MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product Name CAS # Product Use Distributed by LYSOL Gel Bathroom Cleaner Mixture This MSDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the Canadian Workplace Hazardous Materials Information System (WHMIS). This MSDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation. Bathroom cleaner Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue Unit #2 Mississauga, ON L4W 5S9 In Case of Emergency: 1-800-338-6167 Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887 LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 HEALTH / 2 FLAMMABILITY 0 PHYSICAL HAZARD 0 PERSONAL PROTECTION B 0 2 0 2. Hazards Identification Emergency Overview CAUTION MAY IRRITATE EYES. DO NOT get in eyes. Keep out of reach of children. Potential short term health effects Routes of exposure Eye, Skin contact,, Ingestion. Eyes May cause eye irritation. Skin Non-irritating to the skin. For sensitive skin or prolonged use, wear rubber gloves. Not expected to be a skin sensitizer. None expected during normal conditions of use. Ingestion May be harmful if swallowed. Target organs Skin. Eyes. Chronic effects Signs and symptoms Symptoms may include redness, oedema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. 3. Composition/Information on Ingredients Components CAS # Percent 2-Propanol, 1-butoxy- 5131-66-8 1-5 Citric acid Hydroxyacetic acid 77-92-9 1-5 79-14-1 1-5 #20454 Page: 1 of 7 Issue date 05-September-2013
Components CAS # Percent Sulfonated sodium salts, propylene derivatives Alcohols, C6-10, ethoxylated propoxylated 119345-04-9 1-5 68987-81-5 0.5-1.5 4. First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice In case of eye contact, IMMEDIATELY rinse eyes thoroughly with plenty of water. Remove any contact lenses and continue rinsing eyes for at least 15 minutes. Get medical attention if irritation occurs. If on skin, rinse well with water. If symptoms develop or persist seek medical advice. Move to fresh air. If swallowed, call a Poison Control Centre or doctor immediately. DO NOT induce vomiting. Rinse mouth with water. NEVER give an unconscious person anything to ingest. Treat patient symptomatically. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighers Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Not flammable by WHMIS criteria. Treat for surrounding material. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Do not discharge into lakes, streams, ponds or public waters. Advise authorities if product has penetrated drains, sewers or water pipes. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. #20454 Page: 2 of 7 Issue date 05-September-2013
7. Handling and Storage Handling Storage Exposure limit values Engineering controls Personal protective equipment Eye/Face protection Eye / face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations Appearance Colour Form Odour Odour threshold Physical state ph Freezing point Boiling point Pour point Evaporation e Flash point Auto-ignition temperature Flammability Limits in Air, Upper, % by Volume Flammability Limits in Air, Lower, % by Volume Ensure adequate ventilation. Avoid contact with eyes, skin and clothing. Read label before using product. Do not use or mix with other cleaners. Use good industrial hygiene practices in handling this material. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. NOTE: DO NOT use on natural marble. Keep container tightly closed. Store in a cool dry place inaccessible to children and pets. 8. Exposure Controls/Personal Protection Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH. General ventilation normally adequate. Consult the product label for special protection or precautions that have been identified for using this product under directed consumer use conditions. The following recommendations are given for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure. Avoid contact with eyes. Wear safety glasses with side shields. Emergency responders should wear full eye and face protection. No special requirements under normal use conditions. For sensitive skin or prolonged use, wear rubber gloves. Emergency responders should wear impermeable gloves. As required by employer code. Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible. Not normally required under normal use conditions. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of vapours generated by this product during a spill or other clean-up operations. Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact. Clear Green Gel Characteristic Liquid. 2 (Acidic) 9. Physical and Chemical Properties > 93.30 C (> 199.94 F) Tagliabue #20454 Page: 3 of 7 Issue date 05-September-2013
Vapour pressure Vapour density Specific gravity 1.015 (Water = 1) Partition coefficient (n-octanol/water) Solubility (Water) Complete Relative density Viscosity VOC Percent volatile Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products 10. Stability and Reactivity Reacts vigorously with alkaline material. Hazardous polymerisation does not occur. Stable under recommended storage conditions. DO NOT MIX WITH BLEACH or use in conjunction with other household products. Excessive heat. Exposure to moisture. Caustics. May include and are not limited to: Oxides of carbon. 11. Toxicological Information Toxicological data Components Species 2-Propanol, 1-butoxy- (CAS 5131-66-8) Dermal Rabbit Alcohols, C6-10, ethoxylated propoxylated (CAS 68987-81-5) Dermal Rabbit Citric acid (CAS 77-92-9) Dermal Rabbit Mouse Test results 3100 mg/kg 3300 mg/kg >= 3000 mg/kg 2745 mg/kg 500 mg/kg 5040 mg/kg 3000 mg/kg #20454 Page: 4 of 7 Issue date 05-September-2013
Components Hydroxyacetic acid (CAS 79-14-1) Species Guinea pig Sulfonated sodium salts, propylene derivatives (CAS 119345-04-9) Test results 7.7 mg/l/4h 1920 mg/kg 1950 mg/kg Effects of acute exposure Eye contact Skin contact Ingestion Sensitisation Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products May cause eye irritation. Non-irritating to the skin. For sensitive skin or prolonged use, wear rubber gloves. Not expected to be a skin sensitizer. None expected during normal conditions of use. May be harmful if swallowed. 12. Ecological Information Ecotoxicity Persistence and degradability Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Hydroxyacetic acid -1.11 Chemical fate information 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations. Do not reuse container. Rinse container and offer for recycling where facilities exist. Empty container can be disposed of as household trash or rinsed and recycled where appropriate. #20454 Page: 5 of 7 Issue date 05-September-2013
. 14. Transport Information U.S. Department of Transportation (DOT): Classification: Not regulated Proper shipping name U.S. DOT Hazard Class Subsidiary Risk Packing group DOT RQ (lbs) ERG NO Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Status Packing group IMDG (Marine Transport): Classification: Not regulated Proper shipping name Class Subsidiary Risk Packing group IMDG Page Marine pollutant EMS MFAG Maximum Quantity IATA/ICAO (Air): Classification: Not regulated Proper shipping name Class Subsidiary Risk: Packing group Maximum Quantity 15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Product Registration: Product is compliant with CCCR regulatory guidelines; a specific registration is not required for this product. Canada NPRI VOCs with Additional Reporting Requirements: Mass reporting threshold/identification Number 2-Propanol, 1-butoxy- (CAS 5131-66-8) 1 tonnes Canada WHMIS Ingredient Disclosure: Threshold limits Citric acid (CAS 77-92-9) 1 % Hydroxyacetic acid (CAS 79-14-1) 1 % WHMIS Classification Exempt - Consumer product #20454 Page: 6 of 7 Issue date 05-September-2013
. Inventory Status Country(s) or region Inventory Name On Inventory (Yes/No)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Disclaimer This product should only be used as directed on the label and for the purpose intended. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Further information LYSOL Gel Bathroom Cleaner, 750 ml 368066v3.0 Issue date Effective date Expiry Date 05-September-2013 01-September-2013 01-September-2016 Prepared by Reckitt Benckiser Regulatory Department Phone: 800-333-3899 Other Information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z400.1/Z129.1-2010 Standard. No #20454 Page: 7 of 7 Issue date 05-September-2013