PRODUCT SAFETY DATA SHEET MSDS No.: 31154 Version No.: 10 Revision Date: 27 Jul, 2006 1. PRODUCT AND COMPANY IDENTIFICATION Label Name: Outer / Shipper Name: Other Names: Product Name: Proper Shipping Name: Poisons Schedule No. (SUSDP) Australia: Recommended / Intended Use: Finish Power Powder Finish Lemon Powder Finish Regular Powder Finish Orange Powder None Finish Powder Not scheduled Detergent for use in domestic automatic dishwashers Customer Product Codes: 35051001 35054001 35057001 0036006 0038207 35054002 35057002 0036007 0038209 35068002 0036008 0039837 Variant Name: Regular Regular Regular Regular Regular Lemon Lemon Lemon Lemon Lemon Orange Orange Sizes: 240g bottle 1kg box 2kg box 1kg bottle 2kg bottle 1kg box 2kg box 1kg bottle 2kg bottle 3kg bottle 1kg bottle 2kg bottle Supplier: AUSTRALIA Reckitt Benckiser (Australia) Pty Limited 44 Wharf Road, West Ryde NSW 2114 TEL: (02) 9857 2000 NEW ZEALAND Reckitt Benckiser (New Zealand) Limited Lincoln Manor 289 Lincoln Road, Henderson, Auckland 1231 TEL: (09) 839 0200 Emergency Telephone Number: After Hours (5 pm to 8 am EST Australia): +61 (02) 9857 2444 MSDS No.: 31154 Version No.: 10 Page 1 of 11
POISONS CENTRE INFORMATION Australian Business Number (ABN): Australia - 13 1126 New Zealand - 0800 764 766 or 0800 POISON 17 003 274 655 2. HAZARDS IDENTIFICATION Product Hazard Classification HAZARDOUS SUBSTANCE ACCORDING TO CRITERIA OF NOHSC AUSTRALIA NON-DANGEROUS GOODS ACCORDING TO ADG CODE Hazard Classification: Xi - Irritant Risk Phrase(s): Safety Phrase(s): Safety Combination Phrases: R36 - Irritating to eyes. S 2 - Keep out of the reach of children. S46 - If swallowed, seek medical advice immediately and show this container or label. S24/25 - Avoid contact with skin and eyes. UN Number: Proper Shipping Name: Dangerous Good Class: Subsidary Risk: Hazchem code: Packing Group: Not a dangerous good Page 2 of 11
3. COMPOSITION / INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Chemical Name CAS No. Proportion (% w/w) Sodium tripolyphosphate 7758-29-4 10 - <30 Sodium sulphate 7757-82-6 10 - <30 Sodium carbonate peroxyhydrate 15630-89-4 1 - <5 Protease 9014-01-1 0.1 - <1 Alpha-amylase 9000-90-2 <0.1 Alkoxylated alcohol 68937-66-6 0.1 - <1 Benzotriazole 95-14-7 0.1 - <1 Sodium silicate (amorphous non-crystalline) 1344-09-8 1 - <5 Disodium carbonate 497-19-8 30-60 The other ingredients to 100%w/w are classified as not hazardous according to NOHSC (Australia) 4. FIRST AID MEASURES General Advice: Show this safety data sheet to the doctor in attendance. If poisoning occurs, contact a doctor or Poisons Information Centre. (Phone: Australia 13 1126, New Zealand 0800 764 766 or 0800 POISON) Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a doctor. Skin Contact: Inhalation: Ingestion: Rinse immediately with plenty of water for at least 15 minutes. If irritation occurs and persists, contact a doctor. Move to fresh air. If breathing difficulties are experienced, seek medical advice. Give 2 glasses of water to drink. Do not induce vomiting. Contact a doctor or Poisons Information Centre. Major effects of Acute Exposure: Irritating to eyes. Major effects of Chronic Exposure: Medical Attention and Special Treatment: The chronic effects of this product has not been determined. Treat symptomatically Page 3 of 11
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Hazards from Combustion Products: Precautions for Fire Fighters: Hazchem code: Water spray Foam Carbon dioxide (CO2) Thermal decomposition can lead to release of irritating gases and vapours. This product contains inorganic oxidants that can liberate oxygen when heated and contribute to the combustion process. Carbon dioxide can also be released in a fire. 6. ACCIDENTAL RELEASE MEASURES Emergency and Evacuation Procedures: Personal Precautions: Environmental Precautions: Contain and signpost spill. Depending on spill size, collect spill according to instructions below. Avoid dust formation. Do not let product enter drains or natural waterways. Methods and Materials for Containment and Clean Up Minor / Small Spills: Major / Large Spills: Scoop up spill and wash area with water. Shovel into suitable container for disposal. Moisten product if dust generation is of concern. 7. HANDLING AND STORAGE HANDLING Precautions for Safe Handling: Safe Handling Advice: Ensure adequate ventilation. Avoid contact with skin and eyes. STORAGE Conditions for Safe Storage: Incompatible Products: KEEP OUT OF REACH OF CHILDREN. Keep product and empty container away from heat and sources of ignition. Store in a cool, dry area out of direct sunlight. Acids. Bases. Reducing agents Moisture Page 4 of 11
8. EXPOSURE CONTROLS / PERSONAL PROTECTION National Exposure Standards: Exposure Standards have been set for the following ingredients: Protease (9014-01-1) Australian TWA = 0.00006 mg/m³ Australian Exposure Standard Peak Limitation Peak limitation TWA - The Time-Weighted Average airborne concentration over an eight-hour working day, for a five-day working week over an entire working life. According to current knowledge this concentration should neither impair the health or, not cause undue discomfort to, nearly all workers. Peak Limitation - A ceiling concentration which should not be exceeded over a measurement period which should be as short as possible but not exceeding 15 minutes. Biological Limit Values Engineering Controls: Personal Protective Equipment: Eye Protection: Hand Protection: Skin and Body Protection: Respiratory Protection: Hygiene Measures: No biological limit values allocated. Ensure adequate ventilation. Maintain air concentrations below exposure standards. Use the following personal protective equipment when handling bulk quantities of product: Goggles. PVC or other plastic material gloves. Lightweight protective clothing. Breathing apparatus only if aerosol or dust is formed. Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Appearance: Colour: ph Vapour Pressure: Vapour Density Solid Powder White with blue flecks 11.0-11.4 (50% aqueous @ 25 C) Negligible Not determined. Water Solubility: 300g/L @ 20 C Fat solubility: Specific Gravity / Density: Flash Point: Slightly soluble. 1.1-1.2 g/ml (untapped) Not flammable Available Oxygen: 0.33-0.63% Revision Date: 27 Jul, 2006 MSDS No.: 31154 Version No.: 10 Product Name: Finish Powder Page 5 of 11
10. STABILITY AND REACTIVITY Chemical Stability: Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Hazardous Reactions: Polymerization: Stable under recommended storage conditions. Prolonged exposure to high or low temperatures. Acids, Bases, Water., Reducing agents. Oxides of carbon, silicon, sulphur, phosphorous, and oxygen. This product contains inorganic oxidants that can liberate oxygen when heated. Carbon dioxide can also be released when heated. Hazardous polymerisation does not occur. Page 6 of 11
11. TOXICOLOGICAL INFORMATION PRODUCT TOXICITY DATA The toxicology of this product has not been determined. The hazard identifications in Sections 2, 11 and 15 of the MSDS were derived from the known effects of the individual ingredients and their concentrations in the product. COMPONENT TOXICITY DATA The following component toxicity data was considered to determine the overall toxicity of this product. Sodium silicate (amorphous non-crystalline) (1344-09-8) LD50 Oral 1300-2200 mg/kg rat Eye Irritation Severe eye irritation Skin Irritation Irritating to skin Sodium tripolyphosphate (7758-29-4) LD50 Oral 4100 mg/kg rat LD50 Dermal >7940 mg/kg rabbit Disodium carbonate (497-19-8) LD50 Oral 4090 mg/kg rat Eye Irritation Moderate eye irritation Sodium carbonate peroxyhydrate (15630-89-4) LD50 Oral 1900-3000 mg/kg rat Inhalation LC50 4h 4.58 mg/l rat Eye Irritation Irritating to eyes Skin Irritation Irritating to skin and mucous membranes Protease (9014-01-1) Sensitization This ingredient is a known skin sensitiser. Benzotriazole (95-14-7) LD50 Oral 560 mg/kg rat LD50 Dermal >2000 mg/kg rabbit Inhalation LC50 4h 1910 mg/m 3 3h Eye Irritation Slight irritant Skin Irritation Non-irritant SUMMARY OF PRODUCT TOXICITY EFFECTS Acute Effects: Eye irritation: Skin irritation: Inhalation Ingestion Chronic Effects: The product is expected to have the following acute health effects: Will cause irritation to the eye May cause irritation of the skin. Dusts may cause irritation to the upper respiatory tract. Due to the alkalinity of this product, damage to the gastrointestinal tract may be expected. Percarbonate may release oxygen and cause stomach discomfort. The chronic toxicity of this product has not been determined. Product contains enzymes (respiratory sensitisers), hence chronic exposure to dusts may elicit allergic response in sensitised individuals.. Revision Date: 27 Jul, 2006 MSDS No.: 31154 Version No.: 10 Product Name: Finish Powder Page 7 of 11
12. ECOLOGICAL INFORMATION PRODUCT ECOTOXICITY DATA The ecotoxicity of this product has not been determined. However, the following component information is available. COMPONENT ECOTOXICITY DATA The following component ecotoxicity data was considered to determine the overall ecotoxicity of this product. Sodium tripolyphosphate (7758-29-4) Aquatic toxicity: Sodium sulphate (7757-82-6) Ecotoxicity Data Benzotriazole (95-14-7) Ecotoxicity Data Aquatic toxicity: Disodium carbonate (497-19-8) Ecotoxicity Data LCo Goldorfen = >1600 mg/l 48h EC50 = >1000mg/L (bacteria) (OECD 209) LC50 = 13 mg/l bluegill sunfish 96h Static LC50 = 13500 mg/l fathead minnow 24h LC50 = 17500 mg/l mosquito fish 96h LC50 = 4547mg/L water flea 96h EC50 = 141.6mg/L water flea 48h EC50 = 15.4 mg/l freshwater algae 96h LC50 = 39 mg/l trout 96h LCo Brachydanio rerio = 100mg/L EC50 green algae = 231 mg/l 72h LC50 = 320 mg/l bluegill 96h static SUMMARY OF PRODUCT ECOTOXICITY DATA Ecotoxicity: Biodegradability and Persistence: Mobility: Aquatic life may be affected by ph change from this product. No information available. No information available 13. DISPOSAL CONSIDERATIONS Disposal Methods and Containers: Special Precautions for Landfill or Incineration: Bulk quantities of product must be disposed of according to Local, State and Federal regulations. Contact relevant authority for details. Do not allow bulk product to be disposed of in the sewerage or natural waterways. Waste material may require neutralisation prior to disposal. Good ventilation is required during neutralisation due to the release of gases. Revision Date: 27 Jul, 2006 MSDS No.: 31154 Version No.: 10 Product Name: Finish Powder Page 8 of 11
14. TRANSPORT INFORMATION UN Number: ADG (Australian Road and Rail) Australia Road and Rail Transport: Proper Shipping Name: Dangerous Good Class: Subsidiary Risk: Packing Group: Hazchem code: Classified as Not Dangerous Goods for the purpose of transport by road or rail. Refer to relevant regulations for storage and transport requirements. Not a dangerous good IMDG / IMO (Sea) Proper Shipping Name: Dangerous Good Class: Subsidiary Risk: Packing Group: Not a dangerous good IATA / ICAO (Air) Proper Shipping Name: Dangerous Good Class: Subsidiary Risk: Packing Group: Not a dangerous good Page 9 of 11
15. REGULATORY INFORMATION Product Hazard Classification HAZARDOUS SUBSTANCE ACCORDING TO CRITERIA OF NOHSC AUSTRALIA NON-DANGEROUS GOODS ACCORDING TO ADG CODE Hazard Classification: Risk Phrase(s): Safety Phrase(s): Safety Combination Phrases: Poisons Schedule No. (SUSDP) Australia: Regulatory Approvals: Xi - Irritant R36 - Irritating to eyes. S 2 - Keep out of the reach of children. S46 - If swallowed, seek medical advice immediately and show this container or label. S24/25 - Avoid contact with skin and eyes. Not scheduled Not applicable Australian Inventory of Chemical Substances (AICS): All the constituents of this product are listed on the Australian Inventory of Chemical Substances (AICS). Page 10 of 11
16. OTHER INFORMATION Key: Reason for revision: NOHSC = National Occupational Health and Safety Commission (Australia) SUSDP = Standard for the Uniform Scheduling of Drugs and Poisons (Australia) ADG = Australian Code for the Transport of Dangerous Goods by Road and Rail ADR = International Regulations Concerning the Carriage of Dangerous Goods by Road RID = European Agreements Concerning the International Carriage of Dangerous Goods by Rail IMDG = International Maritime Organization Rules IATA = International Air Transport Association ICAO = International Civil Aviation Organization Update formula & product codes. Revision Date: 27 Jul, 2006 Prepared by: Reckitt Benckiser Regulatory, Safety & Environmental Services (Australia) Phone: +61 2 9857 2000 This MSDS has been prepared according to the National Code of Practice for the Preparation of Safety Data Sheets 2nd Edition [NOHSC:2011(2003)]. The information contained in this Safety Data Sheet was compiled using the latest and most reliable information available to Reckitt Benckiser. The information is provided without warranty, expressed or implied regarding its correctness or accuracy. Similarly no warranty expressed or implied regarding the product described herein shall be created by or inferred from any statement or omission from this Safety Data Sheet nor will Reckitt Benckiser assume any liability for any loss or damage arising out of the use of this information. It is solely the responsibility of the user to determine safe conditions for use of this product and to assume liability for any loss, damage or expense whatsoever arising out of the product's improper use. This document is only current on the day of viewing. Printed copies are UNCONTROLLED unless they are part of a Quality/Technical Manual or attached to a letter referring to a Purchase Order Number. End of Safety Data Sheet Page 11 of 11