Cellini Colors. Color Pigments for Color Cosmetics and Personal Care Products. Technical Information

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Cellini Colors Color Pigments for Color Cosmetics and Personal Care Products Technical Information November 2016

Cellini Colors Cellini colors were the first line of cosmetic effect pigments that combined clean and intense FDA approved organic colors with pearlescent effect enhancing pigments. They are especially easy to work with because the colorant is predispersed, and because they contain a wetting agent that makes them hydrophobic. Cellini colors offer a novel, luminescent look that adds brightness and depth to a broad range of cosmetics, especially lip, face, and eye products. In eye shadows, they give more intense shades than have been available before. Also, the Cellini Blue grade is the first absorption blue pearl that can be used in lip area products in the U.S. As value added colorants, Cellini colors can make cosmetic production easier. The predispersed organic pigment can help manufacturers avoid the sometimes arduous task of grinding, deagglomerating and dispersing standalone organic colorants. In addition, the presence of a wetting agent may allow manufacturers to eliminate many of the process steps needed to create hydrophobic surfaces. The wetting agent in Cellini colors also tends to reduce colorant bleed in aqueous systems. This agent can also improve performance in wet/dry applications and makes Cellini colors especially effective in powders, lipsticks, and other anhydrous applications. Four of the five Cellini grades (Blue, Yellow, Green and Coral) are designated for broad application in the U.S., including eye area applications. Cellini Red was created for eye-area cosmetics in Japan, however it is not allowed for eyearea use in the U.S. Cellini Colors Typical Properties CELLINI GRADE* COLORANT COMPONENT PARTICLE SIZE (μm) RANGE** DENSITY (kg/l) APPROX. BULK DENSITY**** lb/ft 3 g/100cm 3 Yellow 220CY5F Yellow 5 Lake 95% between 6-48 μm *** 16 26 Red 420CR7F Red 7 Lake 95% between 6-48 μm *** 16 26 Coral 420CR40F Red 40 Lake 95% between 6-48 μm *** 16 26 Blue 620CB1C Blue 1 Lake 95% between 6-48 μm *** 16 26 Green 820CGBYF Yellow 5 Lake and Blue 1 Lake 95% between 6-48 μm *** 16 26 * Please refer to individual product specification sheets for certifiable product specifications ** The particle size results will vary depending on the light scattering instrument used. The values listed (as % by weight) are the results using a Malvern Mastersizer *** due to hydrophobic wetting agent, density is not tested **** Determined by ASTM Method D-716-86 Cellini Colors Page 2 November 2016

Applications Formulating Guidelines Red 40 Lake, found in Cellini Coral, is not approved for use in Japan, while Red 7 Lake, found in Cellini Red, is not approved for eye applications in the U.S. All other Cellini Colors are approved under conditions normally encountered in cosmetic and personal care formulation, production, and use. However, all grades should be tested in potential formulations before commercialization in order to determine if performance will be acceptable. Since regulations change over time, we recommend that appropriate use of each colorant be confirmed against each region s current cosmetic regulations. Physical and Chemical Properties Solubility Cellini color pigments are composed of both inorganic and organic components. The organic colorants present may become soluble in certain formulations. The potential for organic colorant bleed should be a part of the stability protocol for these grades. Please note that these pigments are hydrophobic and may not disperse in water. ph Specifications Due to the presence of the hydrophobic wetting agent, the ph of these pigments is not tested. For product specifications, refer to the respective specification sheet (separate document) for each Cellini product. The color additive components in the products identified in this data sheet meet the applicable FDA (21 CFR Part 73), EU Cosmetic Regulation EC/1223/2009 (Annex IV, including EC-231-2012 requirements), Japan MHW, Korean Cosmetics Colorants Standard, and China s Cosmetic Safety and Technical Standard (2015 version) specifications and purity requirements. Microbial status for Cellini products: Total aerobic bacteria <100 CFU/g max. Yeast & mold <100 CFU/g max. Gram-negative bacteria absent in 10g E. coli absent in 10g Pseudomonas aeruginosa absent in 10g Staphylococcus aureus absent in 10g Storage Safety Data Sheet Cellini color pigments have storage stability of at least 10 years from the date of manufacture, provided that they are stored in unopened original containers, protected from light, and under normal conditions of temperature and humidity. A Safety Data Sheet for each Cellini pigment is available. Cellini Colors Page 3 November 2016

Further Product Ranges Bi-Lite Bismuth Oxychloride/Mica Pigments Cellini Colors Chione Pigments Chroma-Lite Colors Cloisonné Colors Duocrome Iridescent Colors Flamenco Pearlescent and Iridescent Pigments Gemtone Colors Mearlite and Biju Ultra Bismuth Oxychloride Pigments Mearlmica Specialty Performance Mica MultiReflections Iridescent Pigments Pearl-Glo Bismuth Oxychloride Pigments Reflecks Pearlescent and Iridescent Pigments and Colors Reflecks Dimensions Pearlescent and Iridescent Pigments and Colors Reflecks MultiDimensions Color Changing Pigments Timica Luster Pigments Appendix Cellini Product Compositions Component By Weight CI No. CAS No. EINECS No. Cellini Yellow 220CY5F - INCI Name: Mica (and) Titanium Dioxide (and) Yellow 5 Lake (and) Hydrogenated Mica 41 50 % 77019 12001-26-2 310-127-6 TiO 2 22 32 % 77891 13463-67-7 236-675-5 FD&C Yellow 5 Aluminum Lake 19 23 % 19140:1 12225-21-7 235-428-9 Cellini Red 420CR7F - INCI Name: Mica (and) Titanium Dioxide (and) Red 7 Lake (and) Hydrogenated Mica 37 52 % 77019 12001-26-2 310-127-6 TiO 2 29 43 % 77891 13463-67-7 236-675-5 D&C Red 7 Calcium Lake 12 14 % 15850:1 5281-04-9 n.a. Cellini Coral 420CR40F - INCI Name: Mica (and) Titanium Dioxide (and) Red 40 Lake (and) Hydrogenated Mica 37 52 % 77019 12001-26-2 310-127-6 TiO 2 29 43 % 77891 13463-67-7 236-675-5 FD&C Red 40 Aluminum Lake 12 14 % 16035:1 68583-95-9 271-524-7 Cellini Colors Page 4 November 2016

Appendix Cellini Product Compositions Component By Weight CI No. CAS No. EINECS No. Cellini Blue 620CB1C - INCI Name: Mica (and) Titanium Dioxide (and) Blue 1 Lake (and) Hydrogenated Mica 33 43 % 77019 12001-26-2 310-127-6 TiO 2 29 40 % 77891 13463-67-7 236-675-5 FD&C Blue 1 Aluminum Lake 19 23 % 42090:2 68921-42-6 272-939-6 Cellini Green 820CGBYF - INCI Name: Mica (and) Titanium Dioxide (and) Blue 1 Lake (and) Yellow 5 Lake (and) Hydrogenated Mica 23 39 % 77019 12001-26-2 310-127-6 TiO 2 29 39 % 77891 13463-67-7 236-675-5 FD&C Blue 1 Aluminum Lake 19 23 % 42090:2 68291-42-6 272-939-6 FD&C Yellow 5 Aluminum Lake 9 12 % 19140:1 12225-21-7 235-428-9 Product Range Product PRD-No. Cellini Yellow 220CY5F 30501548 Cellini Red 420CR7F 30501554 Cellini Coral 420CR40F 30501553 Cellini Blue 620CB1C 30501567 Cellini Green 820CGBYF 30501569 Cellini Yellow 220CY5F 30501548 Cellini Colors Page 5 November 2016

Contacts Asia Pacific North America BASF Colors & Effects Shanghai Ltd. BASF Colors & Effects USA LLC No 300, Jiang Xin Sha Road 24710 West Eleven Mile Road 200137 Shanghai Southfield, MI 48034 China USA Europe South America BASF Colors & Effects GmbH BASF S/A An der Rheinschanze 1 Av. das Nações Unidas, 14171 67059 Ludwigshafen Crystal Tower 11 th floor, Germany Morumbi 04538-132, São Paulo Brazil Visit our website: www.colors-effects.basf.com This document, or any answers or information provided herein by BASF, does not constitute a legally binding obligation of BASF. While the descriptions, designs, data and information contained herein are presented in good faith and believed to be accurate, it is provided for your guidance only. Because many factors may affect processing or application/use, we recommend that you make tests to determine the suitability of a product for your particular purpose prior to use. It does not relieve our customers from the obligation to perform a full inspection of the products upon delivery or any other obligation.no WARRANTIES OF ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. = Registered trademark of BASF = Trademark of BASF Cellini Colors Page 6 November 2016