CELLULOBEADS

CELLULBEADS www.daitokasei.com No.6 Revised: 23 ctober, 2013 DAIT KASEI KGY Co.,LTD.

CELLULBEADS / Treated CELLULBEADS We developed spherical hydrophilic cellulose beads. There are several grades depending on its diameter from 4 to 200 microns. We can also provide hydrophobic treated CELLULBEADS. CELLULBEADS Spherical Cellulose Beads Product Name INCI Name Property Remarks CELLULBEADS USF CELLULSE Ultimate Soft Focus Effect Superior Absorption of il Diameter* 4 μm CELLULBEADS D-5 CELLULSE Absorption of Water and il Diameter* < 10 μm CELLULBEADS D-10 CELLULSE Absorption of Water and il Diameter * < 15 μm CELLULBEADS D-30 CELLULSE Absorption of Water and il Diameter * < 30 μm CELLULBEADS D-50 CELLULSE Absorption of Water and il Diameter * < 50 μm CELLULBEADS D-100 CELLULSE Absorption of Water and il Diameter * < 100 μm CELLULBEADS D-200 CELLULSE Absorption of Water and il Diameter * < 200 μm CELLULBEADS D-500 CELLULSE Absorption of Water and il Diameter * < 500 μm * Median Diameter Treated CELLULBEADS Hydrophobic Treated CELLULBEADS Product Name INCI Name Property Remarks TS-0.5 CELLULBEADS D-5 ITT-0.5 CELLULBEADS D-10 TRIETHXYCAPRYLYL SILANE, CELLULSE ISPRPYL TITANIUM TRIISSTEARATE, CELLULSE Water Repellency Lipophilic Excellent Smoothness Water Repellency Lipophilic Excellent Smoothness Can Treat on other size of CELLULBEADS Can Treat on other size of CELLULBEADS

Color CELLULBEADS / MISCELL PW Color CELLULBEADS is the complex of CELLUSE and color pigments which keeps very good spreadability of CELLULBEADS. MISCELL PW is Potassium Succinate treated CELLULBEADS, which can hold high amount of moisture, and gives moisturizing property. Color CELLULBEADS CELLULBEADS containing 33% of color pigments Product Name INCI Name Property Remarks CELLULBEADS D-10(Y-33P) CELLULSE, IRN XIDES Excellent Smoothness Absorption Water and il Color: Yellow Complex with Yellow Iron xide Diameter* < 15 μm CELLULBEADS D-10(R-33P) CELLULSE, IRN XIDES Excellent Smoothness Absorption Water and il Color: Red Complex with Red Iron xide Diameter* < 15 μm CELLULBEADS D-10(UB-33) CELLULSE, IRN XIDES, SILICA Excellent Smoothness Absorption Water and il Color: Black Complex with Black Iron xide Diameter* < 15 μm CELLULBEADS D-10(Ti-33) CELLULSE, TITANIUM DIXIDE, ALUMINUM HYDRXIDE Excellent Smoothness Absorption Water and il Color: White Complex with Titanium Dioxide Diameter* < 15 μm * Median Diameter MISCELL PW PTASSIUM SUCCINATE treated CELLULBEADS Product Name INCI Name Property Remarks MISCELL PW PTASSIUM CELLULSE SUCCINATE Superior hydrophilicity Good Dispersability in Water Absorption of Water MISCELL PW D-5 MISCELL PW D-10 MISCELL PW D-30 MISCELL PW D-50 MISCELL PW D-100 MISCELL PW D-200

CELLULBEADS USF Cellulose Beads with Ultimate Soft Focus Effect Property 1. Ultimate Soft Focus Effect 10%Gel 2. Vegetable rigin for Natural Concept Certified Haze Index (%) 100 90 80 70 60 50 40 30 20 10 CELLULBEADS USF CELLULBEADS D-5 PMMA Talc Ultrafine Ti2 Ti2 Silica Excellent Hazy Effect! 0 0 10 20 30 40 50 60 70 80 90 100 Total transmission (%) 3. Spherical Beads with Median Diameter: about 4 micron 4. Very Light Powder with Superior il Absorption 1 300.0 Specific Gravity (g/ml) 0.8 0.6 0.4 0.2 il Absorption (ml/100g) 250.0 200.0 150.0 100.0 50.0 0 USF D-5 D-10 0.0 USF D-5 PMMA

Ultimate Poreless Primer D5 Free -SPF 20- No. D/038 <Phase> <Ingredient> <%> <Trade Name> <Supplier> A DIMETHICNE/PEG-10/15 3.50 KSG-210 Shin Etsu CRSSSPLYMER (AND) DIMETHICNE A PEG-9 PLYDIMETHYLSILXYETHYL 2.00 KF-6028 Shin Etsu DIMETHICNE A DIMETHICNE (6cs) 5.00 KF-96A 6cs Shin Etsu A ISNNYL ISNNANATE 4.50 SALACS 99 Nisshin illio A ETHYLHEXYL METHXYCINNAMATE 10.00 UVINUL MC-80 BASF A QUATERINIUM-18 HECTRITE 1.20 BENTNE 38 V CG A DIM EHICNE/VINYL DIM ETHICNE 5.00 KSG-16 Shin Etsu CRSSPLYMER (AND) DIMETHICNE A DIMETHICNE 25.00 KF-96L-2cs B CELLULBEADS USF 10.00 DAIT KASEI C DE-INIZED WATER 28.30 C MAKILENE GC 5.00 DKE C SDIUM CITRATE 0.20 C PRESERVATIVE 0.30 TTAL : 100.00 BLANK (10% PMMA) D/038 (10% USF) Apply Powder Foundation

CELLULBEADS Advantage of CELLULBEADS - Vegetal rigin (Safety Data is available) - Smooth Feeling as Spherical powder - Can control the diameter from 4 to 200 microns - Superior Hydrophilicity - Absorption of Water and il We developed Spherical Cellulose Beads, CELLULBEADS. The various grades of CELLULBEADS can be applied in different type of the formula, skin care, make up, body care, and deodorant products. 5μm 10μm 30μm 50μm 100μm 200μm Smooth Feeling Soft Focus Effect Massage Effect Scrubbing Skin Care Under Make-up Massage Cream Cleansing Foundation Foundation New D-5 D-10 D-30 D-50 D-100 D-200 D-500 Diameter (μm) <10 <15 20-40 40-60 80-120 150-200 400-500 Water Content (%) Heavy Metal (ppm) <8 <8 <8 <8 <8 <8 <8 <10ppm <10ppm <10ppm <10ppm <10ppm <10ppm <10ppm As (ppm) <2ppm <2ppm <2ppm <2ppm <2ppm <2ppm <2ppm Water Absorption (%) il Absorption (ml/100g) Specific Gravity (g/cc) 150 140 140 140 140 140 400~500 ~70 ~60 ~60 ~56 ~53 ~50 ~240 0.59 0.71 0.81 0.91 0.95

Baby Sun Screen Non nano D5 Free -SPF30- No. DS/076 <Phase> <Ingredient> <%> <Trade Name> <Supplier> A DIMETHICNE 6.90 KF-96L-2CS Shin Etsu A LAURETH-7 0.50 A PHENYL TRIMETHICNE 2.50 KF-56 A TRIDECYL ISNNANATE 6.00 SALACS 913 A SYNTHETIC WAX 0.40 SASL WAX C-80 A ARACHIDYLBEHENATE 0.60 WAXENL 822 A PEG-10 DIMETHICNE 2.10 KF-6017 Shin Etsu A Daitopersion Zn-70-300(DM) 35.00 DAIT KASEI A CELLULBEADS D-10 3.00 DAIT KASEI B DE-INIZED WATER 34.95 B MAKILENE GC 3.00 DKE B SDIUM CHLRIDE 0.50 B SDIUM DEHYDRACETATE 0.15 B TETRASDIUM EDTA 0.10 B PRESERVATE 0.30 B SACRAN-05 4.00 DAIT KASEI TTAL : 100.00 <MANUFACTURING PRCEDURE> 1. Prepare Phase A and Phase B separately. 2. Heat Phase A and Phase B to 80 separately, and cool to 50. 3. Adjust loss of water and dimethicone(2cs) evaporated during heating. 4. Add Phase B to Phase A and keep stirring until the mixture is homogeneous. Bumping Eye Shadow/Face Powder No. DP/030 Eye Shadow Face Powder <Phase> <Ingredient> <%> <%> <Trade Name> <Supplier> (CLR PWDER) A MST-1 TALC SX 8.40 - DAIT KASEI A MST-1 MICA SX 12.00 25.05 DAIT KASEI A MST-1 Ti2 R250-3.00 DAIT KASEI A MST-1 YELLW No.602P - DAIT KASEI A MST-1 RED No.211P - 0.30 DAIT KASEI A MST-1 BLACK No.710P - 0.15 DAIT KASEI A MST-3 DK PEARL GLD 1.30 - DAIT KASEI A MST-3 DK PEARL BRNZE 5.30 - DAIT KASEI A CELLULBEADS D-10 5.00 5.00 DAIT KASEI B DE-INIZED WATER 62.70 60.20 B GLYCERIN 4.80 4.80 B XANTHAN GUM 0.20 0.20 KELTRL CG-T B PRESERVATIVE 0.30 0.30 TTAL : 100.00 100.00 <MANUFACTURING PRCEDURE> 1. Blend uniformly phase A in a mixer. 2. Prepare phase B. 3. Add phase A into phase B under stirring and mix well. 4. Pour in suitable containers and heat at 60C until complete drying(15g, 30hours). Peeling Massage Lotion/Cream No. D-0066-AD Lotion Cream +Scrub <Phase> <Ingredient> <%> <%> <%> <Trade Name> <Supplier> (CREAM BASE) A MAKILENE GC 10.00 10.00 10.00 DKE A MAKIMUSSE 12 - DAIT KASEI A DE-INIZED WATER 6.70 28.70 28.70 A ALCHL 10.00 - - A PRESERVATIVE 0.30 0.30 0.30 B PHENYL TRIMETHICNE 20.00 20.00 20.00 KF-56 Shin Etsu B DAITSL 5000AD 53.00 40.00 40.00 DAIT KASEI TTAL : 100.00 100.00 100.00 (FINAL CMPUND) CREAM BASE 95.00 CELLULBEADS D-200 5.00 DAIT KASEI 100.00 <MANUFACTURING PRCEDURE> 1. Disperse MAKIMUSSE 12 in MAKILENE GC, add the rest of Phase A, and prepare gel. 2. Prepare Phase B (Add PHENYL TRIMETHICNE to DAITSL 5000AD under stirring). 3. Add Phase B into Phase A, and keep stirring until the mixture is homogeneous.

Massage Scrub Gel No. D/044 <Phase> <Ingredient> <%> <Trade Name> <Supplier> (GEL BASE) A MAKIMUSSE 400 0.50 DAIT KASEI A MAKILENE GC 5.00 DKE A SACRAN-05 2.00 DAIT KASEI A PRESERVATIVE 0.30 A DE-INIZED WATER 92.20 TTAL : 100.00 (FINAL CMPUND) B GEL BASE 97.00 B CELLULBEADS D-500 3.00 DAIT KASEI TTAL : 100.00 <MANUFACTURING PRCEDURE> 1. Disperse MAKIMUSSE in MAKILENE GC and Preservative and add water to prepare gel. 2. Mix well Phase B. Peeling Massage Cream No. D/045 <Phase> <Ingredient> <%> <Trade Name> <Supplier> (CREAM BASE) A MAKILENE GC 10.00 DKE A MAKIMUSSE 12 DAIT KASEI A DE-INIZED WATER 28.70 A PRESERVATIVE 0.30 B PHENYL TRIMETHICNE 20.00 KF-56 Shin Etsu B DAITSL 5000AD 40.00 DAIT KASEI TTAL : 100.00 (FINAL CM PUND) CREAM BASE 95.00 CELLULBEADS D-500 5.00 DAIT KASEI 100.00 <MANUFACTURING PRCEDURE> 1. Disperse M AKIM USSE 12 in M AKILENE GC, add the rest of Phase A, and prepare gel. 2. Prepare Phase B (Add PHENYL TRIM ETHICNE to DAITSL 5000AD under stirring). 3. Add Phase B into Phase A, and keep stirring until the mixture is homogeneous.

Color CELLULBEADS By our technology of CELLULBEADS, we developed Color CELLULBEADS, which is spherical complex of cellulose and color pigments. CELLULBEADS D-10(UB-33) CELLULBEADS D-10(Ti-33) The Advantage of Color CELLULBEADS 1. Superior Smoothness Color pigments are dispersed in and on the surface of CELLULBEADS, so the superior smooth feeling can be maintained. 2. Unique Application CELLULBEADS D-10(UB-33) in mascara formulation enhance smooth application, separate each eye lash, and gives volume-up effect. CELLULBEADS containing 33% of color pigments Product Name CELLULBEADS D-10 (Ti-33) CELLULBEADS D-10 (Y-33P) CELLULBEADS D-10 (R-33P) CELLULBEADS D-10 (UB-33) Color Pigment Titanium Dioxide Yellow Iron xide Red Iron xide Black Iron xide The particle size of Color CELLULBEADS D-10 is about 15 μm. CELLULBEADS D-10(DCR30-33), complex of Cellulose and D&C Red No.30 is available. The other possibility of color, size, and the pigments are available upon customers request.

Volumizing Separate Mascara No. DM/015 <Phase> <Ingredient> <%> <Trade Name> <Supplier> A CARNAUBA 5.50 A BEESWAX 9.00 A STEARIC ACID 2.00 LUNAC S-98 Kao Chemicals A GLYCERYL STEARATE SE 2.00 RHEDL MS165V Kao Chemicals A PRPYLENE GLYCL STEARATE 2.00 HMTEX PS-200 Kao Chemicals A PLYISBUTENE 2.00 A DIMETHICNE 5.00 KF-96L-2CS Shin Etsu B WD-IB50 20.00 DAIT KASEI B DE-INIZED WATER 19.60 B MAKILENE GC 2.00 DKE B MAKIMUSSE 12 0.10 DAIT KASEI B AMINMETHYL PRPANEDIL 0.50 B PRESERVATIVE 0.30 C DAITSL 5000STY 30.00 DAIT KASEI TTAL : 100.00 (FINAL CMPUND) MASCARA BASE 97.00 CELLULBEADS D-10(CB2-15) 3.00 DAIT KASEI TTAL : 100.00 <MANUFACTURING PRCEDURE> 1. Heat the mixture of Phase A and Phase B to 80C separately. 2. Adjust loss of water and dimethicone(2cs) evaporated during heating. 3. Add Phase A into Phase B, and keep stirring until the mixture is homogeneous. 4. Add Phase C under stirring below 50C. 5. Mix well CELLULBEADS in mascaea base. +18.0 % longer Eye Lash Model Length: 7.71mm Volume: 10.57mm 2 Length: 9.10mm Volume: 18.13mm 2 +71.5 % volume-up [REMARK] We don t take any responsibility concerning to use of these formulations. These formulations are suggested as guidance. The health and safety test has not been established by testing. Evaluation and testing are needed to the final formulation.

Treated CELLULBEADS We developed treated CELLULBEADS, which shows high water repellency, and suitable for make-up products like foundation. Advantage of Treated CELLULBEADS 1. Water Repellency and Characteristic Feeling We succeeded to give water repellency to hydrophilic CELLULBEADS by surface treatment technology. Because of the surface treatment, we can also get a characteristic feeling of treatment agent. TS Treated ITT Treated Si Si Si CELLULBEADS Si Ti Ti Ti Ti Ti CELLULBEADS Ti Ti (INCI Name: TRIETHXYCAPRYLYLSILANE) (INCI Name: ISPRPYL TITANIUM TRIISSTEARATE) CH CH 2 CH 2 CH 3 3 CH 3 CH 2 CH 2 CH 2 Si CH 2 CH 3 CH 3 II I H 35 C 17 C Ti CH CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 CH 3 3 Product Name Contact Angle ( ) TS-0.5 CELLULBEADS D-5 146 TS-0.5 CELLULBEADS D-10 148 ITT-0.5 CELLULBEADS D-5 145 ITT-0.5 CELLULBEADS D-10 149 * The treatment % of CELLULBEADS D-5, D-10 is 0.5%, and that of D-200 is 0.1%. 2. Viscosity of dispersion in oil When we disperse treated CELLULBEADS in oil (Cyclomethicone or Squalane), treated CELLULBEADS shows much lower viscosity than non treated as the below figure shows. Please try new formula of Sunscreen containing high amount of treated CELLULBEADS with very low viscosity. 200 CELLULBEADS/Cyclomethicone=65/35 (v/v) 200 CELLULBEADS/Squalane=65/35 (v/v) 180 Cyclomethicone 180 Squalane 160 160 Viscosity (Pa s) 140 120 100 80 60 Viscosity (Pa s) 140 120 100 80 60 40 40 20 20 0 0 Non Treated TS ITT Non Treated TS ITT

2Way Powder Foundation Ingredient <CLR PWDER> TS-2 TALC JA-46R TS-2 SERICITE FSE TS-2 Ti2 CR-50 TS-2 YELLW LLXL TS-2 RED R-516L TS-2- BLACK BL-100 TS-0.5 CELLULBEADS D-10 CELLULBEADS D-10 Methylparaben DF-0019- TSD10 27.00 40.00 10.00 2.00 0.60 0.30 20.00-0.10 Composition (%) BLANK 27.00 40.00 10.00 2.00 0.60 0.30-20.00 0.10 Water proof performance of treated CELLULBEADS D-10 in Powder Foundation DF-0019-TSD10 containing TS-0.5 CELLULBEADS D-10 DF-0019-BLANK containing Non-treated D-10 Total 100.00 <Binder Base 14> Dimethicone (and) Trimethylsiloxysilicate Dimethicone (20cs) Phenoxyethanol Tocopherol 29.85 70.00 0.10 0.05 Total 100.00 <Final Compound> Color Powder Binder Base 14 95.00 5.00 Method: Applied powder foundation containing 20% of CELLULBEADS D-5 or TS-0.5 CELLULBEADS D-5 on the artificial skin (2mg/cm2), and put the droplet of water on the surface. Total 100.00 Sun Screen Milk Ingredient Product Name DS-0013-ITTD10 Composition (%) BLANK <Phase A> Phenyl Trimethicone Tridecyl isononanoate Cyclomethicone Dimethicone/vinyldimethicone crosspolymer (and) dimethicone Daitopersion Zn-50 Daitopersion Ti-30 ITT-0.5 CELLULBEADS D-10 CELLULBEADS D-10 <Phase B> De-ionized water 1,3-Butylene glycol Sodium chloride Disodium EDTA Pheonip KF-56 SALACS 913 KF-995 KSG-16 7.65 30.00 20.00 20.00-15.00 3.00 0.05 0.30 7.65 30.00 20.00-20.00 15.00 3.00 0.05 0.30 Total 100.00 Viscosity 730 mpas (Spindle M3, 30rpm) 16,660 mpas (Spindle M4, 12rpm) [REMARK] We don t take any responsibility concerning to use of these formulations. These formulations are suggested as guidance. The health and safety test has not been established by testing. Evaluation and testing are needed to the final formulation.

MISCELL PW PTASSIUM SUCCINATE treated CELLULBEADS We developed MISCELL PW, CELLULBEADS treated with PTASSIUM SUCCINATE. Advantage of MISCELL PW - Smooth Feeling - Superior retaining of Water () - Different diameter of MISCELL PW is available. MISCELL PW D-5 K + Plant CELLULBEADS H H H H H H SUCCINATE 30 CELLULBEADS The Difference of Water Absorption Water Retaining Property of MISCELL PW Torque 25 20 15 10 5 MISCELL PW D-5 CELLULBEADS D-5 0 0 10 20 30 40 Water Supply (ml) Water absorption(ml/100g) MISCELL PW D-5 230.5 CELLULBEADS D-5 172.5 Speed of Evaporation (mg/min) CELLULBEADS D-5 MISCELL PW D-5 Water Time (min) - Measurement condition- Temperature: 40 Sample Weight: 25mg (Pigment: Water/20:80)

Ingredients Moist Powdery Lotion Formula No. D-0039-PW Moist Powdery Gel Formula No. D-0038-PW Composition (%) Glycerin 5.00 8.00 Sodium Hyaluronate 0.10 - Sodium Polyacrylate 0.50 - Sodium Polyacrylate - Preservative 0.30 0.30 MISCELL PW D-5 0.50 5.00 De-ionized Water 88.60 85.70 Ethanol 5.00 - Total 100.00 100.00 2Way Powder Foundation Ingredient <CLR PWDER> Composition (%) Formula No. DF-0020-PW 1. PTASSIUM SUCCINATE treated 3. Spherical TS-2 TALC JA-46R TS-2 SERICITE FSE TS-2 Ti2 CR-50 TS-2 YELLW LLXL TS-2 RED R-516L TS-2- BLACK BL-100 MISCELL PW D-5 Methylparaben 27.00 50.00 10.00 2.00 0.60 0.30 10.00 0.10 Total 100.00 2. Vegetal rigin Surface of Skin <Binder Base 14> Dimethicone (and) Trimethylsiloxysilicate Dimethicone (20cs) Phenoxyethanol Tocopherol 29.85 70.00 0.10 0.05 Total 100.00 <Final Compound> Color Powder Binder Base 14 90.00 10.00 Property of MISCELL PW in the formula: 1. Absorption and Retaining of Water () 2. Powdery Feeling 3. Smooth Feeling Total 100.00 [REMARK] We don t take any responsibility concerning to use of these formulations. These formulations are suggested as guidance. The health and safety test has not been established by testing. Evaluation and testing are needed to the final formulation.