SAFETY DATA SHEET Issuing Date: 12-Apr-2016 Version 1 1. IDENTIFICATION Product Name Product ID: Product Type: Recommended Use Manufacturer The Art of Shaving Eau de Toilette Green 90711674_RET_NG Finished Product - Consumer (Retail) Use Only Personal Beauty Care Product. The Procter & Gamble Company Sharon Woods Innovation Center 11510 Reed Hartman Highway Cincinnati OH 45241 +1 513 626-2500 Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5 Professional Products: 1-800-465-2945; Retail Products: 1-800-465-2945 E-mail Address Emergency Telephone pgsds.im@pg.com Transportation (24 HR) CHEMTREC - 1-800-424-9300 (U.S./ Canada) or 1-703-527-3887 Mexico toll free in country: 800-681-9531 2. HAZARD IDENTIFICATION "Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product. This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Eye Damage / Irritation Category 2B Flammable Liquids Category 2 Signal Word DANGER Hazard Statements Hazard pictograms Causes eye irritation Highly flammable liquid and vapor Page 1 / 7
Precautionary Statements Precautionary Statements - Response Precautionary Statements - Storage Precautionary Statements - Disposal Hazards not otherwise classified (HNOC) Keep container tightly closed Keepawayfrom heat/sparks/openflames/hotsurfaces. Nosmoking Wash hands thoroughly after handling In case of fire: Use water, CO2, dry chemical, or foam for extinction IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Store in a well-ventilated place. Keep cool Dispose of contents/container to an approved waste disposal plant Dispose of contents/container in accordance with local regulation None 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation Chemical Name Synonyms Trade Secret CAS-No Weight % Ethanol Ethanol No 64-17-5 40-100 Linalyl acetate 1,6-Octadien-3-ol, No 115-95-7 1-5 3,7-dimethyl-, 3-acetate Geranyl acetate 2,6-Octadien-1-ol, No 105-87-3 0.1-1.0 3,7-dimethyl-, 1-acetate, (2E)- Limonene D-Limonene No 5989-27-5 0.1-1.0 Benzyl salicylate Benzoic acid, 2-hydroxy-, No 118-58-1 0.1-1.0 phenylmethyl ester Coumarin 2H-1-Benzopyran-2-one No 91-64-5 0.1-1.0 First aid measures for different exposure routes 4. FIRST AID MEASURES Eye contact Skin contact Ingestion Inhalation IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Not an expected route of exposure. If swallowed:. Clean mouth with water and afterwards drink plenty of water. None under normal use. Page 2 / 7
Most important symptoms/effects, acute and delayed May cause eye irritation. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flammable properties Suitable extinguishing media Unsuitable Extinguishing Media Special hazard Special protective equipment for fire-fighters Specific hazards arising from the chemical Flammable liquid and vapor Carbon dioxide (CO 2). Dry chemical. Alcohol-resistant foam. Do not use a solid water stream as it may scatter and spread fire. Fumes may catch fire. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. None. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Advice for emergency responders None under normal use conditions. Use personal protective equipment as required. Methods and materials for containment and cleaning up Methods for containment Methods for cleaning up.. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Keep away from open flames, hot surfaces and sources of ignition. Keep container closed when not in use. Never return spills in original containers for re-use. Use personal protective equipment as required. Keep out of the reach of children. Conditions for safe storage, including any incompatibilities Technical measures/storage conditions Storage Conditions Incompatible products Keep away from open flames, hot surfaces and sources of ignition. Store away from other materials. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a cool/low-temperature, well-ventilated, dry place away from heat and ignition sources. None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Page 3 / 7
Exposure Guidelines Exposure guidelines are not relevant when product is used as intended in a household setting. Exposure controls Engineering Measures Manufacturing Sites: Ensure adequate ventilation Not applicable Personal Protective Equipment Eye Protection Manufacturing Sites: Safety glasses with side-shields No special protective equipment required Hand Protection Manufacturing Sites: Wearprotectivenaturalrubber,nitrilerubber,Neoprene orpvcgloves Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion Protective gloves Skin and Body Protection Manufacturing Sites: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact No special protective equipment required Respiratory Protection No special protective equipment required 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20 C Appearance Odor Odor threshold Liquid colorless Clear Pale Yellow amber characteristic Property Values Note ph value 5-7 Melting/freezing point Boiling point/boiling range 78 C / 172 F Flash point 15-21 C / 59-69.8 F Closed cup Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limit Lower Flammability Limit Vapor pressure Vapor density Relative density Water solubility Partition coefficient: n-octanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer products. Page 4 / 7
10. STABILITY AND REACTIVITY Reactivity Stability Hazardous polymerization Hazardous Reactions Conditions to Avoid Materials to avoid None under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. None under normal processing. Keep away from open flames, hot surfaces and sources of ignition. None in particular. Hazardous Decomposition Products None under normal use. Product Information Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Inhalation Skin contact Ingestion Eye contact Avoid contact with eyes. Irritating to eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Respiratory sensitization Germ cell mutagenicity Neurological Effects Reproductive toxicity Developmental toxicity Teratogenicity STOT - single exposure STOT - repeated exposure Target Organ Effects Aspiration hazard Carcinogenicity Irritating to eyes. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability Bioaccumulative potential Mobility Other adverse effects.... 13. DISPOSAL CONSIDERATIONS Page 5 / 7
Waste treatment Waste from Residues / Unused Products Contaminated packaging California Hazardous Waste Codes (non-household setting) Disposal recommendations Products covered by this MSDS, in their original form, when disposed as waste, are ignitable hazardous waste, D001, according to Federal RCRA regulations(40 CFR 261). Disposal should be in accordance with applicable regional, national and local laws and regulations. 331 Products covered by this SDS, in their original form, when disposed from a commercial facility as waste, are ignitable hazardous waste, D001, according to Federal RCRA regulations(40 CFR 261). Disposal should be in accordance with Local, State and Federal regulations. 14. TRANSPORT INFORMATION DOT UN no UN1266 UN Proper shipping name Perfumery products Description UN1266, Perfumery products, 3, II, Ltd. Qty. Hazard Class 3 Packing Group II Special Provisions 149, IB2, T4, TP1, TP8 Emergency Response Guide 127 Number DOT Comment Consumer retail packages may be shipped as Limited Quantity IMDG UN Number UN1266 UN Proper shipping name Perfumery products Description UN1266, Perfumery products, 3, II, (15 C c.c.), Ltd. Qty. Transport hazard class(es) 3 Packing Group II Special precautions for user 163 EmS-No F-E, S-D IMDG Comment Consumer retail packages may be shipped as Limited Quantity IATA UN no UN1266 UN Proper shipping name Perfumery products Description UN1266, Perfumery products, 3, II, Ltd. Qty. Hazard Class 3 Packing Group II ERG Code 3L IATA comment Can also be shipped as ID8000 Consumer Commodity The shipper is responsible for identifying any exemptions, including Limited Quantity, that may apply based on package size U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 CERCLA Page 6 / 7
Food and Drug Administration (FDA) The product described in this Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Clean Water Act California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) International Inventories United States Product is a personal care product and regulated under FDA. Canada This product is in compliance with CEPA for import by P&G. Legend United States Toxic Substances Control Act Section 8(b) Inventory (TSCA) CEPA - Canadian Environmental Protection Act Perfumes contained with the products comply with appropriate IFRA guidance. 16. OTHER INFORMATION Issuing Date: 12-Apr-2016 Revision Date: 12-Apr-2016 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7