Material Safety Data Sheet Carbon Standard, 1000 ppm, Inorganic. Section 1 - Chemical Product and Company Identification

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An ISO9001 Certified Company Material Safety Data Sheet Section 1 - Chemical Product and Company Identification MSDS Name: Catalog Numbers: LC12900 Synonyms: None Company Identification: LabChem Inc 200 William Pitt Way Pittsburgh, PA 15238 Company Phone Number: (412) 826-5230 Emergency Phone Number: (800) 424-9300 CHEMTREC Phone Number: (800) 424-9300 or 011-703-527-3887 Section 2 - Composition, Information on Ingredients CAS# Chemical Name: Percent 497-19-8 Sodium Carbonate 0.44 144-55-8 Sodium Bicarbonate 0.35 7732-18-5 Water >99 Section 3 - Hazards Identification Emergency Overview Appearance: clear, colorless solution Caution! May cause mild eye irritation. Target Organs: none Potential Health Effects Eye: May cause mild eye irritation. Skin: Not hazardous to skin. Ingestion: Not hazardous if swallowed. Inhalation: Not hazardous if inhaled. - 1 -

Chronic: Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence of chemical remains. Get medical aid. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: Do not induce vomiting. Give conscious victim 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid if irritation or symptoms occur. Inhalation: Move victim to fresh air immediately. Get medical aid if irritation or other symptoms appear. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Autoignition Temperature: Flash Point: Not flammable NFPA Rating: Health- 0, Flammability- 0, Instability- 0 Explosion Limits: Lower: n/a Upper: n/a Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material such as sand, vermiculite, or diatomaceous earth, and transfer to a suitable container labeled for later disposal. Section 7 - Handling and Storage - 2 -

Handling: Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation. Storage: Store tightly capped in a cool, dry, well-ventilated area away from incompatible materials. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities using or storing this material should be equipped with an eyewash and safety shower. Provide local exhaust or general dilution ventilation. Exposure Limits: Chemical Name: ACGIH NIOSH OSHA Sodium Carbonate None None None Sodium Bicarbonate None None None Water None None none OSHA Vacated PELs: None Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133. Do not wear contact lenses when working with chemicals. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134. Always use a NIOSH-approved respirator when necessary. Section 9 - Physical and Chemical Properties Physical State: Liquid Color: Colorless Odor: Odorless ph: Alkaline Vapor Pressure: Vapor Density: Evaporation Rate: Viscosity: Boiling Point: Freezing/Melting Point: Decomposition Temperature: Solubility in water: Soluble Specific Gravity/Density: 1.0 Molecular Formula: Molecular Weight: - 3 -

Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, excess heat. Incompatibilities with Other Materials: Acids Hazardous Decomposition Products: Carbon dioxide Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS: CAS# 7732-18-5: ZC0110000 CAS# 497-19-8: VZ4050000 CAS# 144-55-8: VZ0950000 LD50/LC50: CAS# 7732-18-5: Oral, rat: LD50 = >90 ml/kg CAS# 497-19-8: Oral, rat: LD50 = 4090 mg/kg Inhalation, rat: LC50 = 2300 mg/m3/2h CAS# 144-55-8 : Oral, rat: LD50 = 4220 mg/kg Carcinogenicity: CAS# 7732-18-5: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. CAS# 497-19-8: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. CAS# 144-55-8: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. Epidemiology: Teratogenicity: Reproductive: Mutagenicity: Neurotoxicity: No information found. Section 12 - Ecological Information - 4 -

Section 13 - Disposal Considerations Dispose of in accordance with Federal, State, and local regulations. US DOT Shipping Name: Not regulated Hazard Class: UN Number: Packing Group: Section 14 - Transport Information Section 15 - Regulatory Information US Federal TSCA: CAS# 7732-18-5 is listed on the TSCA Inventory. CAS# 497-19-8 is listed on the TSCA Inventory. CAS# 144-55-8 is listed on the TSCA Inventory. SARA Reportable Quantities (RQ): CERCLA/SARA Section 313: OSHA - Highly Hazardous: US State State Right to Know: California Regulations: None European/International Regulations Canadian DSL/NDSL: CAS# 7732-18-5 is listed on the Canadian Domestic Substances List. CAS# 497-19-8 is listed on the Canadian Domestic Substances List. CAS# 144-55-8 is listed on the Canadian Domestic Substances List. Canada Ingredient Disclosure List: CAS# 7732-18-5 is not listed on the Canadian Ingredient Disclosure List. CAS# 497-19-8 is listed on the Canadian Ingredient Disclosure List. CAS# 144-55-8 is not listed on the Canadian Ingredient Disclosure List. Section 16 - Other Information - 5 -

MSDS Creation Date: January 1, 2001 Revision Date: October 11, 2012 Material Safety Data Sheet Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc. assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application. - 6 -