Material Safety Data Sheet MSDS Number: 1088061 Revision date: 07/18/2012 Print date: 07/18/2012 MSDS Number: 1088061 Product name: Citric Acid Solution Product Codes: CDY3720 Synonyms: Chemical Family: Acid Product Type: Renal Container Information: Plastic, HDPE 4 L Product Use: Cleaning agent for machinery and equipment. Supplier BAXTER HEALTHCARE CORPORATION DEERFIELD, ILLINOIS 60015 (800) 422-9837 or (224) 948-4770 Emergency telephone number 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PROSAR: USA (888) 990-0996 OUTSIDE USA (651)917-6114 CHEMTREC: USA (800) 424-9300 OUTSIDE USA (743)741-6089 2. COMPOSITION/INFORMATION ON INGREDIENTS Weight % UN Number: Classification: 80 20 Xi; R38, R41 3. HAZARDS IDENTIFICATION Emergency overview: Principle routes of exposure: Inhalation: Ingestion: Skin contact: Eye contact: DANGER! CAUSES EYE, SKIN, AND DIGESTIVE TRACT BURNS. Avoid skin contact. Avoid eye contact. Do not ingest. Wash thoroughly after handling. Skin. Eye contact. Ingestion. Inhalation not likely under normal use conditions. May cause burns to the mouth, throat, and stomach. Gastrointestinal effects (may include nausea/vomiting, abdominal pain, diarrhea, dry mouth, colic). Can cause skin irritation. Can cause eye irritation. 4. FIRST AID MEASURES Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention.
Ingestion: Eye contact: Notes to physician: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Treat symptomatically and supportively. 5. FIRE FIGHTING MEASURES Suitable extinguishing media: Special protective equipment for firefighters: Specific methods: Flash point: Autoignition temperature: Flammable limits in air-lower (%): Flammable limits in air-upper (%): Use foam or all purpose dry chemicals to extinguish. Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. No information available. Not determined 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Methods for cleaning up: Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Follow all fire fighting procedures (Section 5). No information available. If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid-proof container for disposal. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. 7. HANDLING AND STORAGE Handling: Technical measures/precautions: Do not ingest. Avoid skin contact. Avoid eye contact. Wash thoroughly after handling. Storage: Technical measures/conditions: Keep containers tightly closed in a cool, well-ventilated place. Incompatible products: Acrolein. Benzyl alcohol. Lithium aluminum hydride. Sodium ozonate. Nickel nitride. Thorium phosphate. Tris-iso-butyl aluminium-nfpa 491M. Occupational Exposure Limits 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA- Time Weighted Average: OSHA- Short Term Exposure Limit: OSHA- Ceiling Limits ACGIH- Time Weighted Average: ACGIH- Short Term Exposure Limit: ACGIH- Ceiling Limit Value:
Engineering measures: Provide general or local exhaust ventilation. Personal protective equipment: Respiratory protection: Hand protection: Skin and body protection: Eye protection: No personal respiratory protective equipment normally required. Use chemical resistant, impervious gloves. Disposable outer garments, or impervious garments of equal or greater protection. Safety glasses with side-shields. Goggles, face shield, or other full-face protection if potential exists for direct exposure to aerosols or splashes. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Appearance: Aqueous solution Color: Clear Odor: Odorless ph: 1.13 Molecular weight: Not applicable. Boiling point/range: Melting point/range: Density: Vapor pressure: Evaporation rate: Solubility: Soluble in water. Partition coefficient (n-octanol/water): Viscosity: % Volatile by Volume: 10. STABILITY AND REACTIVITY Stability: Polymerization: Hazardous decomposition products: Materials to avoid: Stable under recommended storage conditions. Not applicable Oxidizing agents. Organic materials.
11. TOXICOLOGICAL INFORMATION LD50 Dermal LC50 Inhalation LD50 Oral - - - - - 3000 mg/kg (rat) Acute toxicity: Chronic toxicity: Carcinogenic effects: Mutagenic effects: Reproductive toxicity: FDA Pregnancy Catagory May cause burns to eyes, skin, and digestive tract. Gastrointestinal effects (may include nausea/vomiting, abdominal pain, diarrhea, dry mouth, colic). Repeated exposure may cause erosion of teeth. Target Organs: skin and eyes. Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. No data is available on the product itself. No data is available on the product itself. Not considered teratogenic based on animal data. 12. ECOLOGICAL INFORMATION Environmental properties: Ecotoxicity effects: Bioaccumulation: Ecotoxicity - Water Flea Data. 120 mg/l EC50 72 h 1516 mg/l LC50. Lepomis macrochirus 96 h No data available No data available Fish Species Ecotoxicity Ecotoxicity - Freshwater Algae Data... Ecotoxicity - Microtox Data = 14 mg/l EC50 Photobacterium phosphoreum 13. DISPOSAL CONSIDERATIONS Waste Classification: Waste from residues / unused products: RCRA Hazardous Waste, Corrosivity Characteristic, D002 Waste disposal must be in accordance with appropriate Federal, State, and local regulations. 14. TRANSPORT INFORMATION DOT: DOT shipping name: UN Number: 1760 DOT Packing Group: DOT Hazard class: 8 TDG (Canada): TDG Proper shipping name: TDG UN/NA Number: 1760 TDG Packing Group:
TDG Hazard class: ADR/RID: ADR Official Transport Name: ADR Proper shipping name: ADR UN/NA number: ADR Hazard Class: 8 1760 8 ICAO / IATA: IATA Proper shipping name: IATA UN Number: 1760 IATA Primary Hazard: 8 IATA Packing group: ICAO ERG Code: IMO / IMDG: IMDG Proper Shipping Name: IMDG Hazard Class and Division: IMDG Packing Group: IMDG Subsidiary Risks: 15. REGULATORY INFORMATION U.S. Regulations: TSCA Inventory List - OTHER REGULATIONS: Japanese Inventory (ENCS) This product complies with TSCA This product does not comply with JPENCS Weight % RCRA Status: CERCLA Reportable Quantity: STATE REGULATIONS: CERCLA/SARA - 302 Ext. haz. substances: Listed as Sara 313 title : 80 Not Listed Not Listed Not Listed Not Listed 20 Not Listed Not Listed Not Listed Not Listed California Prop. 65 Minnesota Right-To -Know: Florida Right-to-Know Reporting List: Rhode Island Right-to-Know List: Massachusetts Right-to-Know List: Pennsylvania Right-to-Know: New Jersey Right-to-Know: Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed CANADIAN REGULATIONS: Canada DSL Inventory List - This product does not comply with DSL WHMIS hazard class: E corrosive material EU EINECS List - This product does not comply with EINECS Risk Phrases: NONE
Safety Phrases: NONE This data sheet contains changes from the previous version in section(s)?: New MSDS format. Changes to Section 1. Additional information: Not Available. 16. OTHER INFORMATION Prepared by: Technology Resources, Baxter Healthcare Corporation To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. End of safety data sheet: