MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: CCW-500 Synonyms: Rubberized asphalt. Manufacturer/Supplier Phone Numbers Carlisle Coatings & Waterproofing Incorporated Medical Emergency: 900 Hensley Lane CHEMTREC(USA): (800) 424-930 Wylie, TX 75098 CHEMTREC(International):: Internet Address: www.carlisle-ccw.com Fax Number: (972) 442-0076 Fax Number: (972) 442-0076 MSDS Assistance: (972) 442-6545 Fax On Demand: NA 2. COMPONENT INFORMATION Component CAS No. Percent Hazardous in Blend Range Petroleum Asphalt 8052-42-4 9-25 Yes Hydrotreated Heavy Naphthenic Distillate 64742-52-5 < 20 Yes Calcium Carbonate 1317-65-3 0-50 No This product is hazardous according OSHA 29 CFR 1910.1200. Hazards: Flammable/Combustible No Acute Toxin No Chronic Toxin Pressure No Reactive No Exposure Limit No Carcinogen No Target Organ Other 2A. OTHER INGREDIENTS Greater than 3% Component CAS No. Rubber Copolymer 9003-55-8 Plant Extract 8016-81-7 3. HAZARDS IDENTIFICATION Emergency and Hazards Overview: Contact with hot material may cause thermal burns. Once cool, repeated skin contact with rubberized asphalt may result in slight irritation. Prolonged skin contact may cause an increased risk of skin cancer, liver damage and reproduction effects based on laboratory animals tests. Skin cleansing studies with aromatic oils show that the toxic effects are not likely to occur to humans if good personal hygiene practices are used. May be harmful if swallowed. Read and understand all health and safety information on the product label and Material Safety Data Sheet before use. Page 1 of 6
Ratings Health 3* Flammability 1 Reactivity 0 *Chronic health effects Primary Route of Exposure: Skin x Inhalation x Eye x Ingestion x Health Effect Information Eye Contact: May cause eye irritation if wiped or rubbed into eyes. Skin Contact: May cause skin irritation on prolonged or repeated contact. Inhalation: Inhalation issues only apply when the material is hot (see below). Once cool, inhalation of fumes is unlikely. Ingestion: There are no known health effects due to ingestion. Ingestion is unlikely due to the nature of this product. Medical Conditions Aggravated by Exposure: Prolonged contact with oil residues in this product may produce effects including skin cancer. The International Agency for Research on Cancer (IARC) has concluded that Occupational exposures to oxidized bitumens and their emissions during roofing are probably carcinogenic to humans. While this product is not based on oxidized asphalts, fractions may become oxidized when heated to the necessary application temperature and released to the air. Also, this petroleum-based product contains a variable amount of polycyclic aromatic compounds (PAC s), including polynuclear aromatic hydrocarbons (PAH s) which have been shown to cause cancer and respiratory damage in humans and laboratory animals. See Section 11 for additional information. 4. FIRST AID INFORMATION Eye Contact: Flush with water for 15 minutes. Get medical attention immediately. Skin Contact: Hot Material Immediately drench or immerse area in water to assist cooling. DO NOT try to remove product from burned area after it has cooled. Seek immediate medical attention. Medical personnel can soften and remove cooled product with petroleum jelly or mineral oil. Cool Material - Wipe off and wash skin with soap and water. Promptly remove contaminated clothing and wash before reuse. See a physician if irritation develops. Inhalation: Hot Material If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, trained personnel should administer oxygen. If breathing has stopped, give artificial respiration and seek medical attention. Cool Material - No known adverse effect. Ingestion:. Due to the nature of this product ingestion is unlikely. Consult a physician immediately. Notes to Physician: This product contains asphalt and mineral process oil. Page 2 of 6
5. FIRE AND EXPLOSION INFORMATION Flammable Properties Flash Point: >450 F (>230 C) Flame Extension: NA Flammable Limits in Air Upper Percent: NA Lower Percent: NA Auto ignition Temperature: >650 F (>340 C) Test Method: COC Test Method: NA Test Method: NA NFPA Classification: H 2 F 1 R 0 Extinguishing Media: CO2, foam, dry chemical or water spray. Use water to cool fire-exposed containers. Treat as a fuel oil fire. Fire Fighting Measures Special Fire Fighting Procedures and Equipment: Wear NIOSH/MSHA approved respirators, or self-contained breathing apparatus(scba) and full fire-fighting protective gear. Unusual Fire and Explosion Conditions: None known. Hazardous Combustion By-Products: CO, CO2, unburned hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Personnel Safeguards: Evacuate non-essential personnel to safe areas. Clean-up responders should wear proper protective clothing and gloves before entering the affected area. Regulatory Notifications: Certain component of this product is defined as hazardous according to U.S. EPA. Spill reporting requirements and reportable quantities vary by region. Consult all applicable state and local regulations. For Canada, observe all precautions noted above. Containment and Clean up: Observe above precautions, thoroughly clean the area and remove materials for disposal. Avoid run-off into storm sewers, ditches and waterways. 7. HANDLING AND STORAGE INFORMATION Handling: Avoid prolonged contact with skin. Use protective gloves. Avoid rubbing eyes while handling. When hot, avoid inhaling vapors, fumes or mist. Use this product with adequate ventilation. Storage: Store in dry, cool environment. Keep containers closed when not in use. Empty Container Warnings Drums: NA Plastic: NA Page 3 of 6
8. EXPOSURE CONTROLS / PERSONAL PROTECTION INFORMATION Exposure Limits and Guidelines Component CAS No. Exposure Limit Asphalt 8052-42-4 5 mg/m3 TWA Hydrotreated Naphthenic 64742-52-5 5 mg/m3 TWA, 10 mg/m3 ACGIH Distillate Plant Extract 8016-81-7 OSHA PEL: 15 mg/m3, ACGIH TLV: 10 mg/m3 Personal Protective Equipment Eye/Face Protection: Wear safety goggles and face shield during hot melt application. Skin Protection: Use protective insulation gloves during hot melt application. Respiratory Protection: Provide adequate ventilation to maintain vapors below PEL/TWA. If vapor levels are exceeded, use NIOSH approved respirator, both during and immediately after application, until vapor levels are below limits. Personal Hygiene: Avoid rubbing eyes during handling. Due to the nature of this product ingestion is unlikely. Use good personal hygiene practices to avoid incidental ingestion. Engineering Controls: Follow NIOSH guidelines for controlling exposure to fumes that are found in Asphalt Fume Exposures During the Application of Hot Asphalt to Roofs DHHS (NIOSH) Publication No. 2003-112 (June 2003). These include: 1. Use kettles of appropriate size for the job, 2. Make sure kettle lids fit tightly, close the lid when product is not being added and minimize the number of times that the lid must be opened, 3. Place the kettle downwind from workers, 4. Place the kettle away from air intake vents, doors and windows, 5. Restrict access to the area around the kettle, 6. Calibrate and check the operation of kettle thermometers at least monthly. Ventilation: If material is heated or otherwise made airborne, provide local exhaust or area ventilation to maintain concentration of vapors below 5 mg/m3 PEL/TWA. If conditions are above the maximum PEL/TWA, workers must use appropriate certified respirators in accordance with their company s respiratory protection program, local regulations or 29 CFR 1910.134. Other: Source of clean water should be available in the work area for flushing eyes and skin. Wash thoroughly with soap and water after use and before eating. Page 4 of 6
9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Black rubberized asphalt Odor: Slight petroleum odor ph: NA DOT Corrosivity: NA Boiling Point: >1000 F (>540 C) Melting Point: 190 to 231F Specific Gravity: 1.2-1.5 Pour Point: >300F Solubility in Water: Negligible Octanol/Water Coefficient: Log Kow = NA Vapor Pressure: NA Vapor Density (air=1): NA Volatile by Volume: Negligible Volatile Organic Content: Negligible Molecular Weight: NA Average Carbon Number: NA Viscosity @ 77F: Solid 10. STABILITY AND REACTIVITY INFORMATION Chemical Stability: Stable under normal condition. Conditions to Avoid: Avoid extreme heat, fire and temperature. Incompatible Materials to Avoid: Avoid strong acids, strong oxidizers. 11. TOXICOLOGICAL INFORMATION (will only print available data) Primary Eye Irritation: Irritating Primary Skin Irritation: May be irritating Acute Dermal Toxicity: NA Subacute Dermal Toxicity: NA Dermal Sensitization: NA Inhalation Toxicity: NA Inhalation Sensitization: NA Oral Toxicity: Mineral oil mist, LD50(mouse): 22,000 mg/kg Mutagenicity: NA Carcinogenicity: In October 2011, The International Agency for Research on Cancer (IARC) classified occupational exposures to oxidized bitumen (asphalt) and their emissions during roofing as being probably carcinogenic to humans (Group 2A). The Working group concluded that there was limited evidence in humans for the carcinogenicity of occupational exposures to bitumens and bitumen emissions during roofing. In experimental animals there was limited evidence of carcinogenicity for oxidized bitumens (Class 2), which are mainly used in roofing or waterproofing and sufficient evidence of carcinogenicity for fume condensates of these oxidized bitumens. Reproductive Toxicity: NA Teratogenicity: NA Immunotoxicity: NA Neurotoxicity: NA No other toxicological information available Page 5 of 6
12. ECOLOGICAL INFORMATION Aquatic Toxicity: Not known Terrestrial Toxicity: Not known Chemical Fate and Transport: Not known No other ecological information available 13. DISPOSAL INFORMATION Regulatory Information: Consult all regulations (federal, state, provincial, local etc.) or a qualified waste disposal firm when characterizing waste for disposal. Waste Disposal Methods: Dispose of in accordance with all applicable regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation (DOT) Highway / Rail (Bulk): Not classified Highway / Rail (Non-Bulk): Not classified The DOT description is provided to assist in the proper shipping classification of this product and may not be suitable for all shipping descriptions. International Information Vessel: IMDG Regulated: Not classified IMDG Not Regulated Air: ICAO Regulated: Not classified ICAO Not Other: No other information available. 15. Regulatory Information Regulatory Lists U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory or exempt from listing on the TSCA Inventory. Sara Section 313: This product contains Polycyclic Aromatic Compounds (PAC s) listed under SARA Section 313 Chemicals: Regulatory Lists Searched This product contains a mixture of one or more components found on the following State List at or above OSHA de minimus quantities: Health & Safety: NA Environmental: NA International: NA State: FL, MA, MN, PA, RI National Inventories: NA SARA 311 / 312 Categories (For the chemicals above) Acute: Yes Chronic: Yes Fire: No Pressure: No Reactive: No Regulated: No Page 6 of 6
California Proposition 65 Information: Warning! This product contains substances known to the state of California to cause cancer. Canadian WHMIS Classification Class: Controlled Class D2A Very Toxic Material based on IARC classification of Oxidized Bitumen as a Group 2A Probably Carcinogen. WARNING May cause eye, skin and respiratory irritation Precautions: Avoid skin or eye contact. Wear protective clothing and/or equipment during handling. Use with adequate ventilation. Contains: Petroleum Asphalt (CAS No 8052 42 4), Hydrotreated Heavy Naphthenic Distillate (CAS No 64742 52 5), Plant Extract (CAS No 8016 81 7), Calcium Carbonate (CAS No 1317 65 3) First Aid: For skin or eye contact flush with running water for at least 15 minutes while removing clothing. If ingested, do not induce vomiting. If inhaled, remove victim to fresh air. If breathing stopped, begin artificial respiration. Call physician. AVERTISSEMENT! Peut causer une irritation des yeux, la peau et des voies respiratoires. Précautions: Eviter la peau ou les yeux. Porter des vêtements protecteurs et/ou équipment de sécurité pendant la manipulation. Utiliser avec une ventilation adéquate. Contient: Bitume de pétrole (no CAS 8052 42 4), hydrotraités distillat naphténique lourd (no CAS 64742 52 5), extrait de plante (no CAS 8016 81 7), calcium carbonate (no CAS 1317 65 3) Premiers soins: En cas de contact peau ou les yeux, rincer à l'eau courant pendant au moins 15 minutes tout en retirant les vêtements. En cas d'ingestion, ne pas faire vomir. En cas d'inhalation, transporter la victime à l'air frais. Si la respiration s'arrête, pratiquer la respiration artificielle. Appeler un médecin. KEEP OUT OF REACH OF CHILDREN CONSERVER HORS DE LA PORTÉE DES ENFANTS SEE MATERIAL SAFETY DATA SHEET FOR THIS VOIR FICHE SIGNALETIQUE POUR CE PRODUIT Carlisle Coatings and Waterproofing Incorporated 900 Hensley Lane Wylie, TX 75098 972 442 6545 www.carlisle ccw.com Division: 4 Page 7 of 6
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations (CPR). This MSDS contains all the information required by the CPR. European Union Classification Hazard Symbol: Toxic Risk Phrases: R45 Safety Phrases: S38, S45, S53 Other Regulations: No other information available. 16. OTHER INFORMATION Health and Environmental Label Language All ingredients contained in this product are included on the US EPA Toxic Substances Control Act (TSCA) inventory or exempt from listing on the TSCA inventory. All ingredients contained in this product comply with the requirements of the Canadian Environmental Protection Act (CEPA) and are listed on the Domestic Substance List (DSL) or Non-Domestic Substance List (NDSL). MSDS Revisions Previous Version Date:03/01/11 Section Old Information: New Information: IARC information, WHMIS information Prepared By: Research & Development Date: 03/31/12 Disclaimer of Warranty: The information contained herein is based upon data and information available to us, and reflects our best professional judgement. This product may be formulated in part with components purchased from other companies. In many instances, especially when proprietary or trade secret materials are used, Carlisle Coating and Waterproofing Inc. rely upon the hazard evaluation of such components submitted by that product s manufacturer or importer. No warranty of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of such data or information. The results to be obtained from the use thereof, or that any such use does not infringe any patent, since the information contained herein may be applied under conditions of use beyond our control and with which we may be unfamiliar, we do not assume responsibility for the results of such application. This information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the material for his particular use. Page 8 of 6