Material Safety Data Sheet Sodium Carbonate Solutions. Section 1 - Chemical Product and Company Identification

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An ISO9001 Certified Company Material Safety Data Sheet Section 1 - Chemical Product and Company Identification MSDS Name: Catalog Numbers: LC22970, LC22975, LC22980, LC22990, LC23000, LC23020, LC23350, LC23380, LC23390 Synonyms: None Company Identification: LabChem Inc 200 William Pitt Way Pittsburgh, PA 15238 Company Phone Number: (412) 826-5230 Emergency Phone Number: (800) 424-9300 CHEMTREC Phone Number: (800) 424-9300 or 011-703-527-3887 Section 2 Composition, Information on Ingredients CAS# Chemical Name: Percent 7732-18-5 Water >89 497-19-8 Sodium carbonate 0.12-10.6 Section 3 - Hazards Identification Emergency Overview Appearance: Clear, colorless solution Caution. May cause eye and skin irritation. May cause respiratory and digestive tract irritation. Target Organs: None known. Potential Health Effects Eye: May cause eye irritation. May cause skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: May cause respiratory irritation. Chronic: Repeated exposure may cause dermatitis and conjunctivitis. - 1 -

Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence of chemical remains. Get medical aid at once. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid. Ingestion: Do not induce vomiting unless directed by qualified medical personnel. If victim is conscious, give 2-4 cupfuls of water to dilute the alkali. Get medical aid. Inhalation: Move victim to fresh air. If breathing is difficult, give oxygen. Give artificial respiration if necessary. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Autoignition Temperature:. Flash Point:. NFPA Rating: Health- 1, Flammability- 0, Instability- 0. Explosion Limits: Lower: n/a Upper: n/a Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in suitable containers labeled for later disposal Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. - 2 -

Storage: Store tightly closed at room temperature. Protect from heat and incompatibles. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities using or storing this material should be equipped with an eyewash and safety shower. Provide local exhaust or general dilution ventilation. Exposure Limits: Chemical Name: ACGIH NIOSH OSHA Water Sodium carbonate OSHA Vacated PELs: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133. Do not wear contact lenses when working with chemicals. Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134. Always use a NIOSH-approved respirator when necessary. Section 9 - Physical and Chemical Properties Physical State: Clear liquid Color: Colorless Odor: Odorless ph: Alkaline Vapor Pressure: 14mm Hg @20 C Vapor Density: 0.7 (H2O=1) Evaporation Rate: < Ether Viscosity:. Boiling Point: 212 F (100 C) Freezing/Melting Point: 32 F (0 C) Decomposition Temperature:. Solubility in water: Soluble. Specific Gravity/Density: 1.0 1.1 Molecular Formula:. Molecular Weight:. - 3 -

Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, excess heat. Incompatibilities with Other Materials: Acids, aluminum, phosphorus pentoxide, fluorine, lithium. Hazardous Decomposition Products: Carbon dioxide, toxic fumes of sodium oxide. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS: CAS# 7732-18-5: ZC0110000. CAS# 497-19-8: VZ4050000. LD50/LC50: CAS# 7732-18-5: Oral, rat: LD50 = >90 ml/kg. CAS# 497-19-8: Inhalation, mouse: LC50 =1200 mg/m3/2h Inhalation, rat: LC50 =2300 mg/m3/2h Oral, mouse: LD50 = 6600 mg/kg Oral, rat: LD50 = 4090 mg/kg. Carcinogenicity: CAS# 7732-18-5: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. CAS# 497-19-8: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. Epidemiology: Sodium carbonate is a severe eye, skin, and mucous membrane irritant. Teratogenicity: Reproductive: Mutagenicity: Neurotoxicity: Section 12 - Ecological Information - 4 -

Section 13 - Disposal Considerations Dispose of in accordance with Federal, State, and local regulations. US DOT Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: Section 14 - Transport Information Section 15 - Regulatory Information US Federal TSCA: CAS# 7732-18-5 is listed on the TSCA Inventory. CAS# 497-19-8 is listed on the TSCA Inventory. SARA Reportable Quantities (RQ):. CERCLA/SARA Section 313:. OSHA - Highly Hazardous:. US State State Right to Know: Not available California Regulations: None. European/International Regulations Canadian DSL/NDSL: CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 497-19-8 is listed on Canada's DSL List. Canada Ingredient Disclosure List: CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List. CAS# 497-19-8 is listed on Canada's Ingredient Disclosure List. Section 16 - Other Information MSDS Creation Date: February 17, 1998 Revision Date: November 8, 2011 Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc. assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application. - 5 -