Aristoflex Velvet. Public. Clariant BU ICS Personal Care

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Aristoflex Velvet Clariant BU ICS Personal Care 30.10.2013

2 Clariant, BU ICS Personal Care, 30.10.2013 Consumer Insights: Luxury wanted Consumers are looking for more from their everyday products Not just moisturization or cleansing They want to satisfy their need via small indulgences Consumers want to buy products that make them feel good about themselves Source: Euromonitor

3 Clariant, BU ICS Personal Care, 30.10.2013 What is Aristoflex Velvet? INCI: Polyacrylate Crosspolymer-11 Features - 100% active powder - Preservative-free - EO / PEG- free - Pre-neutralized - Ready to use, easy to incorporate & disperse

4 Aristoflex Velvet offers unique benefits in a wide range of applications smooth and velvety sensory broad ph range and thickening Aristoflex Velvet particle compatibility with solvents

5 Aristoflex Velvet offers unique benefits in a wide range of applications smooth and velvety sensory broad ph range and thickening Aristoflex Velvet particle compatibility with solvents

6 Clariant, BU ICS Personal Care, 30.10.2013 Aristoflex Velvet delivers a superior sensory profile smooth and velvety sensory Soft and Smooth skin feel during application and rub in Leaves skin feeling soft and moisturized due to slower breaking effect Homogenous distribution on skin Diminishes sticky skin feel, even in presence of high glycerin content (up to 9%) Delivers nice shiny and glossy emulsions providing excellent spreadability Our focus is sensorics

7 Clariant, BU ICS Personal Care, 30.10.2013 Suitable for a broad range of formulations smooth and velvety sensory Emulsifier-Free Cream Gels Pampering, quick absorbing, velvet skin feel in a light emulsifier-free gel Day & Night Creams A pleasant velvety, pampering daily care cream, with a small play time, light cushioning effect, and easily absorbing without leaving any sticky residues on the skin. Anti-Aging Creams A rich, nourishing cream leaving a pleasant soft and velvet skin feel. Balms, Serums, Lotions Light, fast absorbing balms, with a pleasant velvet skin feel Facial Toner Soft, velvety feeling, effective skin balancing and cleansing with a soothing effect Cleansing Milks Mild, soft cleansing with a velvet after feel Soothing Hand Sanitizer Effective performance; not drying to the skin. Skin feels well cared for after application Nail Polish Remover Effective performance due to high amount of solvents, also with stabilized particles

8 Aristoflex Velvet offers unique benefits in a wide range of applications smooth and velvety sensory broad ph range and thickening Aristoflex Velvet particle compatibility with solvents

9 Good thickener and texturizer for oil-in-water emulsions and thickening Viscosity @ 1/s [mpas] 50000 40000 30000 20000 10000 0 Emulsion without polymer Emulsion with 0.5% Aristoflex Velvet Gives pleasant texture and body with good spread ability. Gently melts while applying and then leaves skin feeling soft and velvety.

10 Excellent stability at high temperature tan delta 2 1.8 1.6 1.4 1.2 1 0.8 0.6 0.4 0.2 0 25 30 35 40 45 50 55 60 Temperature [ C] and thickening Emulsion without polymer Emulsion with 0.5% Aristoflex Velvet 1% Aristoflex Velvet aqueous solution Aristoflex Velvet shows excellent high temperature stability in formulations

11 Excellent stability at high temperature tan delta < 1 and thickening Emulsion without polymer Emulsion with 0.5% Velvet Emulsion with 0.5% AVC Emulsion with 0.5% Xanthan Emulsion with 0.5% Carrageenan 0 10 20 30 40 50 60 70 Temperature [ C] Aristoflex Velvet supports high temperature stability in formulations

12 Viscosity in aqueous solutions and thickening 1000000 log Viscosity (mpas) 100000 10000 1000 100 0 0.5 1 1.5 2 % Aristoflex Polymer in water 1% aqueous Aristoflex Velvet Gel Aristoflex Velvet is a good gelling agent for aqueous systems with an elegant rheology with a smooth and velvet skin feel

13 Aristoflex Velvet offers unique benefits in a wide range of applications smooth and velvety sensory broad ph range and thickening Aristoflex Velvet particle compatibility with solvents

14 Compatibility with Organic Solvents Viscosity of 1.0% aqueous Aristoflex Velvet solution in combination with isopropanol, acetone and ethanol compatibility with solvents 25000 Viscosity / mpas 20000 15000 10000 5000 Isopropanol Acetone Ethanol 0 0 20 40 60 80 100 amount of solvent (%) Excellent compatibility with high amount of organic solvents

15 Compatibility with Organic Solvents Comparison: Aristoflex Velvet versus competitor compatibility with solvents 60000 Viscosity / mpas 50000 40000 30000 20000 10000 Carbomer = Ultrez 21 Carbomer Aristoflex Velvet 0 20 30 40 50 60 70 80 80 % Ethanol Excellent compatibility with high amount of ethanol compared to Carbomer

16 Turbidity in 50% Organic Solvents Aristoflex Velvet produces clear formulations in the presence of high amounts of solvents compatibility with solvents Turbidity / NTU 10 8 6 4 2 0 NTU Standard Aceton 50% Ethanol 50% Isopropanol Clear if NTU < 10 50% Soothing Hand Sanitizer with 70% Ethanol Aristoflex Velvet has excellent rheological and optical properties with solvents - Ideal for high clarity formulations (toners, gels, nail polish removers, etc.)

17 Aristoflex Velvet offers unique benefits in a wide range of applications smooth and velvety sensory broad ph range and thickening Aristoflex Velvet particle compatibility with solvents

18 Stabilization of various particles Aristoflex Velvet provides excellent suspending and stabilizing properties in a variety of products - even low viscosity formulations particle Stabilization of: colorful beads exfoliating scrubs microcapsules sparkling pearls Nail polish remover with 30% Ethanol, 30% Ethylacetate shimmering particles Excellent of particles for outstanding optical effects

19 Aristoflex Velvet offers unique benefits in a wide range of applications smooth and velvety sensory broad ph range and thickening Aristoflex Velvet particle compatibility with solvents

20 Broad ph usage spectrum Aristoflex Velvet can be used over a wide ph range allowing formulations with good viscosity properties from ph 3-8 broad ph range Viscosity / mpas 25000 20000 15000 10000 5000 Aristoflex Velvet allows easy incorporation of: Alpha Hydroxy Acid (AHA) Benzoic Acid Salicylic Acid due to low ph spectrum 0 0 5 10 15 ph Can be used at low ph allows formaldehyde and paraben-free preservation

21 Clariant, BU ICS Personal Care, 30.10.2013 Proven electrolyte tolerance (viscosity in aqueous solution with 2% polymer) broad ph range 100000 log Viscosity (mpas) 80000 60000 40000 20000 0 0 0.5 1 1.5 2 Salt Tolerance (NaCl %) Carbomer Aristoflex Velvet Proven salt tolerance superior to Carbomer

22 Aristoflex Velvet offers unique benefits in a wide range of applications New smooth & velvet skin feel With good spread ability and absorption ph: 3-8 Formaldehyde & paraben - free preservation High compatibility with AHAs Very easy to use Pre-neutralized broad ph range smooth and velvety sensory Aristoflex Velvet and thickening High temperature Good thickening properties Gives body and texture to formulations Colorful beads Exfoliating scrubs Microcapsules Sparkling pearls Shimmering particles particle compatibility with solvents Excellent compatibility with organic solvents High clarity formulations

23 Formulation Recipes

24 Emulsifier-Free Cream Gel A Myritol 318 Caprylic/Capric Triglyceride Emollient 3.00 % Isopropylpalmitate Emollient 3.00 % Soybean Oil Glycine Soja Emollient 1.00 % B Glycerine Humactant 4.00 % Procedure I Mix the components of A II Mix the components of B III Add C to A IV Add II to III and stir until the cream is homogenious V Add D to IV and stir for 10 minutes VI Finaly adjust the ph with E to 5.5-6.0 Water ad 100 % C Aristoflex Velvet (Clariant) Polyacrylate Crosspolymer-11 Rheology Modifier 1.50 % D Parfume Cotton 0.15 % Nipaguard POB (Clariant) Phenoxyethanol (and) Piroctone Olamine (and) Benzoic Acid Preservative 0.80 % Viscosity (Brookfield, 20 C 20 rpm): 14650 mpas Appearance: White Cream Gel Clariant Internal No: AVI 8769 E NaOH 20% Neutralizer q.s.

25 Day Cream A Myritol 318 Caprylic/Capric Triglyceride Cetiol MM Myristyl Myristate Lanette O Cetearylalkohol Imwitor 370 Glyceryl Stearate Citrate Eutanol G Octyldodecanol Emollient 3.00 % Emollient 2.50 % Emolient 2.00 % Emulsifier 1.00 % Emollient 1.00 % Procedure I Mix the components of A and melt at approx. 80 C. II Mix the components of B and heat at approx. 80 C. III Add C to I. IV Add II to III and stir until cool. V Add D one after another to IV and stir until homogeneous. VI Finaly adjust the ph to 6-6.5 with E. B Glycerin Humectant 7.50 % C Water ad 100 % Aristoflex Velvet (Clariant) Polyacrylate Crosspolymer-11 Rheology modifier 0.60 % D Ethanol Diluent 3.00 % Xiameter PMX 200 50cs Dimethicone Skin Conditioning 3.00 % Appearance: White cream Viscosity (Brookfield, 20 C 20 rpm): 24000 mpas Clariant internal No: AVI 1643 Parfume Cotton 0.15% Nipaguard POM (Clariant) Phenoxyethanol (and) Piroctone Olamine (and) Methylparaben Preservative 0.80 % E NaOH 10% Neutralizer q.s.

26 Nourishing Cream A Tegosoft TN Alkylbenzoate Cetiol OE Dicaprylyl Ether Emollient 3.00 % Emollient 2.50 % Squalan Emollient 2.00 % Cetylalkohol Stabilizer 1.50 % Lanette 22 Behenyl Alcohol Cetiol SB 45 Butyrospermum Parkii (Shea) Butter Lanette O Cetearyl Alcohol Cetiol MM Myristyl Myristate Imwitor 370 Glyceryl Stearate Citrate Stabilizer 2.00% Emollient 5.00 % Stabilizer 2.20% Emollient 1.50 % Emulsifier 2.00 % Procedure I Mix the components of A II Mix the components of B III Add C to A IV Add II to III and stir until the cream is homogenious V Add D to IV and stir for 10 minutes VI Finaly adjust the ph with E to 5.5-6.0 Appearance: soft white cream Viscosity (Brookfield, 20 C 20 rpm): 21350 mpas Clariant internal No: Ba 90-16 B Glycerine Humactant 7.00% Water ad100 % C Aristoflex Velvet (Clariant) Polyacrylate Crosspolymer-11 Rheology Modifier 0.30 % D Xiameter PMX 200 50cs Dimethicone Dow Corning 245 Cyclopentasiloxane Skin Conditioning 1.50 % Skin Conditioning 1.50 % Parfume Cotton 0.30 % Nipaguard POM (Clariant) Phenoxyethanol (and) Piroctone Olamine (and) Methylparaben Preservative 0,80 % E NaOH 10% Neutralizer q.s.

27 Gentle to Your Skin Toner A Emulsogen HCO 040 PEG-40 Hydogentated Castor Oil Solubulizer 1.00 % Fragrance 0.2 % B Water ad 100 % Ucare JR 400 Polyquaternium-10 Skin Conditioning Agent 0.025 % C Trisodium EDTA Skin Conditioning Agent 0.25 % D Glycerin Humectant 2.00 % Citric Acid 25 % Neutralizer q.s. Aristoflex Velvet (Clariant) Polyacrylate Crosspolymer-11 Rheology Modifier 0.50 % E Nipaguard M (Clariant) Methylparabene Polyglykol 400 (Clariant) PEG-8 Preservative 0.1 % Skin Conditioning Agent 1.5 % Procedure Mix components of A II Mix components of B and dissolve thoroughly III Add components of C to II and adjust ph to 6.0 IV Add III to II and stir until dissolved V Add D to IV and stir until dissolved VI Meanwhile blend the components of E and add to V VII Control and if necessary adjust ph to 6 Appearance: clear, light viscous liquid Viscosity (Brookfield, 20 C 20 rpm): 410 mpas Clariant internal No: 122/10-7

28 28 Soothing Hand Sanitizer A Water Ad 100 Aristoflex Velvet (Clariant) Polyacrylate Crosspolymer-11 Rheology Modifier 0.45 % B Ethanol Diluent 70.00 % Glycerin Humectant 2.00 % Dow Corning 5324 PEG-12 Dimethicone Aloe Vera Gel Aloe Barbadensis Leaf Juice Conditioning Agent 0.50% Active 0.10 % Procedure I Mix the components of A. II After completely solution add the components of B. III Stir until homogenous. ph: 6.6 Appearance: clear gel Viscosity (Brookfield, 20 C 20 rpm): 2940 mpas Clariant internal No: MiH 189-90

29 Clariant, BU ICS Personal Care, 30.10.2013 Aristoflex Velvet complements our existing polymer range

30 Clariant, BU ICS Personal Care, 30.10.2013 Aristoflex Velvet complements our existing polymer range

31 Clariant, BU ICS Personal Care, 30.10.2013 Aristoflex Velvet complements our existing polymer range

32 Clariant, BU ICS Personal Care, 30.10.2013 Aristoflex Velvet complements our existing polymer range

33 Clariant, BU ICS Personal Care, 30.10.2013 Aristoflex Velvet complements our existing polymer range

34 Clariant, BU ICS Personal Care, 30.10.2013 Aristoflex Velvet complements our existing polymer range

35 Clariant, BU ICS Personal Care, 30.10.2013 Aristoflex Velvet complements our existing polymer range

Thank you very much for your attention! Clariant BU ICS Personal Care 30.10.2013