Material Safety Data Sheet Sodium Nitrate, 5.0M. Section 1 - Chemical Product and Company Identification

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An ISO9001 Certified Company Material Safety Data Sheet Section 1 - Chemical Product and Company Identification MSDS Name: Catalog Numbers: LC24665 Synonyms: Adjustor for Chloride Ion Specific Electrodes Company Identification: LabChem Inc 200 William Pitt Way Pittsburgh, PA 15238 Company Phone Number: (412) 826-5230 Emergency Phone Number: (800) 424-9300 CHEMTREC Phone Number: (800) 424-9300 or 011-703-527-3887 Section 2 Composition, Information on Ingredients CAS# Chemical Name: Percent 7631-99-4 Sodium nitrate 43 7732-18-5 Water 57 Section 3 - Hazards Identification Emergency Overview Appearance: clear, colorless solution Warning! Causes serious eye and skin irritation. May cause respiratory tract irritation. Target Organs: None. Potential Health Effects Eye: Causes eye irritation. Causes skin irritation. Ingestion: Ingestion of large amounts may cause gastrointestinal irritation. Inhalation: May cause respiratory tract irritation. Chronic:. - 1 -

Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence of chemical remains. Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: Do not induce vomiting. Give conscious victim 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid at once. Inhalation: Move victim to fresh air immediately. Get medical aid if irritation or other symptoms appear. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Extinguishing Media: Use water only! Autoignition Temperature:. Flash Point:. NFPA Rating: Health- 1, Flammability- 0, Instability- 0 Explosion Limits: Lower: n/a Upper: n/a Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in suitable containers labeled for later disposal. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Avoid inhalation and ingestion. Avoid contact with eyes and skin. - 2 -

Storage: Store capped at room temperature. Protect from heat and incompatibles. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities using or storing this material should be equipped with an eyewash and safety shower. Provide local exhaust or general dilution ventilation. Exposure Limits: Chemical Name: ACGIH NIOSH OSHA Sodium nitrate Water OSHA Vacated PELs: None Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133. Do not wear contact lenses when working with chemicals. Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134. Always use a NIOSH-approved respirator when necessary. Section 9 - Physical and Chemical Properties Physical State: Solid Color: Colorless Odor: Odorless ph: Not available Vapor Pressure: Not available Vapor Density: Not available Evaporation Rate: Not available Viscosity: Not available Boiling Point: Not available Freezing/Melting Point: Not available Decomposition Temperature: Not available Solubility in water: Soluble Specific Gravity/Density: Not available Molecular Formula: NaNO3 Molecular Weight: 84.99-3 -

Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizable materials, including antimony, cyanides, sodium hypophosphite, powdered aluminum or aluminum oxide, sodium thiosulfate, metal sulfides, sodium acetate, fluorine, zinc, and trichloroethylene. Hazardous Decomposition Products: Oxides of nitrogen. Hazardous Polymerization: Has not been reported Section 11 - Toxicological Information RTECS: CAS# 7631-99-4: WC5600000 CAS# 7732-18-5: ZC0110000 LD50/LC50: CAS# 7631-99-4: Oral, rabbit: LD50 = 2680 mg/kg Oral, rat: LD50 = 1267 mg/kg CAS# 7732-18-5: Oral, rat: LD50 = >90 ml/kg Carcinogenicity: CAS# 7631-99-4: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. Epidemiology: Teratogenicity: Reproductive: Mutagenicity: Neurotoxicity: Section 12 - Ecological Information Ecotoxicity: This material will not cause oxygen depletion in aquatic systems. It has a low potential to affect aquatic organisms, secondary waste treatment microorganisms, and the growth of some plants. It has a moderate potential to affect the germination of some plants. - 4 -

Section 13 - Disposal Considerations Dispose of in accordance with Federal, State, and local regulations. US DOT Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: Section 14 - Transport Information Section 15 - Regulatory Information US Federal TSCA: CAS# 7631-99-4 is listed on the TSCA Inventory. CAS# 7732-18-5 is listed on the TSCA Inventory. SARA Reportable Quantities (RQ):. CERCLA/SARA Section 313:. OSHA - Highly Hazardous:. US State State Right to Know: Sodium nitrate can be found on the following state Right-to-Know lists: New Jersey, Florida, Pennsylvania, Massachusetts. California Regulations: None European/International Regulations Canadian DSL/NDSL: CAS# 7631-99-4 is listed on the Canadian Domestic Substances List. CAS# 7732-18-5 is listed on the Canadian Domestic Substances List. Canada Ingredient Disclosure List: CAS# 7631-99-4 is listed on the Canadian Ingredient Disclosure List. CAS# 7732-18-5 is not listed on the Canadian Ingredient Disclosure List. Section 16 - Other Information MSDS Creation Date: April 11, 1999 Revision Date: February 21, 2013 Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application. - 5 -