Page: 1 Compilation date: 12/03/14 Revision No: 5 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: Product code: Synonyms: MITRE BONDER KIT ADHESIVE D512 SUPER GLUE ETHYL-2-CYANOACRYLATE ESTER 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of substance / mixture: Cyanoacrylate adhesive 1.3. Details of the supplier of the safety data sheet Company name: Tel: Fax: Email: Delta Adhesives Limited Units 39-40 Claycliffe Business Park Cannon Way Barugh Green Barnsley, South Yorkshire S75 1JU +44 (0) 1226 381 571 +44 (0) 1226 381 722 info@delta-adhesives.co.uk 1.4. Emergency telephone number Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CHIP: Classification under CLP: Most important adverse effects: Xi: R36/37/38 STOT SE 3: H335; Eye Irrit. 2: H319; Skin Irrit. 2: H315; -: EUH202 Irritating to eyes, respiratory system and skin. 2.2. Label elements Label elements under CLP: Hazard statements: Signal words: Hazard pictograms: H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. EUH202: Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Warning GHS07: Exclamation mark
Page: 2 Precautionary statements: Label elements under CHIP: Hazard symbols: P261: Avoid breathing vapours. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor if you feel unwell. Irritant. Risk phrases: Safety phrases: Precautionary phrases: R36/37/38: Irritating to eyes, respiratory system and skin. S2: Keep out of the reach of children. S46: If swallowed, seek medical advice immediately and show this container or label. Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. 2.3. Other hazards PBT: This substance is not identified as a PBT substance. Section 3: Composition/information on ingredients 3.2. Mixtures Hazardous ingredients: ETHYL-2-CYANOACRYLATE EINECS CAS CHIP Classification CLP Classification Percent 230-391-5 7085-85-0 Xi: R36/37/38 Eye Irrit. 2: H319; STOT SE 3: H335; Skin Irrit. 2: H315 75-90% Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water. Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in warm soapy water. Cyanoacrylate gives off heat on solidification. In rare cases a large drop will generate enough heat to burn. Burns should be treated normally after the
Eye contact: Ingestion: Inhalation: SAFETY DATA SHEET Page: 3 adhesive has been removed from the skin. If lips are accidentally stuck together apply warm water to the lips and encourage maximum wetting. Peel or roll lips apart. Do not try to pull the lips apart with direct opposing action. Bathe the eye with running water for 15 minutes. If the eye is bonded closed, release eyelashes with warm water by covering with wet pad. Cyanoacrylate will bond to eye protein and will cause periods of weeping which will help to debond the adhesive. Keep eye covered until debonding is complete. Do not force eye open. Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause any abrasive damage. Wash out mouth with water. Ensure that breathing passages are not obstructed. The product will polymerise immediately in the mouth making it almost impossible to swallow. Saliva will slowly seperate the solidified product from the mouth (several hours). Consult a doctor. Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed Skin contact: There may be irritation and redness at the site of contact. Eye contact: Cyanoacrylate will bond to eye protein and will cause periods of weeping which will help to debond the adhesive. In adry atmosphere,,50% RH, vapours may cause irritation and lachrymatory effect. Ingestion: Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000 mg/kg (rat). It is almost impossible to swallow as it rapidly polymerises in the mouth. Inhalation: In dry atmospheres with <50% humidity, vapours may irritate the eyes and respiratory system. Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals. Delayed / immediate effects: Immediate effects can be expected after short-term exposure. 4.3. Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Eye bathing equipment should be available on the premises. Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Use foam, Carbon Dioxide or dry powder as extinguishing media. 5.2. Special hazards arising from the substance or mixture Exposure hazards: In combustion emits toxic fumes. 5.3. Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Page: 4 Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Ensure adequate ventilation Do not use cloths for mopping up. 6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. 6.3. Methods and material for containment and cleaning up Clean-up procedures: Polymerise with water and scrape off floor. 6.4. Reference to other sections Reference to other sections: Refer to section 8 of SDS. Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Suitable packaging: For optimum shelf life product should be stored in original containers at 2-8 deg C Must only be kept in original packaging. 7.3. Specific end use(s) Section 8: Exposure controls/personal protection 8.1. Control parameters Hazardous ingredients: ETHYL-2-CYANOACRYLATE Workplace exposure limits: Respirable dust State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL UK - 1.5 mg/m3 - - 8.2. Exposure controls Engineering measures: Respiratory protection: Hand protection: Eye protection: Skin protection: Ensure there is exhaust ventilation of the area. Not applicable. Polyethylene or polypropylene gloves are recommended when using large volumes. Do not use PVC, Rubber, Nylon or Cotton gloves. Safety glasses. Ensure eye bath is to hand. Protective clothing.
Page: 5 Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Colour: Odour: Solubility in water: Also soluble in: Liquid Colourless Sharp characteristic odour. Insoluble Acetone. (Completely soluble) Boiling point/range C: 150 Flash point C: 85 Vapour pressure: 0.293 mmhg Relative density: 1.04 9.2. Other information Other information: Not applicable. Section 10: Stability and reactivity 10.1. Reactivity Reactivity: Stable under recommended transport or storage conditions. 10.2. Chemical stability Chemical stability: Stable under normal conditions. 10.3. Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below. 10.4. Conditions to avoid Conditions to avoid: Rapid exothermic polymerisation will occur in the presence of water, amines, alkalis and alcohols. 10.5. Incompatible materials Materials to avoid: Strong oxidising agents. Strong acids. Water. 10.6. Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes. Section 11: Toxicological information 11.1. Information on toxicological effects Toxicity values: Route Species Test Value Units ORAL RAT LD50 >5000 mg/kg
Page: 6 DERMAL RBT LD50 >2000 mg/kg Relevant effects for mixture: Effect Route Basis Irritation OPT INH DRM Hazardous: calculated Symptoms / routes of exposure Skin contact: Eye contact: There may be irritation and redness at the site of contact. Cyanoacrylate will bond to eye protein and will cause periods of weeping which will help to debond the adhesive. In adry atmosphere,,50% RH, vapours may cause irritation and lachrymatory effect. Ingestion: Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000 mg/kg (rat). It is almost impossible to swallow as it rapidly polymerises in the mouth. Inhalation: In dry atmospheres with <50% humidity, vapours may irritate the eyes and respiratory system. Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals. Delayed / immediate effects: Immediate effects can be expected after short-term exposure. Section 12: Ecological information 12.1. Toxicity Ecotoxicity values: Not applicable. 12.2. Persistence and degradability Persistence and degradability: Biodegradable. 12.3. Bioaccumulative potential Bioaccumulative potential: No data available. 12.4. Mobility in soil Mobility: No data available. 12.5. Results of PBT and vpvb assessment PBT identification: This substance is not identified as a PBT substance. 12.6. Other adverse effects Other adverse effects: No data available. Section 13: Disposal considerations 13.1. Waste treatment methods Disposal operations: Dispose of in accordance with local and national regulations. Polymerise by adding slowly to water (10:1) and dispose of as water insoluble, non-toxic solid chemical in authorised landfill or incinerate under controlled conditions. Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: SAFETY DATA SHEET The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. Page: 7 Section 14: Transport information Transport class: This product does not require a classification for transport. Section 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2. Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. Section 16: Other information Other information Other information: Phrases used in s.2 and 3: Legal disclaimer: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. * indicates text in the SDS which has changed since the last revision. EUH202: Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. R36/37/38: Irritating to eyes, respiratory system and skin. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]