MATERIAL SAFETY DATA SHEET Product name Synonym(s) 800001739 CAS # Product Use Manufacturer 1. Product and Company Identification Gumout X Fuel Injector Cleaner Mixture Fuel Injector Cleaner ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON L7G 0C6 CA Phone: 1-905-693-8900 Emergency Telephone: 1-877-504-935. Hazards Identification Emergency overview WARNING COMBUSTIBLE LIQUID AND VAPOUR. CONTAINS MATERIAL WHICH MAY CAUSE CANCER. MAY CAUSE SKIN IRRITATION. MAY CAUSE EYE IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. Potential short term health effects Routes of exposure Eyes Skin Eye, Skin contact, Skin absorption,, Ingestion. May be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Ingestion Target organs Chronic effects Signs and symptoms Isopropylbenzene (CAS 98-8-8) Potential environmental effects See section 1. May cause respiratory irritation. Can be absorbed through the skin. Aspiration of material into lungs can cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. Eyes. Skin. Respiratory system. Blood. Prolonged or repeated exposure can cause drying, defatting and dermatitis. Contains material which may cause cancer. Symptoms may include redness, oedema, drying, defatting and cracking of the skin. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. 3. Composition/Information on Ingredients Components CAS # Percent Solvent naphtha (petroleum), heavy aliphatic Solvent naphtha (petroleum), light aromatic 1,,4-Trimethyl benzene Polyolefin alkyl phenol alkyl amine (HMIRA # 8109) 1,3,5-Trimethylbenzene Isopropylbenzene 6474-96-7 60-100 6474-95-6 3-7 95-63-6 1-5 Proprietary 1-5 108-67-8 0.5-1.5 98-8-8 0.1-1 #01 Page: 1 of 7
4. First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. If you feel unwell, seek medical advice (show the label where possible). Show this safety data sheet to the doctor in attendance. Keep away from sources of ignition. No smoking. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Combustible by WHMIS criteria. Dry chemical. Carbon dioxide. Foam. Sand. Water Fog. Do not use water jet. Material will float and may ignite on surface of water. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Irritating and toxic gases or fumes may be released during a fire. Oxides of nitrogen. Oxides of carbon. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Remove sources of ignition. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills to original containers for re-use. 7. Handling and Storage Handling Storage Avoid contact with eyes, skin and clothing. Avoid breathing vapours or mists of this product. Use only with adequate ventilation. Use good industrial hygiene practices in handling this material. When using do not eat or drink. Wash thoroughly after handling. Keep container tightly closed. Keep away from heat and flame. Do not store at temperatures above 10 F (49 C). Store in a closed container away from incompatible materials. Keep out of reach of children. #01 Page: of 7
Occupational exposure limits US. ACGIH Threshold Limit Values Components 1,,4-Trimethyl benzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Isopropylbenzene (CAS 98-8-8) Exposure limits Engineering controls Personal protective equipment Eye/Face protection Hand protection 8. Exposure Controls/Personal Protection Type TWA TWA TWA Value 5 ppm 5 ppm 50 ppm Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH. Use only under good ventilation conditions or with respiratory protection. Wear safety glasses with side shields. Rubber gloves. Confirm with a reputable supplier first. Skin and body protection As required by employer code. Respiratory protection General hygiene considerations Appearance Colour Form Odour Odour threshold Physical state ph Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability Limits in Air, Upper, % by Volume Flammability Limits in Air, Lower, % by Volume Heat of combustion Vapour pressure Vapour density Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practices. When using do not eat or drink. Clear Light yellow Liquid Mild Kerosene Liquid. 9. Physical and Chemical Properties 80.6 C (177.0 F) Setaflash Closed Tester Specific gravity 0.78-0.8 Partition coefficient (n-octanol/water) Solubility (Water) Relative density Viscosity VOC Percent volatile Negligible 0.83 g/cm3 (ASTM D-405) #01 Page: 3 of 7
10. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products This product may react with strong oxidising agents. Hazardous polymerisation does not occur. Stable under recommended storage conditions. Heat, open flames, static discharge, sparks and other ignition sources. Avoid high temperatures. Do not mix with other chemicals. Strong oxidising agents. May include and are not limited to: Irritating and/or toxic fumes and gases may be emitted upon the products decomposition. Oxides of nitrogen. Oxides of carbon. 11. Toxicological Information Toxicological data Components Species 1,,4-Trimethyl benzene (CAS 95-63-6) Rat Rat 1,3,5-Trimethylbenzene (CAS 108-67-8) Rat Isopropylbenzene (CAS 98-8-8) Mouse Rat Solvent naphtha (petroleum), heavy aliphatic (CAS 6474-96-7) Test results > 3160 mg/kg >= 3160 mg/kg > 000 ppm, 48 Hours 3661 ppm 380 mg/kg 4 mg/m3/4h 3000 mg/kg 8970 mg/kg 3160 mg/kg 000 ppm, 7 Hours 4.7 mg/l, Hours 8000 mg/l/4h 8000 ppm, 4 Hours 1400 mg/kg > 3000 mg/kg 500 mg/kg #01 Page: 4 of 7
Components Species Solvent naphtha (petroleum), light aromatic (CAS 6474-95-6) Rat Test results 3000 mg/kg 5. mg/l/4h 4700 mg/kg Effects of acute exposure Eye contact Skin contact May be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Ingestion Sensitisation Chronic effects Carcinogenicity Isopropylbenzene (CAS 98-8-8) May cause respiratory irritation. Can be absorbed through the skin. Aspiration of material into lungs can cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. IARC Monographs. Overall Evaluation of Carcinogenicity Mutagenicity Isopropylbenzene (CAS 98-8-8) Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Hazardous by WHMIS criteria. Contains a potential carcinogen. Isopropylbenzene - IARC group B (possibly carcinogenic) 1. Ecological Information Volume 101 - B Possibly carcinogenic to humans. Ecotoxicity Ecotoxicological data Components 1,,4-Trimethyl benzene (CAS 95-63-6) Crustacea Aquatic Fish See below EC50 1,3,5-Trimethylbenzene (CAS 108-67-8) Aquatic Fish Isopropylbenzene (CAS 98-8-8) Algae Crustacea Aquatic Fish IC50 EC50 Species Daphnia Fathead minnow (Pimephales promelas) Goldfish (Carassius auratus) Algae Daphnia Solvent naphtha (petroleum), light aromatic (CAS 6474-95-6) Crustacea EC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) Daphnia Test results 6.14 mg/l, 48 Hours 7.19-8.8 mg/l, 96 hours 9.89-15.05 mg/l, 96 hours.6 mg/l, 7 Hours 0.6 mg/l, 48 Hours.7 mg/l, 96 hours 6.14 mg/l, 48 Hours Persistence and degradability #01 Page: 5 of 7
Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Isopropylbenzene 3.66 Chemical fate information 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations. Review federal, provincial, and local government requirements prior to disposal. 14. Transport Information Transportation of Dangerous Goods (TDG- Canada) Basic shipping requirements: UN number UN168 Proper shipping name PETROLEUM DISTILLATES, N.O.S.; Hazard class 3 Packing group III Special provisions 9 TDG Canadian federal regulations 15. Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada NPRI VOCs with Additional Reporting Requirements: Mass reporting threshold/identification Number 1,,4-Trimethyl benzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Solvent naphtha (petroleum), light aromatic (CAS 6474-95-6) Canada WHMIS Ingredient Disclosure: Threshold limits WHMIS status 1 TONNES 1 TONNES 1 TONNES 1,,4-Trimethyl benzene (CAS 95-63-6) 0.1 % 1,3,5-Trimethylbenzene (CAS 108-67-8) 0.1 % Isopropylbenzene (CAS 98-8-8) 1 % WHMIS Classification WHMIS labeling Controlled Class B - Division 3 - Combustible Liquid, Class D - Division A, B #01 Page: 6 of 7
Inventory status Country(s) or region Inventory Name On Inventory (Yes/No)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Severe Serious Moderate Slight Minimal LEGEND 4 3 1 0 HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION * 0 X 0 Disclaimer Issue date Effective date Expiry Date Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 8-November-014 01-December-014 01-December-017 Prepared by Dell Tech Laboratories Ltd. Phone: (519) 858-501 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z400.1/Z19.1-010 Standard. #01 Page: 7 of 7