moles EO < 1 CAS-No.: 68439-45-2 Acute Tox. 4 - H302 Eye Dam. 1 - H318 Xn;R22. Xi;R41.
Report Date : 03/06/2013 4 / 9 TERPINOLENE RECT < 0.01 CAS-No.: 586-62-9 209-578-0 Flam. Liq. 3 - H226 Asp. Tox. 1 - H304 Xn;R65. N;R51/53. XANTHAN GUM < 1 CAS-No.: 11138-66-2 234-394-2 Not classified Not classified The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion Do not induce vomiting. Rinse mouth thoroughly. Drink a few glasses of water or milk. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues. 4.2. Most important symptoms and effects, both acute and delayed Inhalation. Prolonged or repeated exposure may cause lung inflammation. Ingestion Risk of severe pulmonary problems in case of accidental aspiration. Stomach pain and nausea. Diarrhoea. Main danger is lung damage by aspiration. Skin contact Repeated or prolonged exposure can cause dryness and cracking. Prolonged or repeated skin contact may cause dermatitis. Eye contact May cause temporary eye irritation. Burning feeling and temporary redness. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media
Report Date : 03/06/2013 5 / 9 Extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide or dry powder. 5.2. Special hazards arising from the substance or mixture Hazardous combustion products In combustion, emit toxic fumes. 5.3. Advice for firefighters Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of spray mist and contact with skin and eyes. Exclude sources of ignition and ventilate the area. Spillages will give slippery surfaces, to avoid accidents they should be contained with sand or sawdust. 6.2. Environmental precautions Do not allow to enter drains, sewers or watercourses. 6.3. Methods and material for containment and cleaning up Ventilate well. Dam and absorb spillages with sand, earth or other non-combustible material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. 6.4. Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Avoid inhalation of vapours. 7.2. Conditions for safe storage, including any incompatibilities Protect from light, including direct sunrays. Store in tightly closed original container in a dry, cool and well-ventilated place. Must only be kept in the original packaging. If repackaging is required, ensure that the new container is compatible with this product. 7.3. Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes 1,2,3-Propanetriol Aliphatic cycloparaffinic hydrocarbon 10 mg/m3 30 mg/m3 1000 mg/m3 8.2. Exposure controls Protective equipment
Report Date : 03/06/2013 6 / 9 Engineering measures Provide adequate ventilation. Respiratory equipment Self-contained breathing apparatus should be available in the case of emergency. Hand protection Hydrocarbon proof gloves for aromatic hydrocarbon. Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures Wash hands at the end of each work shift and before eating, smoking and using the toilet. Skin protection As necessary to prevent contact SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Emulsion. Colour Milky. Odour Kerosene. Solubility Emulsible in water. Relative density 0.98 @ 20 C Viscosity Slightly viscous 9.2. Other information SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity 10.2. Chemical stability Stable under normal temperature conditions and recommended use. 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight. 10.5. Incompatible materials Materials To Avoid Strong oxidising agents 10.6. Hazardous decomposition products Emit toxic fumes under fire conditions
Report Date : 03/06/2013 7 / 9 SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Inhalation Prolonged inhalation of mists may cause lung inflammation. Ingestion Harmful: may cause lung damage if swallowed. May also cause nausea Diarrhoea. Main danger is of lung damage by aspiration If swallowed, or in case of vomiting, hazard of entering the lungs. Skin contact Repeated exposure may cause skin dryness or cracking. Defatting action of hydocarbon solvents may lead to dermatitis. Eye contact May cause temporary eye irritation. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 12.1. Toxicity 12.2. Persistence and degradability Degradability The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. 12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION
Report Date : 03/06/2013 8 / 9 General Road Transport Notes The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID). Not Classified Rail Transport Notes Sea Transport Notes 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) 14.4. Packing group 14.5. Environmental hazards 14.6. Special precautions for user 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Environmental Protection (Duty of Care ) Regulations 1991 Special Waste Regulations 1996 (as amended) EH40/2002 Registry of Toxic Effects of Chemical Substances Suppliers' Safety Data Sheets Carriage of Dangerous Goods by Road and Rail Regulations 1994 Control of Pollution (Special Waste) Regulations 1980 Approved Carriage list (3rd ed) Approved Classification and Labelling Guide (5th Ed) The compilation of safety data sheets ACoP (3rd Ed) Approved Supply List (8th Ed) List of Wastes (England) Regulations 2005 (SI 2005 No 895) The Carriage of Dangerous Goods by Road Regulations 1996 Dangerous Substances (Notification and Marking of sites) Regulations 1990 Management of Health & Safety at Work Regulations 1999 Detergent regulation (EC) No.648/2004 CLP Regulation 1272/2008 Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation European Council Directive 1999/13/EC("Solvents Emissions Directive") Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1997/2006 of the European Parliament and of the Council on the Registration, Authorisation and Restriction of Chemicals (REACH) 15.2. Chemical Safety Assessment SECTION 16: OTHER INFORMATION General information Preservative used: Mixture of Tetramethylol acetylene diurea(cas5395-50-6) and isothiazolone(cas55965-84-7) at non hazardous concentration. Issued By BRETT BRIDGETT
Report Date : 03/06/2013 9 / 9 Safety Data Sheet Status Approved. Date April 2013 Risk Phrases In Full R34 R10 R22 R48/22 R65 R36 R38 R43 NC R66 R41 R23/24/25 R51/53 R50/53 Hazard Statements In Full H318 H319 H314 H315 H226 H302 H304 H317 H373 EUH066 H331 H301 H311 H411 H410 H400 Causes burns. Flammable. Harmful if swallowed. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Harmful: may cause lung damage if swallowed. Irritating to eyes. Irritating to skin. May cause sensitisation by skin contact. Repeated exposure may cause skin dryness or cracking. Risk of serious damage to eyes. Toxic by inhalation, in contact with skin and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Causes serious eye damage. Causes serious eye irritation. Causes severe skin burns and eye damage. Causes skin irritation. Flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause damage to organs <<Organs>> through prolonged or repeated exposure. Repeated exposure may cause skin dryness or cracking. Toxic if inhaled. Toxic if swallowed. Toxic in contact with skin. Toxic to aquatic life with long lasting effects. Very toxic to aquatic life with long lasting effects. Very toxic to aquatic life. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.