Material Safety Data Sheet C"pyright, 2010, 3M C"mpany. All rights reserved. C"pying and/"r d"wnl"ading "f this inf"rmati"n f"r the purp"se "f pr"perly utilizing 3M pr"ducts is all"wed pr"vided that: (1) the inf"rmati"n is c"pied in full with n" changes unless pri"r written agreement is "btained fr"m 3M, and (2) neither the c"py n"r the "riginal is res"ld "r "therwise distributed with the intenti"n "f earning a pr"fit there"n. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Perfect-It(TM) Rubbing C"mp"und PN 06085, 06086, 06087, 39060 MANUFACTURER: 3M DIVISION: Aut"m"tive Aftermarket ADDRESS: 3M Center St. Paul, MN 55144-1000 Issue Date: 03/03/10 Supercedes Date: 03/09/09 D=cument Gr=up: 22-5036-3 EMERGENCY PHONE: 1-800-364-3577 "r (651) 737-6501 (24 h"urs) Pr=duct Use: Intended Use: Aut"m"tive SECTION 2: INGREDIENTS Ingredient C.A.S. N=. % by Wt WATER 7732-18-5 40-70 ALUMINUM OZIDE 1344-28-1 10-30 KEROSENE 8008-20-6 10-30 CASTOR OIL 8001-79-4 1-5 POLOZAMINE Mixture 0.3-2.0 WHITE MINERAL OIL (PETROLEUM) 8042-47-5 0.5-1.5 NAPHTHALENE 91-20-3 <= 0.08 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Od=r, C=l=r, Grade: White liquid; S"lvent "d"r General Physical F=rm: Liquid Immediate health, physical, and envir=nmental hazards: May cause target "rgan effects. C"ntains a chemical "r chemicals which can cause cancer. Page 1 =f 9
3.2 POTENTIAL HEALTH EFFECTS Eye C=ntact: Mild Eye Irritati"n: Signs/sympt"ms may include redness, pain, and tearing. Skin C=ntact: Mild Skin Irritati"n: Signs/sympt"ms may include l"calized redness, swelling, and itching. May be abs"rbed thr"ugh skin and cause target "rgan effects. Inhalati=n: Intenti"nal c"ncentrati"n and inhalati"n may be harmful "r fatal. Respirat"ry Tract Irritati"n: Signs/sympt"ms may include c"ugh, sneezing, nasal discharge, headache, h"arseness, and n"se and thr"at pain. Pr"l"nged "r repeated exp"sure may cause: Pneum"c"ni"sis: Sign/sympt"ms may include persistent c"ugh, breathlessness, chest pain, increased am"unts "f sputum, and changes in lung functi"n tests. May be abs"rbed f"ll"wing inhalati"n and cause target "rgan effects. Ingesti=n: Gastr"intestinal Irritati"n: Signs/sympt"ms may include abd"minal pain, st"mach upset, nausea, v"miting and diarrhea. May be abs"rbed f"ll"wing ingesti"n and cause target "rgan effects. Target Organ Effects: Central Nerv"us System (CNS) Depressi"n: Signs/sympt"ms may include headache, dizziness, dr"wsiness, inc""rdinati"n, nausea, sl"wed reacti"n time, slurred speech, giddiness, and unc"nsci"usness. Pr"l"nged "r repeated exp"sure may cause: Kidney/Bladder Effects: Signs/sympt"ms may include changes in urine pr"ducti"n, abd"minal "r l"wer back pain, increased pr"tein in urine, increased bl""d urea nitr"gen (BUN), bl""d in urine, and painful urinati"n. Carcin=genicity: C"ntains a chemical "r chemicals which can cause cancer. Page 2 =f 9
Ingredient C.A.S. N=. Class Descripti=n Regulati=n NAPHTHALENE 91-20-3 Grp. 2B: P"ssible human carc. Internati"nal Agency f"r Research "n Cancer NAPHTHALENE 91-20-3 Anticipated human carcin"gen Nati"nal T"xic"l"gy Pr"gram Carcin"gens OIL MIST, MINERAL SEQ100910 Grp. 1: Carcin"genic t" Internati"nal Agency f"r Research "n Cancer humans OIL MIST, MINERAL SEQ100910 Kn"wn human carcin"gen Nati"nal T"xic"l"gy Pr"gram Carcin"gens SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The f"ll"wing first aid rec"mmendati"ns are based "n an assumpti"n that appr"priate pers"nal and industrial hygiene practices are f"ll"wed. Eye C=ntact: Skin C=ntact: Flush eyes with large am"unts "f water. If signs/sympt"ms persist, get medical attenti"n. Wash affected area with s"ap and water. If signs/sympt"ms devel"p, get medical attenti"n. Inhalati=n: Rem"ve pers"n t" fresh air. If signs/sympt"ms devel"p, get medical attenti"n. If Swall=wed: D" n"t induce v"miting unless instructed t" d" s" by medical pers"nnel. Give victim tw" glasses "f water. Never give anything by m"uth t" an unc"nsci"us pers"n. Get medical attenti"n. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Aut=igniti=n temperature Flash P=int Flammable Limits - LEL Flammable Limits - UEL > 212 ºF [Test Meth"d: Cl"sed Cup] 5.2 E`TINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carb"n di"xide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Pr=cedures: (SCBA). Wear full pr"tective equipment (Bunker Gear) and a self-c"ntained breathing apparatus Unusual Fire and Expl=si=n Hazards: N"ne inherent in this pr"duct. N=te: See STABILITY AND REACTIVITY (SECTION 10) f=r hazard=us c=mbusti=n and thermal dec=mp=siti=n inf=rmati=n. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Page 3 =f 9
Evacuate unpr"tected and untrained pers"nnel fr"m hazard area. The spill sh"uld be cleaned up by qualified pers"nnel. Ventilate the area with fresh air. F"r large spill, "r spills in c"nfined spaces, pr"vide mechanical ventilati"n t" disperse "r exhaust vap"rs, in acc"rdance with g""d industrial hygiene practice. Warning! A m"t"r c"uld be an igniti"n s"urce and c"uld cause flammable gases "r vap"rs in the spill area t" burn "r expl"de. F"r larger spills, c"ver drains and build dikes t" prevent entry int" sewer systems "r b"dies "f water. Place in a cl"sed c"ntainer appr"ved f"r transp"rtati"n by appr"priate auth"rities. Disp"se "f c"llected material as s""n as p"ssible. Observe precauti"ns fr"m "ther secti"ns. Call 3M- HELPS line (1-800-364-3577) f"r m"re inf"rmati"n "n handling and managing the spill. C"ntain spill. W"rking fr"m ar"und the edges "f the spill inward, c"ver with bent"nite, vermiculite, "r c"mmercially available in"rganic abs"rbent material. Mix in sufficient abs"rbent until it appears dry. C"llect as much "f the spilled material as p"ssible. Clean up residue with detergent and water. In the event =f a release =f this material, the user sh=uld determine if the release qualifies as rep=rtable acc=rding t= l=cal, state, and federal regulati=ns. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Av"id eye c"ntact. D" n"t eat, drink "r sm"ke when using this pr"duct. Wash exp"sed areas th"r"ughly with s"ap and water. Av"id breathing "f vap"rs, mists "r spray. Av"id skin c"ntact. Keep "ut "f the reach "f children. Av"id breathing "f dust created by cutting, sanding, grinding "r machining. 7.2 STORAGE Keep c"ntainer in well-ventilated area. SECTION 8: E`POSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Pr"vide appr"priate l"cal exhaust ventilati"n "n "pen c"ntainers. Pr"vide appr"priate l"cal exhaust f"r cutting, grinding, sanding "r machining. If exhaust ventilati"n is n"t available, use appr"priate respirat"ry pr"tecti"n. Use general diluti"n ventilati"n and/"r l"cal exhaust ventilati"n t" c"ntr"l airb"rne exp"sures t" bel"w Occupati"nal Exp"sure Limits and/"r c"ntr"l mist, vap"r, "r spray. If ventilati"n is n"t adequate, use respirat"ry pr"tecti"n equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Pr=tecti=n Av"id eye c"ntact. The f"ll"wing eye pr"tecti"n(s) are rec"mmended: Safety Glasses with side shields, Indirect Vented G"ggles. 8.2.2 Skin Pr=tecti=n Av"id skin c"ntact. Select and use gl"ves and/"r pr"tective cl"thing t" prevent skin c"ntact based "n the results "f an exp"sure assessment. C"nsult with y"ur gl"ve and/"r pr"tective cl"thing manufacturer f"r selecti"n "f appr"priate c"mpatible materials. Gl"ves made fr"m the f"ll"wing material(s) are rec"mmended: Ne"prene, Nitrile Rubber. 8.2.3 Respirat=ry Pr=tecti=n Av"id breathing "f vap"rs, mists "r spray. Av"id breathing "f dust created by cutting, sanding, grinding "r machining. Select "ne "f the f"ll"wing NIOSH appr"ved respirat"rs based "n airb"rne c"ncentrati"n "f c"ntaminants and in acc"rdance with OSHA regulati"ns: Half facepiece "r fullface air-purifying respirat"r with "rganic vap"r cartridges and P100 particulate prefilters. C"nsult the current 3M Respirat"ry Selecti"n Guide f"r additi"nal inf"rmati"n "r call 1-800-243-4630 f"r 3M technical assistance. Page 4 =f 9
8.2.4 Preventi=n =f Swall=wing D" n"t eat, drink "r sm"ke when using this pr"duct. Wash exp"sed areas th"r"ughly with s"ap and water. 8.3 E`POSURE GUIDELINES Ingredient Auth=rity Type Limit Additi=nal Inf=rmati=n ALUMINUM OZIDE CMRG TWA 1 fiber/cc ALUMINUM OZIDE OSHA TWA, respirable 5 mg/m3 fracti"n ALUMINUM OZIDE OSHA TWA, as t"tal dust 15 mg/m3 KEROSENE ACGIH TWA, as t"tal 200 mg/m3 Skin N"tati"n* hydr"carb"n vap"r, n"n-aer"s"l KEROSENE CMRG TWA 500 ppm NAPHTHALENE ACGIH TWA 10 ppm Skin N"tati"n* NAPHTHALENE ACGIH STEL 15 ppm Skin N"tati"n* NAPHTHALENE OSHA TWA 50 mg/m3 OIL MIST, MINERAL ACGIH TWA, as mist 5 mg/m3 OIL MIST, MINERAL ACGIH STEL, as mist 10 mg/m3 WHITE MINERAL OIL (PETROLEUM) CMRG TWA 5 mg/m3 WHITE MINERAL OIL (PETROLEUM) CMRG STEL 10 mg/m3 * Substance(s) refer t" the p"tential c"ntributi"n t" the "verall exp"sure by the cutane"us r"ute including muc"us membrane and eye, either by airb"rne "r, m"re particularly, by direct c"ntact with the substance. Vehicles can alter skin abs"rpti"n. SOURCE OF EZPOSURE LIMIT DATA: ACGIH: American C"nference "f G"vernmental Industrial Hygienists CMRG: Chemical Manufacturer Rec"mmended Guideline OSHA: Occupati"nal Safety and Health Administrati"n AIHA: American Industrial Hygiene Ass"ciati"n W"rkplace Envir"nmental Exp"sure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Od=r, C=l=r, Grade: White liquid; S"lvent "d"r General Physical F=rm: Liquid Aut=igniti=n temperature Flash P=int > 212 ºF [Test Meth"d: Cl"sed Cup] Flammable Limits - LEL Flammable Limits - UEL B=iling p=int 100 ºC Density 8.8-9.1 lb/gal Vap=r Pressure 18 mmhg [@ 20 ºC] Specific Gravity 1.05-1.1 [Ref Std: WATER=1] ph 7.5-8.5 S=lubility In Water S=lubility in Water Evap=rati=n rate Hazard=us Air P=llutants M"derate 0.1296 % weight Page 5 =f 9
V=latile Organic C=mp=unds 16.39 % [Test Meth"d: calculated SCAQMD rule 443.1] [Details: excluding exempt c"mp"unds] K=w - Oct/Water partiti=n c=ef Percent v=latile 82 % VOC Less H2O & Exempt S=lvents 591.05 g/l [Test Meth"d: calculated SCAQMD rule 443.1] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and C=nditi=ns t= Av=id: 10.1 C=nditi=ns t= av=id N"ne kn"wn 10.2 Materials t= av=id N"ne kn"wn Hazard=us P=lymerizati=n: Hazard"us p"lymerizati"n will n"t "ccur. Hazard=us Dec=mp=siti=n =r By-Pr=ducts Substance Carb"n m"n"xide Carb"n di"xide Oxides "f Nitr"gen C=nditi=n During C"mbusti"n During C"mbusti"n During C"mbusti"n SECTION 11: TO`ICOLOGICAL INFORMATION Please c"ntact the address listed "n the first page "f the MSDS f"r T"xic"l"gical Inf"rmati"n "n this material and/"r its c"mp"nents. SECTION 12: ECOLOGICAL INFORMATION ECOTO`ICOLOGICAL INFORMATION N"t determined. CHEMICAL FATE INFORMATION N"t determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disp=sal Meth=d: Since regulati"ns vary, c"nsult applicable regulati"ns "r auth"rities bef"re disp"sal. Page 6 =f 9
Since regulati=ns vary, c=nsult applicable regulati=ns =r auth=rities bef=re disp=sal. SECTION 14:TRANSPORT INFORMATION ID Number(s): LB-K100-0674-3, 60-4550-3485-4, 60-4550-3486-2, 60-4550-3487-0, 60-4550-3488-8, 60-4550-3638-8, 60-4550-3747-7, 60-4550- 5178-3, 60-4550-5180-9, 60-4550-5181-7 Please c=ntact the emergency numbers listed =n the first page =f the MSDS f=r Transp=rtati=n Inf=rmati=n f=r this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS C"ntact 3M f"r m"re inf"rmati"n. 311/312 Hazard Categ=ries: Fire Hazard - N" Pressure Hazard - N" Reactivity Hazard - N" Immediate Hazard - Yes Delayed Hazard - Yes Secti=n 313 T=xic Chemicals subject t= the rep=rting requirements =f that secti=n and 40 CFR part 372 (EPCRA): Ingredient C.A.S. N= % by Wt ALUMINUM OZIDE 1344-28-1 10-30 This material c=ntains a chemical which requires exp=rt n=tificati=n under TSCA Secti=n 12[b]: Ingredient (Categ=ry if applicable) C.A.S. N= Regulati=n Status NAPHTHALENE 91-20-3 T"xic Substances C"ntr"l Act (TSCA) 4 Test Applicable Rule Chemicals STATE REGULATIONS C"ntact 3M f"r m"re inf"rmati"n. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. N=. Classificati=n NAPHTHALENE 91-20-3 **Carcin"gen ** WARNING: c"ntains a chemical which can cause cancer. CHEMICAL INVENTORIES Page 7 =f 9
The c"mp"nents "f this pr"duct are in c"mpliance with the chemical n"tificati"n requirements "f TSCA. All applicable chemical ingredients in this material are listed "n the Eur"pean Invent"ry "f Existing Chemical Substances (EINECS), "r are exempt p"lymers wh"se m"n"mers are listed "n EINECS. C"ntact 3M f"r m"re inf"rmati"n. INTERNATIONAL REGULATIONS C"ntact 3M f"r m"re inf"rmati"n. This MSDS has been prepared t= meet the U.S. OSHA Hazard C=mmunicati=n Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classificati=n Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: N"ne Nati"nal Fire Pr"tecti"n Ass"ciati"n (NFPA) hazard ratings are designed f"r use by emergency resp"nse pers"nnel t" address the hazards that are presented by sh"rt-term, acute exp"sure t" a material under c"nditi"ns "f fire, spill, "r similar emergencies. Hazard ratings are primarily based "n the inherent physical and t"xic pr"perties "f the material but als" include the t"xic pr"perties "f c"mbusti"n "r dec"mp"siti"n pr"ducts that are kn"wn t" be generated in significant quantities. Revisi"n Changes: C"pyright was m"dified. Secti"n 13: Waste disp"sal meth"d inf"rmati"n was m"dified. Secti"n 9: Pr"perty descripti"n f"r "pti"nal pr"perties was m"dified. Secti"n 14: ID Number(s) Template 1 was m"dified. Secti"n 2: Ingredient table was m"dified. Secti"n 8: Exp"sure guidelines ingredient inf"rmati"n was m"dified. Secti"n 3: Carcin"genicity table was m"dified. Secti"n 15: EPCRA 313 inf"rmati"n was added. Secti"n 15: EPCRA 313 text was added. Secti"n 10.1 C"nditi"ns t" av"id was added. Secti"n 10.2 Materials t" av"id was added. Secti"n 6: Release measures inf"rmati"n was added. Secti"n 6: Release measures inf"rmati"n was added. Secti"n 6: Release measures inf"rmati"n was added. Secti"n 10: Materials t" av"id physical pr"perty was added. Secti"n 10: C"nditi"ns t" av"id physical pr"perty was added. Secti"n 6: Release measures inf"rmati"n was deleted. Secti"n 13: EPA hazard"us waste number (RCRA) heading was deleted. Secti"n 13: EPA hazard"us waste number (RCRA) inf"rmati"n was deleted. Secti"n 10: Materials and c"nditi"ns t" av"id physical pr"perty was deleted. Secti"n 8: Exp"sure guidelines legend was deleted. Page 8 =f 9
DISCLAIMER: The inf"rmati"n in this Material Safety Data Sheet (MSDS) is believed t" be c"rrect as "f the date issued. 3M MAKES NO WARRANTIES, EZPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is resp"nsible f"r determining whether the 3M pr"duct is fit f"r a particular purp"se and suitable f"r user's meth"d "f use "r applicati"n. Given the variety "f fact"rs that can affect the use and applicati"n "f a 3M pr"duct, s"me "f which are uniquely within the user's kn"wledge and c"ntr"l, it is essential that the user evaluate the 3M pr"duct t" determine whether it is fit f"r a particular purp"se and suitable f"r user's meth"d "f use "r applicati"n. 3M pr"vides inf"rmati"n in electr"nic f"rm as a service t" its cust"mers. Due t" the rem"te p"ssibility that electr"nic transfer may have resulted in err"rs, "missi"ns "r alterati"ns in this inf"rmati"n, 3M makes n" representati"ns as t" its c"mpleteness "r accuracy. In additi"n, inf"rmati"n "btained fr"m a database may n"t be as current as the inf"rmati"n in the MSDS available directly fr"m 3M. 3M MSDSs are available at www.3m.c=m Page 9 =f 9