Glass Fiber Kit (UK Only) PP-310/311 PP-00310 2.00 IE EA 29.09.1999 MSDS_IE This safety data sheet has been prepared in accordance with the requirements of EC Directives 1999/45/EC and 2001/58/EC and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name Manufacturer/Supplier Address PP-00310 Glass Fiber Kit (UK Only) PP-310/311 Henkel Loctite Adhesives Ltd. Watchmead, Welwyn Garden City, Herts., AL7IJB. UK Phone Number 01 707 358800 Fax Number 01 707 358900 Emergency Phone Number +353-1-4599301/+353-87-2629625/+353-1-4046444 2. COMPOSITION / INFORMATION ON INGREDIENTS Nature Glass fibre repair kit. Mixture of Unsaturated Polyester Resin and Inorganic Fillers Hazardous Components in Product for EC Component Name CAS / EINECS Concentration R Phrases Classification Styrene Monomer 100-42-5 20.00-40.00 R10, R20, R36/38 3. HAZARD IDENTIFICATION Flammable. Harmful by inhalation. Irritating to eyes, respiratory system and skin. 4. FIRST AID MEASURES First Aid - Inhalation Remove affected person to fresh air, and if still feeling unwell seek medical attention. First Aid - Skin Wash skin with plenty of soap and water. First Aid - Eyes Flush eyes immediately with plenty of water for at least 15 minutes. First Aid - Ingestion Rinse mouth with water then give plenty of water to drink. Do not induce vomiting. Seek medical advice. 5. FIRE FIGHTING MEASURES No unusual fire hazards. If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Thermal decomposition would produce a complex variety of chemical species, some of which could be irritating and/or harmful if inhaled in significant volumes. MSDS_IE Page 1 of 4
Glass Fiber Kit (UK Only) PP-310/311 PP-00310 2.00 IE EA 29.09.1999 MSDS_IE 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Eliminate sources of ignition. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. 7. HANDLING AND STORAGE Handling Use in well ventilated area. Avoid inhaling vapour. Adequate ventilation is recommended to remove traces of odour. Avoid sources of ignition - no smoking. Avoid contact with skin and eyes. Storage Storage temperature range 1 C to 25 C. Store away from heat in a cool, well-ventilated area. Store away from direct sunlight. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits Styrene Monomer SE: NGV 20ppm 8h TWA. ACGIH: TLV 50ppm (213mg/m3) 8h TWA. ACGIH: STEL 100ppm (426mg/m3) 15min TWA. Good industrial hygiene practices should be observed. In circumstances where there is a potential for prolonged or repeated skin contact, the use of disposable gloves (polyethylene, natural rubber or equivalent ester-resistant material) is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Paste. Colour Grey. Odour Characteristic. ph N/A Boiling Range/Point ( C) > 150 Flash Point (CC) ( C) 32 Specific Gravity 1.12. Solubility in Water (kg/m³) Insoluble. Solubility in Acetone Insoluble Vapour Pressure (mmhg <10 @25 C) Explosion Limits (%) N/A 10. STABILITY AND REACTIVITY The product is relatively stable under normal conditions of use. Extreme heat or exposure to flame should be avoided. MSDS_IE Page 2 of 4
Glass Fiber Kit (UK Only) PP-310/311 PP-00310 2.00 IE EA 29.09.1999 MSDS_IE 11. TOXICOLOGICAL INFORMATION Inhalation This product is harmful by inhalation. Inhalation of vapours may cause headaches or dizziness. May cause irritation to respiratory system and mucous membranes if used in confined spaces. Skin This product is classified as a skin irritant. Solvent may remove essential oils from the skin making it susceptible to attack from other chemicals. Eyes This product is an irritant to the eyes. Vapours may be irritating to eyes causing lachrymatory effect. Ingestion This product is considered to be of low toxicity. May irritate the digestive tract. Ingestion of large quantities may cause damage to liver or kidneys. 12. ECOLOGICAL INFORMATION Keep away from drains and open waters. Biodegradable product of low ecotoxicity. Biological and Chemical Oxygen Demands (BOD and COD) of cured Loctite products are insignificant. In the cured state contribution of this product to Environmental Hazards is insignificant in comparison to articles in which it is used. 13. DISPOSAL CONSIDERATIONS After use, tubes, cartons and bottles containing residual product should be disposed of as "chemically contaminated waste" in an authorised legal land fill site or incinerated. Dispose of in accordance with local and national regulations. Incineration under controlled conditions recommended. Contribution of this product to waste is very insignificant in comparison to article in which it is used. Regulations governing disposal of individual articles apply. 14. TRANSPORT INFORMATION UN Number 3269 Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) 15. REGULATORY INFORMATION Contains Labelling Information Polyester Resin kit, flammable liquid, Class 3, Pkg. Grp. III. Polyester Resin kit, flammable liquid, Class 3.3, Pkg. Grp. III. Polyester Resin kit, flammable liquid, Class 3, Item No. 5 (c). Styrene Monomer Harmful None None R phrases R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. MSDS_IE Page 3 of 4
Glass Fiber Kit (UK Only) PP-310/311 PP-00310 2.00 IE EA 29.09.1999 MSDS_IE 15. REGULATORY INFORMATION S phrases Voluntary Labelling 16. OTHER INFORMATION MSDS data revised 29 September 1999 Hazardous Components in Product for EC Component Name S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of S16 Keep away from sources of ignition - No Smoking. N/A R Phrases Styrene Monomer R10, R20, R36/38 R10 R10 Flammable. R20 R20 Harmful by inhalation. R36/38 R36/38 Irritating to eyes and skin. Prepared by: Dr. Prabhu Kulkarni FICI.,FIOSH., MBIRA., Senior HRA Specialist. Supersedes Safety Data Sheet No: PP-00310 dated 16th March 1996 Further Information may be obtained from:-, Health and Regulatory Affairs - Europe, Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: +353-1-4046444. Fax: +353-1-4510806. The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). MSDS_IE Page 4 of 4
Extra Hardener (Phthalate Free) PP-30 &31. PP-00030 2.00 IE EA 12.09.2003 MSDS_IE This safety data sheet has been prepared in accordance with the requirements of EC Directives 1999/45/EC and 2001/58/EC and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name Manufacturer/Supplier Address PP-00030 Extra Hardener (Phthalate Free) PP-30 &31. Henkel Loctite Adhesives Ltd. Watchmead, Welwyn Garden City, Herts., AL7IJB. UK Phone Number 01 707 358800 Fax Number 01 707 358900 Emergency Phone Number +353-1-4599301/+353-87-2629625/+353-1-4046444 2. COMPOSITION / INFORMATION ON INGREDIENTS Nature Organic peroxide hardener for polyester fillers. Organic peroxide Hazardous Components in Product for EC Component Name CAS / EINEC Concentration R Phrases Classification Dibenzoyl peroxide 94-36-0 202-327- 40.00-60.00 R2, R36, R43 E, Xi 6 Dipropyleneglycol Dibenzoate 27138-31-4 248-20.00-30.00 258-5 Zinc distearate 557-05-1 209-151-9 1.00-3.00 R37 Xi 3. HAZARD IDENTIFICATION Oxidising. Irritating to eyes. May cause sensitisation by skin contact. Prolonged contact with skin, particularly damaged skin, may cause sensitization or dermatitis in sensitive individuals. 4. FIRST AID MEASURES First Aid - Inhalation Remove affected person to fresh air, and if still feeling unwell seek medical attention. First Aid - Skin Wash with plenty of soap and water. If irritation persists, seek medical advice. First Aid - Eyes Flush eyes with plenty of water for at least 15 minutes. If irritation persists seek medical attention. First Aid - Ingestion Rinse mouth with water then give plenty of water to drink. Do not induce vomiting. Seek medical advice. 5. FIRE FIGHTING MEASURES If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Thermal decomposition would produce a complex variety of chemical species, some of which could be irritating and/or harmful if inhaled in significant volumes. MSDS_IE Page 1 of 4
Extra Hardener (Phthalate Free) PP-30 &31. PP-00030 2.00 IE EA 12.09.2003 MSDS_IE 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Eliminate sources of ignition. Absorb spillage onto an inert absorbent material and place in a closed container for disposal. 7. HANDLING AND STORAGE Handling Use in well ventilated area. Vapours should be extracted to avoid inhalation. Avoid sources of ignition - no smoking. Avoid contact with skin and eyes. Storage Storage temperature range 1 C to 25 C. Store away from heat in a cool, well-ventilated area. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Good industrial hygiene practices should be observed. In circumstances where there is a potential for prolonged or repeated skin contact, the use of polyvinyl chloride or nitrile rubber gauntlets or equivalent solvent resistant gloves is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Paste. Colour White. Odour Faint ph N/A Boiling Range/Point ( C) Not applicable. Decomposes before boiling. Flash Point (CC) ( C) >50 Specific Gravity 1.14-1.15. Solubility in Water (kg/m³) Slightly soluble Solubility in Acetone Insoluble Vapour Pressure (mmhg Less than 0.1 at 20 C. @25 C) Explosion Limits (%) N/A 10. STABILITY AND REACTIVITY Stable under normal conditions. Destabilised by reducing agents. 11. TOXICOLOGICAL INFORMATION Inhalation Irritating to respiratory system. Skin Prolonged contact may cause some irritation. Eyes This product may cause severe damage to the eyes. Ingestion May irritate the digestive tract. Ingestion of large quantities may cause damage to liver or kidneys. 12. ECOLOGICAL INFORMATION Biodegradable product of low ecotoxicity. MSDS_IE Page 2 of 4
Extra Hardener (Phthalate Free) PP-30 &31. PP-00030 2.00 IE EA 12.09.2003 MSDS_IE 12. ECOLOGICAL INFORMATION Avoid disposing of the container, even when empty, into the environment. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. Incineration under controlled conditions recommended. 14. TRANSPORT INFORMATION UN Number 3108 Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) 15. REGULATORY INFORMATION Contains Labelling Information Oxidizing Organic peroxide, type E solid, CLass 5.2, Pkg. Grp. II. Organic Peroxide, type E, solid, (dibenzoyl peroxide) Class 5.2, Pkg.Gr. ll, EmS F-J, S-R. Organic peroxide, type E, solid, (dibenzoyl peroxide) Class 5.2, label 5.2. Classification code: P1 Benzoyl peroxide Irritant R phrases S phrases Voluntary Labelling 16. OTHER INFORMATION MSDS data revised 12 September 2003 Hazardous Components in Product for EC Component Name Dibenzoyl peroxide Dipropyleneglycol Dibenzoate Zinc distearate R2 R36 R37 R43 Supersedes Safety Data Sheet No: PP-00030 dated 21/05/2003. Prepared by: R7 May cause fire. R36 Irritating to eyes. R43 May cause sensitisation by skin contact. S2 Keep out of the reach of children. S3/7 Keep container tightly closed in a cool place. S15 Keep away from heat. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 Wear suitable gloves and eye/face protection. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. N/A R Phrases R2, R36, R43 R37 R2 Risk of explosion by shock, friction, fire or other sources of ignition. R36 Irritating to eyes. R37 Irritating to respiratory system. R43 May cause sensitisation by skin contact. Dr. Josie Guthrie Senior Regulatory Scientist MSDS_IE Page 3 of 4
Component Name Extra Hardener (Phthalate Free) PP-30 &31. PP-00030 2.00 IE EA 12.09.2003 MSDS_IE R Phrases Further Information may be obtained from:-, Health and Regulatory Affairs - Europe, Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: +353-1-4046444. Fax: +353-1-4510806. This safety data sheet was prepared in accordance with Commission Directive 2001/59/EC adapting to technical progress for the 28th time Council Directive 67/548/EEC and Commission Directive 1999/45/EC. The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Attention of users is drawn to the possible hazards from improper use of the product(s). Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. MSDS_IE Page 4 of 4